CN102010544A - Plastic compound paper - Google Patents
Plastic compound paper Download PDFInfo
- Publication number
- CN102010544A CN102010544A CN 201010193721 CN201010193721A CN102010544A CN 102010544 A CN102010544 A CN 102010544A CN 201010193721 CN201010193721 CN 201010193721 CN 201010193721 A CN201010193721 A CN 201010193721A CN 102010544 A CN102010544 A CN 102010544A
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- CN
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- Prior art keywords
- paper
- extrusion coating
- coating
- parts
- coupling agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 150000001875 compounds Chemical class 0.000 title claims abstract description 12
- 239000004033 plastic Substances 0.000 title claims abstract description 12
- 229920003023 plastic Polymers 0.000 title claims abstract description 12
- 239000000123 paper Substances 0.000 claims abstract description 54
- 239000007822 coupling agent Substances 0.000 claims abstract description 18
- 239000011248 coating agent Substances 0.000 claims abstract description 16
- 238000000576 coating method Methods 0.000 claims abstract description 16
- 239000000835 fiber Substances 0.000 claims abstract description 13
- 239000000843 powder Substances 0.000 claims abstract description 13
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 12
- 229920000642 polymer Polymers 0.000 claims abstract description 12
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 7
- 239000003365 glass fiber Substances 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 239000010425 asbestos Substances 0.000 claims abstract description 3
- 229910052895 riebeckite Inorganic materials 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 18
- -1 polypropylene Polymers 0.000 claims description 18
- 239000000758 substrate Substances 0.000 claims description 17
- 238000007765 extrusion coating Methods 0.000 claims description 16
- 239000004793 Polystyrene Substances 0.000 claims description 11
- 238000005266 casting Methods 0.000 claims description 11
- 229920002223 polystyrene Polymers 0.000 claims description 11
- 239000012463 white pigment Substances 0.000 claims description 10
- 239000004743 Polypropylene Substances 0.000 claims description 8
- 238000007766 curtain coating Methods 0.000 claims description 8
- 239000004744 fabric Substances 0.000 claims description 8
- 238000003754 machining Methods 0.000 claims description 8
- 229920001155 polypropylene Polymers 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 5
- 239000000314 lubricant Substances 0.000 claims description 5
- 239000011159 matrix material Substances 0.000 claims description 5
- 239000004677 Nylon Substances 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 230000004927 fusion Effects 0.000 claims description 4
- 229920001778 nylon Polymers 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 2
- 239000003605 opacifier Substances 0.000 claims description 2
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 239000003351 stiffener Substances 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 239000000080 wetting agent Substances 0.000 claims description 2
- 229920002994 synthetic fiber Polymers 0.000 claims 1
- 239000012209 synthetic fiber Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 8
- 229920002521 macromolecule Polymers 0.000 abstract description 4
- 229920005989 resin Polymers 0.000 abstract description 4
- 239000011347 resin Substances 0.000 abstract description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract description 3
- 238000003851 corona treatment Methods 0.000 abstract description 3
- 238000003490 calendering Methods 0.000 abstract 1
- 238000009472 formulation Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 abstract 1
- 229920005992 thermoplastic resin Polymers 0.000 description 4
- 239000002131 composite material Substances 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002985 plastic film Substances 0.000 description 3
- 229920006255 plastic film Polymers 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000012764 mineral filler Substances 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- 229920004935 Trevira® Polymers 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229940089401 xylon Drugs 0.000 description 1
Abstract
The invention discloses a plastic compound paper. In a production method, Macromolecule polymers and high-temperature resistance fibers are added into calcium carbonate powder, the pelleting is carried out through high mixing, and then sheets are produced through calendering so as to replace offset paper and paper bases of other coating paper (such as chrome paper and coating byelaya paper) in the market; and the formulation comprises the following components in parts by weight: 50-70 parts of the calcium carbonate powder, 10-20 parts of the macromolecule polymer, 10-20 parts of the high-temperature fiber asbestos or glass fibers, 1-3 parts of coupling agents and 0.3-1.5 parts of zinc stearate. In the invention, macromolecule resins with a single component are adopted, the high-temperature fibers are added to realize multiple interface, and corona treatment can be carried out to increase printable performance and coating adhesion, that is to say, no plant fiber is adopted (so that trees are not needed to be hewed and destroying vegetation is not destroyed), and meanwhile, the cost is also greatly reduced.
Description
Technical field
The present invention relates to a kind of plastic paper that does not have xylon, the alternative paper of using of particularly a kind of enamelled paper and coating white duplex board.
Background technology
Paper can recorded information, is life, and daily necessities become the human carrier that exchanges with life, but nature also can't bear to bear a heavy burden, and carry the mankind to a large amount of felling of forest and the destruction of vegetation; The substitute of seeking a kind of paper is the new research topics of people.United States Patent (USP) 3799828 provides a kind of synthetic paper of laminar structure, is the printability difference problem that solves plastic film, and it makes film have printability by the micropore that forms in the skin of laminar structure.Japanese Patent 73004876 provides similar techniques, it has proposed a plurality of plastic microporous and has caused opacity, printability is provided simultaneously, has formed these micropores by near the interface of sheet between two or more mutually mutual exclusive thermoplastic resins are formed that forms by described mixture that the second-order transition temperature of mixture or softening temperature, stretch.Chinese patent 971127670, it is single or multilayered structure that a kind of synthetic plastic paper of knowing clearly is provided, its surface is tridimensional network, and plastics composite is selected from mutual exclusive thermoplastic resin, by at plastic film at horizontal or longitudinal stretching, plastic film portion within it is increased with surface formation micropore, and the printability of synthetic paper improves thereupon.
Summary of the invention
Main purpose of the present invention is to provide a kind of plastic synthetic paper, and it can replace double gummed paper and the paper substrate (as: paper substrates of enamelled paper, coated white cardboard etc.) of other coating with paper on the market.
Of the present inventionly be achieved in that at present
Technical scheme one:
A kind of extrusion coating paper, by weight, it comprises following component: Paris white 50-70, high molecular polymer 10-20, high temperature fiber asbestos or glass fibre 10-20, coupling agent 1-3, Zinic stearas 0.3-1.5 and industrial wax 5-9%.Close white silk of above composition or high mixing are a granulated into Φ 2-3mm, and length 3-5mm is again through fusion extrusion casting or roll into corresponding sheet material.
In a preferred embodiment of the present invention, described prescription is 60 parts of dicalcium powders, coupling agent 1.5, Zinic stearas 0.5, industrial wax 7, polystyrene 15, glass fibre 10-15, close white silk of above composition or high mixing are a granulated into Φ 2-3mm, length 3-5mm is again through fusion extrusion casting or roll into corresponding sheet material.
Aforesaid high molecular polymer can be a kind of or its mixture in polypropylene, polyethylene, polystyrene, the nylon.
Aforementioned Paris white can be lightweight carbonic acid powder, heavy calcium carbonate.
Aforementioned coupling agent is organic chromium complex compound, silicane, titanate ester or aluminic acid compound coupling agent.Coupling agent is the material that a class has two different properties functional groups, a part of functional group in their molecules can with reactive organic molecule, another part functional group can with the reaction of the planar water on inorganics surface, form firm bonding.The effect of coupling agent in matrix material be it can with some radical reaction on strongthener surface, can react with matrix resin again, between strongthener and resin matrix, form an interfacial layer, interfacial layer can transmit stress, thereby strengthened bond strength between strongthener and the resin, improved performance of composites, can also prevent simultaneously not with other medium to contacting permeation, improve interfacial state, helped ageing-resistant, the proof stress and the electrical insulation capability of goods.
The present invention also can adopt technical scheme two:
A kind of extrusion coating paper, with the cloth is matrix, with filler, high molecular polymer, coupling agent, lubricant, carry out the curtain coating Compound Machining on the casting machine extruding, and make corresponding paper substrate (sheet material) through press polish and remake corresponding coating (white pigment and papermaking auxiliary material) and just can replace enamelled paper on the existing market as printed layers.
Described high molecular polymer can be a kind of or its mixture in polypropylene, polyethylene, polystyrene, the nylon.
Described auxiliary material comprises a kind of of gloss-imparting agent, stiffening agent, fluidizer, dispersion agent, wetting agent, opacifier, white dyes, toning agent or several.
Described white pigment is a kind of of kaolin, talcum powder, lime carbonate, titanium dioxide or several, and described filler is light calcium carbonate or water-ground limestone or talcum powder.
In a preferred embodiment of the present invention, used synthon are polypropylene fibre cloth or polyacrylonitrile macrofiber cloth.Synthon are meant that with oil, Sweet natural gas, coal etc. be raw material, by a series of chemical reaction, make synthetic macromolecular compound, again the filamentary material of making through the course of processing such as spray silk, curing, cut-out.
In another preferred embodiment of the present invention, used synthon are trevira (ES), also claim polyster fibre, are used for the polyester staple fiber that is of papermaking.These fiber characteristics are high, fast light alkaline-resisting, the crease-resistant pleats of excellent, the wet stability of typing, about 255 ℃ of fusing point.
Aforesaid extrusion coating paper, the component that comprises following weight part: described filler-calcium carbonate powder 50～70, high molecular polymer 10-20, coupling agent 1-3, Zinic stearas 0.3-1.5, industrial wax 3-5, carry out the curtain coating Compound Machining on the casting machine extruding, and make paper substrate through press polish, coating white pigment and papermaking auxiliary material on paper substrate again, and make after drying.
More preferably, comprise following component by weight it: 60 parts of dicalcium powders, coupling agent 1.5, Zinic stearas 0.5, industrial wax 7, polystyrene 15, carry out the curtain coating Compound Machining on the casting machine extruding, and make paper substrate through press polish, coating white pigment and papermaking auxiliary material on paper substrate again, and make after drying.
Zinic stearas is white or little yellow fine-powder.Little tool special odor.Molecular formula: RCOOZn, 125 ℃ ± 5 ℃ of fusing points, relative density 1.095.It is as adding lustre to lubricant.
Described coupling agent is organic chromium complex compound, silicane, titanate ester or aluminic acid compound coupling agent.Wherein silane coupling agent is selected from KH550, KH560, KH570, KH602 or KH792.
Traditional method is to be selected from mutual exclusive thermoplastic resin by plastics composite, a plurality of compositions are realized many outer boundaries, the present invention adopts the high molecular polymer (resin) of single component to cooperate mineral filler, generation micropore and every sticking power are given plastic paper and can be printed and coating, the interface and the surface that also can cooperate corona treatment mineral filler and thermoplastic resin again, thereby increase printability and coating sticking power, plastic paper of the present invention does not adopt any vegetable fibre (need not fall trees and vegetation destruction), and plant of no use is made process of pulp.Safeguarded natural, ecological significantly, reduced large-scale source of pollution and produced that for the human lives has created good environment, cost also is greatly diminished simultaneously.
Embodiment
Embodiment one
Get 60 parts of dicalcium powders (weight), silane coupling agent (KH550) 1.5, Zinic stearas 0.5, industrial wax 5, polystyrene 18, glass fibre 15 mixes or stirs, and is a granulated into Φ 2-3mm, and length 3-5mm is again through fusion extrusion casting or roll and the extrusion coating paper sheet material.Also can cooperate the corona treatment sheet surface to increase printability and coating sticking power again.
Embodiment two
With the polypropylene filament non-woven fabrics is base material, get 60 parts of dicalcium powders (weight), silane coupling agent (KH550) 1.5, Zinic stearas 0.5, industrial wax 5, polystyrene 18, carry out the curtain coating Compound Machining on the casting machine extruding, and make paper substrate through press polish, coating white pigment and papermaking auxiliary material on paper substrate again, and make after drying.
Embodiment three
With the polypropylene filament non-woven fabrics is base material, get 65 parts of dicalcium powders (weight), silane coupling agent (KH550) 1.5, Zinic stearas 0.5, industrial wax 5, polystyrene 18, carry out the curtain coating Compound Machining on the casting machine extruding, and make paper substrate through press polish, coating white pigment and papermaking auxiliary material on paper substrate again, and make after drying.
Above-mentioned only is specific embodiments of the invention, but design concept of the present invention is not limited thereto, and allly utilizes this design that the present invention is carried out the change of unsubstantiality, all should belong to the behavior of invading protection domain of the present invention.
Claims (11)
1. extrusion coating paper, by weight, it comprises following component: Paris white 50-70, high molecular polymer 10-20, high temperature fiber asbestos or glass fibre 10-20, coupling agent 1-3, Zinic stearas 0.3-1.5 and industrial wax 5-9%.
2. according to right 1 described a kind of extrusion coating paper, it is characterized in that described high molecular polymer is a kind of or its mixing of polypropylene, polyethylene, polystyrene, nylon.
3. according to right 1 described a kind of extrusion coating paper, it is characterized in that, comprise following component by weight it: 60 parts of dicalcium powders, coupling agent 1.5, Zinic stearas 0.5, industrial wax 7, polystyrene 15, glass fibre 10-15.
4. an extrusion coating paper is a matrix with the cloth, with filler, high molecular polymer, coupling agent, lubricant carries out the curtain coating Compound Machining extruding on the casting machine, and make the plastics paper substrate through press polish, coating white pigment and papermaking auxiliary material on paper substrate again, and make after drying.
5. according to right 4 described a kind of extrusion coating papers, it is characterized in that described synthetic fiber cloth is polypropylene fibre cloth or polyacrylonitrile macrofiber cloth or polyester staple fibre cloth.
6. according to right 4 described a kind of extrusion coating papers, it is characterized in that described auxiliary material comprises a kind of in gloss-imparting agent, stiffening agent, fluidizer, dispersion agent, wetting agent, opacifier, white dyes, the toning agent or several.
7. according to right 4 described a kind of extrusion coating papers, it is characterized in that described high molecular polymer is polypropylene, polyethylene, polystyrene, nylon, wherein a kind of or several.
8. according to right 4 described a kind of extrusion coating papers, it is characterized in that described white pigment is a kind of of kaolin, talcum powder, lime carbonate, titanium dioxide or several, described filler is light calcium carbonate or water-ground limestone or talcum powder.
9. a kind of extrusion coating paper according to claim 4, the component that comprises following weight part: described filler-calcium carbonate powder 50～70, high molecular polymer 10-20, coupling agent 1-3, lubricant: Zinic stearas 0.3-1.5, industrial wax 3-5, extruding on the casting machine curtain coating Compound Machining after the fusion, and make the plastics paper substrate through press polish, coating white pigment and papermaking auxiliary material on paper substrate again, and make after drying.
10. according to right 4 described a kind of extrusion coating papers, it is characterized in that, comprise following component by weight it: 60 parts of dicalcium powders, coupling agent 1.5, lubricant: Zinic stearas 0.5, industrial wax 7; Polystyrene 15 carries out the curtain coating Compound Machining extruding, and makes paper substrate through press polish on the casting machine, coating white pigment and papermaking auxiliary material on paper substrate again, and make after drying.
11., it is characterized in that described coupling agent is a silane coupling agent according to right 1 or 4 described a kind of extrusion coating papers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010193721A CN102010544B (en) | 2010-06-07 | 2010-06-07 | Plastic compound paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010193721A CN102010544B (en) | 2010-06-07 | 2010-06-07 | Plastic compound paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102010544A true CN102010544A (en) | 2011-04-13 |
| CN102010544B CN102010544B (en) | 2012-10-17 |
Family
ID=43840887
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010193721A Expired - Fee Related CN102010544B (en) | 2010-06-07 | 2010-06-07 | Plastic compound paper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102010544B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103061200A (en) * | 2011-10-19 | 2013-04-24 | 香港格林天使科技有限公司 | Novel environment-friendly stone paper and preparation method thereof |
| CN108485061A (en) * | 2018-03-22 | 2018-09-04 | 温州大学苍南研究院 | A kind of technique producing extrusion coating paper using polyolefin feed back |
| CN108586915A (en) * | 2018-03-22 | 2018-09-28 | 温州大学苍南研究院 | A kind of extrusion coating paper |
| CN109463184A (en) * | 2018-11-09 | 2019-03-15 | 河北互之源新科技有限公司 | The Novel paper of orchard worker's industry |
| CN112647298A (en) * | 2020-12-21 | 2021-04-13 | 兰州大学 | Fiber material for removing adhesive tape traces and preparation method thereof |
| CN114988758A (en) * | 2021-08-25 | 2022-09-02 | 林佑生 | Stone paper substrate master batch, stone paper and preparation method of stone paper |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1134872A (en) * | 1995-08-31 | 1996-11-06 | 南亚塑胶工业股份有限公司 | Method for mfg. synthesized paper and products thereof |
| JP2001192467A (en) * | 2000-01-13 | 2001-07-17 | Tobe Shoji Kk | Plastic-compounded paper and method for producing the same |
| US20020041060A1 (en) * | 1998-03-05 | 2002-04-11 | Lung Meng Environmental Friendly Paper Products Hong Kong (Holdings) Limited | Process for the manufacture of environmentally friendly papers and compositions therefor |
| CN1415656A (en) * | 2002-10-16 | 2003-05-07 | 广东华业包装材料有限公司 | Synthetic paper able to be coated and its preparation method |
| CN101649087A (en) * | 2009-05-14 | 2010-02-17 | 李美香 | Plastic composite paper |
-
2010
- 2010-06-07 CN CN201010193721A patent/CN102010544B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1134872A (en) * | 1995-08-31 | 1996-11-06 | 南亚塑胶工业股份有限公司 | Method for mfg. synthesized paper and products thereof |
| US20020041060A1 (en) * | 1998-03-05 | 2002-04-11 | Lung Meng Environmental Friendly Paper Products Hong Kong (Holdings) Limited | Process for the manufacture of environmentally friendly papers and compositions therefor |
| JP2001192467A (en) * | 2000-01-13 | 2001-07-17 | Tobe Shoji Kk | Plastic-compounded paper and method for producing the same |
| CN1415656A (en) * | 2002-10-16 | 2003-05-07 | 广东华业包装材料有限公司 | Synthetic paper able to be coated and its preparation method |
| CN101649087A (en) * | 2009-05-14 | 2010-02-17 | 李美香 | Plastic composite paper |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103061200A (en) * | 2011-10-19 | 2013-04-24 | 香港格林天使科技有限公司 | Novel environment-friendly stone paper and preparation method thereof |
| CN108485061A (en) * | 2018-03-22 | 2018-09-04 | 温州大学苍南研究院 | A kind of technique producing extrusion coating paper using polyolefin feed back |
| CN108586915A (en) * | 2018-03-22 | 2018-09-28 | 温州大学苍南研究院 | A kind of extrusion coating paper |
| CN109463184A (en) * | 2018-11-09 | 2019-03-15 | 河北互之源新科技有限公司 | The Novel paper of orchard worker's industry |
| CN112647298A (en) * | 2020-12-21 | 2021-04-13 | 兰州大学 | Fiber material for removing adhesive tape traces and preparation method thereof |
| CN114988758A (en) * | 2021-08-25 | 2022-09-02 | 林佑生 | Stone paper substrate master batch, stone paper and preparation method of stone paper |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102010544B (en) | 2012-10-17 |
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Application publication date: 20110413 Assignee: Xiamen Yahe Paper Composite Materials Co., Ltd. Assignor: Li Meixiang Contract record no.: 2013350000125 Denomination of invention: Plastic composite paper Granted publication date: 20121017 License type: Exclusive License Record date: 20130805 Application publication date: 20110413 Assignee: Xiamen Yahe Paper Composite Materials Co., Ltd. Assignor: Li Meixiang Contract record no.: 2013350000125 Denomination of invention: Plastic composite paper Granted publication date: 20121017 License type: Exclusive License Record date: 20130805 |
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Assignee: Xiamen Yahe Paper Composite Materials Co., Ltd. Assignor: Li Meixiang Contract record no.: 2013350000125 Date of cancellation: 20140721 Assignee: Xiamen Yahe Paper Composite Materials Co., Ltd. Assignor: Li Meixiang Contract record no.: 2013350000125 Date of cancellation: 20140721 |
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Effective date of registration: 20151020 Address after: Nanping City, Fujian province 353000 Yanping District New Road No. 231 Patentee after: Ye Keming Address before: 361000 Fujian province Xiamen City Siming District of Xiamen East Beach No. 23 room 604 Patentee before: Chen Cuan Effective date of registration: 20151020 Address after: Nanping City, Fujian province 353000 Yanping District New Road No. 231 Patentee after: Ye Keming Address before: 361000 Fujian province Xiamen City Siming District of Xiamen East Beach No. 23 room 604 Patentee before: Chen Cuan |
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