CN101994063A - Weathering steel with yield strength of more than 700MPa and manufacturing method thereof - Google Patents
Weathering steel with yield strength of more than 700MPa and manufacturing method thereof Download PDFInfo
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Abstract
The invention relates to Cr-containing weathering steel with the yield strength of more than 700MPa, good toughness and high corrosion resistance, and a manufacturing method thereof. The weathering steel comprises the following components in percentage by weight: 0.02 to 0.10 percent of C, 0.1 to 0.4 percent of Si, 0.3 to 1.3 percent of Mn, less than or equal to 0.01 percent of P, less than or equal to 0.006 percent of S, 0.2 to 0.5 percent of Cu, 2.5 to 10 percent of Cr, 0.2 to 1.0 percent of Ni, 0.02 to 0.06 percent of Nb, 0.01 to 0.05 percent of Al, less than or equal to 0.005 percent of N, 0.02 to 0.10 percent of Ti and the balance of Fe and inevitable impurities. A steel plate made of the steel has the yield strength of more than 700MPa and good toughness; meanwhile, the relative corrosion rate of the steel is reduced by one time compared with that of the conventional weathering steel, so the steel meets the requirement of improving the corrosion resistance of steel for railway vehicles and fulfils the aims of prolonging the service life and reducing maintenance cost.
Description
Technical field
The invention belongs to low alloy steel and make the field, the high anti-corrosion that relates to the good-toughness of a kind of yield strength more than 700MPa contains Cr weathering steel and manufacture method thereof.
Background technology
Weathering steel, or claim weather resisting steel.Under atmosphere Service Environment condition, in the steel between each alloying element interaction takes place, generating with the alpha-feooh on the surface is the fine and close rusty scale of main component, its Thermodynamically stable does not participate in the cathode reduction process of steel galvanic corrosion.The enrichment of elements such as copper, chromium makes rusty scale have ion selectivity and sees through characteristic in the rusty scale, thereby significantly improves the atmospheric corrosion resistance of weathering steel.Weathering steel is widely used in fields such as rail truck manufacturing, container manufacture and bridge construction, outdoor pylon because of its higher corrosion resistance.
At present, both at home and abroad with regard to high-strength weathering steel and manufacture method application thereof multinomial patent, as 2007 disclosed " a kind of high-strength weathering steel and production method thereof " (CN200610125365.2), " a kind of air corrosion resisting high strength low alloy metal and production method thereof " (CN200510111858.6), Japan disclosed in 1992 " HIGH CORROSION RESISTANT STEEL SHEE " (JP04235250A), the U.S. calendar year 2001 disclosed " Ultra low carbon bainitic weatheringsteel " (US6315946) etc.The low Cr weathering steel of steel grade that this several patents (application) is related, Cr content is generally below 0.7%, and its erosion resistance and intensity are lower, are difficult to satisfy requirement of actual application.
1998 disclosed " corrosion-resisting steel " (JP10025550A), 2000 disclosed " CORROSIONRESISTANT STEEL IN THE SOIL " (JP2000336463), 2002 disclosed " corrosion-resistant steel of matrix and heat affected zone good-toughness " (JP2002363704) etc. the related steel grade of several patents (application) on composition, all belong to high Cr weathering steel, its Cr content mostly is between the 9-14% generally more than 7%.Cr content in the steel grade that 2002 disclosed " building structure is with containing the Cr corrosion-resistant steel " (JP2002285298) put down in writing is 5-10%.In addition, in order to improve intensity, the steel grade of the middle record of these patents (application) also contains Mo, the B of inequality, Zr, Co, W etc.The interpolation of these elements has increased manufacturing cost and manufacture difficulty on the one hand, and is unfavorable to the welding and the toughness of steel plate on the other hand.
2004 disclosed " corrosion-resisting steel of heat affected zone good-toughness " (JP2004162119) steel grade of middle record contains the C of mass percentage content up to 0.45-0.65%, though improved the intensity of steel, influenced the welding property of steel greatly.
This shows that weathering steel of the prior art can't satisfy the requirement of using at present and making fully, need a kind of erosion resistance height of exploitation, intensity height, produce economic weathering steel.
Summary of the invention
The object of the present invention is to provide a kind of weathering steel, its good-toughness, and have high-corrosion resistant high-strength, can be used for fields such as rail truck manufacturing, container manufacture and bridge construction, outdoor pylon.
For achieving the above object, weathering steel provided by the present invention, its composition quality degree (wt%) is: C 0.02-0.10, Si 0.1-0.4, Mn 0.3-1.3, P≤0.01, S≤0.006, Cu 0.2-0.5, Cr 2.5-10, Ni 0.2-1.0, Nb 0.02-0.06, Al 0.01-0.05, N≤0.005, Ti 0.02-0.10, all the other are Fe and unavoidable impurities.
In addition, the present invention also provides a kind of manufacture method of above-mentioned weathering steel, comprise that molten iron takes off S, converter top bottom blowing, external refining, continuous casting, slab reheat, controlled rolling, controlled chilling deeply, batches, finishing, wherein, the temperature of described slab reheat is more than 1200 ℃, described controlled rolling comprises that roughing and two sections of finish rolling are rolling, and described controlled chilling is cooled to 550-650 ℃ with the rate of cooling of 10-40 ℃/s.
Preferably, described roughing is controlled at more than 950 ℃, accumulative total deflection 〉=80%; The outlet temperature of described finish rolling is 800-900 ℃, and more preferably, the outlet temperature of described finish rolling is not less than 850 ℃.
To further specify the present invention below.
Weathering steel requires to have higher intensity and corrosion resistance, has good impelling strength and welding property simultaneously.In the present invention, the applicant finds, improves the content of Cr in the steel, can significantly improve the atmospheric corrosion resistance of steel, as shown in Figure 1.Simultaneously, add the toughness that trace alloying element can improve steel.Trace alloying element in the steel is not to play a role separately, and the applicant adopts the mode of compound interpolation alloying element, obtains best effect with less alloy adding, reaches cost-benefit maximization.Below the design of alloying constituent of the present invention is described:
C is a strengthening element main in the steel, can significantly improve the intensity of steel plate; But more C is unfavorable to steel plate welding, toughness and plasticity.Low C design has been to limit the formation of pearlitic structure and other carbide, guarantees that the microstructure of steel is equal phase constitution, has avoided the potential difference between the out-phase to cause galvanic corrosion, has improved the corrosion resisting property of steel.Therefore limiting its mass percentage content is 0.02-0.08%.
The content of Si is controlled at 0.10-0.40%.Si has higher solid solubility in steel, can increase ferrite volume fraction in the steel, crystal grain thinning, thereby help improving toughness, but too high levels can cause welding property to descend, so its mass percentage content is controlled at 0.10-0.40%.
Mn has stronger solution strengthening effect, can significantly reduce the transformation temperature of steel simultaneously, and the microstructure of refinement steel is important highly malleablized element.But Mn content too much makes hardening capacity increase, thereby causes weldability and welding heat influence area toughness to worsen, so its mass percentage content is controlled at 0.3-1.3%.
The existence of S will worsen the atmospheric corrosion resistance of steel, and P can effectively improve the atmospheric corrosion resistance of steel, but P content is crossed high toughness and the plasticity that reduces steel of meeting; Simultaneously, the existence of P easily causes segregation.Thereby extremely low S, the P content of steel grade design employing of the present invention, its mass percentage content is respectively P≤0.01%, S≤0.006%.
Cr has significant effect to the passivation ability that improves steel; can promote the steel surface to form fine and close passive film or protectiveness rusty scale; its enrichment in rusty scale can effectively improve the selective permeation characteristic of rusty scale to corrosive medium; but too high Cr has improved the manufacturing cost of steel plate on the one hand; unfavorable to welding and toughness simultaneously, so control its mass percentage content between 2.5-10%.
Ni can improve intensity to improve the flexible element simultaneously, and can improve hardening capacity, can effectively stop the hot-short check crack that causes of Cu.Because Ni is the noble metal element, for cost factor, and too high Ni can improve the adhesivity of oxide skin, is pressed in the steel and can forms the hot rolling defective on the surface.So its mass percentage content is defined as 0.2-1.0%.
Cu has identical substantially effect with Ni, solid solution and precipitation strength effect is arranged, with the suitable proportioning of Ni, can significantly improve the atmospheric corrosion resistance of steel, but too high unfavorable to welding, and check crack easily takes place during hot rolling, its mass percentage content is controlled at 0.20-0.50%.
Nb is strong carbide forming element, formed fine carbide particle energy thinning microstructure, and produce the precipitation strength effect, significantly improve the intensity of steel plate, but more Nb is unfavorable to welding, so its mass percentage content is defined as 0.02-0.06%.
Al is the reductor that adds in the steel, and mass percentage content is that the Al of 0.01-0.05% helps crystal grain thinning, improves the toughness and tenacity of steel.
The Ti that adds 0.01-0.10% grows up for the austenite crystal that suppresses in the bad thermal process again of plate, suppresses ferrite crystal grain simultaneously and grow up in recrystallize controlled rolling process, improves the toughness of steel.
N can reduce the toughness and the welding property of steel, therefore controls its quality percentage composition≤0.005%.
In the manufacture method provided by the present invention, it is in order to guarantee S content low in the steel that molten iron takes off S deeply; The converter top bottom blowing is in order to control the C content in the steel.
Take all factors into consideration the microalloy element carbonitride in austenite solubility behavior and heat-processed in the austenite crystal behavior of growing up, the temperature of lay special stress on slab reheat of the present invention is more than 1200 ℃.Controlled rolling technology is divided into two sections of roughing and finish rolling.Wherein, for guaranteeing the recrystallize grain refinement effect, roughing is controlled at more than 950 ℃, accumulative total deflection 〉=80%; For guaranteeing the deformation grain refinement effect, the outlet temperature of finish rolling is controlled at 800-900 ℃, if finished product thickness increases, can suitably reduce finishing temperature, preferably is not less than 850 ℃.After this carry out controlled chilling, be cooled to 550-650 ℃,, be cooled to room temperature again, finishing tough through batching with the rate of cooling of 10-40 ℃/s.
With respect to traditional weathering steel, the present invention has the following advantages:
1. the yield strength of steel grade of the present invention reaches more than the 700MPa, belongs to high-strength weathering steel, satisfies the requirement that vehicle reduces member dead weight;
2. the adding of moderate content alloying elements cr makes steel grade of the present invention have good atmospheric corrosion resistance, with respect to traditional weathering steel, the atmospheric corrosion resistance of this steel grade is more than doubled, can replace traditional high-strength weathering steel, be applied to fields such as rail vehicle, freight container, bridge and outdoor pylon, use and maintenance cost to reduce;
3. steel grade of the present invention has good low-temperature flexibility, and under-40 ℃ of conditions, thickness is that the ballistic work of the above steel plate of 10mm is more than 60J;
4. steel grade of the present invention adopts controlled rolling and controlled cooling (TMCP) fabrication process, do not need after rolling to heat-treat, but the hot-rolled state supply of material has effectively guaranteed delivery cycle, has reduced production cost.
Description of drawings
Fig. 1 is that the Cr element is to improving the effect synoptic diagram of steel weathering resistance.
Adopt the weather-proof steel grade of mass percentage content in the 1-9% scope of 500Kg vacuum induction furnace laboratory refining Cr, with plain carbon stool (Q345B, 0Cr) and traditional weathering steel (Q450NQR1,0.5Cr) be comparative example, soak into the cycle infiltration cyclic corrosion experiment that corrosion test method (TB/T2375-93) is carried out 72h by railway with the weathering steel cycle.The relative corrosion rate of different Cr content steel plates this shows that as shown in Figure 1 with respect to traditional weathering steel, after Cr content in the steel alloy was above 3.5%, the atmospheric corrosion resistance of steel was expected to improve 1 times.
Embodiment
According to the composition requirement of steel grade of the present invention, on the 500kg of testing laboratory vacuum induction furnace, smelt steel of the present invention, the chemical ingredients of each embodiment is as shown in table 1.Billet heating temperature is more than 1200 ℃, finishing temperature 800-900 ℃, and roll postcooling to 550 and ℃-650 ℃ batch, air cooling is to room temperature subsequently.The mechanical property of the steel that obtains is as shown in table 2.
The chemical ingredients of table 1 various embodiments of the present invention (wt%)
| Composition | C | Si | Mn | P | S | Al | Cu | Cr | Ni | Nb | Ti | N |
| A | 0.026 | 0.25 | 0.59 | 0.01 | 0.003 | 0.030 | 0.32 | 3.0 | 0.3 | 0.019 | 0.023 | 0.0035 |
| B | 0.032 | 0.3 | 0.65 | 0.01 | 0.004 | 0.024 | 0.35 | 5.05 | 0.49 | 0.038 | 0.062 | 0.0040 |
| C | 0.032 | 0.38 | 0.35 | 0.010 | 0.004 | 0.023 | 0.45 | 4.47 | 0.89 | 0.048 | 0.021 | 0.0047 |
| D | 0.080 | 0.39 | 0.95 | 0.011 | 0.005 | 0.015 | 0.25 | 5.90 | 0.29 | 0.038 | 0.081 | 0.0043 |
| E | 0.062 | 0.15 | 1.15 | 0.011 | 0.005 | 0.037 | 0.46 | 7.57 | 0.65 | 0.054 | 0.018 | 0.0041 |
The mechanical property of table 2 various embodiments of the present invention steel
With plain carbon stool Q345B and high-strength weathering steel Q450NQR1 is comparative sample, soaks into the cycle infiltration cyclic corrosion experiment that corrosion test method (TB/T2375-93) is carried out 72h by railway with the weathering steel cycle.Try to achieve average corrosion rate by calculation sample unit surface corrosion weight loss amount, and then try to achieve the relative erosion rate of steel grade.The atmospheric corrosion resistance of each embodiment steel grade and compared steel is as shown in table 3.
The atmospheric corrosion resistance of table 3 various embodiments of the present invention steel
| Steel grade | Average corrosion rate (mg/cm 2·h) | Relative erosion rate (%) |
| Q345B | 0.48009676 | 100.0 |
| Q450NQR1 | 0.19749611 | 41.0 |
| A | 0.11536241 | 23.9596773 |
| B | 0.09856708 | 20.4714478 |
| C | 0.1039275 | 21.5847555 |
| D | 0.07419292 | 15.4091647 |
| E | 0.03485333 | 7.23870553 |
Yield strength by steel grades scope of design of the present invention and rolling technology control techniques gained embodiment steel reaches more than the 700MPa, and unit elongation has good impelling strength and lower yield tensile ratio simultaneously more than 16%; The atmospheric corrosion resistance comparing result also shows that the atmospheric corrosion resistance of steel grade of the present invention is more than doubled with respect to the performance requriements (corrosion rate≤55% relatively) of traditional high-strength weathering steel.Therefore, weathering steel of the present invention can replace traditional weathering steel and weathering steel commonly used at present fully, is applied to satisfy the demand in rail vehicle, freight container manufacturing and fields such as bridge and outdoor pylon under the atmospheric environment condition.
Claims (5)
1. weathering steel, its composition quality degree is:
C：0.02-0.10
Si：0.1-0.4
Mn：0.3-1.3
P：≤0.01
S：≤0.006
Cu：0.2-0.5
Cr：2.5-10
Ni：0.2-1.0
Nb：0.02-0.06
Al：0.01-0.05
N：≤0.005
Ti：0.02-0.10
Surplus is Fe and unavoidable impurities.
2. make the method for weathering steel as claimed in claim 1, comprise that molten iron takes off S, converter top bottom blowing, external refining, continuous casting, slab reheat, controlled rolling, controlled chilling deeply, batches, finishing, wherein, the temperature of described slab reheat is more than 1200 ℃, described controlled rolling comprises that roughing and two sections of finish rolling are rolling, and described controlled chilling is cooled to 550-650 ℃ with the rate of cooling of 10-40 ℃/s.
3. method as claimed in claim 2 is characterized in that, described roughing is controlled at more than 950 ℃, accumulative total deflection 〉=80%.
4. as claim 2 or 3 described methods, it is characterized in that the outlet temperature of described finish rolling is 800-900 ℃.
5. as claim 2 or 3 described methods, it is characterized in that the outlet temperature of described finish rolling is not less than 850 ℃.
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Cited By (17)
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| CN103343295A (en) * | 2013-05-21 | 2013-10-09 | 马钢(集团)控股有限公司 | Sheet steel with high strength, high corrosion resistance and yield strength of 700 Mpa and production method thereof |
| CN103469094A (en) * | 2013-08-21 | 2013-12-25 | 日照钢铁控股集团有限公司 | Chloride ion corrosion resistant pipeline steel and preparation method thereof |
| CN103882322A (en) * | 2014-03-13 | 2014-06-25 | 济钢集团有限公司 | 590 Mpa-grade high-strength structural steel plate and manufacturing method thereof |
| CN105861954A (en) * | 2015-01-23 | 2016-08-17 | 新疆丰泰化工科技有限公司 | Alloy steel liner for Mannheim furnace |
| CN107557698A (en) * | 2017-08-02 | 2018-01-09 | 包头钢铁（集团）有限责任公司 | Highly corrosion resistant type railway compartment steel of RE-treated and preparation method thereof |
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| CN111235464A (en) * | 2020-03-06 | 2020-06-05 | 马鞍山钢铁股份有限公司 | Titanium microalloyed economical high-strength weathering steel and production method thereof |
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| CN115141974A (en) * | 2022-06-15 | 2022-10-04 | 宝山钢铁股份有限公司 | High-strength high-plasticity hot-rolled strip steel with high weather resistance and manufacturing method thereof |
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| CN105861954A (en) * | 2015-01-23 | 2016-08-17 | 新疆丰泰化工科技有限公司 | Alloy steel liner for Mannheim furnace |
| CN107557698A (en) * | 2017-08-02 | 2018-01-09 | 包头钢铁（集团）有限责任公司 | Highly corrosion resistant type railway compartment steel of RE-treated and preparation method thereof |
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Application publication date: 20110330 |