CN102085161A - Porous polymethyl methacrylate powder containing functional material for cosmetics, preparation method thereof, and cosmetic composition containing same - Google Patents
Porous polymethyl methacrylate powder containing functional material for cosmetics, preparation method thereof, and cosmetic composition containing same Download PDFInfo
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- CN102085161A CN102085161A CN2010100004983A CN201010000498A CN102085161A CN 102085161 A CN102085161 A CN 102085161A CN 2010100004983 A CN2010100004983 A CN 2010100004983A CN 201010000498 A CN201010000498 A CN 201010000498A CN 102085161 A CN102085161 A CN 102085161A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/0279—Porous; Hollow
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
- A61K8/606—Nucleosides; Nucleotides; Nucleic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/56—Compounds, absorbed onto or entrapped into a solid carrier, e.g. encapsulated perfumes, inclusion compounds, sustained release forms
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Abstract
The present invention relates to a porous polymethyl methacrylate powder for cosmetics, comprising: (a) porous polymethyl methacrylate; and (b) a functional material for cosmetics impregnated into the porous polymethyl methacrylate, and a preparation method thereof. According to the composition, the porous polymethyl methacrylate powder can contain functional materials used in cosmetics (moisturization, ultraviolet screening, whitening, wrinkles reduction, and stimulus prevention) in large quantities without regard to the cosmetic formulation.
Description
Technical field
The present invention relates to contain the porous polymethyl methacrylate powder and the manufacture method thereof of the functional materials that is useful on cosmetics (preserve moisture, block ultraviolet, whiten, wrinkle removing, the anti-stimulation), more particularly, the present invention relates to can impregnation a large amount of liquid state and solid-state used for cosmetic functional materials, particularly also can easily the used for cosmetic functional materials be used for the porous polymethyl methacrylate powder and the manufacture method thereof of the cosmetics dosage form (toner dosage form) of those use amounts that define the such liquid parts of water or oils.
Background technology
Various used for cosmetic functional materials are owing to have difficult dissolubility, thus its existence need when being used for cosmetics water or oils such can be with the shortcoming of using after the disposable dissolving of its dissolved substances.Therefore, functional components can be used in the hard-core cosmetics dosage form of consumption (basic emulsifying dosage form or tone emulsifying dosage form) to the such liquid parts of water or oils, but, this existence must be used the specified liquid parts that can dissolve selected functional components, and the consumption of described liquid parts must can be with its dissolved shortcoming.In addition, exist and to preserve moisture, to whiten and problem that functional material that wrinkle removing is such is difficult to application in the very limited cosmetics dosage form (toner dosage form) of the consumption of the such liquid parts of water or oils.
Summary of the invention
The present invention finishes for the problem that solves prior art existence as mentioned above, its purpose is to provide a kind of porous polymethyl methacrylate powder, this powder can be used in multiple cosmetics dosage form, can contain the functional materials that is used for cosmetics in a large number (preserve moisture, block ultraviolet, whiten, wrinkle removing, the anti-stimulation).
Another object of the present invention is to provide a kind of porous polymethyl methacrylate manufacturing method of power, described powder can be used in multiple cosmetics dosage form, can contain the functional materials that is used for cosmetics in a large number (preserve moisture, block ultraviolet, whiten, wrinkle removing, the anti-stimulation).
Another object of the present invention is to provide a kind of cosmetic composition that contains porous polymethyl methacrylate powder, and described porous polymethyl methacrylate powder contains functional materials (preserve moisture, block ultraviolet, whiten, wrinkle removing, the anti-stimulation).
To achieve these goals, the invention provides a kind of used for cosmetic porous polymethyl methacrylate powder, this powder contains (a) porous polymethyl methacrylate and the used for cosmetic functional materials that (b) infiltrates in described porous polymethyl methacrylate.
In addition, the invention provides a kind of cosmetic composition, it contains the porous polymethyl methacrylate powder that above-mentioned impregnation has functional materials.
In addition, the invention provides a kind of used for cosmetic porous polymethyl methacrylate manufacturing method of power, it comprises the steps: that (a) drops into the porous polymethyl methacrylate step of mixer; (b) step of input functional materials in described mixer; (c) make the rotation of described mixer, described functional materials is infiltrated up to step in the described porous polymethyl methacrylate.
Effect excellence when the porous polymethyl methacrylate that contains the used for cosmetic functional materials of the present invention is used for the cosmetics dosage form, can be used in multiple dosage form and needn't consider the dosage form (Emulsion or powder) of cosmetics, and can use a large amount of functional materials.
Description of drawings
Fig. 1 a is ultraviolet is infiltrated up to the product that obtains behind the 1 weight portion porous polymethyl methacrylate with liquid material PARSOL MCX (manufacturing of DSM society) the practical photograph of blocking that 1 weight portion is used for cosmetics of embodiment 1.
Fig. 1 b is the practical photograph that the 1 weight portion mixed liquor with used for cosmetic distilled water and used for cosmetic polymer viscosifier Sepigel 305 (manufacturing of SEPPIC society) of embodiment 2 is infiltrated up to the product that obtains behind the 1 weight portion porous polymethyl methacrylate.
Fig. 1 c is the practical photograph that the 1 weight portion mixed liquor that will be dissolved with the solid-state raw material VC-IP that whitens of used for cosmetic (manufacturing of Nikko chemical society) in oil component CETIOL-LC (manufacturing of COGNIS society) of embodiment 3 is infiltrated up to the product that obtains behind the 1 weight portion porous polymethyl methacrylate.
The specific embodiment
The invention provides a kind of used for cosmetic porous polymethyl methacrylate powder, it contains (a) porous polymethyl methacrylate and the used for cosmetic functional materials that (b) infiltrates in described porous polymethyl methacrylate.
In addition, the invention provides a kind of cosmetic composition, it contains the porous polymethyl methacrylate powder that above-mentioned impregnation has functional materials.
In addition, the invention provides a kind of used for cosmetic porous polymethyl methacrylate manufacturing method of power, it comprises the steps: that (a) drops into the porous polymethyl methacrylate step of mixer; (b) step of input functional materials in described mixer; (c) make the rotation of described mixer, described functional materials is infiltrated up to step in the described porous polymethyl methacrylate.
Among the present invention, " used for cosmetic functional materials " is meant to sneak into can bring into play when being applied to skin in the cosmetic composition and preserves moisture, whitens, wrinkle removing, blocks the material of the such function of ultraviolet, both comprised that liquid also comprised solid matter.
As such examples of substances, can enumerate and be selected from by the American Avocado Tree extract, Fumaria officinalis (fumitory) extract, Radix Ginseng (ニ Application ジ Application) extract, Cortex Moutan extract, Radix Puerariae extract, collinsonia canadensis (Collinsonia canadensis) extract, the Herba Equiseti Hiemalis (lady ' s horsetail) extract, garment or robe made of feathers grass (lady ' s mantle) extract, Herba Equiseti Arvinsis (horsetail) extract, the bean embryo extract, wheat malt germ extract, Radix Dauci Sativae extract, Thallus Laminariae (Thallus Eckloniae) extract, Radix Sangusorbae extract, Cortex Cinnamomi extract, Rhizoma Zingiberis Recens extract, Herba Ephedrae extract, the Trimeresurus stejnegeri extract, in the group that various extracts such as vitaminF and Fructus Mali pumilae seed extract are formed one or more, the preferred use contained α-bisabolol, asiaticoside (asiaticoside), various commercially available products (the ProductName: Alpha-Melight of the active component that adenosine or Radix Ginseng extract are such, FMLT Gotusphere, SNLT Adenosphere, Herbex Ginseng, Mutiex BSASM etc.).
Below, the present invention is carried out more specific description.
(1) preparation of porous polymethyl methacrylate
This step is the step of preparing as the porous polymethyl methacrylate powder of substrate, and this substrate is used for impregnation used for cosmetic functional materials.
Described porous polymethyl methacrylate is spheric macromolecule Organic Ingredients, can use the employed common porous polymethyl methacrylate in this area, the particle diameter of preferred single particle is that 5～15 μ m, particularly oil absorption and water absorption are above, the preferred 1.6cc/g～3.0cc/g of 1.5cc/g.
Under the few situation of oil absorption and water absorption, during the liquid functional materials of impregnation more than 40%, these functional materials are difficult to be infiltrated up to equably in each polymethyl methacrylate, and the result causes state humidity, not dry and comfortable (powdery) of the final product of making.
The step of the used for cosmetic functional materials of (2) impregnation liquid state
This step is to make liquid used for cosmetic functional materials be infiltrated up to step in the porous polymethyl methacrylate of described step (1).
Specifically, after porous polymethyl methacrylate powder and liquid cosmetic put into the mixer (for example Henschel agitator (hansle mixer)) that is rotated running with functional materials, carry out high speed rotating, make liquid cosmetic be infiltrated up to the inside of porous polymethyl methacrylate with functional materials.
At this moment, with respect to the above-mentioned porous polymethyl methacrylate of 100 weight portions, the liquid cosmetic that infiltrate is preferably 1～100 weight portion with the consumption of functional materials, more preferably 10～100 weight portions.Importantly, preferably with the cooperation limit of used for cosmetic functional materials in cosmetics that will infiltrate with interior and can show that more than the Min. of usefulness serve as the interpolation benchmark.
As the mixer that is rotated running, preferred Henschel agitator, but be not limited to this, so long as powder and the blended common equipment of liquid can be got final product, be not particularly limited in use.
Carry out in the blended operation after porous polymethyl methacrylate and the liquid cosmetic that will infiltrate put into the Henschel agitator with functional materials, at first, after dropping into the porous polymethyl methacrylate, (for example 500～1000rpm) be rotated down with low speed, with about 8～12 minutes, dropped into the liquid cosmetic functional materials in preferred about 10 minutes, after dropping into end, so that (for example 2000～3000rpm) rotations are about 1～5 minute at a high speed, preferred about 3 minutes, make liquid used for cosmetic functional materials be infiltrated up to the inside of porous polymethyl methacrylate.
The input method of described liquid cosmetic with functional materials had no particular limits,, preferably use aerojet, dropping (dropping) method etc. from considering to the aspect of the inside of porous polymethyl methacrylate infiltration easily.
(3) step of the solid-state used for cosmetic functional materials of impregnation
This step is that solid, cosmetic is infiltrated up to step in the porous polymethyl methacrylate of described step (1) with functional materials.
Under the situation of solid-state used for cosmetic functional materials, can operate by the process identical with the method for the used for cosmetic functional materials of (2) impregnation liquid state, difference is, solid, cosmetic can not be put in the porous polymethyl methacrylate with solid state with functional materials, so seeking can be disposable with the functional substance dissolves of solid, cosmetic, infiltrate after with certain proportion it being dissolved fully.
(4) contain the stabilization step of the porous polymethyl methacrylate of used for cosmetic functional materials
This step is to improve the step of the degree of stability of the porous polymethyl methacrylate powder that contains the used for cosmetic functional materials that described (2), (3) step obtain.
Specifically, in the porous polymethyl methacrylate powder that contains the used for cosmetic functional materials that the result as described step (2), (3) obtains, use under the situation of the used for cosmetic functional materials that contains moisture, water evaporates takes place in final products when preserving, so must prevent this problem.
Therefore, according to the present invention,, can further add thickening agent or wetting agent in order to prevent the water evaporates in the final products preservation.Containing under the situation that is soaked with this used for cosmetic functional materials that contains moisture, the evaporation of moisture when suppressing long preservation, can before being infiltrated up to the porous polymethyl methacrylate, it in the aqueous solution that contains the used for cosmetic functional materials that will infiltrate, add the evaporation that thickening agent as described above or wetting agent suppress moisture.
As the thickening agent that is used for above-mentioned purpose, for example can enumerate at least a material in the group that is selected from guar gum (guargum), locust bean gum (locust bean gum), pectin, xanthan gum (xanthane gum), carboxyl ethylene polymer (carboxyvinyl polymer), cellulose derivative and ethanol composition, preferably use the series of polymers thickening agent.
Wetting agent can be enumerated at least a material in the group that for example is selected from glycerol, propylene glycol, butanediol, Polyethylene Glycol, Sorbitol, sodium lactate (sodium lactate), 2-pyrrolidone-5-carboxylic acid, dipropylene glycol, maltose alcohol, hyaluronic acid and natto gum (natto gum) composition.
At this moment, with respect to the total aqueous solution of 100 weight portions, the input amount of thickening agent or wetting agent is in 10 weight portions, is preferably 0.1～5 weight portion, and can obtain desired effect this moment, so be preferred.
The present invention also provides the cosmetic composition that contains by the porous polymethyl methacrylate powder that contains the used for cosmetic functional components of said method manufacturing.
At this moment, be used as under the situation of cosmetics, consider preserve moisture, block the ultraviolet effect, relax skin irritation, usefulness such as whitening effect, wrinkle removing and with other the Combination of cosmetics constituent and dosage form when forming property etc., with respect to the cosmetic composition gross weight, the above-mentioned content that contains the porous polymethyl methacrylate powder of used for cosmetic functional components is preferably 0.1～20 weight %.
Cosmetic composition of the present invention can be made variform, for example can make dosage forms such as emulsion, astringent, cream (oil-in-water type, water-in-oil type, multiplephase), solution, suspension (no water system and water system), anhydrous product (oil and glycol system), gel (ゲ Le), facial film, skin lotion, powder.As mentioned above, cosmetic composition of the present invention has the particular dosage form of being not limited to, with the irrelevant advantage of the character of input functional materials.
Cosmetic composition of the present invention can contain normally used carrier.As the example of such carrier, can enumerate alcohol, oil, surfactant, fatty acid, silicone oil, wetting agent, wetting agent, thickening agent, oil preparation, antiseptic, stabilizing agent, ultraviolet screening agent, developer, spice etc.With respect to the gross weight of cosmetic composition of the present invention, the content of described carrier is about 0.5 weight %～about 99.9 weight %, be preferably about 80 weight % of the weight of compositions～about 99.9 weight %.But above-mentioned dosage form or application site, application quantity etc. because of cosmetic composition of the present invention is made into can change described ratio.
Below, in order to understand the present invention, enumerate preferred embodiment, but following embodiment only being of the present invention giving an example, scope of the present invention is not limited to following embodiment.
Embodiment
The manufacturing of [embodiment 1] porous polymethyl methacrylate powder (infiltration of liquid functional materials)
Dropping into the 600g oil absorption in having the volumetrical Henschel agitator of 10L is the porous polymethyl methacrylate powder of 1.8cc/g.With 400rpm running Henschel agitator in, with about 10 minute, in aerojet mode drop into ultraviolet that 600g be used for the liquid state of cosmetics block raw material PARSOL-MCX (DSM society manufacturing) thereafter.Feed intake finish after, with about 3 minutes of 1800rpm running Henschel agitator.
Contain 50%PARSOL-MCX (chemical name: methoxyl group cinnamic acid monooctyl ester by final manufacturing, OctylMethoxycinnamatea) porous polymethyl methacrylate powder through the analysis result of HPLC quantitative test as can be known, the infiltrated PARSOL-MCX of 49.9 weight %, its profile has been kept the character of dry and comfortable (powdery) of porous polymethyl methacrylate.
The manufacturing of [embodiment 2] porous polymethyl methacrylate powder (containing liquid water)
At first, in the 594g distilled water that will infiltrate, drop into 6g used for cosmetic polymer viscosifier Sepiplus 400 (manufacturings of SEPPIC society), stir then and mix.
Dropping into the 600g oil absorption in having the volumetrical Henschel agitator of 10L is the porous polymethyl methacrylate powder of 1.8cc/g.With 400rpm running Henschel agitator in, with about 10 minute, in aerojet mode drop into 600g above-mentioned pre-prepd aqueous solution thereafter.Feed intake finish after, with about 3 minutes of 1800rpm running Henschel agitator.
The moisture analysis result that is obtained through hydro-tester by the porous polymethyl methacrylate powder that contains 50% distilled water of final manufacturing as can be known, the infiltrated moisture of 49.7 weight %, profile has kept the character of dry and comfortable (powdery) of porous polymethyl methacrylate.
The manufacturing of [embodiment 3] porous polymethyl methacrylate powder (solid-state functional materials infiltrates)
At first, the solid-state raw material VC-IP that whitens of the 100g that will infiltrate (manufacturing of Nikko chemical society) puts among the 300g oil component CETIOL-LC (manufacturing of COGNIS society), then, stirs, dissolves.Be heated to about 40 ℃ during dissolving, confirm that it dissolves fully.
Dropping into the 600g oil absorption in having the volumetrical Henschel agitator of 10L is the porous polymethyl methacrylate powder of 1.6cc/g.With 400rpm running Henschel agitator time, with about 10 minute, in aerojet mode drop into 400g above-mentioned pre-prepd VC-IP solution thereafter.Feed intake finish after, with about 3 minutes of 1800rpm running Henschel agitator.
Contain 10%VC-IP (chemical name: Ascorbyl Tetraisopalmitate by final manufacturing, Ascorbyl Tetraisopalmitate) the quantitative test analysis result that porous polymethyl methacrylate powder obtains through HPLC as can be known, the infiltrated VC-IP of 9.6 weight %, profile has kept the character of dry and comfortable (powdery) of porous polymethyl methacrylate.
The manufacturing of [embodiment 4] cosmetic composition
The porous polymethyl methacrylate powder that contains PARSOL-MCX, 3.0 weight % zinc stearates, 15.0 weight % alkyl silane surface treatment Muscovitums (SUNMICA-AS, first theory of evolution (strain) society make), 23.0 weight % alkyl silane surface treatment sericites (SUNSERI-AS, first theory of evolution (strain) society make), 44.0 weight % alkyl silane surface treatment Talcums (SUNTALC-AS, first theory of evolution (strain) society make) and 5.0 weight %1 with described embodiment 1 manufacturing of 10.0 weight %, the 3-butanediol mixes, and makes cosmetics.
[reference example]
As above-mentioned embodiment 2, wherein, do not use 6g polymer viscosifier Sepiplus400 (manufacturing of SEPPIC society), only use the 600g distilled water, make the porous polymethyl methacrylate powder contain 50% moisture.
The moisture analysis result that is obtained through hydro-tester by the porous polymethyl methacrylate powder that contains 50% distilled water of final manufacturing as can be known, 49.8% the moisture that infiltrated, profile has kept the character of dry and comfortable (powdery) of porous polymethyl methacrylate.
[comparative example 1]
As above-mentioned embodiment 4, wherein, the porous polymethyl methacrylate powder that contains PARSOL-MCX that replaces embodiment 1 to make, use porous polymethyl methacrylate powder (SUNPMMA-P, (advanced person) department hold a memorial ceremony for) the 5 weight % and the liquid ultraviolet that use in the existing cosmetics to block 5 weight % respectively with raw material PARSOL-MCX (manufacturing of DSM society), in addition, implement with the method identical, make cosmetics with the foregoing description 4.
[test example 1]
Under room temperature, Kaifeng state relatively the foregoing description 2 contain the 49.7% water evaporates degree that has been added the porous polymethyl methacrylate powder that contains 49.8% moisture of the porous polymethyl methacrylate powder of moisture of polymer viscosifier and above-mentioned reference example.Its process and the results are shown in following table 1.
[table 1]
Shown in above-mentioned table 1, the evaporation degree result of the test of the moisture that carries out under the same terms of identical room temperature, Kaifeng state shows, containing of embodiments of the invention 2 49.7% has been added the porous polymethyl methacrylate powder of moisture of polymer viscosifier after normal temperature condition was placed 24 hours, evaporation capacity of moisture content is about 1%, relative therewith, the porous polymethyl methacrylate powder that contains 49.8% moisture of reference example is after normal temperature condition is placed 24 hours, evaporation capacity of moisture content is 40%, and most water evaporates has been fallen.
[test example 2]
The porous polymethyl methacrylate powder that contains the used for cosmetic functional components that the foregoing description 1, embodiment 2, embodiment 3 make is the oil content or the moisture of impregnation about 50% respectively, but still shown the inherent profile (character of dry and comfortable (powdery)) of porous polymethyl methacrylate.Its result sees Fig. 1 a, Fig. 1 b and Fig. 1 c respectively.
[test example 3]
Utilize optical element determinator (Optometrics 290, Optometrics society make), for the cosmetics of the foregoing description 4 and comparative example 1 manufacturing the shielding degree (SPF) of UV-B is measured 8 times repeatedly, and represented with its meansigma methods.It the results are shown in following table 2.
[table 2]
Shown in above-mentioned table 2, to compare with comparative example 1, the cosmetics of embodiments of the invention 4 have shown high SPF.By such result as can be known, compare with the situation that used for cosmetic blocks the ultraviolet material with use porous polymethyl methacrylate, with of the present invention when containing porous polymethyl methacrylate powder that used for cosmetic blocks the ultraviolet functional mass and being used for the cosmetics dosage form, block ultraviolet usefulness or equal, perhaps obtained the high-caliber ultraviolet power of blocking.
Claims (15)
1. used for cosmetic porous polymethyl methacrylate powder, this powder contain (a) porous polymethyl methacrylate and (b) the used for cosmetic functional materials of infiltration in described porous polymethyl methacrylate.
2. used for cosmetic porous polymethyl methacrylate powder as claimed in claim 1 is characterized in that the oil absorption of described porous polymethyl methacrylate is that 1.5cc/g～3.0cc/g and water absorption are 1.5cc/g～3.0cc/g.
3. used for cosmetic porous polymethyl methacrylate powder as claimed in claim 1 is characterized in that, with respect to the described porous polymethyl methacrylate of 100 weight portions, the content of functional materials is 1 weight portion～100 weight portions.
4. used for cosmetic porous polymethyl methacrylate powder as claimed in claim 1 is characterized in that this powder also further contains wetting agent or thickening agent.
5. used for cosmetic porous polymethyl methacrylate powder as claimed in claim 4, it is characterized in that described wetting agent is at least a material that is selected from the group that glycerol, propylene glycol, butanediol, Polyethylene Glycol, Sorbitol, sodium lactate, 2-pyrrolidone-5-carboxylic acid, dipropylene glycol, maltose alcohol, hyaluronic acid and natto gum form.
6. used for cosmetic porous polymethyl methacrylate powder as claimed in claim 4, it is characterized in that described thickening agent is at least a material that is selected from the group that guar gum, locust bean gum, pectin, xanthan gum, carboxyl ethylene polymer, cellulose derivative and ethanol forms.
7. used for cosmetic porous polymethyl methacrylate powder as claimed in claim 1 is characterized in that, described functional materials be have moisture-keeping functions, block the ultraviolet function, whitening function, wrinkle removing function or the anti-material that stimulates function.
8. used for cosmetic porous polymethyl methacrylate powder as claimed in claim 1 is characterized in that described functional materials contains α-bisabolol, asiaticoside, adenosine or Radix Ginseng extract as active component.
9. cosmetic composition, said composition contain and are selected from each porous polymethyl methacrylate powder of claim 1～8.
10. used for cosmetic porous polymethyl methacrylate manufacturing method of power, it comprises the steps: that (a) drops into the porous polymethyl methacrylate step of mixer; (b) step of input functional materials in described mixer; (c) make the rotation of described mixer, described functional materials is infiltrated up to step in the described porous polymethyl methacrylate.
11. used for cosmetic porous polymethyl methacrylate manufacturing method of power as claimed in claim 10, it is characterized in that the oil absorption of the porous polymethyl methacrylate of described input mixer is that 1.5cc/g～3.0cc/g and water absorption are 1.5cc/g～3.0cc/g.
12. used for cosmetic porous polymethyl methacrylate manufacturing method of power as claimed in claim 10, it is characterized in that, in the described step (c), put into the porous polymethyl methacrylate of mixer, 1 weight portion that infiltrates～100 weight portion functional materials with respect to 100 weight portions.
13. used for cosmetic porous polymethyl methacrylate manufacturing method of power as claimed in claim 10 is characterized in that, described used for cosmetic porous polymethyl methacrylate powder also further contains wetting agent or thickening agent.
14. used for cosmetic porous polymethyl methacrylate manufacturing method of power as claimed in claim 10, it is characterized in that, described functional materials be have moisture-keeping functions, block the ultraviolet function, whitening function, wrinkle removing function or the anti-material that stimulates function.
15. used for cosmetic porous polymethyl methacrylate manufacturing method of power as claimed in claim 10 is characterized in that described functional materials contains α-bisabolol, asiaticoside, adenosine or Radix Ginseng extract as active component.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020090119510A KR20110062708A (en) | 2009-12-04 | 2009-12-04 | Porous polymethylmetacrylate powder comprising functional material for cosmetics. preparation method thereof, and cosmetic composition comprising the same |
| KR10-2009-0119510 | 2009-12-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102085161A true CN102085161A (en) | 2011-06-08 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010100004983A Pending CN102085161A (en) | 2009-12-04 | 2010-01-15 | Porous polymethyl methacrylate powder containing functional material for cosmetics, preparation method thereof, and cosmetic composition containing same |
Country Status (3)
| Country | Link |
|---|---|
| KR (1) | KR20110062708A (en) |
| CN (1) | CN102085161A (en) |
| WO (1) | WO2011068333A2 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103202774A (en) * | 2013-04-11 | 2013-07-17 | 丽鑫生技化妆品（上海）有限公司 | Container structure for loading cosmetics and manufacture method thereof |
| CN108324594A (en) * | 2018-03-05 | 2018-07-27 | 苏州绿叶日用品有限公司 | A kind of anti-wrinkle composition, the product and preparation method thereof being made from it |
| CN108366953A (en) * | 2015-10-30 | 2018-08-03 | 株式会社资生堂 | Composition |
| CN108366918A (en) * | 2015-09-30 | 2018-08-03 | 爱茉莉太平洋股份有限公司 | Scoria powder particle is impregnated in poromeric composite granule, contains its cosmetic composition and preparation method thereof |
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| KR101470850B1 (en) | 2013-04-03 | 2014-12-09 | 코스맥스 주식회사 | Manufacturing method of macroporous Poly methyl methacrylate |
| US20160089310A1 (en) * | 2013-05-16 | 2016-03-31 | Dsm Ip Assets B.V. | Topical compositions |
| KR101683995B1 (en) * | 2014-11-06 | 2016-12-21 | 선진뷰티사이언스(주) | The cosmetic composition comprising the porous soft bead |
| KR102116545B1 (en) | 2015-06-30 | 2020-05-28 | (주)아모레퍼시픽 | Composite Powder of Porous Polymer Impregnated with Jade Powder Particle, Cosmetic Composition Comprising the Same and the Manufacturing Method Thereof |
| WO2017057886A1 (en) * | 2015-09-30 | 2017-04-06 | (주)아모레퍼시픽 | Composite powder in which porous polymer is impregnated with scoria powder particles, cosmetic composition containing same, and process for producing same |
| KR102506399B1 (en) * | 2015-11-30 | 2023-03-06 | 주식회사 엘지생활건강 | Composition for stabilizing polyphenolic effective ingredient |
| KR101999973B1 (en) * | 2017-08-29 | 2019-07-15 | 코스맥스 주식회사 | A Stick-form Cosmetic Composition Comprising Porous Powder And A Preparing Method Thereof |
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| KR19980055065A (en) * | 1996-12-28 | 1998-09-25 | 성재갑 | Eyeshadow Composition Containing Glycerin |
| KR100600470B1 (en) * | 2004-10-26 | 2006-07-13 | 주식회사 선진화학 | Preparing method of porous polymethylmethacrlate |
| KR101404965B1 (en) * | 2007-04-09 | 2014-06-13 | (주)아모레퍼시픽 | Mesoporous composite powder containing metallic oxides and the method for preparing thereof |
| KR100953144B1 (en) * | 2008-01-15 | 2010-04-16 | 코스맥스 주식회사 | The massage mousse pack cosmetic composition of foam type using carbon dioxide |
-
2009
- 2009-12-04 KR KR1020090119510A patent/KR20110062708A/en not_active Application Discontinuation
-
2010
- 2010-01-15 CN CN2010100004983A patent/CN102085161A/en active Pending
- 2010-11-25 WO PCT/KR2010/008399 patent/WO2011068333A2/en active Application Filing
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103202774A (en) * | 2013-04-11 | 2013-07-17 | 丽鑫生技化妆品（上海）有限公司 | Container structure for loading cosmetics and manufacture method thereof |
| CN103202774B (en) * | 2013-04-11 | 2015-06-10 | 丽鑫生技化妆品（上海）有限公司 | Container structure for loading cosmetics and manufacture method thereof |
| CN108366918A (en) * | 2015-09-30 | 2018-08-03 | 爱茉莉太平洋股份有限公司 | Scoria powder particle is impregnated in poromeric composite granule, contains its cosmetic composition and preparation method thereof |
| TWI725994B (en) * | 2015-09-30 | 2021-05-01 | 南韓商愛茉莉太平洋股份有限公司 | Complex powder of porous polymer containing scoria powder particle, cosmetic composition comprising thereof and the manufacturing method thereof |
| CN108366918B (en) * | 2015-09-30 | 2021-07-27 | 爱茉莉太平洋股份有限公司 | Composite powder obtained by impregnating volcanic cinders powder particles in porous polymer, cosmetic composition containing same, and method for producing same |
| CN108366953A (en) * | 2015-10-30 | 2018-08-03 | 株式会社资生堂 | Composition |
| CN108366953B (en) * | 2015-10-30 | 2021-12-21 | 株式会社资生堂 | Composition comprising a metal oxide and a metal oxide |
| CN108324594A (en) * | 2018-03-05 | 2018-07-27 | 苏州绿叶日用品有限公司 | A kind of anti-wrinkle composition, the product and preparation method thereof being made from it |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2011068333A3 (en) | 2011-10-27 |
| KR20110062708A (en) | 2011-06-10 |
| WO2011068333A2 (en) | 2011-06-09 |
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Application publication date: 20110608 |