CN102061033A - Method for preparing scratch resistant type elastomer toughening polypropylene composite material - Google Patents
Method for preparing scratch resistant type elastomer toughening polypropylene composite material Download PDFInfo
- Publication number
- CN102061033A CN102061033A CN2010106038466A CN201010603846A CN102061033A CN 102061033 A CN102061033 A CN 102061033A CN 2010106038466 A CN2010106038466 A CN 2010106038466A CN 201010603846 A CN201010603846 A CN 201010603846A CN 102061033 A CN102061033 A CN 102061033A
- Authority
- CN
- China
- Prior art keywords
- rev
- auxiliary agent
- rotating speed
- elastomerics
- scrape resistant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 30
- -1 polypropylene Polymers 0.000 title claims abstract description 29
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 29
- 239000002131 composite material Substances 0.000 title claims abstract description 13
- 229920001971 elastomer Polymers 0.000 title abstract description 5
- 239000000806 elastomer Substances 0.000 title abstract description 5
- 238000000034 method Methods 0.000 title abstract description 5
- 230000003678 scratch resistant effect Effects 0.000 title abstract 6
- 239000000203 mixture Substances 0.000 claims abstract description 43
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 34
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 12
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 12
- 238000005303 weighing Methods 0.000 claims description 21
- 238000005453 pelletization Methods 0.000 claims description 16
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 15
- 238000001125 extrusion Methods 0.000 claims description 14
- 238000002360 preparation method Methods 0.000 claims description 11
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 9
- 239000012764 mineral filler Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 abstract description 18
- 238000012545 processing Methods 0.000 abstract description 2
- 239000011256 inorganic filler Substances 0.000 abstract 1
- 229910003475 inorganic filler Inorganic materials 0.000 abstract 1
- 238000007790 scraping Methods 0.000 description 15
- 235000006708 antioxidants Nutrition 0.000 description 9
- 238000012360 testing method Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 2
- 239000011246 composite particle Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229940040145 liniment Drugs 0.000 description 1
- 239000000865 liniment Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a method for preparing a scratch resistant type elastomer toughening polypropylene composite material. The method for preparing the scratch resistant type elastomer toughening polypropylene composite material comprises the following steps of: processing a part of a scratch resistant auxiliary agent and elastomers into master batches; and adding the master batches to a mixture of polypropylene, inorganic fillers and an antioxidant for extruding and granulating to obtain a product. The product prepared by using the method can be used for greatly improving the efficiency of the scratch resistant auxiliary agent, has stable property and good scratch resistant property and can be widely applied to occasions having higher requirements on material surfaces.
Description
Technical field
The present invention relates to a kind of preparation method of scrape resistant type tenacity-increased profax, specifying is a kind of processing method that improves elastic body toughening polypropylene composite material surface scraping and wiping resistance performance.
Background technology
Polypropylene material is used for engineering plastics need pass through tough-increased and reinforced modification.General by adding the inorganic rigid particle enhancing, add thermoplastic elastomer toughening.After adding inorganic particulate and elastomerics, the PP material surface is easy to scratch, and promptly shows as the decline of scraping and wiping resistance performance.Thereby adopt interpolation scrape resistant auxiliary agent to improve its surperficial scraping and wiping resistance performance usually.
Main its principle of scrape resistant auxiliary agent is the skin friction coefficient that reduces material at present, improves the smooth property on its surface.At present technology is still for simply mixing the scrape resistant auxiliary agent with polypropylene, mineral filler, elastomerics and passing through the direct extruding pelletization of twin screw extruder.This technology can be so that the scrape resistant auxiliary agent migrates to the polypropylene-base surface, but elastomer particles also has part to be dispersed to the polypropylene-base surface simultaneously, caused composite material surface discontinuous, the surperficial smooth degree that weakened has reduced the efficient of scrape resistant auxiliary agent.
Conventional scrape resistant type polypropylene composite material complete processing for polypropylene, mineral filler, elastomerics, scrape resistant auxiliary agent, antioxidant is disposable extrudes, because anti-scratch liniment is the transport property auxiliary agent, by form the film of one deck low-friction coefficient at material surface, improve the scraping and wiping resistance performance of material.But because elastomerics is a disperse phase in just expecting, have part and be exposed to material surface, according to a conventional method, the scrape resistant auxiliary agent all trends towards being scattered in the external phase fully in extrusion, be difficult to enter elastomerics, be exposed to the elastomerics of material surface, material surface continuous thin film layer is cut off, reduce the scraping and wiping resistance performance of material.
Summary of the invention
The present invention seeks to by forming master batch earlier, the mode of granulation solves the relatively poor problem of polypropylene composite material surface scraping and wiping resistance performance of passing through elastic body toughening at present again, and the efficient that further improves existing scrape resistant auxiliary agent.
A kind of preparation method of scrape resistant type elastic body toughening polypropylene composite material, described polypropylene composite material comprises polypropylene, mineral filler, the mixture of elastomerics, scrape resistant auxiliary agent, antioxidant; It is characterized in that getting earlier 5%-20% weight percentage scrape resistant auxiliary agent and elastomerics and make master batch, the scrape resistant auxiliary agent of surplus, master batch and other component blend extruding pelletizations, wherein elastomerics accounts for the 5%-20% of polypropylene, mineral filler and elastomerics three weight summation.
Concrete preparation process is as follows:
(1) elastomerics and 5%-20% weight percentage scrape resistant auxiliary agent mixed under 300 ~ 500 rev/mins rotating speed 1 ~ 3 minute, mixed under 1500 ~ 2000 rev/mins rotating speed 10 ~ 15 minutes again, obtained pre-composition;
(2) with (1) described pre-composition through the twin screw extruder extruding pelletization, obtain master batch, the twin screw extruder extrusion temperature is 150 ~ 170 ℃;
(3) take by weighing polypropylene, master batch by formula rate, the scrape resistant auxiliary agent of surplus, antioxidant mixed under 300 ~ 500 rev/mins rotating speed 1 ~ 2 minute, mixed under 1500 ~ 2000 rev/mins rotating speed 10-15 minute;
(4) take by weighing a certain amount of superfine talcum powder by formula rate and be added in (3) described mixture, under 300 ~ 500 rev/mins rotating speed, mixed 8 ~ 10 minutes, obtain mixture;
(5) (4) described mixture is got product through the twin screw extruder extruding pelletization, extrusion temperature is 170 ~ 200 ℃.
The preparation method of a kind of scrape resistant type elastic body toughening polypropylene composite material of the present invention can significantly improve the efficient of scraping auxiliary agent, and is with low cost.Successfully overcome the influence of elastomeric interpolation to the material scraping and wiping resistance performance.The products obtained therefrom performance is adjustable, can extensively substitute external product, is applied to field, all kinds of middle and high end.
The scrape resistant type elastic body toughening polypropylene composite particle of present method preparation is guaranteeing under the constant situation of its physical and chemical performance after testing, under the scrape resistant stress condition of 10N, △ L value is not higher than 1.5(and detects by the company standard Q/SQR.04.137-2010 of Saic Chery Automobile Co., Ltd).
Embodiment
The preparation method of scrape resistant type tenacity-increased profax of the present invention illustrates the specific embodiment of the present invention by following examples:
Embodiment 1
Distribute material and measure its scraping and wiping resistance performance and the reference comparison by the different technology conditions preparation is low by preparation method of the present invention.
(1) take by weighing the elastomerics of 15 mass parts, the scrape resistant auxiliary agent of 0.6 mass parts mixed under 500 rev/mins rotating speed 2 minutes, mixed under 1500 rev/mins rotating speed 10 minutes again, obtained pre-composition;
(2) with (1) described pre-composition through the twin screw extruder extruding pelletization, obtain master batch, the twin screw extruder extrusion temperature is 150 ~ 170 ℃;
(3) take by weighing the polypropylene of 65 mass parts, the master batch of 15.6 mass parts, the scrape resistant auxiliary agent of 3.4 mass parts, the anti-oxidant auxiliary agent of 0.3 mass parts and under 500 rev/mins rotating speed, mixed 1 minute, under 2000 rev/mins rotating speed, mixed 10 minutes;
(4) superfine talcum powder that takes by weighing 20 mass parts is added in (3) described mixture, mixes under 500 rev/mins rotating speed 10 minutes, obtains mixture;
Take by weighing superfine talcum powder 20 mass parts and be added in (3) described mixture by formula rate, under 500 rev/mins rotating speed, mixed 10 minutes, obtain mixture;
(5) (4) described mixture is got product through the twin screw extruder extruding pelletization, extrusion temperature is 170 ~ 200 ℃.
After testing, this material scraping and wiping resistance performance, under 10N pressure, △ L value is 0.32.
Reference
(1) polypropylene 65 mass parts that take by weighing by formula rate, elastomerics 15 mass parts, scrape resistant auxiliary agent 4 mass parts, antioxidant 0.3 mass parts mixed under 500 rev/mins rotating speed 2 minutes, mixed under 2000 rev/mins rotating speed 12 minutes;
(2) take by weighing superfine talcum powder 20 mass parts by formula rate and be added in (1) described mixture, under 500 rev/mins rotating speed, mixed 8 minutes, obtain mixture;
(3) (2) described mixture is got product through the twin screw extruder extruding pelletization, extrusion temperature is 170 ~ 200 ℃.
After testing, this material scraping and wiping resistance performance, under 10N pressure, △ L value is 1.2.
Embodiment 2
(1) take by weighing the elastomerics of 5 mass parts, the scrape resistant auxiliary agent of 0.2 mass parts mixed under 300 rev/mins rotating speed 1 minute, mixed under 2000 rev/mins rotating speed 15 minutes again, obtained pre-composition;
(2) with (1) described pre-composition through the twin screw extruder extruding pelletization, obtain the elastomerics master batch, the twin screw extruder extrusion temperature is 150 ~ 170 ℃;
(3) take by weighing the polypropylene of mass parts 75, the master batch of 5.2 mass parts, the scrape resistant auxiliary agent of 3.8 mass parts, the anti-oxidant auxiliary agent of 0.3 mass parts and under 300 rev/mins rotating speed, mixed 1 minute, under 1500 rev/mins rotating speed, mixed 15 minutes;
(4) superfine talcum powder that takes by weighing 20 mass parts is added in (3) described mixture, mixes under 300 rev/mins rotating speed 8 minutes, obtains mixture;
(5) (4) described mixture is got product through the twin screw extruder extruding pelletization, extrusion temperature is 170 ~ 200 ℃.
After testing, this material scraping and wiping resistance performance, under 10N pressure, △ L value is 0.15.
Reference
(1) polypropylene 75 mass parts that take by weighing by formula rate, elastomerics 5 mass parts, scrape resistant auxiliary agent 4 mass parts, antioxidant 0.3 mass parts mixed under 500 rev/mins rotating speed 2 minutes, mixed under 2000 rev/mins rotating speed 12 minutes;
(2) take by weighing superfine talcum powder 20 mass parts by formula rate and be added in (1) described mixture, under 500 rev/mins rotating speed, mixed 8 minutes, obtain mixture;
(3) (2) described mixture is got product through the twin screw extruder extruding pelletization, extrusion temperature is 170 ~ 200 ℃.
After testing, this material scraping and wiping resistance performance, under 10N pressure, △ L value is 0.8.
Embodiment 3
(1) take by weighing the elastomerics of 20 mass parts, the scrape resistant auxiliary agent of 0.8 mass parts mixed under 400 rev/mins rotating speed 1.5 minutes, mixed under 1800 rev/mins rotating speed 12 minutes again, obtained pre-composition;
(2) with (1) described pre-composition through the twin screw extruder extruding pelletization, obtain the elastomerics master batch, the twin screw extruder extrusion temperature is 150 ~ 170 ℃;
(3) take by weighing the polypropylene of 60 mass parts, the master batch of 20.8 mass parts, the scrape resistant auxiliary agent of 3.2 mass parts, the anti-oxidant auxiliary agent of 0.3 mass parts and under 400 rev/mins rotating speed, mixed 1 minute, under 1500 rev/mins rotating speed, mixed 12 minutes;
(4) superfine talcum powder that takes by weighing 20 mass parts is added in (3) described mixture, mixes under 400 rev/mins rotating speed 9 minutes, obtains mixture;
Take by weighing the superfine talcum powder of 20 mass parts and be added in (3) described mixture by formula rate, under 400 rev/mins rotating speed, mixed 9 minutes, obtain mixture;
(5) (4) described mixture is got product through the twin screw extruder extruding pelletization, extrusion temperature is 170 ~ 200 ℃.
After testing, this material scraping and wiping resistance performance, under 10N pressure, △ L value is 0.5.
Reference
(1) polypropylene 60 mass parts that take by weighing by formula rate, elastomerics 20 mass parts, scrape resistant auxiliary agent 4 mass parts, antioxidant 0.3 mass parts mixed under 500 rev/mins rotating speed 2 minutes, mixed under 2000 rev/mins rotating speed 12 minutes;
(2) take by weighing 20 mass parts superfine talcum powders, 20 mass parts by formula rate and be added in (1) described mixture, under 500 rev/mins rotating speed, mixed 8 minutes, obtain mixture;
(3) (2) described mixture is got product through the twin screw extruder extruding pelletization, extrusion temperature is 170 ~ 200 ℃.
After testing, this material scraping and wiping resistance performance, under 10N pressure, △ L value is 1.3.
Claims (1)
1. the preparation method of a scrape resistant type elastic body toughening polypropylene composite material, described polypropylene composite material comprises polypropylene, mineral filler, the mixture of elastomerics, scrape resistant auxiliary agent, antioxidant; It is characterized in that getting earlier 5%-20% weight percentage scrape resistant auxiliary agent and elastomerics and make master batch, the scrape resistant auxiliary agent of surplus, master batch and other component blend extruding pelletizations, wherein elastomerics accounts for the 5%-20% of polypropylene, mineral filler and elastomerics three weight summation;
Concrete preparation process is as follows:
(1) elastomerics and 5%-20% weight percentage scrape resistant auxiliary agent mixed under 300 ~ 500 rev/mins rotating speed 1 ~ 3 minute, mixed under 1500 ~ 2000 rev/mins rotating speed 10 ~ 15 minutes again, obtained pre-composition;
(2) with (1) described pre-composition through the twin screw extruder extruding pelletization, obtain master batch, the twin screw extruder extrusion temperature is 150 ~ 170 ℃;
(3) take by weighing polypropylene, master batch by formula rate, the scrape resistant auxiliary agent of surplus, antioxidant mixed under 300 ~ 500 rev/mins rotating speed 1 ~ 2 minute, mixed under 1500 ~ 2000 rev/mins rotating speed 10-15 minute;
(4) take by weighing a certain amount of superfine talcum powder by formula rate and be added in (3) described mixture, under 300 ~ 500 rev/mins rotating speed, mixed 8 ~ 10 minutes, obtain mixture;
(5) (4) described mixture is got product through the twin screw extruder extruding pelletization, extrusion temperature is 170 ~ 200 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106038466A CN102061033B (en) | 2010-12-24 | 2010-12-24 | Method for preparing scratch resistant type elastomer toughening polypropylene composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010106038466A CN102061033B (en) | 2010-12-24 | 2010-12-24 | Method for preparing scratch resistant type elastomer toughening polypropylene composite material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102061033A true CN102061033A (en) | 2011-05-18 |
| CN102061033B CN102061033B (en) | 2012-08-22 |
Family
ID=43996546
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010106038466A Active CN102061033B (en) | 2010-12-24 | 2010-12-24 | Method for preparing scratch resistant type elastomer toughening polypropylene composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102061033B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103087399A (en) * | 2012-12-28 | 2013-05-08 | 宁波长华汽车装饰件有限公司 | High-toughness high-strength halogen-free flame-resistant polypropylene |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1990534A (en) * | 2005-12-28 | 2007-07-04 | 上海日之升新技术发展有限公司 | Process for preparing wear-resisting polypropene composite material for vehicle |
| WO2009092420A1 (en) * | 2008-01-25 | 2009-07-30 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer compositions |
| CN101845195A (en) * | 2010-05-07 | 2010-09-29 | 浙江俊尔新材料有限公司 | Wear-resistant thermoplastic elastomer and preparation method thereof |
| CN101864115A (en) * | 2010-06-03 | 2010-10-20 | 浙江俊尔新材料有限公司 | Scratch resistant and shock proof propylene-ethylene block copolymerization polypropylene modified material |
-
2010
- 2010-12-24 CN CN2010106038466A patent/CN102061033B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1990534A (en) * | 2005-12-28 | 2007-07-04 | 上海日之升新技术发展有限公司 | Process for preparing wear-resisting polypropene composite material for vehicle |
| WO2009092420A1 (en) * | 2008-01-25 | 2009-07-30 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer compositions |
| CN101845195A (en) * | 2010-05-07 | 2010-09-29 | 浙江俊尔新材料有限公司 | Wear-resistant thermoplastic elastomer and preparation method thereof |
| CN101864115A (en) * | 2010-06-03 | 2010-10-20 | 浙江俊尔新材料有限公司 | Scratch resistant and shock proof propylene-ethylene block copolymerization polypropylene modified material |
Non-Patent Citations (2)
| Title |
|---|
| 《polymer testing》 20070701 Thomas Koch etal. Evaluation of scratch resistance in multiphase PP blends 第928－929页 1 第26卷, 第7期 * |
| 《塑料工业》 20100120 范潇潇等 汽车内饰件用低气味耐刮擦聚丙烯的研制 第81页 第38卷, 第1期 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103087399A (en) * | 2012-12-28 | 2013-05-08 | 宁波长华汽车装饰件有限公司 | High-toughness high-strength halogen-free flame-resistant polypropylene |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102061033B (en) | 2012-08-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104235521B (en) | A kind of antimicrobial PE tube | |
| TW200920789A (en) | An elastomer composite and method for producing it | |
| CN103483658B (en) | Rubber compound high in safety performance of processing and technology thereof | |
| CN105713304B (en) | Pre-dispersed masterbatch particles of rubber accelerator tetrabutylthiuram disulfide and preparation method thereof | |
| CN102643480A (en) | Anti-static alloy composite material and preparation method thereof | |
| CN103770238A (en) | Novel production technology for carrier-free plastic filled modified master batch | |
| CN104072843B (en) | A kind of multiple dimensioned composite functional agglomerate and preparation method thereof | |
| CN102061033B (en) | Method for preparing scratch resistant type elastomer toughening polypropylene composite material | |
| CN102241853B (en) | Calcium-whisker-modified polyethylene composite material and preparation method thereof | |
| CN101817962B (en) | Polyvinyl chloride/epoxy resin blend and preparation method thereof | |
| CN104672885A (en) | TPV (thermoplastic vulcanizate) alloy material for bonding encapsulation of PETG (polyethylene terephthalate glycol) and preparation method of TPV alloy material | |
| CN101798407B (en) | Method for commixing vulcanized rubber powder produced by utilizing waste rubber and rubber plastic material | |
| CN104341710B (en) | Electronic equipment part wear-resisting anti-static composite material and preparation method thereof | |
| CN103113709A (en) | Special high-filling master batch for acrylonitrile butadiene styrene and preparation method thereof | |
| CN103772898B (en) | A kind of rub resistance POM material and preparation method thereof | |
| CN105017600A (en) | Tackifying master batch production process | |
| CN101531786B (en) | A black honed conductive plastic | |
| CN105602120B (en) | A kind of pre-dispersed masterbatch particles of rubber accelerator package and preparation method thereof | |
| CN106987048A (en) | A kind of POE talcum powder master batch | |
| CN103214734A (en) | Multifunctional polypropylene masterbatch and preparation method thereof | |
| CN102604248A (en) | Non-migration-type macromolecule conductive masterbatch applied to IC (integrated circuit) carrier tape material and preparation method of conductive masterbatch | |
| CN103113696B (en) | A kind of extrusion grade fluoroplastic compositions of supercritical CO 2 secondary process | |
| CN106967272B (en) | Preparation method of high-cohesiveness and high-strength PA encapsulating material | |
| CN102888076A (en) | Preparation process of self-lubricating wear-resistant injection molding molybdenum disulfide polyformaldehyde | |
| CN101792601A (en) | High-fluidity injection-level nylon 6 and preparation process thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Preparation method of scratch resistant elastomer toughened polypropylene composite material Granted publication date: 20120822 Pledgee: Zijin Branch of Nanjing Bank Co.,Ltd. Pledgor: NANJING JINSHAN AUTOMOBILE ENGINEERING PLASTIC Co.,Ltd. Registration number: Y2024980036131 |