CN102093793A - Medium-high polyvinyl chloride (PVC) emulsion paint - Google Patents

Medium-high polyvinyl chloride (PVC) emulsion paint Download PDF

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Publication number
CN102093793A
CN102093793A CN 201010621326 CN201010621326A CN102093793A CN 102093793 A CN102093793 A CN 102093793A CN 201010621326 CN201010621326 CN 201010621326 CN 201010621326 A CN201010621326 A CN 201010621326A CN 102093793 A CN102093793 A CN 102093793A
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agent
emulsion paint
emulsion
nano
powder
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CN 201010621326
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Chinese (zh)
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王奇
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Individual
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Abstract

The invention discloses medium-high polyvinyl chloride (PVC) emulsion paint which is prepared from the following raw materials in parts by weight: 9-30 of film forming substance, 30-60 of pigment and filler, 0.1-0.5 of defoaming agent, 0.2-1 of thickening and leveling agent, 0.1-1 of dispersing agent, 0-5 of nano powder, 20-45 of de-ionized water and 0-5 of other auxiliaries. The medium-high PVC emulsion paint has the advantages of good wiping and wet resistance and low cost, and is safe and environment-friendly.

Description

High PVC emulsion paint in a kind of
Technical field
The present invention relates to technical field of coatings, specifically is a kind of middle high PVC emulsion paint.
Background technology
China's coating industry was through the sound development in more than 30 years, and industry competition is standard day by day, and the safety and environmental protection performance of product also improves greatly.The human consumer needn't be again before more than ten years, and one mentions coating, just associate the solvent based coating sharp aroma in when construction, think not environmental protection of coating.
Present coating products cannot be mentioned in the same breath already, the output of water-borne coatings has accounted for more than 30% of coating ultimate production, all be to use water as thinner, product the construction and use in because of not with an organic solvent, the VOC quantity discharged significantly reduces, perhaps detect not come out, several g/L are perhaps only arranged, far below the emulsion paint limit standard of 120g/L in the new national standard and the wood lacquer limit standard more than the 300g/L.So, the general character healthy, that environmental protection has become brand coating.Along with holding as scheduled of Shanghai World's Fair, the low-carbon (LC) notion day by day becomes common people's topic that what's frequently heard can be repeated in detail.In World Expo, many museums have all released the low-carbon (LC) theory, and some low-carbon (LC) lacquer products are that World Expo has increased the beautiful scenery line.Except the low-carbon (LC) notion, the green of coating products also shows clean flavor, aldehydes removal, low VOC, anti-radon, no benzene, low toxicity, do not contain free TDI, do not contain all many-sides such as heavy metal.Clean flavor emulsion paint on the market is middle low PVC mostly now, its cost height, and the market price height is difficult to popularization and application in the ordinary people.On its performance, particularly moisture-proof smears more far short of what is expectedly than traditional emulsion paint, particularly after having constructed, is difficult to allow the user accept with the easy shedding of wet towel wiping.
Summary of the invention
The technical problem to be solved in the present invention provides a kind of middle high PVC emulsion paint, and the existing anti-wiping of emulsion paint of solution is moist poor, the problem that cost is high.
Technical scheme of the present invention is:
High PVC emulsion paint in a kind of, it is that feedstock production by following weight part ratio forms: filmogen: 9-30, color stuffing: 30-60, defoamer: 0.1-0.5, thickening leveling agent: 0.2-1, dispersion agent: 0.1-1, nano-powder: 0-5, deionized water: 20-45, other auxiliary agents: 0-5.
Described a kind of in the high PVC emulsion paint, it is that feedstock production by following weight part ratio forms: filmogen: 9-25, color stuffing: 40-55, defoamer: 0.2-0.5, thickening leveling agent: 0.5-1, dispersion agent: 0.3-0.9, nano-powder: 2-5, deionized water: 25-40, other auxiliary agents: 2-4.
Described filmogen is selected ACRYLIC EMULSION, benzene emulsion, pure-acrylic emulsion or VAE emulsion for use; Described nano-powder is selected TiO for use 2, SiO 2And Al 2O 3The mixing of one or more in the nano-powder.
Described color stuffing is selected lime carbonate or titanium dioxide for use; Described defoamer is selected silicone emulsion for use; The agent of nonionic polyurethane class thickening leveling is selected in described thickening leveling agent for use; Described dispersion agent is selected polycarboxylate sodium's dispersion agent for use.
Described other auxiliary agents are one or more the mixing in film coalescence aid, Antisepticize and mildew preventive, the softening agent.
Described film coalescence aid is selected alcohol ester 12 for use; Described Antisepticize and mildew preventive is selected copper 8-quinolinolate for use; Described softening agent is selected diethyl phthalate for use.
Film coalescence aid of the present invention is selected alcohol ester 12 for use, is high boiling point environmental protection auxiliary agent; The agent of nonionic polyurethane class thickening leveling is solvent-free auxiliary agent, and is biodegradable; The silicone emulsion defoamer has the water and milk voltinism; Dispersion agent is selected polycarboxylate sodium's dispersion agent for use, is solvent-free low smell sodium salt dispersion agent.Because the adding of nano-powder makes the high PVC emulsion paint that makes have the moist and water tolerance of good anti-wiping.
Advantage of the present invention: a, the wet white problem of taking off can not appear wiping; B, environment-friendly tasteless; C, cost are low; D, alkaline-resisting, scrubbing resistance.
Every performance of the present invention and environmental protection index meet every requirement of GB/T9756-2009 and HJ/T201-2005, and solve middle high PVC lacquer wet rubbing and taken off white problem, the clean flavor lacquer in low field in belonging to, price is low, is suitable for promoting.
Embodiment
Embodiment 1
(1), the high PVC emulsion paint, it is that feedstock production by following weight part ratio forms: ACRYLIC EMULSION: 95 parts, rutile type: 480 parts, silicone emulsion defoamer: 3 parts, the agent of nonionic polyurethane class thickening leveling: 8 parts, polycarboxylate sodium's dispersion agent: 6.5 parts, nano-powder (TiO 2And Al 2O 3Nano-powder): 50 parts, deionized water: 12: 27.5 parts of 330 parts, alcohol ester.
(2), preparation method: under the whipped state of decollator, add ACRYLIC EMULSION, silicone emulsion defoamer and polycarboxylate sodium's dispersion agent by weight successively, low speed disperseed 5 minutes, slowly add nano-powder again, middling speed was disperseed 20-30 minute, low speed froth breaking 5-10 minute adds alcohol ester 12, the thickening leveling agent of nonionic polyurethane class and deionized water more successively, and middling speed stirred 5-15 minute, by weight than dropping into rutile type mixing stirring, filter discharging at last.
Embodiment 2
(1), middle PVC emulsion paint, it is that feedstock production by following weight part ratio forms: VAE emulsion: 250 parts, rutile type: 400 parts, silicone emulsion defoamer: 4 parts, the agent of nonionic polyurethane class thickening leveling: 10 parts, polycarboxylate sodium's dispersion agent: 6 parts, nano-powder (TiO 2, SiO 2And Al 2O 3Nano-powder): 50 parts, deionized water: 242 parts, 12: 20 parts of alcohol esters, copper 8-quinolinolate: 8 parts, diethyl phthalate: 10 parts.
(2), preparation method: under the whipped state of decollator, add VAE emulsion, silicone emulsion defoamer and polycarboxylate sodium's dispersion agent by weight successively, low speed disperseed 5 minutes, slowly add nano-powder again, middling speed was disperseed 20-30 minute, low speed froth breaking 5-10 minute, add alcohol ester 12, copper 8-quinolinolate, diethyl phthalate, the thickening leveling agent of nonionic polyurethane class and deionized water more successively, middling speed stirred 5-15 minute, by weight than dropping into talcum powder mixing stirring, filter discharging at last.

Claims (6)

1. high PVC emulsion paint in a kind is characterized in that: it is that feedstock production by following weight part ratio forms: filmogen: 9-30, color stuffing: 30-60, defoamer: 0.1-0.5, thickening leveling agent: 0.2-1, dispersion agent: 0.1-1, nano-powder: 0-5, deionized water: 20-45, other auxiliary agents: 0-5.
2. according to claim 1 a kind of in the high PVC emulsion paint, it is characterized in that: it is that feedstock production by following weight part ratio forms: filmogen: 9-25, color stuffing: 40-55, defoamer: 0.2-0.5, thickening leveling agent: 0.5-1, dispersion agent: 0.3-0.9, nano-powder: 2-5, deionized water: 25-40, other auxiliary agents 2-4.
3. a kind of middle high PVC emulsion paint according to claim 1, it is characterized in that: described filmogen is selected ACRYLIC EMULSION, benzene emulsion, pure-acrylic emulsion or VAE emulsion for use; Described nano-powder is selected TiO for use 2, SiO 2And Al 2O 3The mixing of one or more in the nano-powder.
4. a kind of middle high PVC emulsion paint according to claim 3, it is characterized in that: described color stuffing is selected lime carbonate or titanium dioxide for use; Described defoamer is selected silicone emulsion for use; The agent of nonionic polyurethane class thickening leveling is selected in described thickening leveling agent for use; Described dispersion agent is selected polycarboxylate sodium's dispersion agent for use.
5. according to claim 4 a kind of in the high PVC emulsion paint, it is characterized in that: described other auxiliary agents are one or more the mixing in film coalescence aid, Antisepticize and mildew preventive, the softening agent.
6. a kind of middle high PVC emulsion paint according to claim 5, it is characterized in that: described film coalescence aid is selected alcohol ester 12 for use; Described Antisepticize and mildew preventive is selected copper 8-quinolinolate for use; Described softening agent is selected diethyl phthalate for use.
CN 201010621326 2010-12-31 2010-12-31 Medium-high polyvinyl chloride (PVC) emulsion paint Pending CN102093793A (en)

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CN 201010621326 CN102093793A (en) 2010-12-31 2010-12-31 Medium-high polyvinyl chloride (PVC) emulsion paint

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104031506A (en) * 2014-05-22 2014-09-10 滁州市宁扬胶业有限公司 Hard-film emulsion paint
CN104098990A (en) * 2013-04-09 2014-10-15 中南大学 Preparation method for poly(8-hydroxyquinoline) composite anticorrosive coating on metal surface
CN105017899A (en) * 2014-10-30 2015-11-04 合肥蓝天家具制造有限责任公司 Environment-friendly transparent furniture primer
CN105238184A (en) * 2015-11-02 2016-01-13 阜阳市金木工艺品有限公司 Scrub-resistant wood coating and preparation method therefor
CN106065228A (en) * 2016-07-28 2016-11-02 苏州合志电子有限公司 A kind of preparation method of high PVC interiro wall latex paint
CN107573800A (en) * 2017-08-01 2018-01-12 成都博美实润科技有限公司 A kind of water-proof emulsion paint and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1462779A (en) * 2003-05-29 2003-12-24 重庆大学 Water soluble antibacterial nano coating material for inner wall and its manufacturing technique
CN1900187A (en) * 2006-07-06 2007-01-24 北京中化科城技术研究所 Environment friendly emulsion paint
CN101104765A (en) * 2007-08-20 2008-01-16 维新环保涂料(深圳)有限公司 Water-based acrylic acid top-coat
CN101343433A (en) * 2008-08-12 2009-01-14 无锡市虎皇漆业有限公司 Elastic smell-clearing full-effective latex paint and preparation thereof
CN101412892A (en) * 2007-10-19 2009-04-22 芜湖力特尔涂料制造有限公司 Composite self-cleaning exterior wall nano-emulsion paint and preparation thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1462779A (en) * 2003-05-29 2003-12-24 重庆大学 Water soluble antibacterial nano coating material for inner wall and its manufacturing technique
CN1900187A (en) * 2006-07-06 2007-01-24 北京中化科城技术研究所 Environment friendly emulsion paint
CN101104765A (en) * 2007-08-20 2008-01-16 维新环保涂料(深圳)有限公司 Water-based acrylic acid top-coat
CN101412892A (en) * 2007-10-19 2009-04-22 芜湖力特尔涂料制造有限公司 Composite self-cleaning exterior wall nano-emulsion paint and preparation thereof
CN101343433A (en) * 2008-08-12 2009-01-14 无锡市虎皇漆业有限公司 Elastic smell-clearing full-effective latex paint and preparation thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104098990A (en) * 2013-04-09 2014-10-15 中南大学 Preparation method for poly(8-hydroxyquinoline) composite anticorrosive coating on metal surface
CN104098990B (en) * 2013-04-09 2017-07-14 中南大学 A kind of preparation method of the poly- 8 oxyquinoline composite anti-corrosive coating in metal surface
CN104031506A (en) * 2014-05-22 2014-09-10 滁州市宁扬胶业有限公司 Hard-film emulsion paint
CN105017899A (en) * 2014-10-30 2015-11-04 合肥蓝天家具制造有限责任公司 Environment-friendly transparent furniture primer
CN105238184A (en) * 2015-11-02 2016-01-13 阜阳市金木工艺品有限公司 Scrub-resistant wood coating and preparation method therefor
CN106065228A (en) * 2016-07-28 2016-11-02 苏州合志电子有限公司 A kind of preparation method of high PVC interiro wall latex paint
CN107573800A (en) * 2017-08-01 2018-01-12 成都博美实润科技有限公司 A kind of water-proof emulsion paint and preparation method thereof

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Application publication date: 20110615