CN102040273A - Method for inhibiting growth of cyanobacteria - Google Patents
Method for inhibiting growth of cyanobacteria Download PDFInfo
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- CN102040273A CN102040273A CN2009102357741A CN200910235774A CN102040273A CN 102040273 A CN102040273 A CN 102040273A CN 2009102357741 A CN2009102357741 A CN 2009102357741A CN 200910235774 A CN200910235774 A CN 200910235774A CN 102040273 A CN102040273 A CN 102040273A
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Abstract
The invention discloses a method for inhibiting the growth of cyanobacteria, comprising the following steps of: 1, acidification on a water body to be processed: charging CO2 gas into an inoculated alga solution, and acidifying the alga solution by utilizing the characteristic that CO2 and water react to generate H<+> so that the pH value of the alga solution can reach a preset acidity; 2, continuous CO2 charging: regularly charging CO2 into the alga solution in the daily light period so that the pH value of the alga solution can reach the preset acidity after the acidification process starts; and 3, charging pause: stopping CO2 charging when the alga solution is changed to be almost clear from aqua before CO2 charging and the value of chlorophyll a is close to 0 or the inhibition effect does not change remarkably with the acidifying treatment time, wherein the step 2 further comprises a step of monitoring the pH value of the alga solution and the chlorophyll a: measuring the pH value of the alga solution and the chlorophyll a before CO2 charging every day. By utilizing a method of using CO2 to acidify alga growth environment to inhibit the growth of the cyanobacteria, the invention can effectively inhibit the growth of the cyanobacteria with strong practical operability and does not have the problem of secondary pollution.
Description
Technical field
The present invention relates to the eutrophy lake and administer technical field, relate in particular to the technical field that suppresses blue algae growth.
Technical background
In recent years, along with the development and use of the quick increase of the continuous development of society, population and lake resource and water resources is prevented and treated relative deficiency, lake pollution is on the rise, and wherein emphasis lakes such as Dian Chi, Chaohu and Taihu Lake are particularly serious.The outburst of wawter bloom then is a principal character of lake severe contamination.The outburst of wawter bloom makes that water taste becomes that raw meat is smelly, the DO reduction of profundal zone, the release of toxic substance, the increase that influences water supply quality and water purification cost, the variation of aquatic ecological.Wherein the easiest formation wawter bloom, range of influence is the widest, toxicity is the strongest is the Cyanophyta algae.Blue-green algae is a kind of former at first ancient algae prokaryotic organism, often breeds in a large number summer, and there is the floating foam of stench flavor corrupt dead back in water surface formation one deck blue-greenish colour.In the lake of outburst blue-green alga bloom, dominant population is generally microcystis kutz or Anabaena, and in addition, the algae toxin toxicity that microcystic aeruginosa produced in the microcystis kutz is maximum.Therefore, about how controlling and remove the problem that algae in the polluted lake and algae toxin have become numerous Chinese scholars researchs effectively.
The most frequently used control algae and algae removal technology generally can be divided into chemical technology, physical technique and biotechnology at present.
Chemical algae removing technology: control the algae grows breeding by throw in chemicals (as the weedicide on copper sulfate and ferrous sulfate, titanium dioxide bromine, some wide spectrum meanings etc.) to water body.Though this method is simple and easy to do, time saving and energy saving, this method can not fundamentally be improved water quality, and is opposite, along with getting more and more of dosage, the continuous replacing of pharmacy variety, to second environmental pollution also in continuous increase, thereby make water quality environment form serious vicious cycle.
The physics algae removal technology: that uses in many supplying drinking waters waters (as reservoir) at present is many, comprises that mainly the clay flocculation removes algae, mechanical process except that algae, microfiltration membrane and gac and the method for dredging is removed algae etc.And to utilize gac to remove Microcystin (MC) also be each Running-water Company method relatively more commonly used at present.This method can directly reduce TN and the TP that is accumulated in the bed mud of top layer to a certain extent, but microorganism and living environment thereof that gathering nitrogen phosphorus function is arranged in the destructible bed mud cause most of the nitrogen phosphorus can't be built up in the bottom, lake, and be dissolved in the lake water.
Biological algae removal technology: utilize cultivate biological or cultivate, the vital movement of the biology of inoculation, to water pollutant transform, degraded and transferance, thereby water body environment health is restored.But use this method might cause beyond thought secondary pollution.As Chinese patent (publication number: CN101134623) proposed a kind of method of comprehensive treatment of polluted water by inhibiting growth of blue algae.This method comprises: on contaminated waters, become " Lian Chi " with float type fence circle, " Lian Chi " cast anchor is fixed on the water surface breeding Herba Eichhorniae in " Lian Chi "; Control Herba Eichhorniae breeding quantity is in time salvaged the Herba Eichhorniae of " superfluous relatively "; To salvage the Herba Eichhorniae of " superfluous relatively ", can be used for increasing newly " Lian Chi " breeding breeding, also can produce biogas, as the new forms of energy raw material through anaerobically fermenting.Though this method has reduced the nitrogen and phosphorus content in the lake water to a certain extent, how to salvage the Herba Eichhorniae that covers with to suffering from and but become problem demanding prompt solution.
More than three kinds of traditional methods starting point of administering wawter blooms be with the algae be direct object (physical method removes algae, chemical agent kills algae) or indirectly object (biological method removes N, P) control and remove.These traditional methods all reach purpose except that algae in short-term, but in the long run, the drawback that these methods show makes it to become the effective ways except that algae.Therefore, the research theme that to seek a kind of effective and favourable algae control method be Chinese scholars.
Present numerous scholar mostly carries out the research of algal control around the influence factor of algal grown.The influence factor of algal grown comprises illumination, temperature, pH, nutritive salt, CO
2Etc. condition, and temperature, N/P ratio, pH value are considered to influence most important, the most basic environmental factor of Microcystis aeruginosa growth.The same with other influence factors, to be studied comparatively thoroughly by people about pH to the influence of algal grown, research thinks that various algal growns all have its suitable pH value scope, pH influences the algae grows reproduction speed, and then has influence on the succession of kind; PH all produces certain influence for composition and the scale of plant plankton, generally speaking, and blue-green algae preference higher pH.Yet the mode that changes change pH values in these processs of the test is chemical reagent such as using NaOH, HCl, and is that the contrast condition obtains different inhibition degree with the initial value that changes pH mostly.This is the shortage actual operation for utilization change pH administers actual pollution for the principle of condition inhibition algal grown lake.
Summary of the invention
Order of the present invention is to provide a kind of method that suppresses blue algae growth, does not need to use the soda acid chemical reagent, the growth of blue-green algae in the inhibition rich lake that just can be effective and favourable.
For achieving the above object, the present invention proposes a kind of method that suppresses blue algae growth, comprises the steps: step 1: staying water is carried out acidifying: feed CO to postvaccinal algae liquid
2Gas utilizes CO
2Produce H with the water reaction
+Characteristic algae liquid is carried out acidifying, make algae liquid pH reach a predefined acidity; Step 2: ventilation continuously: after acidification began, regularly to the ventilation of algae liquid, pH reached predefined acidity to algae liquid between the photoperiod of every day; Step 3: end ventilation: the light green before algae liquid is by ventilation fades near clarification, and the value of chlorophyll a approaches 0, perhaps suppresses effect and with the acidification time considerable change does not take place, and stops ventilation.
Wherein, the step that also comprises monitoring algae liquid pH and chlorophyll a in step 2: to pH and the chlorophyll a of algae liquid measure before the ventilation every day.
Wherein, in step 1, described predefined acidity be pH below 6.5, preferably, described predefined acidity is that pH value is between 6.0~6.5.
Wherein, in step 2, the ventilatory frequency of every day depends on the variation of algae liquid pH between photoperiod, if actual measurement pH value deducts the difference of setting pH value greater than more than 0.2 before the ventilation, then increase ventilatory frequency, the pH that makes algae liquid between photoperiod with the pH maximum difference of setting less than 0.2.
Wherein, in step 2,, increase gas flow rate along with the continuous reduction of pH.
Wherein, in step 1, when frond begins to enter logarithmic phase in the water, feed CO to postvaccinal algae liquid
2Gas.
Wherein, in step 1, if desire to make blue-green algae inactivation in the algae liquid, then with water acidification to pH≤6.0; Blue-green algae stopped growing in for some time in the algae liquid if only need, then with water acidification to pH about 6.5.
Wherein, in step 3, suppressing effect, with the acidification time considerable change not to take place be that the value that considerable change or chlorophyll a no longer take place for the color of algae liquid tends towards stability.
Wherein, ventilate every day during photosynthesis, and ventilatory frequency is 2~4 times/day.
Preferably, every day, ventilatory frequency was 2~4 times/day (about unanimities of the timed interval of each ventilation treatment between the every day photoperiod, and it is evenly distributed between photoperiod.If ventilatory frequency is 4 times, ventilate from 7 of mornings, should or ventilate in 4 hours every 3 so).
And in step 2, the continuous reduction along with pH should increase gas flow rate so that pH at short notice (within 30 minutes) reach the acidity level of setting.Specifically, desire to make pH to reduce to 6.5, generally ventilate with the flow velocity about 40ml/min by value greater than 6.5; If desire to make pH reduce to 6.0 again, then need flow velocity is increased to the 80ml/min; And if make pH reduce to 5.5 by 6.0, then need flow velocity is increased to more than the 100ml/min.
In addition, in step 1, frond enters logarithmic phase at the beginning in the water, just feeds CO to postvaccinal algae liquid
2Gas, best results; Feeding also has certain effect stationary phase, but effect is relatively poor than logarithmic phase.
Effect of the present invention:
Method of the present invention is utilized CO
2The method of acidifying algal grown environment suppresses blue algae growth, can suppress the growth of blue-green algae effectively, and actual operation is strong, and does not have the secondary pollution problem.
Description of drawings
Fig. 1 suppresses the block diagram of blue algae growth method for the present invention;
Fig. 2 is the chlorophyll a variation diagram in time of the embodiment of the invention 1 empty groove and acidifying groove;
Fig. 3 is the chlorophyll a variation diagram in time of the embodiment of the invention 2 empty grooves and acidifying groove;
Fig. 4 is the chlorophyll a variation diagram in time of the embodiment of the invention 3 empty grooves and acidifying groove.
Embodiment
The method that traditional use acid-base reagent is regulated pH has been abandoned in this research, by different CO
2Air flow obtains different pH, and then investigates the influence of different pH to the microcystic aeruginosa growth, suppresses the growth of blue-green algae in the water.
Fig. 1 suppresses the block diagram of blue algae growth method for the present invention, as shown in Figure 1, and the CO that utilizes proposed by the invention
2The method that suppresses blue algae growth is as follows:
Step 1: staying water is carried out acidifying: feed CO to postvaccinal algae liquid
2Gas utilizes CO
2Produce H with the water reaction
+Characteristic algae liquid is carried out acidifying, make algae liquid pH reach a predefined acidity;
Step 2: ventilation continuously: after acidification began, regularly to the ventilation of algae liquid, pH reached predefined acidity to algae liquid between the photoperiod of every day;
Step 3: end ventilation: the light green before algae liquid is by ventilation fades near clarification, and the value of chlorophyll a approaches 0, perhaps suppresses effect and with the acidification time considerable change does not take place, and stops ventilation.
Wherein, in step 2, also can comprise the step of a monitoring algae liquid pH and chlorophyll a: to pH and the chlorophyll a of algae liquid measure before the ventilation every day.
Particularly, in step 1, enter the logarithmic phase beginning to solution (postvaccinal algae liquid) ventilation, utilize CO from algae
2Produce H with the water reaction
+Characteristic algae liquid is carried out acidifying, algae liquid pH is reached below 6.5, in addition, consider that other hydrobionts in the actual lake such as fish are also comparatively responsive to the variation of pH, preferably, it is 6.0~6.5 more suitable that pH is transferred to.
In step 2, in acidization, every day, regularly (before the ventilation) measured the pH of algae liquid and the value of chlorophyll a, grasped the variation of pH and must adjust ventilatory frequency with suitable; Monitoring to chlorophyll a then is in order to understand the algae grows situation and to be subjected to the inhibition degree, with the time of determining to stop to ventilate.
And, in step 2, the ventilatory frequency of every day depends on the variation of algae liquid pH between photoperiod, if the pH of actual measurement has departed from the pH value of setting (actual measurement pH value deducts the difference of setting pH value greater than more than 0.2) at short notice significantly before ventilating for the second time, then increase ventilatory frequency, make pH farthest approaching pH (both are advisable less than 0.2 by maximum difference) that sets between photoperiod of algae liquid; Otherwise, then need not to increase ventilatory frequency.In addition, in venting process, note to adjust gas flow rate, the continuous reduction along with pH should increase gas flow rate so that pH at short notice (within 20 minutes) reach the acidity level of setting.Specifically, desire to make pH to reduce to 6.5, generally ventilate with the flow velocity about 40ml/min by value greater than 6.5; If desire to make pH reduce to 6.0 again, then need flow velocity is increased to the 80ml/min; And if make pH reduce to 5.5 by 6.0, then need flow velocity is increased to more than the 100ml/min.
In step 3, light green before algae liquid is by ventilation fades to and is close to clarification, the value of chlorophyll a approaches 0, illustrate that then the algae in the algae liquid obtains good restraining, or suppress effect with the generation considerable change of acidification time, as, the value that considerable change or chlorophyll a no longer take place the color of algae liquid tends towards stability, and stops ventilation this moment.
In addition, in step 1, if desire to make blue-green algae inactivation in the algae liquid, then with water acidification to pH≤6.0; Blue-green algae stopped growing in for some time in the algae liquid if only need, then with water acidification to pH between 6.0~6.5, preferable about 6.5.
And preferably, every day, ventilatory frequency was 2~4 times/day (about unanimities of the timed interval of each ventilation treatment between the every day photoperiod, and it is evenly distributed between photoperiod.If ventilatory frequency is 4 times, ventilate from 7 of mornings, should or ventilate in 4 hours every 3 so).
Below describe enforcement of the present invention in detail by specific embodiment, purpose is help to understand spirit of the present invention, but not as the qualification to the scope of the present invention.
Embodiment 1:
This test is provided with a blank groove (not air channel) and an acidifying groove (air channel).
1, algal species cultivation: the microcystic aeruginosa algae kind that 1L1 is in logarithmic phase inserts the tank of the M11 nutrient solution that 10L is housed, and (be of a size of among 40mm * 25mm * 30mm) and cultivate, algae liquid concentration is about 10
6Cell/L.Culture condition is: illumination 2000lx, 27 ℃ of temperature, Light To Dark Ratio 14: 10.
2, nutrient solution acidifying: began solution is carried out acidification at second day that cultivates, the pH of setting is 6.0.
3, continue ventilation: ventilatory frequency is 2 times/day, is respectively 10:00 and the 16:00 of every day.Each ventilation treatment to pH value of solution reaches at 6.0 o'clock to be stopped.
4, monitoring nutrient solution pH and chlorophyll a: pH and the chlorophyll a of measuring solution before and after ventilation every day.The pH value that the result shows algae liquid in the acidifying groove by being raised to about 7.0 6.0 of 4 o'clock noons before that day, changed greatlyyer before 10 ventilations every day, reached about 6.0 again after ventilation; Rose again before the ventilation at 4 o'clock in afternoon, rise to about 6.3, after ventilation, return back to about 6.0 again.In whole culturing process, the chlorophyll a in the blank groove all is higher than the acidifying groove.Fig. 2 is the chlorophyll a variation diagram in time of embodiment 1 empty groove and acidifying groove, as shown in Figure 2, from logarithmic phase (the postvaccinal second day) beginning of growth curve, the chlorophyll difference of two grooves constantly increases, reach intimate steady state to (beginning in the 15th day) this difference of growing stationary phase, reached maximum value 32.56% at 19 days that cultivate.
5, end ventilation: extremely the chlorophyll a in the 20th day acidifying groove of cultivating and the difference of the chlorophyll a in the blank groove tend towards stability, and solution is shoaled by the light green before ventilating in the acidifying groove, near clarifying, stop ventilation.
Embodiment 2:
This test is provided with a blank groove (not air channel) and three acidifying grooves (air channel).
1, algal species cultivation: the microcystic aeruginosa algae kind that 1L is in logarithmic phase inserts the M11 nutrient solution that 10L is housed, and (prescription of M11 nutrient solution contains NaNO for it consists of in the 1L deionized water
3100mg, K
2HPO
410mg, MgSO
47H
2O75mg, CaCl
22H
2O40mg, Na
2CO
320mg, ironic citrate 6mg, Na
2EDTA2H
2O1mg.This experiment replaces deionized water to get rid of the interference of bacterium to greatest extent with high purity water) tank (be of a size of among 40mm * 25mm * 30mm) and cultivate, algae liquid concentration is about 10
6Cell/L.Culture condition is: illumination 2000lx, 27 ℃ of temperature, Light To Dark Ratio 14: 10.
2, nutrient solution acidifying: solution carries out acidification in second day that cultivates begins three grooves, and it is 5.5,6.0 and 6.5 that the pH of setting is respectively.
3, continue ventilation: ventilatory frequency is 4 times/day, is respectively 7:00,10:00,13:00 and the 16:00 of every day.The pH of solution reaches to 5.5,6.0 respectively and stopped in 6.5 o'clock in each ventilation treatment to three groove.
4, monitoring nutrient solution pH and chlorophyll a: pH and the chlorophyll a of measuring solution before and after ventilation every day, the result shows: the pH in the illumination period three every day acidifying groove and the pH difference of setting are little, Fig. 3 is the chlorophyll a variation diagram in time of embodiment 2 empty grooves and acidifying groove, as shown in Figure 3, from logarithmic phase (the postvaccinal second day) beginning of growth curve, the value of chlorophyll a constantly increases in the blank groove, and the value of chlorophyll a changes not quite in three acidifying grooves, tends to be steady.
5, end ventilation: extremely the chlorophyll a in the 11st day three acidifying grooves cultivating is near 0, and solution becomes clarification by the light green before ventilating, and think that effect of algae restraint is good this moment, stops to ventilate.
Embodiment 3:
This test is provided with a blank groove (not air channel) and three acidifying grooves (air channel).
1, algal species cultivation: the microcystic aeruginosa algae kind that 1L is in logarithmic phase inserts the M11 nutrient solution that 10L is housed, and (prescription of M11 nutrient solution contains NaNO for it consists of in the 1L deionized water
3100mg, K
2HPO
410mg, MgSO
47H
2O75mg, CaCl
22H
2O40mg, Na
2CO
320mg, ironic citrate 6mg, Na
2EDTA2H
2O1mg.This experiment replaces deionized water to get rid of the interference of bacterium to greatest extent with high purity water) tank (be of a size of among 40mm * 25mm * 30mm) and cultivate, algae liquid concentration is about 10
6Cell/L.Culture condition is: illumination 2000lx, 27 ℃ of temperature, Light To Dark Ratio 14: 10.
2, nutrient solution acidifying: solution carries out acidification in the 15th day (beginning to enter the time of stationary phase) cultivating begins three grooves, and it is 5.5,6.0 and 6.5 that the pH of setting is respectively.
3, continue ventilation: ventilatory frequency is 3 times/day, is respectively 8:00,12:00, the 16:00 of every day.The pH of solution reaches to 5.5,6.0 respectively and stopped in 6.5 o'clock in each ventilation treatment to three groove.
4, monitoring nutrient solution pH and chlorophyll a: pH and the chlorophyll a of measuring solution before and after ventilation every day, the result shows: the pH in the illumination period three every day acidifying groove and the pH difference of setting are little, Fig. 4 is the chlorophyll a variation diagram in time of embodiment 3 empty grooves and acidifying groove, as shown in Figure 4, from beginning stationary phase (postvaccinal the 15th day) of growth curve, the value of chlorophyll a is in maximum and tends towards stability in the blank groove, and the value of chlorophyll a changes and differs in three acidifying grooves, wherein the condition of pH=6.5 is not obvious to the restraining effect of microcystic aeruginosa, and the condition of pH=6.0 and pH=5.5 has certain restraining effect to microcystic aeruginosa, pH=6.0 after ventilation treatment, the maximum reduction of chlorophyll a is respectively 9.83% in the acidifying groove of pH=5.5,24.03%, and tangible frond sinkage all appears, obvious layering takes place in material in the groove, pH be 5.5 acidifying groove degree the most very, the upper strata nutrient solution is almost clear state.
5, end ventilation: the chlorophyll a to the 23rd day three acidifying grooves cultivating does not continue to take place considerable change, stops ventilation.
The present invention utilizes CO
2The method of acidifying algal grown environment suppresses blue algae growth, and the technical program can suppress the growth of blue-green algae effectively, and actual operation is strong, and does not have the secondary pollution problem.In addition, CO
2Present exactly topmost greenhouse gases, a large amount of dischargings of greenhouse gases can cause global warming, thereby bring unpredictable disaster for the Human's production activity.Therefore, utilize CO
2Administer with serious pollution blue-green alga bloom, realized turning waste into wealth, improved environmental problem greatly.
Certainly; the present invention also can have other various embodiments; under the situation that does not deviate from spirit of the present invention and essence thereof; those of ordinary skill in the art work as can make various corresponding changes and distortion according to the present invention, but these corresponding changes and distortion all should belong to the protection domain of the appended claim of the present invention.
Claims (10)
1. a method that suppresses blue algae growth is characterized in that, may further comprise the steps:
Step 1: staying water is carried out acidifying: feed CO to postvaccinal algae liquid
2Gas utilizes CO
2Produce H with the water reaction
+Characteristic algae liquid is carried out acidifying, make algae liquid pH reach a predefined acidity;
Step 2: ventilation continuously: after acidification began, regularly to the ventilation of algae liquid, pH reached predefined acidity to algae liquid between the photoperiod of every day;
Step 3: end ventilation: the light green before algae liquid is by ventilation fades near clarification, and the value of chlorophyll a approaches 0, perhaps suppresses effect and with the acidification time considerable change does not take place, and stops ventilation.
2. the method for inhibition blue algae growth according to claim 1 is characterized in that, also comprises the step of monitoring algae liquid pH and chlorophyll a in step 2: to pH and the chlorophyll a of algae liquid measure before the ventilation every day.
3. the method for inhibition blue algae growth according to claim 1 is characterized in that, in step 1, described predefined acidity is that pH is below 6.5.
4. the method for inhibition blue algae growth according to claim 3 is characterized in that, described predefined acidity is that pH value is between 6.0~6.5.
5. the method for inhibition blue algae growth according to claim 2, it is characterized in that, in step 2, the ventilatory frequency of every day depends on the variation of algae liquid pH between photoperiod, if actual measurement pH value deducts the difference of setting pH value greater than more than 0.2 before the ventilation, then increase ventilatory frequency, the pH that makes algae liquid between photoperiod with the pH maximum difference of setting less than 0.2.
6. the method for inhibition blue algae growth according to claim 1 is characterized in that, in step 2, along with the continuous reduction of pH, increases gas flow rate.
7. the method for inhibition blue algae growth according to claim 1 is characterized in that, in step 1, when frond begins to enter logarithmic phase in the water, feeds CO to postvaccinal algae liquid
2Gas.
8. the method for inhibition blue algae growth according to claim 1 is characterized in that, in step 1, if desire to make blue-green algae inactivation in the algae liquid, then with water acidification to pH≤6.0; Blue-green algae stopped growing in for some time in the algae liquid if only need, then with water acidification to pH about 6.5.
9. the method for inhibition blue algae growth according to claim 1 is characterized in that, in step 3, suppressing effect, with the acidification time considerable change not to take place be that the value that considerable change or chlorophyll a no longer take place for the color of algae liquid tends towards stability.
10. the method for inhibition blue algae growth according to claim 5 is characterized in that ventilate every day during photosynthesis, ventilatory frequency is 2~4 times/day.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102616932A (en) * | 2012-03-27 | 2012-08-01 | 东南大学 | Algae-laden water treatment method and application system thereof |
CN105621546A (en) * | 2016-02-03 | 2016-06-01 | 安徽乙地生态科技有限公司 | Method for controlling cyanobacterial bloom |
CN113016802A (en) * | 2021-02-25 | 2021-06-25 | 南京大学 | Application of fumaric acid in inhibiting growth of blue-green algae |
CN114671546A (en) * | 2022-04-02 | 2022-06-28 | 中国科学院水生生物研究所 | Method for removing algae in water body by enhanced coagulation for eliminating algae-derived organic matter inhibition |
-
2009
- 2009-10-23 CN CN2009102357741A patent/CN102040273A/en active Pending
Non-Patent Citations (1)
Title |
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王欣等: "由CO2浓度差异导致的溶液pH变化对铜绿微囊藻生长的影响", 《中国环境科学学会2009年学术年会论文集(第一卷)》 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102616932A (en) * | 2012-03-27 | 2012-08-01 | 东南大学 | Algae-laden water treatment method and application system thereof |
CN105621546A (en) * | 2016-02-03 | 2016-06-01 | 安徽乙地生态科技有限公司 | Method for controlling cyanobacterial bloom |
CN113016802A (en) * | 2021-02-25 | 2021-06-25 | 南京大学 | Application of fumaric acid in inhibiting growth of blue-green algae |
CN114671546A (en) * | 2022-04-02 | 2022-06-28 | 中国科学院水生生物研究所 | Method for removing algae in water body by enhanced coagulation for eliminating algae-derived organic matter inhibition |
CN114671546B (en) * | 2022-04-02 | 2023-11-03 | 中国科学院水生生物研究所 | Method for removing algae in water body by reinforced coagulation by eliminating inhibition of algae-derived organic matters |
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