CN102001832A - Preparation method of foam glass particles - Google Patents
Preparation method of foam glass particles Download PDFInfo
- Publication number
- CN102001832A CN102001832A CN 201010550152 CN201010550152A CN102001832A CN 102001832 A CN102001832 A CN 102001832A CN 201010550152 CN201010550152 CN 201010550152 CN 201010550152 A CN201010550152 A CN 201010550152A CN 102001832 A CN102001832 A CN 102001832A
- Authority
- CN
- China
- Prior art keywords
- template
- preparation
- foam glass
- glass
- foam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Abstract
The invention relates to a preparation method of foam glass particles, which comprises the following steps of: milling glass balls to 200 meshes for forming glass powder; mixing the glass powder, sodium nitrate, manganese dioxide, ferric oxide and sodium silicate to be made into mixed materials; uniformly drilling a plurality of cylindrical grooves on the surface of a foaming template to obtain the particular foaming template; uniformly injecting the mixed materials into the cylindrical grooves of the particular foaming template; firing the mixed materials in a roller kiln; and pouring out specimens from the particular foaming template to obtain foam glass particles. The invention uses a template method for producing the foam glass particles, and the prepared foam glass particles have narrow dimension distribution, uniform granularity and high production efficiency. The foam glass particles prepared according to the preparation method have good structural intensity, low water absorption rate, low heat conduction coefficient and high sealing porosity, and can be used as good thermal isolation and heat insulation materials. The preparation process has simple operation process, low cost and energy saving and environment protection effect and is applicable to industrial mass production.
Description
Technical field
The present invention relates to a kind of manufacture method of multicellular glass, particularly a kind of preparation method of foam glass particle.
Background technology
Multicellular glass is to utilize the material that scrap glass, flyash, mica, perlite, pumice sand, volcanic ash etc. are rich in glassy phase to be main raw material, add whipping agent, properties-correcting agent, promotor etc., broken and be uniformly mixed into admixtion through fine powder, be placed in the particular mold and heat, make the porous glass material that glass is softening, a kind of inside of formation of foaming, anneal is full of countless even bubbles through 750～900 ℃ of temperature.
Multicellular glass has physical propertiess such as density is little, intensity is high, thermal conductivity is little, it has not only that the inherent of glass material own is permanent, security, reliability, anti-chemical corrodibility and be not subjected to advantages such as ant mouse infringement, and compare with other material of construction, also have heat insulating, waterproof and dampproof, fire prevention, acid and alkali-resistance, a series of high-performances such as density is little, physical strength is high, sound absorption.
Particulate state multicellular glass be by multicellular glass development and a kind of novel environment-friendly insulating material that comes (Chen Hui, Xu Jinyu. heat insulating material-TECHNOpor glass foam glass particle [J]. New Building Materials, 2007 (9): 53), its purposes is quite extensive.Can be used for the bottom of wall, roof, swimming pool, the ground of garage closes the ceiling in parking lot; Be used for the buildings building or transform; Be used for the slope and reinforce, the gradient can reach 45 °, can beautify view simultaneously; Be used for driveway and walkway; Be used for the residential housing of low power consuming and the buildings of environmental requirement is arranged.
The special public clear 63-65617 of the chemical finished product industry of Japan (strain) has released a kind of method of making glass foaming grain, comprise bonded dose of fixed granulation of glass powder and inorganic foaming agent in the technology, whole grain after the granulation, be coated with release agent, in rotary kiln, burn till foaming, this glass foaming grain is mainly as lagging material, skeleton and sound absorbent material.Past is used the dish-type granulators granulation always, and shortcoming is that size distribution is wide, needs screening, and bonds between the particle, and the spy opens clear 53-1402424 and proposes glass-whipping agent mixed powder is made the noodles shape, burns the method for face foamed glass particle then.But this method can not obtain even-grained particle.And noodles shape work in-process are frangible, easily adhesion, easily sticking furnace wall when burning till.
CN10774764A discloses a kind of glass block with a large amount of holes, and color is a white, and bore hole size is 0.5～2mm, is evenly distributed.Adjusting by the foam grain addition is interconnected between the hole.The powder that this glass raw material grinds for the scrap glass fragment is sneaked into foam grain therein.By the thermal treatment sintering process, placeholder is decomposed to form hole, and glass powder sinters porous blocks into.These holes have increased the surface-area of glass, have reduced the apparent density of block, and have improved sound-absorbing and heat-insulating capability.But this method can not be used to prepare particulate state multicellular glass.
Sun Ke; Deng (Sun Ke; once of heap of stone; Wang Tao; six Zhong Hai. prepare grand permeability sintered glass particle [J] in the mixer granulator fast. the silicate circular; 2006,25 (4): 172-175) investigated the influence of in quick mixer granulator amount of water, granulation time, alr mode, studied the influence of sintering temperature to granule strength and porosity to grand permeability glass particle granulation process.The prepared foam glass particle density of this method is bigger, and particle surface percentage of open area height, simultaneously, adopts that to stir the prepared particle size distribution of method of granulating wider.
In recent years, along with further research and development to particulate state multicellular glass application facet, find that particulate state multicellular glass is as the heat-insulation and heat-preservation material time, wider particle distribution range has greatly limited its result of use as good heat preserving and insulating material and packing material, it is narrow how to prepare distribution of particle sizes, preparation technology is simple, and the foam glass particle of excellent property becomes the problem of needing solution in the foam glass particle production badly.
Summary of the invention
The objective of the invention is to overcome the shortcoming of above-mentioned prior art, a kind of method that adopts template to prepare foam glass particle is provided.The foam glass particle that the present invention is prepared, the granularity size is consistent, and density is little, the intensity height, thermal conductivity is little, can be used as good building heat preservation lagging material and packing material.
For achieving the above object, the preparation method that the present invention adopts is:
The first step: the preparation of admixtion: at first, with various glass cullet cleanings, oven dry, broken, ball milling to the 200 order formation glass powder of collecting; Secondly, according to massfraction with 94% glass powder, 3% SODIUMNITRATE, 1% Manganse Dioxide, 1% ferric oxide, 1% water glass are put into mixer and are mixed to uniformity coefficient greater than 98% compound; Then, spray into the atomized water of compound 5% in mixer, batch mixing forms the admixtion of preparation foam glass particle after 30 minutes again;
Second step: the preparation of particle dress foaming template: at first, the template surface that will foam polishes flat; Secondly, getting out several diameters on smooth buffed surface uniformly is 2～5mm, the cylindrical groove of dark 2～4mm, and will foam template and cylindrical groove are cleaned out; Then, be that 400 purpose aluminum oxide water mill slurries uniformly spray on foaming template surface and cylindrical groove top layer with granularity, promptly make particulate state foaming template behind the natural airing;
The 3rd step: the preparation of foam glass particle: at first, admixtion is injected the cylindrical groove of particulate state foaming template uniformly, work loading height and the particulate state template that foams is equal; Then, the particulate state template that foams is pushed in the roller kiln, burn till according to following system: with the heat-up rate of 2 ℃/min, be warming up to 600 ℃ from room temperature, insulation 20～30min, the heat-up rate with 5 ℃/min is warming up to 760 ℃ then, insulation 10～30min, rate of temperature fall with 1 ℃/min is cooled to room temperature then, from particulate state foaming template sample is poured out and promptly gets foam glass particle.
Glass cullet of the present invention adopt ordinary plate glass, container glass;
The foaming template adopts aluminum oxide, sillimanite, silicon carbide or mullite refractory to make;
400 purpose aluminum oxide water mill slurries of foaming template inner-wall spraying are to be that 95% aluminum oxide and 5% kaolin add water after cross 400 mesh standard sieves behind the ball milling and be prepared from massfraction, and coating thickness is less than 0.5mm.
The present invention utilizes template to produce foam glass particle, prepared foam glass particle narrow size distribution, epigranular, production efficiency height.The foam glass particle structural strength that makes according to preparation method of the present invention is good, water-intake rate is low, thermal conductivity is little, sealed porosity rate height, can be used as good heat-insulating material.Preparation technology's operating process of the present invention is simple, with low cost, and energy-conserving and environment-protective are suitable for industrialized mass production.
Description of drawings
Fig. 1 is that the present invention prepares the used foaming template of foam glass particle synoptic diagram.Wherein 1 is the foaming template, and 2 is cylindrical groove
Embodiment
Second step: referring to Fig. 1, the preparation of particle dress foaming template: at first, will be of a size of: foaming template 1 surface finish that the aluminum oxide of 600mm * 400mm * 40mm is made is smooth; Secondly, getting out several diameters on smooth buffed surface uniformly is 2mm, the cylindrical groove 2 of dark 2mm, and will foam template 1 and cylindrical groove 2 are cleaned out; Then, be that 400 purpose aluminum oxide water mill slurries uniformly spray on foaming template 1 surface and cylindrical groove 2 top layers with granularity, promptly make particulate state foaming template behind the natural airing;
Described 400 purpose aluminum oxide water mill slurries are to be that 95% aluminum oxide and 5% kaolin add water after cross 400 mesh standard sieves behind the ball milling and be prepared from massfraction, and coating thickness is less than 0.5mm;
The 3rd step: the preparation of foam glass particle: at first, admixtion is injected the cylindrical groove 2 of particulate state foaming template uniformly, work loading height and the particulate state template that foams is equal; Then, the particulate state template 1 that foams is pushed in the roller kiln, burn till according to following system: with the heat-up rate of 2 ℃/min, be warming up to 600 ℃ from room temperature, insulation 20min, the heat-up rate with 5 ℃/min is warming up to 760 ℃ then, insulation 10min, rate of temperature fall with 1 ℃/min is cooled to room temperature then, from particulate state foaming template sample is poured out and promptly gets foam glass particle.
Embodiment 2, the first step: the preparation of admixtion: at first, and with various glass cullet cleanings, oven dry, broken, ball milling to the 200 order formation glass powder of collecting; Secondly, according to massfraction with 94% glass powder, 3% SODIUMNITRATE, 1% Manganse Dioxide, 1% ferric oxide, 1% water glass are put into mixer and are mixed to uniformity coefficient greater than 98% compound; Then, spray into the atomized water of compound 5% in mixer, batch mixing forms the admixtion of preparation foam glass particle after 30 minutes again;
Second step: the preparation of particle dress foaming template: at first, will be of a size of: foaming template 1 surface finish that the sillimanite of 600mm * 400mm * 40mm is made is smooth; Secondly, getting out several diameters on smooth buffed surface uniformly is 3mm, the cylindrical groove 2 of dark 2mm, and will foam template 1 and cylindrical groove 2 are cleaned out; Then, be that 400 purpose aluminum oxide water mill slurries uniformly spray on foaming template 1 surface and cylindrical groove 2 top layers with granularity, promptly make particulate state foaming template behind the natural airing;
Described 400 purpose aluminum oxide water mill slurries are to be that 95% aluminum oxide and 5% kaolin add water after cross 400 mesh standard sieves behind the ball milling and be prepared from massfraction, and coating thickness is less than 0.5mm;
The 3rd step: the preparation of foam glass particle: at first, admixtion is injected the cylindrical groove 2 of particulate state foaming template uniformly, work loading height and the particulate state template that foams is equal; Then, the particulate state template 1 that foams is pushed in the roller kiln, burn till according to following system: with the heat-up rate of 2 ℃/min, be warming up to 600 ℃ from room temperature, insulation 22min, the heat-up rate with 5 ℃/min is warming up to 760 ℃ then, insulation 12min, rate of temperature fall with 1 ℃/min is cooled to room temperature then, from particulate state foaming template sample is poured out and promptly gets foam glass particle.
Embodiment 3, the first step: the preparation of admixtion: at first, and with various glass cullet cleanings, oven dry, broken, ball milling to the 200 order formation glass powder of collecting; Secondly, according to massfraction with 94% glass powder, 3% SODIUMNITRATE, 1% Manganse Dioxide, 1% ferric oxide, 1% water glass are put into mixer and are mixed to uniformity coefficient greater than 98% compound; Then, spray into the atomized water of compound 5% in mixer, batch mixing forms the admixtion of preparation foam glass particle after 30 minutes again;
Second step: the preparation of particle dress foaming template: at first, will be of a size of: foaming template 1 surface finish that the silicon carbide of 600mm * 400mm * 40mm is made is smooth; Secondly, getting out several diameters on smooth buffed surface uniformly is 3mm, the cylindrical groove 2 of dark 3mm, and will foam template 1 and cylindrical groove 2 are cleaned out; Then, be that 400 purpose aluminum oxide water mill slurries uniformly spray on foaming template 1 surface and cylindrical groove 2 top layers with granularity, promptly make particulate state foaming template behind the natural airing;
Described 400 purpose aluminum oxide water mill slurries are to be that 95% aluminum oxide and 5% kaolin add water after cross 400 mesh standard sieves behind the ball milling and be prepared from massfraction, and coating thickness is less than 0.5mm;
The 3rd step: the preparation of foam glass particle: at first, admixtion is injected the cylindrical groove 2 of particulate state foaming template uniformly, work loading height and the particulate state template that foams is equal; Then, the particulate state template 1 that foams is pushed in the roller kiln, burn till according to following system: with the heat-up rate of 2 ℃/min, be warming up to 600 ℃ from room temperature, insulation 25min, the heat-up rate with 5 ℃/min is warming up to 760 ℃ then, insulation 15min, rate of temperature fall with 1 ℃/min is cooled to room temperature then, from particulate state foaming template sample is poured out and promptly gets foam glass particle.
Embodiment 4, the first step: the preparation of admixtion: at first, and with various glass cullet cleanings, oven dry, broken, ball milling to the 200 order formation glass powder of collecting; Secondly, according to massfraction with 94% glass powder, 3% SODIUMNITRATE, 1% Manganse Dioxide, 1% ferric oxide, 1% water glass are put into mixer and are mixed to uniformity coefficient greater than 98% compound; Then, spray into the atomized water of compound 5% in mixer, batch mixing forms the admixtion of preparation foam glass particle after 30 minutes again;
Second step: the preparation of particle dress foaming template: at first, will be of a size of: foaming template 1 surface finish that the mullite of 600mm * 400mm * 40mm is made is smooth; Secondly, getting out several diameters on smooth buffed surface uniformly is 4mm, the cylindrical groove 2 of dark 3mm, and will foam template 1 and cylindrical groove 2 are cleaned out; Then, be that 400 purpose aluminum oxide water mill slurries uniformly spray on foaming template 1 surface and cylindrical groove 2 top layers with granularity, promptly make particulate state foaming template behind the natural airing;
Described 400 purpose aluminum oxide water mill slurries are to be that 95% aluminum oxide and 5% kaolin add water after cross 400 mesh standard sieves behind the ball milling and be prepared from massfraction, and coating thickness is less than 0.5mm;
The 3rd step: the preparation of foam glass particle: at first, admixtion is injected the cylindrical groove 2 of particulate state foaming template uniformly, work loading height and the particulate state template that foams is equal; Then, the particulate state template 1 that foams is pushed in the roller kiln, burn till according to following system: with the heat-up rate of 2 ℃/min, be warming up to 600 ℃ from room temperature, insulation 26min, the heat-up rate with 5 ℃/min is warming up to 760 ℃ then, insulation 20min, rate of temperature fall with 1 ℃/min is cooled to room temperature then, from particulate state foaming template sample is poured out and promptly gets foam glass particle.
Embodiment 5, the first step: the preparation of admixtion: at first, and with various glass cullet cleanings, oven dry, broken, ball milling to the 200 order formation glass powder of collecting; Secondly, according to massfraction with 94% glass powder, 3% SODIUMNITRATE, 1% Manganse Dioxide, 1% ferric oxide, 1% water glass are put into mixer and are mixed to uniformity coefficient greater than 98% compound; Then, spray into the atomized water of compound 5% in mixer, batch mixing forms the admixtion of preparation foam glass particle after 30 minutes again;
Second step: the preparation of particle dress foaming template: at first, will be of a size of: foaming template 1 surface finish that the aluminum oxide of 600mm * 400mm * 40mm is made is smooth; Secondly, getting out several diameters on smooth buffed surface uniformly is 5mm, the cylindrical groove 2 of dark 3mm, and will foam template 1 and cylindrical groove 2 are cleaned out; Then, be that 400 purpose aluminum oxide water mill slurries uniformly spray on foaming template 1 surface and cylindrical groove 2 top layers with granularity, promptly make particulate state foaming template behind the natural airing;
Described 400 purpose aluminum oxide water mill slurries are to be that 95% aluminum oxide and 5% kaolin add water after cross 400 mesh standard sieves behind the ball milling and be prepared from massfraction, and coating thickness is less than 0.5mm;
The 3rd step: the preparation of foam glass particle: at first, admixtion is injected the cylindrical groove 2 of particulate state foaming template uniformly, work loading height and the particulate state template that foams is equal; Then, the particulate state template 1 that foams is pushed in the roller kiln, burn till according to following system: with the heat-up rate of 2 ℃/min, be warming up to 600 ℃ from room temperature, insulation 28min, the heat-up rate with 5 ℃/min is warming up to 760 ℃ then, insulation 26min, rate of temperature fall with 1 ℃/min is cooled to room temperature then, from particulate state foaming template sample is poured out and promptly gets foam glass particle.
Embodiment 6, the first step: the preparation of admixtion: at first, and with various glass cullet cleanings, oven dry, broken, ball milling to the 200 order formation glass powder of collecting; Secondly, according to massfraction with 94% glass powder, 3% SODIUMNITRATE, 1% Manganse Dioxide, 1% ferric oxide, 1% water glass are put into mixer and are mixed to uniformity coefficient greater than 98% compound; Then, spray into the atomized water of compound 5% in mixer, batch mixing forms the admixtion of preparation foam glass particle after 30 minutes again;
Second step: the preparation of particle dress foaming template: at first, will be of a size of: foaming template 1 surface finish that the mullite of 600mm * 400mm * 40mm is made is smooth; Secondly, getting out several diameters on smooth buffed surface uniformly is 3mm, the cylindrical groove 2 of dark 4mm, and will foam template 1 and cylindrical groove 2 are cleaned out; Then, be that 400 purpose aluminum oxide water mill slurries uniformly spray on foaming template 1 surface and cylindrical groove 2 top layers with granularity, promptly make particulate state foaming template behind the natural airing;
Described 400 purpose aluminum oxide water mill slurries are to be that 95% aluminum oxide and 5% kaolin add water after cross 400 mesh standard sieves behind the ball milling and be prepared from massfraction, and coating thickness is less than 0.5mm;
The 3rd step: the preparation of foam glass particle: at first, admixtion is injected the cylindrical groove 2 of particulate state foaming template uniformly, work loading height and the particulate state template that foams is equal; Then, the particulate state template 1 that foams is pushed in the roller kiln, burn till according to following system: with the heat-up rate of 2 ℃/min, be warming up to 600 ℃ from room temperature, insulation 30min, the heat-up rate with 5 ℃/min is warming up to 760 ℃ then, insulation 30min, rate of temperature fall with 1 ℃/min is cooled to room temperature then, from particulate state foaming template sample is poured out and promptly gets foam glass particle.
The present invention utilizes template to produce foam glass particle, prepared foam glass particle narrow size distribution, epigranular, production efficiency height.The foam glass particle structural strength that makes according to preparation method of the present invention is good, water-intake rate is low, thermal conductivity is little, sealed porosity rate height, and proportion is little, can be used as good heat-insulating material.Preparation technology's operating process of the present invention is simple, with low cost, and energy-conserving and environment-protective are suitable for industrialized mass production.Prepared foam glass particle can be used as top ceiling and floor and the insulated roof that the fine insulating material is used for insulation curtain wall, brick wall, concrete walls, thermal-insulation floor tile, floor plates, roof; Be used for the thermal insulation in refrigerating plant, boats and ships, refrigerator car and isothermal compartment; Also can be used for the insulation that temperature is no more than 300 ℃ heat power equipment.
Claims (4)
1. the preparation method of a foam glass particle is characterized in that carrying out according to the following steps:
The first step: the preparation of admixtion: at first, with various glass cullet cleanings, oven dry, broken, ball milling to the 200 order formation glass powder of collecting; Secondly, according to massfraction with 94% glass powder, 3% SODIUMNITRATE, 1% Manganse Dioxide, 1% ferric oxide, 1% water glass are put into mixer and are mixed to uniformity coefficient greater than 98% compound; Then, spray into the atomized water of compound 5% in mixer, batch mixing forms the admixtion of preparation foam glass particle after 30 minutes again;
Second step: the preparation of particle dress foaming template: at first, the template that will foam (1) surface finish is smooth; Secondly, getting out several diameters on smooth buffed surface uniformly is 2～5mm, the cylindrical groove of dark 2～4mm (2), and will foam template (1) and cylindrical groove (2) are cleaned out; Then, be that 400 purpose aluminum oxide water mill slurries uniformly spray on foaming template (1) surface and cylindrical groove (2) top layer with granularity, promptly make particulate state foaming template behind the natural airing;
The 3rd step: the preparation of foam glass particle: at first, admixtion is injected the cylindrical groove (2) of particulate state foaming template uniformly, work loading height and the particulate state template that foams is equal; Then, the particulate state template (1) that foams is pushed in the roller kiln, burn till according to following system: with the heat-up rate of 2 ℃/min, be warming up to 600 ℃ from room temperature, insulation 20～30min, the heat-up rate with 5 ℃/min is warming up to 760 ℃ then, insulation 10～30min, rate of temperature fall with 1 ℃/min is cooled to room temperature then, from particulate state foaming template sample is poured out and promptly gets foam glass particle.
2. the preparation method of foam glass particle according to claim 1 is characterized in that: described glass cullet employing ordinary plate glass, container glass.
3. the preparation method of foam glass particle according to claim 1 is characterized in that: described foaming template (1) adopts aluminum oxide, sillimanite, silicon carbide or mullite refractory to make.
4. the preparation method of foam glass particle according to claim 1, it is characterized in that: 400 purpose aluminum oxide water mill slurries of described foaming template inner-wall spraying are to be that 95% aluminum oxide and 5% kaolin add water after cross 400 mesh standard sieves behind the ball milling and be prepared from massfraction, and coating thickness is less than 0.5mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105501520A CN102001832B (en) | 2010-11-18 | 2010-11-18 | Preparation method of foam glass particles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010105501520A CN102001832B (en) | 2010-11-18 | 2010-11-18 | Preparation method of foam glass particles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102001832A true CN102001832A (en) | 2011-04-06 |
| CN102001832B CN102001832B (en) | 2012-01-25 |
Family
ID=43809577
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010105501520A Expired - Fee Related CN102001832B (en) | 2010-11-18 | 2010-11-18 | Preparation method of foam glass particles |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102001832B (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102807326A (en) * | 2012-08-20 | 2012-12-05 | 宁波荣山新型材料有限公司 | Polymer-modified low temperature foaming glass thermal insulation material and preparation method thereof |
| CN105392753A (en) * | 2013-04-24 | 2016-03-09 | 知识产权古里亚有限责任公司 | Expanded lightweight aggregate made from glass or pumice |
| CN107572830A (en) * | 2017-10-18 | 2018-01-12 | 崔旸 | A kind of lightweight modified filter material and its preparation method and application |
| US9890083B2 (en) | 2013-03-05 | 2018-02-13 | The Intellectual Gorilla Gmbh | Extruded gypsum-based materials |
| CN108178519A (en) * | 2018-02-08 | 2018-06-19 | 合肥利裕泰玻璃制品有限公司 | A kind of novel foam glass and preparation method thereof |
| US10077597B2 (en) | 2012-06-29 | 2018-09-18 | The Intellectual Gorilla Gmbh | Fire rated door |
| US10196309B2 (en) | 2013-10-17 | 2019-02-05 | The Intellectual Gorilla Gmbh | High temperature lightweight thermal insulating cement and silica based materials |
| US10240089B2 (en) | 2012-06-29 | 2019-03-26 | The Intellectual Gorilla Gmbh | Gypsum composites used in fire resistant building components |
| US10315386B2 (en) | 2012-06-29 | 2019-06-11 | The Intellectual Gorilla Gmbh | Gypsum composites used in fire resistant building components |
| US10414692B2 (en) | 2013-04-24 | 2019-09-17 | The Intellectual Gorilla Gmbh | Extruded lightweight thermal insulating cement-based materials |
| US10442733B2 (en) | 2014-02-04 | 2019-10-15 | The Intellectual Gorilla Gmbh | Lightweight thermal insulating cement based materials |
| US10538459B2 (en) | 2014-06-05 | 2020-01-21 | The Intellectual Gorilla Gmbh | Extruded cement based materials |
| US11072562B2 (en) | 2014-06-05 | 2021-07-27 | The Intellectual Gorilla Gmbh | Cement-based tile |
| CN115259678A (en) * | 2022-08-18 | 2022-11-01 | 东莞南玻晶玉新材料有限公司 | Manufacturing process of semitransparent foamed jade glass |
| CN115262802A (en) * | 2022-08-09 | 2022-11-01 | 江苏正威新材料股份有限公司 | Glass material for building and manufacturing process thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2620597A (en) * | 1947-04-09 | 1952-12-09 | Pittsburgh Corning Corp | Method of preparing cellular glass |
| US20070186587A1 (en) * | 2004-03-12 | 2007-08-16 | Dennert Poraver Gmbh | Method for the manufacture of foam glass pellets |
-
2010
- 2010-11-18 CN CN2010105501520A patent/CN102001832B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2620597A (en) * | 1947-04-09 | 1952-12-09 | Pittsburgh Corning Corp | Method of preparing cellular glass |
| US20070186587A1 (en) * | 2004-03-12 | 2007-08-16 | Dennert Poraver Gmbh | Method for the manufacture of foam glass pellets |
Non-Patent Citations (1)
| Title |
|---|
| 《中国资源综合利用》 20100430 张剑波 等 泡沫玻璃的研究进展 第25-29页 1-4 第28卷, 第4期 2 * |
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10240089B2 (en) | 2012-06-29 | 2019-03-26 | The Intellectual Gorilla Gmbh | Gypsum composites used in fire resistant building components |
| US10435941B2 (en) | 2012-06-29 | 2019-10-08 | The Intellectual Gorilla Gmbh | Fire rated door core |
| US10876352B2 (en) | 2012-06-29 | 2020-12-29 | The Intellectual Gorilla Gmbh | Fire rated door |
| US10315386B2 (en) | 2012-06-29 | 2019-06-11 | The Intellectual Gorilla Gmbh | Gypsum composites used in fire resistant building components |
| US10077597B2 (en) | 2012-06-29 | 2018-09-18 | The Intellectual Gorilla Gmbh | Fire rated door |
| CN102807326B (en) * | 2012-08-20 | 2015-05-27 | 宁波荣山新型材料有限公司 | Polymer-modified low temperature foaming glass thermal insulation material and preparation method thereof |
| CN102807326A (en) * | 2012-08-20 | 2012-12-05 | 宁波荣山新型材料有限公司 | Polymer-modified low temperature foaming glass thermal insulation material and preparation method thereof |
| US9890083B2 (en) | 2013-03-05 | 2018-02-13 | The Intellectual Gorilla Gmbh | Extruded gypsum-based materials |
| US9701583B2 (en) | 2013-04-24 | 2017-07-11 | The Intellectual Gorilla Gmbh | Expanded lightweight aggregate made from glass or pumice |
| US11142480B2 (en) | 2013-04-24 | 2021-10-12 | The Intellectual Gorilla Gmbh | Lightweight thermal insulating cement-based materials |
| US10414692B2 (en) | 2013-04-24 | 2019-09-17 | The Intellectual Gorilla Gmbh | Extruded lightweight thermal insulating cement-based materials |
| CN105392753A (en) * | 2013-04-24 | 2016-03-09 | 知识产权古里亚有限责任公司 | Expanded lightweight aggregate made from glass or pumice |
| US10196309B2 (en) | 2013-10-17 | 2019-02-05 | The Intellectual Gorilla Gmbh | High temperature lightweight thermal insulating cement and silica based materials |
| US11155499B2 (en) | 2014-02-04 | 2021-10-26 | The Intellectual Gorilla Gmbh | Lightweight thermal insulating cement based materials |
| US10442733B2 (en) | 2014-02-04 | 2019-10-15 | The Intellectual Gorilla Gmbh | Lightweight thermal insulating cement based materials |
| US10538459B2 (en) | 2014-06-05 | 2020-01-21 | The Intellectual Gorilla Gmbh | Extruded cement based materials |
| US11072562B2 (en) | 2014-06-05 | 2021-07-27 | The Intellectual Gorilla Gmbh | Cement-based tile |
| CN107572830A (en) * | 2017-10-18 | 2018-01-12 | 崔旸 | A kind of lightweight modified filter material and its preparation method and application |
| US11648526B2 (en) | 2017-10-18 | 2023-05-16 | Jilin Magic Environmental Technology Co., Ltd. | Lightweight modified filter material, preparation method therefor and use thereof |
| CN108178519A (en) * | 2018-02-08 | 2018-06-19 | 合肥利裕泰玻璃制品有限公司 | A kind of novel foam glass and preparation method thereof |
| CN115262802A (en) * | 2022-08-09 | 2022-11-01 | 江苏正威新材料股份有限公司 | Glass material for building and manufacturing process thereof |
| CN115262802B (en) * | 2022-08-09 | 2024-02-23 | 江苏正威新材料股份有限公司 | Glass material for building and manufacturing process thereof |
| CN115259678A (en) * | 2022-08-18 | 2022-11-01 | 东莞南玻晶玉新材料有限公司 | Manufacturing process of semitransparent foamed jade glass |
| CN115259678B (en) * | 2022-08-18 | 2024-03-15 | 东莞南玻晶玉新材料有限公司 | Semitransparent foam jade glass manufacturing process |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102001832B (en) | 2012-01-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102001832B (en) | Preparation method of foam glass particles | |
| CN102838375B (en) | Inorganic foam heat insulating material and preparation method thereof | |
| CN102877614B (en) | Production method of heat insulating and preserving ceramic composite plate with decorative properties | |
| CN102627469B (en) | High-strength light foam ceramic plate and manufacturing method thereof | |
| CN107840612B (en) | High-strength light inorganic energy-saving heat-insulating building material and preparation method thereof | |
| CN101830725B (en) | Light thermal-insulation ceramic tiles and preparation method thereof | |
| CN108033806A (en) | A kind of preparation method of expanded perlite thermal-nsulation brick | |
| CN101182232A (en) | Lightweight ceramic tile and production method | |
| CN102206074A (en) | Environment-friendly decorative, thermal-insulation, sound-insulation, fireproof, anticorrosion material product and manufacturing method thereof | |
| CN103342578A (en) | Porous insulating decorative material prepared by utilizing iron tailings and preparation method thereof | |
| CN102261133A (en) | Glass micro bead/fly ash composite exterior wall insulating board | |
| CN102887721A (en) | Foamed ceramic insulation board and preparation method thereof | |
| CN105924128A (en) | Foamed basalt material and manufacturing method thereof | |
| CN102557540A (en) | Inorganic fireproofing heat-insulation board | |
| CN102115338B (en) | Glazed self-insulation foamed ceramic composite wall material and preparation method thereof | |
| CN104003755A (en) | Process for preparing ventilating brick by using polishing waste residue | |
| CN104609887A (en) | Integral sintering process and equipment for pure microcrystal and microcrystal mixed foamed composite plate | |
| CN105669146A (en) | Autoclaved aerated concrete block containing neutral sodium-salt alkali activated slag concrete and preparation method of autoclaved aerated concrete block | |
| CN105776981A (en) | Heat preservation brick | |
| CN105622158B (en) | A kind of three layers of regrown material of crystallite face bee-hole | |
| CN102219548B (en) | Environment-friendly lightweight ceramic tile foaming agent and preparation method thereof | |
| CN100378024C (en) | Glass micro bead heat insulating fire proof grout | |
| CN105271778B (en) | A kind of color light cellular glass particle and preparation method thereof | |
| CN106085366B (en) | Phase-change material, light phase-change honeycomb concrete plate and preparation method thereof | |
| CN107902979B (en) | Brickwork and manufacturing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120125 Termination date: 20141118 |
|
| EXPY | Termination of patent right or utility model |