CN102086597B - Printed label tape and manufacturing method thereof - Google Patents
Printed label tape and manufacturing method thereof Download PDFInfo
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- CN102086597B CN102086597B CN201010541839A CN201010541839A CN102086597B CN 102086597 B CN102086597 B CN 102086597B CN 201010541839 A CN201010541839 A CN 201010541839A CN 201010541839 A CN201010541839 A CN 201010541839A CN 102086597 B CN102086597 B CN 102086597B
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Abstract
The invention relates to a printed label tape and a manufacturing method thereof, belonging to the technical field of printed label manufacturing. The printed label tape comprises a grey fabric layer and an adhesive layer, and the thickness of the printed label tape is 120-150 mu m, wherein the thickness of the grey fabric layer is 120-130 mu m; the pH value of the printed label tape is 7.5-9.0; and the content of the residual chloride ions is less than or equal to 1.51%. The manufacturing method of the printed label tape comprises a coating treatment step and an aftertreatment step, wherein in the coating treatment step, the grey fabric is glued in a dipping manner; and the gluing formula comprises 20-30wt% of accelerant which contains chlorides, and the chloride content does not exceed 50wt% of the accelerant. The printed label tape provided by the invention can not react with textile products, can not discolor the textile products, and has the advantage of low production cost as compared with the label tapes produced by other methods.
Description
Technical field
The present invention relates to a kind of printing trader's marker tape and preparation method thereof, belong to printing trade mark manufacturing technology field.
Background technology
Trademark belt can be divided into woven trademark belt, printing trader's marker tape and embroidery trademark belt by its manufacturing approach.The embroidery trade mark is the high trade mark ornament of a kind of class, is used for designer clothing mostly, high-grade clothing, and the product of some specific uses, and the scope of application is less at present.Woven trademark belt is claimed the silk weaving trademark belt again; Be that the form with multi-shuttle box, many reed widths, many specifications is woven on jacquard weaving machine; Be most widely used a kind of commodity sign in the trade marks such as present clothes, shoes and hats, towel quilt, it can weave various pictorial trademarks and literal.The raw material that woven trademark belt adopts is generally natural fiber yarn or chemical fibres such as low elastic polyester filament, metallized thread such as the textile high grade yarn, fine denier polyester twisted yarn, assorted look artificial silk of bleaching or dyeing.The raw material gloss of warp thread will be got well, and weft yarn dyeing is gorgeous, and it is high that COLOR FASTNESS is wanted, and color matching is generally 2～3 looks; The computer jacquard loom of introducing, color matching can reach 8 kinds, and the appearance that each trade mark provides according to the user all will be carried out independently grain pattern design, makes card; Last machine test weaving sample puts into production through user's audit, check and correction, affirmation rear, and pattern and the literal knitted are clear; Color matching will be coordinated, and zone face is smooth, and the difference with former state in kind is little.This mode of production production efficiency is low and production cost is high.
The printing trade mark is the trade mark on the base band, printed, independently is cut into single trade mark use then.Height is renderd a service in production than traditional jacquard weave silk weaving, and cost is low.The staple leukorrhea that printing trader's target base band can adopt inkle loom to produce, general bandwidth 1～4cm also can use white rayon satin plain's cloth, the cotton blended cloth of bleaching silk ribbon, plain color nylon cloth etc.; Be cut into the wide made-up belt of 1～5cm, with photomechanical production, chromaticity printing technique is processed finished product; Be generally 2～3 chromatographys, various dyestuff seal slurries will suit on fabric, to print, and the trademark belt after the printing is wanted the appropriateness oven dry or spread out and dry; In order to avoid rub look, staining influences printing quality and effect.Printing trader's target production technology comprise dye, network, whole, inspection, bag, grain pattern making etc., whole flow process is indispensable, it requires, and pattern is accurate, writing is clear, bright in colour, band edge does not loose and takes off, smooth well-pressed, so very high to the requirement of technology.Although printing trader's target production efficiency is high; By most manufacturer is accepted; But it is very strict to specification requirement, production technology words not really up to the mark be easy to regard to the fabric that trade mark occurs and fade, make this trade mark of utilization catch variegated, make the fabric fading of this trade mark of utilization and the trade mark content of formaldehyde is too high, pH value is too high, contain multiple technologies problem such as harmful material.Wherein serious problem is, when existing printing trade mark is applied to dark textile product, is prone to and the dark dye reaction, causes the textile product dark colour to shoal.
Summary of the invention
The objective of the invention is to make and a kind of printing trader's marker tape is provided the technical problem that the color of dark textile product shoals for solving above-mentioned printing trade mark.
Above-mentioned technical purpose of the present invention is achieved through following technical scheme:
A kind of printing trader's marker tape, it comprises grey cloth layer and glue-line, and its thickness is 120～150 μ m, and wherein the grey cloth layer thickness is 120～130 μ m; Its pH value 7.5～9.0, residual chlorine ion concentration≤1.51%.
The residual chlorine ion concentration of present printing trader's marker tape on the market is usually more than 2%.The inventor learns through experiment and detection, works as Cl
-During content≤1.51 wt%, this shortcoming that said printing trader's marker tape makes the deep-colour fabric color shoal can be ignored.
Above-mentioned printing trader's marker tape; Glue-line is that the mode through dip-coating forms on grey cloth, and the trade mark of therefore processing permeates in the grey cloth layer glue is arranged, and therefore can think that the grey cloth layer condenses in glue-line inside; The thickness of glue-line can be thought the thickness of trade mark, and this thickness is only slightly thick than grey cloth thickness.
Preferred as technique scheme, its grey cloth is processed through the plain weave mode, and the red Buddhist nun's number of yarn of processing this grey cloth is 30～75D, and warp count is 80～120, and weft count is 40～60.
Yam count is represented the title of fiber, fineness of yarn, is called for short public, and the N of unit is the heavy length that fiber yarn had of 1g, the numerical value of representing with rice.S is the abbreviation that English props up, and the fineness that is used for Quality Pure Cotton Yarn Production is expressed, and refers to the number of 840 code lengths that cotton yarn had of pounder, promptly has several 840 yards, is exactly several, so S is big more, yarn is thin more.And indicate with red Buddhist nun's number usually for artificial fibres such as polyamide fibre terylene, the conversion relation of red Buddhist nun's number and number is following.
| The red Buddhist nun's number (D) of DENIER | Public (N) | English props up (S) |
| 10 | 900 | 531.5 |
| 20 | 450 | 265.7 |
| 26.6 | 338.7 | 200 |
| 30 | 300 | 177.2 |
| 36 | 250 | 147.6 |
| 40 | 225 | 132.9 |
| 44.3 | 203.2 | 120 |
| 45 | 200 | 118.1 |
| 50 | 180 | 106.3 |
| 53.1 | 169.3 | 100 |
| 55 | 163.6 | 96.6 |
| 60 | 150 | 88.6 |
| 66.4 | 135.5 | 80 |
| 75 | 120 | 70.9 |
| 88.6 | 101.6 | 60 |
The yarn of grey cloth length direction is called warp thread, and the arrangement radical of yarn is a warp count in its 1 inch.The yarn of grey cloth width is called weft yarn, and the arrangement radical of yarn is a weft count in its 1 inch.
Another object of the present invention provides the preparation method of above-mentioned printing trader's marker tape.
A kind of preparation method of printing trader's marker tape comprises coating processing and post processing, and coating is treated to through the mode of dip-coating carries out gluing to grey cloth, and institute's gluing prescription is following,
Synthetic fiber 10～15wt%
Accelerant 20～30wt%
Organic solvent 55～70wt% contains villaumite in the wherein said accelerant, and chloride content is no more than accelerant 50wt%;
Post processing comprises that the washing temperature is 20～30 ℃, washing time 5～10min with handling the coated fabric washing in the dechlorination ionized water that obtains through coating; And said dechlorination ionized water is kept in motion with respect to said coated fabric, and relative speed is 10～15m/min.
In the technique scheme; Synthetic fiber are dissolved in organic solvent form liquid with certain viscosity; What cooperate accelerant then shortly dyes effect, should fill a prescription dip-coating on grey cloth, when later process is caught the required icon of client; Can be with the firmly set of dying color, the situation that not occurring fades fades.
Synthetic fiber strand two ends such as polyamide fibre are contained amino and carboxyl simultaneously, promptly have isoelectric point.When the PH of dye liquor value when isoelectric point is above, the amino degree of ionization of fiber ends is little, and the carboxyl degree of ionization is than higher.Therefore, fiber band negative electrical charge.Calcium chloride belongs to strong electrolyte, in water, can be ionized into chlorion and calcium ion fully, and calcium ion has when higher concentration very that fraction is hydrolyzed into calcium hydroxide and hydrochloric acid, so the aqueous solution is acid.Therefore the dye liquor pH value descends after adding calcium chloride, and when pH value drops to isoelectric point when following, fiber ends carboxyl degree of ionization is little; And amino degree of ionization is than higher; Make the anionic dyestuff approaching with fiber more easily,, thereby play the effect of dying of urging by fiber absorption.Have the scholar to point out, the coordination of hydratable calcium ion ability forms chela platform thing at the hydroxyl place; Removed part hydrogen bond and Van der Waals force between the molecule in the coordination process, thereby made the fiber swelling, structure is loose; Help dyestuff and spread to fibrous inside, simultaneously, the dyestuff accessibility increases; Absorption position and reactive group in the fiber fully expose, these all help REACTIVE DYES on dye and set, be the significantly short major reason of dying effect of its performance.
Usually the villaumite addition is 20～30 wt%, urgees this moment to dye or printing effect the best, and the problem of processing then is like this, makes the residual chlorine ion concentration of final printing trader's marker tape be higher than 2%, and macro manifestations is for can make the textile product color slowly shoal.Then be unfavorable for short dying but directly chloride content is reduced, so the inventor replaced half at least villaumite with other accelerant, such result is that the content of the chlorion in the product is controlled at≤1.51 wt% the most at last.Below be the example explanation that makes an explanation with calcium chloride and calcium carbonate: the inventor looks for through experiment that calcium chloride the best in the present technique scheme is short dyes a little, and the amount of calcium chloride and the color relation of peeling off.Experiment confirm, short the dying of the best of calcium chloride a little is 25～26 wt%; And when the amount of calcium chloride during at 10～20 wt%, the heat release during the calcium chloride dissolving enough helps refuse yarn to be dissolved in the organic solvent, dyes angle and sees from short, and the cloth cover light that can become influence printing effect, but influence degree and not quite.Therefore, the inventor adjusts prescription, and calcium chloride is adjusted into 10～15 wt%, and replenishes the calcium carbonate of 10～15 wt%, to reach equivalence or the approaching short effect of dying.
In post processing, coated fabric is spent the washing of chlorion water, utilize calcium chloride soluble in water and with the Cl in the product
-Absorb and remove a part again, can be with Cl in the product
-Content be controlled at more low-level.Therefore, through the content of reduction calcium chloride with through spending the washing of chlorion water, reach Cl
-Content<1.51 wt%.Because be to remove, so the relative velocity of the contact time of temperature, coated fabric and the dechlorination ionized water of control dechlorination ionized water and dechlorination ionized water and coated fabric is all closely related through dissolving.
Preferred as technique scheme, said synthetic fiber are polyamide fibre.
In the technique scheme, " polyamide fibre " is to occur as this notion of raw material that is main component with the polyamide fibre, and it can be to be any type of object of main component with the polyamide fibre; Be the normally refuse yarn of this raw material that saves production cost in the practical operation, it is to produce or weaving the leftover bits and pieces that is produced in the polyamide fibre product.And use this refuse yarn at first should comprise the removal step of choosing yarn, then refuse yarn is dissolved.
Preferred as technique scheme, said accelerant is selected from one or more in calcium chloride, magnesium chloride, calcium sulfate, magnesium sulfate, the calcium carbonate.
Preferred as technique scheme, said organic solvent is selected from one or more in toluene, ethyl acetate, butyl acrylate, the methyl alcohol.
Preferred as technique scheme, said dechlorination ionized water adopts ion-exchange unit to make, and the operation that in the washing process, all the time said dechlorination ionized water is removed chlorion.
Preferred as technique scheme, said post processing also comprises replaces alkaline-earth metal ions through ion-exchange unit with sodium ion to post processing water, and the operation that said alkaline-earth metal ions is removed.
Adopt the high activity of sodium ion in the ion-exchange unit to remove to replace the foreign ion in the water, make it to form big molecule, stop macromolecular backflow via ion-exchange unit, make water quality comparatively pure, solubility is able to promote.
Preferred as technique scheme, when coating was handled, glue-spread was controlled to be 20～40 g/m
2
Further preferred as technique scheme, when coating was handled, glue-spread was controlled to be 25～30 g/m
2
In sum, the present invention has following beneficial effect:
1, a kind of printing trader's marker tape of the present invention does not have and the textile product reaction, can not make the characteristics of textile product variable color;
2, the present invention has the low advantage of production cost with respect to the trademark belt of additive method production.
Description of drawings
Fig. 1 is the side structure sketch map of a kind of printing trader's marker tape of the present invention;
Fig. 2 is a process chart of the present invention.
The specific embodiment
Following specific embodiment only is to explanation of the present invention; It is not a limitation of the present invention; Those skilled in the art can make the modification that does not have creative contribution to present embodiment as required after reading this specification, but as long as in claim scope of the present invention, all receive the protection of Patent Law.
Embodiment one
A kind of printing trader's marker tape, it comprises grey cloth layer 1 and glue-line 2, and its thickness is 125 μ m, and the grey cloth layer thickness is 120 μ m; Its residual chlorine ion concentration≤1.28%.
The preparation method of above-mentioned printing trader's marker tape, specific as follows:
1. choose the polyamide fibre refuse yarn, then non-polyamide fibre composition is wherein chosen, mixed chlorinated then magnesium, magnesium sulfate are dissolved in the toluene, process glue, are used for grey cloth is carried out dip-coating, and the concrete composition proportion of this glue is following,
Polyamide fibre 10wt%
Magnesium sulfate 10wt%
Magnesium chloride 10wt%
Toluene 70wt%
2. after the nylon grey cloth clean, be dipped in the above-mentioned glue grey cloth is carried out gluing, glue-spread is controlled to be 25g/m
2
3. will pass through gluing and handle the coated fabric washing in the dechlorination ionized water that obtains, the washing temperature is 20～30 ℃, washing time 5～10min; The movement rate of the relative tank of coated fabric is 10～15 m/min; Said dechlorination ionized water adopts ion-exchange unit to make, and the operation that in the washing process, all the time said dechlorination ionized water is removed chlorion; The operation of in addition, said dechlorination ionized water also being removed calcium ions and magnesium ions;
4. cut promptly after the coated fabric that then 3. step is made is dried and get.
Embodiment two
A kind of printing trader's marker tape, it comprises grey cloth layer 1 and glue-line 2, and its thickness is 130 μ m, and the grey cloth layer thickness is 125 μ m; Its residual chlorine ion concentration≤1.34%.
The preparation method of above-mentioned printing trader's marker tape, specific as follows:
1. choose the polyamide fibre refuse yarn, then non-polyamide fibre composition is wherein chosen, mixed chlorinated then calcium, calcium sulfate are dissolved in the butyl acrylate, process glue, are used for grey cloth is carried out dip-coating, and the concrete composition proportion of this glue is following,
Polyamide fibre 12wt%
Calcium sulfate 12wt%
Calcium chloride 12wt%
Butyl acrylate 64wt%
2. after the nylon grey cloth clean, be dipped in the above-mentioned glue grey cloth is carried out gluing, glue-spread is controlled to be 28g/m
2
3. will pass through gluing and handle the coated fabric washing in the dechlorination ionized water that obtains, the washing temperature is 20～30 ℃, washing time 5～10min; The movement rate of the relative tank of coated fabric is 10～15 m/min; Said dechlorination ionized water adopts ion-exchange unit to make, and the operation that in the washing process, all the time said dechlorination ionized water is removed chlorion; The operation of in addition, said dechlorination ionized water also being removed calcium ions and magnesium ions;
4. cut promptly after the coated fabric that then 3. step is made is dried and get.
Embodiment three
A kind of printing trader's marker tape, it comprises grey cloth layer 1 and glue-line 2, and its thickness is 135 μ m, and the grey cloth layer thickness is 130 μ m; Its residual chlorine ion concentration≤1.39%.
The preparation method of above-mentioned printing trader's marker tape, specific as follows:
1. choose the polyamide fibre refuse yarn, then non-polyamide fibre composition is wherein chosen, mixed chlorinated then magnesium, calcium carbonate are dissolved in the methyl alcohol, process glue, are used for grey cloth is carried out dip-coating, and the concrete composition proportion of this glue is following,
Polyamide fibre 13wt%
Calcium carbonate 13wt%
Magnesium chloride 13wt%
Methyl alcohol 61wt%
2. after the nylon grey cloth clean, be dipped in the above-mentioned glue grey cloth is carried out gluing, glue-spread is controlled to be 30g/m
2
3. will pass through gluing and handle the coated fabric washing in the dechlorination ionized water that obtains, the washing temperature is 20～30 ℃, washing time 5～10min; The movement rate of the relative tank of coated fabric is 10～15 m/min; Said dechlorination ionized water adopts ion-exchange unit to make, and the operation that in the washing process, all the time said dechlorination ionized water is removed chlorion; The operation of in addition, said dechlorination ionized water also being removed calcium ions and magnesium ions;
4. cut promptly after the coated fabric that then 3. step is made is dried and get.
Embodiment four
A kind of printing trader's marker tape, it comprises grey cloth layer 1 and glue-line 2, and its thickness is 140 μ m, and the grey cloth layer thickness is 130 μ m; Its residual chlorine ion concentration≤1.43%.
The preparation method of above-mentioned printing trader's marker tape, specific as follows:
1. choose the polyamide fibre refuse yarn, then non-polyamide fibre composition is wherein chosen, mixed chlorinated then calcium, magnesium sulfate are dissolved in the ethyl acetate, process glue, are used for grey cloth is carried out dip-coating, and the concrete composition proportion of this glue is following,
Polyamide fibre 14wt%
Magnesium sulfate 14wt%
Calcium chloride 14wt%
Ethyl acetate 58wt%
2. after the nylon grey cloth clean, be dipped in the above-mentioned glue grey cloth is carried out gluing, glue-spread is controlled to be 35g/m
2
3. will pass through gluing and handle the coated fabric washing in the dechlorination ionized water that obtains, the washing temperature is 20～30 ℃, washing time 5～10min; The movement rate of the relative tank of coated fabric is 10～15 m/min; Said dechlorination ionized water adopts ion-exchange unit to make, and the operation that in the washing process, all the time said dechlorination ionized water is removed chlorion; The operation of in addition, said dechlorination ionized water also being removed calcium ions and magnesium ions;
4. cut promptly after the coated fabric that then 3. step is made is dried and get.
Embodiment five
A kind of printing trader's marker tape, it comprises grey cloth layer 1 and glue-line 2, and its thickness is 140 μ m, and the grey cloth layer thickness is 130 μ m; Its residual chlorine ion concentration≤1.51%.
The preparation method of above-mentioned printing trader's marker tape, specific as follows:
1. choose the polyamide fibre refuse yarn, incite somebody to action the composition of non-polyamide fibre wherein then and choose, mixed chlorinated then calcium, magnesium chloride, magnesium sulfate, calcium carbonate are dissolved in the methyl alcohol, process glue, are used for grey cloth is carried out dip-coating, and the concrete composition proportion of this glue is following,
Polyamide fibre 15wt%
Calcium carbonate 10wt%
Magnesium sulfate 5wt%
Magnesium chloride 5wt%
Calcium chloride 10wt%
Methyl alcohol 55wt%
2. after the nylon grey cloth clean, be dipped in the above-mentioned glue grey cloth is carried out gluing, glue-spread is controlled to be 40g/m
2
3. will pass through gluing and handle the coated fabric washing in the dechlorination ionized water that obtains, the washing temperature is 20～30 ℃, washing time 5～10min; The movement rate of the relative tank of coated fabric is 10～15 m/min; Said dechlorination ionized water adopts ion-exchange unit to make, and the operation that in the washing process, all the time said dechlorination ionized water is removed chlorion; The operation of in addition, said dechlorination ionized water also being removed calcium ions and magnesium ions;
4. cut promptly after the coated fabric that then 3. step is made is dried and get.
Claims (5)
1. the preparation method of printing trader's marker tape comprises coating processing and post processing, and it is characterized in that: coating is treated to through the mode of dip-coating carries out gluing to grey cloth, and institute's gluing prescription is following,
Synthetic fiber 10～15wt%
Accelerant 20～30wt%
Organic solvent 55～70wt% contains villaumite in the wherein said accelerant, and chloride content is no more than accelerant 50wt%;
Post processing comprises that the washing temperature is 20～30 ℃, washing time 5～10min with handling the coated fabric washing in the dechlorination ionized water that obtains through coating; And said dechlorination ionized water is kept in motion with respect to said coated fabric, and relative speed is 10～15m/min;
Said synthetic fiber are polyamide fibre;
Said accelerant is selected from one or more in calcium chloride, magnesium chloride, calcium sulfate, magnesium sulfate, the calcium carbonate;
Said organic solvent is selected from a kind of in toluene, ethyl acetate, butyl acrylate, the methyl alcohol.
2. the preparation method of a kind of printing trader's marker tape according to claim 1 is characterized in that: said dechlorination ionized water adopts ion-exchange unit to make, and the operation that in the washing process, all the time said dechlorination ionized water is removed chlorion.
3. the preparation method of a kind of printing trader's marker tape according to claim 1 is characterized in that: said post processing also comprises replaces alkaline-earth metal ions through ion-exchange unit with sodium ion to post processing water, and the operation that said alkaline-earth metal ions is removed.
4. the preparation method of a kind of printing trader's marker tape according to claim 1 is characterized in that: when coating was handled, glue-spread was controlled to be 20～40g/m
2
5. the preparation method of a kind of printing trader's marker tape according to claim 1 is characterized in that: when coating was handled, glue-spread was controlled to be 25～30g/m
2
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| CN201010541839A CN102086597B (en) | 2010-11-12 | 2010-11-12 | Printed label tape and manufacturing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010541839A CN102086597B (en) | 2010-11-12 | 2010-11-12 | Printed label tape and manufacturing method thereof |
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| CN102086597A CN102086597A (en) | 2011-06-08 |
| CN102086597B true CN102086597B (en) | 2012-09-05 |
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Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102517905B (en) * | 2011-12-02 | 2013-09-11 | 湖州新利商标制带有限公司 | Trademark belt with sand washing resistance and preparation method thereof |
| CN102517825B (en) * | 2011-12-22 | 2013-07-10 | 湖州凯恩涂层有限公司 | Trademark material production system |
| CN103696269A (en) * | 2013-11-12 | 2014-04-02 | 孙光华 | Polyamide coating tape |
| CN103572610B (en) * | 2013-11-13 | 2016-04-13 | 湖州新利商标制带有限公司 | Antistatic and can the trademark belt and preparation method thereof of heat transfer printing |
| CN103572468B (en) * | 2013-11-13 | 2015-01-07 | 湖州新利商标制带有限公司 | Regenerated environmental-friendly yarn label strap and manufacturing method thereof |
| CN104005233B (en) * | 2014-06-12 | 2017-01-11 | 湖州新利商标制带有限公司 | Black nylon trademark tape and manufacturing method thereof |
| CN104562379B (en) * | 2014-12-31 | 2016-03-09 | 湖州恒新商标制带有限公司 | Can be used for terylene fabrics and the preparation method of bar code printing |
| CN104452045B (en) * | 2014-12-31 | 2017-02-22 | 湖州恒新商标制带有限公司 | Nylon environment-friendly trademark fabric and manufacturing method |
| CN105040230A (en) * | 2015-02-13 | 2015-11-11 | 张朝龙 | Novel terylene acetic acid single/double-face hand-tearing printing mark band and making method thereof |
| CN105386203A (en) * | 2015-10-21 | 2016-03-09 | 湖州恒新商标制带有限公司 | Nylon trademark cloth easy to cut and preparing method thereof |
| CN113914107B (en) * | 2021-11-05 | 2024-03-22 | 湖州倍亨纺织有限公司 | Stiffening treatment process and device for trademark tape |
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| CN1059002A (en) * | 1990-09-25 | 1992-02-26 | 尹龙华 | The manufacture method of cloth with microporous film coating |
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| C06 | Publication | ||
| PB01 | Publication | ||
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