CN102029106A - Calcium-based CO2 (carbon dioxide) absorbance furnace - Google Patents

Calcium-based CO2 (carbon dioxide) absorbance furnace Download PDF

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Publication number
CN102029106A
CN102029106A CN201010521871XA CN201010521871A CN102029106A CN 102029106 A CN102029106 A CN 102029106A CN 201010521871X A CN201010521871X A CN 201010521871XA CN 201010521871 A CN201010521871 A CN 201010521871A CN 102029106 A CN102029106 A CN 102029106A
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China
Prior art keywords
furnace body
absorption reaction
furnace
cyclone separator
reaction furnace
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Pending
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CN201010521871XA
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Chinese (zh)
Inventor
吴福儿
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University of Shaoxing
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University of Shaoxing
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Publication date
Application filed by University of Shaoxing filed Critical University of Shaoxing
Priority to CN201010521871XA priority Critical patent/CN102029106A/en
Publication of CN102029106A publication Critical patent/CN102029106A/en
Pending legal-status Critical Current

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Abstract

The invention discloses a calcium-based CO2 (carbon dioxide) absorbance furnace which is used in the technical field of recovery of carbon dioxide for coal-fired boilers, and is characterized by comprising a furnace body of an absorption reaction furnace, wherein a limestone feed port and a burner are mounted on one side of the furnace body of the absorption reaction furnace body, a flue gas input port is oppositely mounted on the other side of the furnace body, a discharge port is mounted at the bottom of the furnace body, a cyclone separator is mounted on one side of the furnace body and communicated with the absorption reaction furnace, a flue gas outlet is arranged at the top of the cyclone separator, a discharge port and a blow-down pipe are arranged at the bottom of the cyclone separator, and the blow-down pipe is connected with the furnace body of the absorption reaction furnace. The calcium-based CO2 absorbance furnace has the characteristics of good reaction effect, simple structure, economical efficiency, good environmental friendliness and the like.

Description

Calcium base CO 2Absorb stove
Technical field:
The present invention relates to a kind of calcium base CO 2Absorb stove, be used in coal-burning boiler absorbing carbon dioxide discharging occasion.
Background technology:
Global warming mainly is because with CO 2Be that the main a large amount of dischargings of greenhouse gases cause the aggravation of global greenhouse effect to cause, control and minimizing CO 2Discharge capacity have important function for the influence that solves atmosphere greenhouse effects and global warming.China is CO 2Discharging big country, discharge capacity accounts for world CO 21/5 of total emission volumn, wherein most of CO 2Produce by fire coal.In the period of quite growing future, China can not change based on the energy general layout of coal, and the coal consumption amount is with sustainable growth.Be in the main production of energy with fossil fuel, CO 2Discharge capacity account for the caused CO of human comings and goings 2More than 70% of total emission volumn is CO 2Maximum single-point fixed discharge, control and reduce CO in coal-fired the production 2Discharging have significant effect for solving atmosphere greenhouse effects and global warming.Therefore separation of C O from the tail gas of coal-burning boiler 2Be very important, from burning and gas-exhausting, separate and reclaim CO 2Technology become very important.
Have based on this, the applicant makes the present invention.
Summary of the invention:
At above-mentioned technical problem to be solved, main purpose of the present invention provides a kind of reasonable in design, applied widely, low energy consumption and the good calcium base CO of the feature of environmental protection 2Absorb stove.
The technical scheme that the present invention takes is as follows, a kind of calcium base CO 2Absorb stove, it is characterized in that: comprise the absorption reaction furnace body, one side of absorption reaction furnace body is equipped with lime stone charging aperture and burner, opposite side is equipped with the flue gas input port in opposite directions, discharging opening is installed on the bottom position of body of heater, and cyclone separator is installed on a side of body of heater and is connected with the absorption reaction stove, and the top of cyclone separator is provided with exhanst gas outlet, the bottom of cyclone separator is provided with discharging opening and blow-down pipe, and blow-down pipe links to each other with the absorption reaction furnace body.
Preferably: the absorption reaction furnace body adopts the asbestos parcel, and the absorption reaction furnace body adopts circular cross section, and flue gas input port, lime stone charging aperture are from the tangent input of body of heater.
Operation principle of the present invention is as follows: CaO absorbs in the absorption reaction stove from the boiler low concentration CO the mixed flue gas that comes out 2, generate CaCO 3Gas-solid mixture is isolated pure CaCO in cyclone separator 3, flowing out from the cyclone separator bottom, unreacting mixture is got back to the absorption reaction stove, and residual air exports emptying from top, generates CaCO 3Temperature required about 650 degree, provide heat by burner; CaO is from raw material mouth input, imports from the flue gas input port from the boiler mixed flue gas that comes out; Finish a working cycles.
Beneficial effect of the present invention is as follows:
1, the present invention adopts calcium-base absorbing agent CaO to absorb in the absorption reaction stove from the boiler low concentration CO the mixed flue gas that comes out 2, generate CaCO 3, effectively reduced CO 2Discharging has good economic benefit and environmental benefit.
2, calcium base CO of the present invention 2Absorb stove, adopt gas approach, lime stone feeding port tangentially to import, spray in opposite directions, form swirling eddy, carry out in order to sufficient reacting from body of heater.
Below in conjunction with accompanying drawing 1 and specific embodiment the present invention is further described in detail, following examples are explanation of the invention but the present invention is not limited to following examples.
Description of drawings:
Fig. 1 is calcium base CO of the present invention 2Absorb the structural representation of stove;
Fig. 2 is calcium base CO of the present invention 2Absorb the profile of stove.
The specific embodiment:
As shown in Figure 1 and Figure 2, calcium base CO of the present invention 2Absorb stove, comprise absorption reaction furnace body 1, one side of absorption reaction furnace body 1 is equipped with lime stone charging aperture 3 and burner 4, opposite side is equipped with flue gas input port 5 in opposite directions, discharging opening 6 is installed on the bottom position of body of heater 1, and cyclone separator 2 is installed on a side of body of heater 1 and is connected with the absorption reaction stove, and the top of cyclone separator 2 is provided with exhanst gas outlet 7, the bottom of cyclone separator 2 is provided with discharging opening 8 and blow-down pipe 9, and discharging opening 8 is used to discharge the pure CaCO of separation 3, blow-down pipe 9 links to each other with absorption reaction furnace body 1, is used for the raw material that unreacted is intact and sends into body of heater 1 continuation reaction.
Operation principle of the present invention is as follows: the mixed flue gas that comes out from coal-burning boiler enters the absorption reaction furnace body 1 from flue gas input port 5, on the other hand, calcium-base absorbing agent CaO imports from charging aperture 3, in the burner 4 coal dust and AIR MIXTURES, ignition produces heat, the temperature of absorption reaction furnace body 1 is remained on about 650 degree, in absorption reaction stove 1, absorb low concentration CO 2, generate CaCO 3
Reaction equation is: CaO+CO 2→ CaCO 3+ 178Kj/mol.
On the other hand, the gas-solid mixture that comes out from absorption reaction stove 1 enters into cyclone separator 2, isolates pure CaCO through cyclone separator 2 3, isolated pure CaCO 3Discharge from the discharging opening 8 of cyclone separator 2 bottoms, unreacted mixture is got back to by blow-down pipe 9 and is continued reaction in the absorption reaction stove 1, residual air is then from exhanst gas outlet 7 emptying on cyclone separator 2 tops, in the absorption reaction furnace body 1, CaO that scraps and residue are emitted from the discharging opening 6 of body of heater 1 bottom.
Among the present invention, absorption reaction furnace body 1 adopts heat-insulating material parcels such as asbestos, preserves heat.Absorption reaction stove 1 adopts circular cross section, and gas approach 5, lime stone charging aperture 3 adopt to spray in opposite directions from the tangent input of body of heater, draw into swirling eddy, fully carry out in order to chemical reaction; The jet of burner 4 then enters from the centre.

Claims (2)

1. calcium base CO 2Absorb stove, it is characterized in that: comprise the absorption reaction furnace body, one side of absorption reaction furnace body is equipped with lime stone charging aperture and burner, opposite side is equipped with the flue gas input port in opposite directions, discharging opening is installed on the bottom position of body of heater, and cyclone separator is installed on a side of body of heater and is connected with the absorption reaction stove, and the top of cyclone separator is provided with exhanst gas outlet, the bottom of cyclone separator is provided with discharging opening and blow-down pipe, and blow-down pipe links to each other with the absorption reaction furnace body.
2. a kind of calcium base CO according to claim 1 2Absorb stove, it is characterized in that: the absorption reaction furnace body adopts the asbestos parcel, and the absorption reaction furnace body adopts circular cross section, and flue gas input port, lime stone charging aperture are from the tangent input of body of heater.
CN201010521871XA 2010-10-28 2010-10-28 Calcium-based CO2 (carbon dioxide) absorbance furnace Pending CN102029106A (en)

Priority Applications (1)

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CN201010521871XA CN102029106A (en) 2010-10-28 2010-10-28 Calcium-based CO2 (carbon dioxide) absorbance furnace

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Application Number Priority Date Filing Date Title
CN201010521871XA CN102029106A (en) 2010-10-28 2010-10-28 Calcium-based CO2 (carbon dioxide) absorbance furnace

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CN102029106A true CN102029106A (en) 2011-04-27

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110500578A (en) * 2019-08-21 2019-11-26 青岛科技大学 A kind of reaction of coupling solid fuel and isolated chemical chain reforming unit and method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1126235A (en) * 1994-06-16 1996-07-10 英国石油化学品有限公司 Waste processing
JP2002273163A (en) * 2001-03-19 2002-09-24 Susumu Otsuki Method for removing carbon dioxide included in combustion exhaust gas
CN101422691A (en) * 2008-11-20 2009-05-06 武汉凯迪电力环保有限公司 Multi-pollutant removing technique and device of fuel coal smoke
CN101612523A (en) * 2009-05-25 2009-12-30 中国石油大学(北京) A kind of tangential gas intake desulfurization tower of semi-dry circulating fluidized bed
CN201823477U (en) * 2010-10-28 2011-05-11 绍兴文理学院 Calcium-based CO2 absorption furnace

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1126235A (en) * 1994-06-16 1996-07-10 英国石油化学品有限公司 Waste processing
JP2002273163A (en) * 2001-03-19 2002-09-24 Susumu Otsuki Method for removing carbon dioxide included in combustion exhaust gas
CN101422691A (en) * 2008-11-20 2009-05-06 武汉凯迪电力环保有限公司 Multi-pollutant removing technique and device of fuel coal smoke
CN101612523A (en) * 2009-05-25 2009-12-30 中国石油大学(北京) A kind of tangential gas intake desulfurization tower of semi-dry circulating fluidized bed
CN201823477U (en) * 2010-10-28 2011-05-11 绍兴文理学院 Calcium-based CO2 absorption furnace

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
《锅炉技术》 20070331 李英杰等 基于钙基吸收剂煅烧/碳酸化循环吸收CO2研究进展 73-76 1 第38卷, 第2期 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110500578A (en) * 2019-08-21 2019-11-26 青岛科技大学 A kind of reaction of coupling solid fuel and isolated chemical chain reforming unit and method

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Application publication date: 20110427