The vehicular prosthetic appliance and the restorative procedure of a kind of contaminated site soil and body of groundwater
Technical field
The present invention relates to a kind of contaminated site soil/water body recovery technique equipment, belong to the environmental protection equipment field.
Background technology
At present, because the influence that developed rapidly by industrial or agricultural and industries such as the energy, traffic, the contaminated soil of China/groundwater level day of year benefit enlarges, and the ecosystem and human health have all been caused serious harm.Propelling along with suburbanization and counter urbanization process, a large amount of city enterprise implements resettlement, enterprise's number of China's closing down, suspending operations, merging with other plants, changing the products or moving the plants to other places in 2008 reaches 22488, these industrial waste places in process of production phenomenons such as " run, drip, leak " and various environmental accident can cause pollutant enter into the soil in place and underground water (document 1: Liao Xiaoyong etc. the urban industry contaminated site: Chinese contaminated environment is repaired the new problem in field. environmental science, 2011), form a large amount of contaminated sites, demand urgently repairing.In addition, the processes such as discharging accumulation of the adopting of a lot of mine developments, choosing, smelting, fortune and waste water and dregs all can cause a large amount of pollutants around entering into soil and underground water (document 2: Chou Rongliang etc. mine and surrounding area many metallic pollutions soil remediation progress. agricultural environment science journal, 2009,28 (6): 1085-1091); The farmland is dirty irritate the pollution problem that is caused also have in recent years a lot of reports (document 3: Chen Cuicui etc. Dunhua irrigated area, Taiyuan City heavy metal pollution of soil feature and evaluation. agricultural environment science journal, 2010,29 (supplementary issues): 069-073); The percolate and the solid waste gas of a lot of refuse landfills also can pollute surrounding soil and underground water; The leakage of gas station's gasoline etc. and the discharging of oil gas also make its peripheral soil and underground water also have pollution in various degree.Therefore, contaminated soil of China and underground water reparation have vast market demand and prospect.
At present, have a lot, comprise biological restoration, physics reparation and chemical repair method etc. at the method for contaminated soil/phreatic reparation.Biological renovation method mainly is the pollutant that utilizes in plant or microorganism absorption or the degraded soil/underground water; Physical method comprises the thermal desorption technology, soil aeration and gas phase extraction technique etc., thermal desorption is to make wherein organic pollution and special metal elements vaporization be converted into gas by heating soil, by special device pernicious gas is carried out the restorative procedure of harmless treatment again, soil aeration and gas phase extraction technique mainly are the methods that feeds fresh air and utilize extraction system that gas is extracted out by in contaminated soil/water body, discharge gaseous contaminant, reach the purpose of purification, better for the treatment effect of volatile organic contaminant; Chemical repair method comprises chemical leaching technology and chemical oxidation/reduction technique etc., chemical oxidation/reduction technique then is meant oxidant/reducing agent is injected pollution medium, make the pollutant in soil or the underground water destroyed within a short period of time by oxidation/reduction reaction, be degraded into nontoxic or endanger less material, can be applicable to petroleum like hydrocarbon, benzene, phenols, MTBE, chloro-carbon solvent, polycyclic aromatic hydrocarbon, the reparation of organic pollutions such as agricultural chemicals and some heavy metals that appraise at the current rate, the drip washing technology is a technology of utilizing surfactant or cosolvent to come wash-out or desorption pollutant, can be used for the reparation of organic matter or heavy-metal contaminated soil and water body.
When carrying out place original position reparation or the reparation of fairly large dystopy, need in contaminated soil or water body, add a large amount of preparation for repairing and (comprise chemical preparation for repairing, eluent and microorganism preparation for repairing etc.), but inject equipment owing to lack corresponding preparation for repairing at present, cause the enforcement of this class reparation also to have bigger difficulty.Mention in the Chinese patent application 200910061186 and utilize original position microwave recovery technique to administer soil pollution, just at topsoil.Mention the deoxidization, degradation of organic pollution in the acceleration soil such as utilizing Zero-valent Iron simple substance in the Chinese patent 200710026561.9, also be to draw the original position reparation that this method is applicable to the severe organic contaminated soil by the post experimental simulation, do not mention contaminated site, how preparation for repairing such as Zero-valent Iron are injected surrounding medium to be repaired in reality.Mention in contaminated soil and underground water in the Chinese patent 200710069637.6 and inject liquor potassic permanganate, hold back explosion pollution thing in district and the Polluted area, but also do not introduce concrete injection equipment and method by chemical oxide removal.Aspect the dystopy improvement of deep soil/phreatic original position reparation and large-scale contaminated soil/water body, how development and utilization effective for repairing equipment (comprises microorganism formulation with preparation for repairing, the chemistry preparation for repairing, eluents etc.) being added in the deep layer soil body/water body, is a key issue that needs solution.
The contaminated site prosthetic appliance of China comprises prosthetic appliances such as SOIL GAS is carried, chemical oxidation, thermal desorption, drip washing at present, rests on exploitation of scientific research equipment or experimental prototype pilot scale stage more, and the commercial application of prosthetic appliance seldom.Countries such as America and Europe have developed a lot of advanced persons' prosthetic appliance, but price is extremely expensive, and might not be adapted at China's application.The equipment of this patent invention can solve the problem of injecting preparation for repairing in original position or the dystopy repair process in deep layer contaminated soil/water body effectively, can improve remediation efficiency, have crucial meaning soil/further developing of field of underground water reparation for promoting China.
Summary of the invention
Technology of the present invention is dealt with problems: overcome the deficiencies in the prior art, provide a kind of portable, quick, economical, effectively can be used in contaminated soil or water body injecting the original position/transposition repaired item of preparation for repairing such as chemistry, biology, eluent.
Technical solution of the present invention: a kind of contaminated site soil and phreatic vehicular repaired item comprise: comprising: delivery lorry 1, dry powder hopper 2, level meter 3, motor 4 feeds intake, mixer 5, mixing tank 6, liquid level gauge 7, liquid preparation flowmeter 8, running water flowmeter 9, liquid preparation magnetic valve 10, entering water electromagnetic valve 11, liquid preparation adds pipeline 12, tap water pipe line 13, electrical control cubicles 14, touch screen operating 15, plunger displacement pump 16, mixed liquor output pipe 17, mixed liquor magnetic valve 18, Pressure gauge 19, mixed liquor flowmeter 20; Dry powder hopper 2 is irritated with batch mixing by the motor 4 that feeds intake and is connected, and level meter 3 is installed in the dry powder hopper 2, is used for the low level indication; The motor 4 that feeds intake is used for adding solid pharmaceutical preparation to mixing tank 6; Agitator 5 is vertically mounted in the mixing tank 6, is used to quicken the dry powder dissolving; Mixing tank 6 is used for dissolving, configuration, stores preparation for repairing, is positioned at motor 4 belows that feed intake, and adds pipeline 12 with liquid preparation and is connected; Liquid level gauge 7 is installed in a distance jar bottom in the mixing tank 6, is used for indicating the liquid of mixing tank whether to reach low level; Liquid preparation flowmeter 8 and running water flowmeter 9 are respectively applied for the flow that liquid is pumped in indication; Liquid preparation magnetic valve 10 and entering water electromagnetic valve 11 are respectively applied for the break-make that the control liquid preparation adds pipeline 12 and tap water pipe line 13, liquid preparation flowmeter 8 and liquid preparation magnetic valve 10 are installed in liquid preparation and add on the pipeline 12, and running water flowmeter 9 and entering water electromagnetic valve 11 are installed on the tap water pipe line 13; Tap water pipe line 13 1 ends are connected with the water source, and the other end communicates with mixing tank 6; Liquid preparation adds pipeline 12 1 ends and is connected with the liquid preparation jar, and the other end communicates with mixing tank 6; Tap water pipe line 13 and liquid preparation add pipeline 12 and are respectively applied for add entry and liquid preparation in mixing tank 6; Touch screen operating 15 and power supply on the electrical control cubicles 14, mixed liquor output pipe 17 and plunger displacement pump 16 link to each other, be used to control the operation of all facilities, solid pharmaceutical preparation is set to add automatically than 21, manual dosage 22 of solid pharmaceutical preparation and liquid preparation add automatically than 23, select the method for operation 24, it is automatic or manual, mode of operation 25, promptly on the spot or long-range, batching mode 26, be solid or liquid, start or stop automatic operation 27, and show solid pharmaceutical preparation dosage 28, flow of inlet water 29, liquid preparation flow 30, mixed liquor output pressure 31 and mixed liquor output flow 32; Plunger displacement pump 16 is installed in the electrical control cubicles next door, is connected with mixed liquor output pipe 17, is used for pumping outward the liquid of mixing tank 6; Mixed liquor output pipe 17 can be used for exporting preparation for repairing in specifying the stratum with after the high pressure ascending pipe is connected; Mixed liquor magnetic valve 18 is installed on the mixed liquor output pipe 17, is used to control the liquid preparation output port; Pressure gauge 19 and mixed liquor flowmeter 20 are installed on the mixed liquor output pipe 17, are used to indicate mixed liquor output pressure and mixed liquor output flow; Above-mentioned all building blocks all are fixed on the delivery lorry 1.
Described prosthetic appliance utilizes container fixing on delivery lorry 1, then container is connected with delivery lorry 1 by bolt, can move at any time as required.
Described prosthetic appliance is connected to the DCS of computer by wireless network, it is Distributed Control System, system is controlled, and utilize solid pharmaceutical preparation dosage, flow of inlet water, liquid preparation flow, mixed liquor output pressure and mixed liquor output flow in the whole injection process of computer record, play the effect of monitoring and statistics.
Top in described electrical control cubicles 14 is equipped with alarm, and when material was positioned at low level in the dry powder hopper 2, alarm can give the alarm, and reminds the operator to add materials; When liquid in the mixing tank 6 was positioned at low liquid level, alarm also can give the alarm, and plunger displacement pump 16 is out of service simultaneously, this moment, system can open entering water electromagnetic valve 11 automatically, and started feed intake motor 4 and mixer 5, began batching, when treating that liquid level attains to a high place in the mixing tank 6, plunger displacement pump 16 restarts; Need reset by fault in the touch screen operating 15 and stop alarm equipment alarm.
A kind of above-mentioned equipment reparation contaminated site soil and phreatic method utilized, performing step is as follows:
(1) with solid pharmaceutical preparation, promptly chemical preparation for repairing, eluent or microorganism preparation for repairing add in the dry powder hopper 2; Utilize the touch screen operating 15 on the electrical control cubicles 14 to carry out local operation, or system is carried out operated from a distance by the DCS that wireless network is connected to computer.After systematic parameter is set, start operation automatically, entering water electromagnetic valve 11 is opened automatically, feed intake motor 4 and mixer 5 starts automatically, begin to dispose the mixing material preparation, after the liquid in the mixing tank surpassed low level, plunger displacement pump 16 started automatically, exported the mixing material preparation with certain flow (10-1000L/h) by output pipe;
(2) liquid preparation is added pipeline 12 and be connected to the carrying liquid preparation, promptly chemical preparation for repairing, the container of eluent or microorganism preparation for repairing; Utilize on the electrical control cubicles 14 touch screen operating 15 to carry out local operation, or system is carried out operated from a distance by the DCS that wireless network is connected to computer.After systematic parameter is set, open liquid preparation magnetic valve 10, start operation automatically, entering water electromagnetic valve 11 is opened automatically, begin to dispose the mixing material preparation, after the liquid in the mixing tank surpassed low level, plunger displacement pump 16 started automatically, exported the mixing material preparation with certain flow (10-1000L/h) by output pipe.
The present invention's advantage compared with prior art is:
(1) equipment is realized pressurization injection preparation for repairing among the present invention, both can be used for the original position reparation and also can be used for the dystopy reparation, can not only be used for the soil remediation of contaminated site, also can be used for underground water pollution and administers.
(2) the present invention can be applied to chemical oxidation restorative procedure, repairing method of microorganism, the multiple recovery technique of chemical leaching method, in mixing tank, add solid oxidizer/reducing agent by the dry powder hopper, or add pipeline by liquid preparation and in mixing tank, add liquid oxidizer/reducing agent, the liquid microbial microbial inoculum, surfactant or cosolvent, add water or other solvent by tap water pipe line then, promptly can dispose the chemical oxidizing agent of desired concn as required, reducing agent, microorganism preparation for repairing, surfactant or cosolvent.
(3) the present invention is by regulating the operating frequency of pump, can be used for to the dissimilar and reparation different depth contaminated soil, for sandy soil and thin solum, the flow of pump can be turned down, and, then can reach the purpose of effective injection by the flow of the big pump of suitable accent for clayey soil and deep soil.
(4) the present invention is with the preparation for repairing configuration-system, pressurization injected system and control system are organically combined, by control system dry powder is added, liquid preparation adds, water inlet, stir, the pump startup process is carried out centralized Control, can also add ratio, the manual dosage of solid pharmaceutical preparation, liquid preparation automatically to solid pharmaceutical preparation adds automatically than being provided with and regulating, realize that the limit disposes marginal not and goes into, be not transported to the scene again and inject and do not need preparation for repairing configured, greatly saved time and expense.
(5) equipment that designs for vehicular of the present invention can move as required at any time, can save the expense of loading and unloading and transportation, and is economical and convenient.
(6) the present invention can monitor and write down solid pharmaceutical preparation dosage in the injection process at any time, flow of inlet water, and the liquid preparation flow, mixed liquor output pressure and mixed liquor output flow are convenient to regulation and control and statistics.
Description of drawings
Fig. 1 is theory of constitution figure of the present invention;
Fig. 2 is the theory of constitution figure of the touch screen operating on the electrical control cubicles of the present invention;
Fig. 3 is the theory diagram of DCS control system of the present invention.
The specific embodiment
As shown in Figure 1, the present invention adds pipeline 12, tap water pipe line 13, electrical control cubicles 14, touch screen operating 15, plunger displacement pump 16, mixed liquor output pipe 17, mixed liquor magnetic valve 18, Pressure gauge 19, mixed liquor flowmeter 20 by delivery lorry 1, dry powder hopper 2, level meter 3, the motor 4 that feeds intake, mixer 5, mixing tank 6, liquid level gauge 7, liquid preparation flowmeter 8, running water flowmeter 9, liquid preparation magnetic valve 10, entering water electromagnetic valve 11, liquid preparation; Dry powder hopper 2 is irritated with mixed liquor by the motor 4 that feeds intake and is connected, and described level meter 3 is installed in the dry powder hopper 2, is used for the low level indication; The motor 4 that feeds intake is used for adding solid pharmaceutical preparation to mixing tank 6; Mixer 5 is vertically mounted in the mixing tank 6, is used to quicken the dry powder dissolving; Mixing tank 6 is used for dissolving, configuration, stores preparation for repairing, is positioned at the motor below that feeds intake, and adds pipeline with liquid preparation and is connected; Liquid level gauge 7 is installed in the distance jar about 0.2m in an end place in the mixing tank 6, is used for indicating the liquid of mixing tank whether to reach low level; Liquid preparation flowmeter 8 and running water flowmeter 9 are respectively applied for the flow of indication input liquid preparation and running water, liquid preparation magnetic valve 10 and entering water electromagnetic valve 11 are respectively applied for the break-make that the control liquid preparation adds pipeline 12 and tap water pipe line 13, liquid preparation flowmeter 8 and liquid preparation magnetic valve 10 are installed in liquid preparation and add on the pipeline 12, and running water flowmeter 9 and entering water electromagnetic valve 11 are installed on the tap water pipe line 13; 13 1 of tap water pipe lines are connected with the water source, and the other end communicates with mixing tank, and liquid preparation adds 12 1 of pipelines and is connected with the liquid preparation jar, and the other end communicates with mixing tank; Tap water pipe line 13 and liquid preparation add pipeline 12 and are respectively applied for add entry and liquid preparation in mixing tank; Touch screen operating 15 and power supply on the electrical control cubicles 14, mixed liquor output pipe and plunger displacement pump link to each other, be used to control the operation of all facilities, as shown in Figure 2, solid pharmaceutical preparation can be set to add automatically than 21, manual dosage 22 of solid pharmaceutical preparation and liquid preparation add automatically than 23, select the method for operation 24, it is automatic or manual, mode of operation 25, promptly on the spot or long-range, batching mode 26, be solid or liquid, start or stop automatic operation 27, and show solid pharmaceutical preparation dosage 28, flow of inlet water 29, liquid preparation flow 30, mixed liquor output pressure 31 and mixed liquor output flow 32; Plunger displacement pump 16 is installed in the electrical control cubicles next door, is connected with mixed liquor output pipe 17, is used for pumping outward the liquid of mixing tank 6; Mixed liquor output pipe 17 is positioned at the container right side, after the high pressure ascending pipe is connected, can be used for exporting preparation for repairing in specifying the stratum; Mixed liquor magnetic valve 18 is installed on the mixed liquor output pipe 17, is used to control the preparation output port; Pressure gauge 19 and mixed liquor flowmeter 20 are installed on the mixed liquor output pipe 17, are used to indicate mixed liquor output pressure and mixed liquor output flow; Above-mentioned all building blocks all are fixed on the delivery lorry 1.
Utilize the present invention to revise the equipment repairing polluted soil or phreatic concrete grammar is: connect power supply, inlet pipeline, mixed liquor output pipe etc. if preparation type is a solid, then add solid pharmaceutical preparation in the dry powder hopper.Open the touch-screen power supply, login enters touch screen operating, selects manually operation/operation automatically.
(1) selects operation automatically, if preparation is a solid, solid pharmaceutical preparation then is set adds ratio automatically, open operation automatically, system opens the motor that feeds intake automatically, solid pharmaceutical preparation in the dry powder hopper is added in the mixing tank, open entering water electromagnetic valve simultaneously, in mixing tank, add running water, start mixer simultaneously, solid pharmaceutical preparation is fully dissolved, be configured to the oxidation preparation of set concentration.If preparation is a liquid, liquid preparation then is set adds ratio automatically, open operation automatically, system opens the liquid preparation magnetic valve automatically, and liquid preparation is added in the mixing tank, opens entering water electromagnetic valve simultaneously, in mixing tank, add running water, start mixer simultaneously, liquid preparation is fully diluted, be configured to the oxidation preparation of set concentration.When liquid in the mixing tank surpassed low level, system can start the plunger displacement pump injection of pressurizeing automatically.
(2) select manually operation, when preparation is solid, set the manual dosage of solid pharmaceutical preparation, the manually opened entering water electromagnetic valve and the motor that feeds intake, the motor that feeds intake can feed intake according to manual dosage of solid pharmaceutical preparation and flow of inlet water, opens 1# and 2# mixer, fully mixes.When preparation was liquid, manually opened entering water electromagnetic valve and liquid preparation magnetic valve according to flow of inlet water regulator solution body preparation flow, made the concentration that liquid preparation is diluted to be needed, and open 1# and 2# mixer, fully mix.When showing on the display screen that liquid level is higher than low low level, can manually boot 1# or the 2# plunger displacement pump injects.
As shown in Figure 3, the DCS control system adopts the wireless ethernet mode to be connected with the contaminated site repaired item, utilizes the wireless network card of computer and the wireless access device of contaminated site repaired item to carry out wireless connections, and step is as follows:
(1) checks " power " and " LAN " indicator lamp that pollutes the wireless access device on the repaired item, just often answer " bright ";
(2) under computer C packing catalogue, set up the file that is called " db ", program and database are installed under this catalogue;
(3) forbidding all except that wireless network card connect the attribute setting that enters wireless network card;
(4) find wireless access, and connect;
(5) enter the DCS system, method of operating is identical with the method for touch-screen system.
Embodiment 1:
Utilize the automatic method of operation to the following 4.5-5.5m in the face of land, coke-oven plant, 7-10m is two-layer to be subjected to inject in the polycyclic aromatic hydrocarbons contaminated serious soil of high concentration solid pharmaceutical preparation potassium permanganate.
Connect power supply, inlet pipeline, mixed liquor output pipe.Opening power, login enters touch screen operating, and systematic parameter is set, and selections preparation type is a solid, and selecting the method for operation be to move automatically, and the setting solid pharmaceutical preparation adds automatically than being 15 ‰.In the dry powder hopper, add potassium permanganate, open operation automatically, system opens entering water electromagnetic valve automatically, in mixing tank, add running water, open the motor that feeds intake simultaneously, the solid pharmaceutical preparation in the dry powder hopper is added in the mixing tank, and start mixer, solid pharmaceutical preparation is fully dissolved, be configured to concentration and be 15 ‰ oxidation preparation.When liquid in the mixing tank surpassed low level, system can start the plunger displacement pump injection of pressurizeing automatically.Flow of inlet water is 500L/h, and after then equipment moved beginning 1.6h automatically, liquid surpassed low level in the reservoir, and plunger displacement pump starts automatically.
When the mixed liquor output pipe is connected to 4.5-5.5m and injects well, the delivery efficiency of plunger displacement pump is adjusted to 50%, promptly the mixed liquor output flow is 500L/h, accumulative total is injected 24h and can be injected 12m to this well
3Concentration is the liquor potassic permanganate of 15g/L, and the average removal rate of PAHs is 94.91% in the 0-7m soil.
When the mixed liquor output pipe is connected to 7-10m and injects well, the delivery efficiency of plunger displacement pump is adjusted to 100%, promptly the mixed liquor output flow is 1000L/h, accumulative total is injected 24h and can be injected 24m to this well
3Concentration is the liquor potassic permanganate of 15g/L; The clearance of PAHs can reach 90.57% in the 7-10m soil.
Embodiment 2:
Utilize the manual method of operation to be subjected to inject in the polycyclic aromatic hydrocarbons contaminated soil of high concentration liquid preparation hydrogen peroxide (concentration is 30%) to the following 4.5-5.5m in the face of land, coke-oven plant.
Connect power supply, inlet pipeline, mixed liquor output pipe.Opening power, login enters touch screen operating, and systematic parameter is set, and the selection preparation type is a liquid, and the method for operation is that manually flow of inlet water is 500L/h, and regulator solution body preparation flow is 500L/h.Open entering water electromagnetic valve and liquid preparation magnetic valve, in mixing tank, add running water, add the liquid preparation hydrogen peroxide simultaneously, open mixer, make the abundant mixing of hydrogen peroxide and water, be configured to 30% oxidation preparation.Behind the equipment operation beginning 0.8h, liquid surpasses low low level in the reservoir, manually boots plunger displacement pump.The mixed liquor output pipe is connected to the injection well, the delivery efficiency of plunger displacement pump is adjusted to 50%, promptly the mixed liquor output flow is 500L/h.Accumulative total is moved 12h, injects 6m in this well
3Concentration is 30% hydrogen peroxide solution, and the clearance of PAHs is 53.1% in the soil.
The non-elaborated part of the present invention belongs to techniques well known.