CN101985401A - Novel fireproof module and manufacturing method thereof - Google Patents
Novel fireproof module and manufacturing method thereof Download PDFInfo
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- CN101985401A CN101985401A CN 201010183208 CN201010183208A CN101985401A CN 101985401 A CN101985401 A CN 101985401A CN 201010183208 CN201010183208 CN 201010183208 CN 201010183208 A CN201010183208 A CN 201010183208A CN 101985401 A CN101985401 A CN 101985401A
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Abstract
The invention discloses a novel fireproof module, which comprises the following components in part by weight: 450 to 460 parts of expanded vermiculite, 295 to 308 parts of high-temperature adhesive and 639.8 to 680.3 parts of aqueous composite macromolecular flame-retardant emulsion adhesive base material. The invention also discloses a preparation method for the novel fireproof module. The novel fireproof module has the characteristics of environment friendliness, high waterproof property and fireproof property.
Description
Technical field
The present invention relates to a kind of novel fire-retardant module and manufacture method thereof, belong to the impregnating material technical field.
Background technology
Along with the develop rapidly of Chinese national economy and the increasing of modernization construction dynamics, energy problem becomes increasingly conspicuous, the production and the usage quantity of electric energy also increase considerably, so also increase thereupon of power-generating enterprise's construction, and the fireproof blocking requirement of its electric wire, cable, electrical equipment also constantly increases.Simultaneously, for improving the fire-resistant requirement of fireproof blocking, domestic existing unit develops the fire retardant module product of new generation of easy construction for the city.In order to catch up with the market paces, domestic fire retardant module has been carried out check and analysis, find its fire retardant module is in propaganda perfectly, and exist a lot of defectives.One, poor water resistance.Test dissipated into particle less than one day with regard to dividing in water; Its two, when carrying out combustion test, along with burning is carried out, the bulging force that the expanded polystyrene veneer of the important materials of its composition fecund is given birth to constantly is dispersed into particulate with module, the baking back claims ashes at last, module is disintegrated, and does not meet fire protection requirement; Its three therefore owing to do not add fire retardant in its polymer binder, certain ignition quality is arranged.
Summary of the invention
The object of the present invention is to provide a kind of novel fire-retardant module and manufacture method thereof, have the high characteristics of environmental protection, water tolerance and fire performance.
A kind of novel fire-retardant module comprises following compositions in weight portion:
Expanded vermiculite (purchasing) 450-460 in the clean Xiang Fanghuobaowencailiaochang of Jiaxing City;
High-temperature adhesives (purchasing bimodal refractory factory) 295-308 in Zichuan District, Zibo City;
The fire-retardant emulsion binding agent base-material of water-soluble composite high molecular polymer 639.8-680.3.
Described novel fire-retardant module preferably includes following compositions in weight portion:
Expanded vermiculite 455;
High-temperature adhesives 300;
The fire-retardant emulsion binding agent base-material 665 of water-soluble composite high molecular polymer.
The fire-retardant emulsion binding agent base-material of described water-soluble composite high molecular polymer comprises following compositions in weight portion:
Polymer binder 280-295;
Halogen-free flame retardants 35-45;
Stibium trioxide powder 4.8-5.3;
Water 320-335.
The fire-retardant emulsion binding agent base-material of described water-soluble composite high molecular polymer preferably includes following compositions in weight portion:
Polymer binder 290;
Halogen-free flame retardants 40;
Stibium trioxide powder (purchasing) 5 in Jinan Chen Xu chemical industry company limited;
Water 330.
Described high-temperature adhesives adopt any one in porcelain powder or the diatomite.
Described polymer binder adopts any one in vinyl acetate between to for plastic-ethylene copolymerization emulsions (VAE), white glues, polyvinyl acetate, the natural rubber; (all purchasing) in Beijing Organic Chemical Plant
Described halogen-free flame retardants adopts any one in triaryl phosphate (IPP), the triguaiacyl phosphate (TDCPP).(all purchasing) in Jinan Chen Xu chemical industry company limited
A kind of manufacture method of novel fire-retardant module may further comprise the steps:
The preparation of a, tackiness agent base-material: polymer binder, halogen-free flame retardants, stibium trioxide powder, water are put into dispersion machine high speed dispersed with stirring according to the above ratio, form the fire-retardant emulsion binding agent base-material of water-soluble composite high molecular polymer;
The preparation of b, major ingredient: lagging material expanded vermiculite and jointing material high-temperature adhesives are put into the stirrer for mixing formation major ingredient that is uniformly dispersed;
C: major ingredient and tackiness agent base-material are mixed, utilize stirrer fully to be uniformly dispersed, form mixed solution;
D, on mould, coat mold oil in advance, utilize the mixed solution among the step c to carry out molding then, compacting again, drying and the demoulding novel fire-retardant module of the present invention.
Beneficial effect of the present invention is: owing to adopt expanded vermiculite among the present invention, this material is the heat insulation expanding material of nontoxic inorganic light weight back-fire relief, in conjunction with the fire-retardant emulsion binder of aqueous, environmental protective composite high-molecular, the inorganic high-temp tackiness agent is composite, and through mix and stir, technological process such as molding, compacting, oven dry makes, the fire-retardant emulsion binder of aqueous, environmental protective composite high-molecular can make performances such as the product of making has certain elasticity, can cut, perforation.Product of the present invention has certain flame retardant resistance when meeting fire, does not produce toxic gas again, environmental protection, and have simultaneously that water tolerance, oil-proofness are good, the characteristics of light weight, ultimate compression strength height, easy construction.
In order further to explain technical scheme of the present invention, the present invention will be described in detail below by specific embodiment.
Embodiment
Embodiment 1
A kind of novel fire-retardant module of present embodiment comprises following compositions in weight portion: expanded vermiculite 450; Porcelain powder 308; The fire-retardant emulsion binding agent base-material 639.8 of water-soluble composite high molecular polymer.The fire-retardant emulsion binding agent base-material of described water-soluble composite high molecular polymer comprises following compositions in weight portion: VAE280; IPP35; Stibium trioxide powder 4.8; Water 320.
The manufacture method of the novel fire-retardant module of present embodiment may further comprise the steps:
The preparation of a, tackiness agent base-material: VAE, IPP, stibium trioxide powder, water are put into dispersion machine high speed dispersed with stirring according to the above ratio, form the fire-retardant emulsion binding agent base-material of water-soluble composite high molecular polymer;
The preparation of b, major ingredient: lagging material expanded vermiculite and jointing material porcelain powder are put into the stirrer for mixing formation major ingredient that is uniformly dispersed;
C: major ingredient and tackiness agent base-material are mixed, utilize stirrer fully to be uniformly dispersed, form mixed solution;
D, on mould, coat mold oil in advance, utilize the mixed solution among the step c to carry out molding then, compacting again, drying and the demoulding novel fire-retardant module of the present invention.
Embodiment 2
A kind of novel fire-retardant module of present embodiment comprises following compositions in weight portion: expanded vermiculite 455; Diatomite 300; The fire-retardant emulsion binding agent base-material 665 of water-soluble composite high molecular polymer.The fire-retardant emulsion binding agent base-material of described water-soluble composite high molecular polymer comprises following compositions in weight portion: white glues 290; TDCPP 40; Stibium trioxide powder 5; Water 330.
The manufacture method of the novel fire-retardant module of present embodiment may further comprise the steps:
The preparation of a, tackiness agent base-material: white glues, TDCPP, stibium trioxide powder, water are put into dispersion machine high speed dispersed with stirring according to the above ratio, form the fire-retardant emulsion binding agent base-material of water-soluble composite high molecular polymer;
The preparation of b, major ingredient: lagging material expanded vermiculite and jointing material diatomite are put into the stirrer for mixing formation major ingredient that is uniformly dispersed;
C: major ingredient and tackiness agent base-material are mixed, utilize stirrer fully to be uniformly dispersed, form mixed solution;
D, on mould, coat mold oil in advance, utilize the mixed solution among the step c to carry out molding then, compacting again, drying and the demoulding novel fire-retardant module of the present invention.
Embodiment 3
A kind of novel fire-retardant module of present embodiment comprises following compositions in weight portion: expanded vermiculite 460; Diatomite 295; The fire-retardant emulsion binding agent base-material 680.3 of water-soluble composite high molecular polymer.The fire-retardant emulsion binding agent base-material of described water-soluble composite high molecular polymer comprises following compositions in weight portion: polyvinyl acetate 295; TDCPP 45; Stibium trioxide powder 5.3; Water 335.
The manufacture method of the novel fire-retardant module of present embodiment may further comprise the steps:
The preparation of a, tackiness agent base-material: polyvinyl acetate, TDCPP, stibium trioxide powder, water are put into dispersion machine high speed dispersed with stirring according to the above ratio, form the fire-retardant emulsion binding agent base-material of water-soluble composite high molecular polymer;
The preparation of b, major ingredient: lagging material expanded vermiculite and jointing material diatomite are put into the stirrer for mixing formation major ingredient that is uniformly dispersed;
C: major ingredient and tackiness agent base-material are mixed, utilize stirrer fully to be uniformly dispersed, form mixed solution;
D, on mould, coat mold oil in advance, utilize the mixed solution among the step c to carry out molding then, compacting again, drying and the demoulding novel fire-retardant module of the present invention.
Embodiment 4
A kind of novel fire-retardant module of present embodiment comprises following compositions in weight portion: expanded vermiculite 458; Porcelain powder 398; The fire-retardant emulsion binding agent base-material 666.9 of water-soluble composite high molecular polymer.The fire-retardant emulsion binding agent base-material of described water-soluble composite high molecular polymer comprises following compositions in weight portion: natural rubber 292; IPP42; Stibium trioxide powder 4.9; Water 328.
The manufacture method of the novel fire-retardant module of present embodiment may further comprise the steps:
The preparation of a, tackiness agent base-material: natural rubber, IPP, stibium trioxide powder, water are put into dispersion machine high speed dispersed with stirring according to the above ratio, form the fire-retardant emulsion binding agent base-material of water-soluble composite high molecular polymer;
The preparation of b, major ingredient: lagging material expanded vermiculite and jointing material porcelain powder are put into the stirrer for mixing formation major ingredient that is uniformly dispersed;
C: major ingredient and tackiness agent base-material are mixed, utilize stirrer fully to be uniformly dispersed, form mixed solution;
D, on mould, coat mold oil in advance, utilize the mixed solution among the step c to carry out molding then, compacting again, drying and the demoulding novel fire-retardant module of the present invention.
The product of embodiment of the invention 1-4 preparation detects accord with Q/ZCK.015-2010 standard-required through national quality technical supervision unit, surpasses national standard and industry standard on integrated performance index.The quality index of gained is:
Outward appearance light golden rod yellow or light gray colour pattern piece
Apparent density (kg/m
3)≤1.0 * 10
3
Water tolerance (d) 〉=30, not swelling, do not ftracture
Oil-proofness (d) 〉=7 corrosion, corrosion phenomenon should not occur
Humidity resistance (h) 〉=120 does not ftracture, not efflorescence
Do not ftracture, not efflorescence in freeze-thawing resistant circulation (inferior) 〉=15
Ultimate compression strength (Mp) irradiation is forward and backward: R 〉=0.1
Expansion character (%) 〉=120
Toxic gas content ppm (mg/m
3) CO≤50 (55)
CO
2 ≤5000(9000)
HCl ≤5(7.5)
HCN ≤10(11)
Anti-irradiation test does not have phenomenons such as dimensional change, cracking
Combustionproperty (level) V-O
Fire resistance period (min) 〉=210.
Claims (8)
1. novel fire-retardant module is characterized in that comprising following compositions in weight portion:
Expanded vermiculite 450-460;
High-temperature adhesives 295-308;
The fire-retardant emulsion binding agent base-material of water-soluble composite high molecular polymer 639.8-680.3.
2. a kind of novel fire-retardant module as claimed in claim 1 is characterized in that described novel fire-retardant module, comprises following compositions in weight portion:
Expanded vermiculite 455;
High-temperature adhesives 300;
The fire-retardant emulsion binding agent base-material 665 of water-soluble composite high molecular polymer.
3. a kind of novel fire-retardant module as claimed in claim 1 is characterized in that the fire-retardant emulsion binding agent base-material of described water-soluble composite high molecular polymer, comprises following compositions in weight portion:
Polymer binder 280-295;
Halogen-free flame retardants 35-45;
Stibium trioxide powder 4.8-5.3;
Water 320-335.
4. a kind of novel fire-retardant module as claimed in claim 3 is characterized in that the fire-retardant emulsion binding agent base-material of described water-soluble composite high molecular polymer, comprises following compositions in weight portion:
Polymer binder 290;
Halogen-free flame retardants 40;
Stibium trioxide powder 5;
Water 330.
5. a kind of novel fire-retardant module as claimed in claim 2 is characterized in that described high-temperature adhesives adopt any one in porcelain powder or the diatomite.
6. a kind of novel fire-retardant module as claimed in claim 4 is characterized in that described polymer binder adopts any one in vinyl acetate between to for plastic-ethylene copolymerization emulsions, white glues, polyvinyl acetate, the natural rubber.
7. a kind of novel fire-retardant module as claimed in claim 4 is characterized in that described halogen-free flame retardants adopts any one in triaryl phosphate, the triguaiacyl phosphate.
8. the manufacture method of a novel fire-retardant module as claimed in claim 1 may further comprise the steps:
The preparation of a, tackiness agent base-material: polymer binder, halogen-free flame retardants, stibium trioxide powder, water are put into dispersion machine high speed dispersed with stirring according to the above ratio, form the fire-retardant emulsion binding agent base-material of water-soluble composite high molecular polymer;
The preparation of b, major ingredient: lagging material expanded vermiculite and jointing material high-temperature adhesives are put into the stirrer for mixing formation major ingredient that is uniformly dispersed;
C: major ingredient and tackiness agent base-material are mixed, utilize stirrer fully to be uniformly dispersed, form mixed solution;
D, on mould, coat mold oil in advance, utilize the mixed solution among the step c to carry out molding then, compacting again, drying and the demoulding novel fire-retardant module of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101832083A CN101985401B (en) | 2010-05-22 | 2010-05-22 | Novel fireproof module and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101832083A CN101985401B (en) | 2010-05-22 | 2010-05-22 | Novel fireproof module and manufacturing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101985401A true CN101985401A (en) | 2011-03-16 |
| CN101985401B CN101985401B (en) | 2012-11-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010101832083A Expired - Fee Related CN101985401B (en) | 2010-05-22 | 2010-05-22 | Novel fireproof module and manufacturing method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999059935A1 (en) * | 1998-05-15 | 1999-11-25 | The Welding Institute | Heat resistant product and method |
| CN101134854A (en) * | 2007-10-08 | 2008-03-05 | 彭桦 | Tunnel fire-proof paint |
| CN101168478A (en) * | 2006-10-24 | 2008-04-30 | 陈振铎 | Fire-proof material, fire retardant module and fire-proof plate prepared from the same |
-
2010
- 2010-05-22 CN CN2010101832083A patent/CN101985401B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999059935A1 (en) * | 1998-05-15 | 1999-11-25 | The Welding Institute | Heat resistant product and method |
| CN101168478A (en) * | 2006-10-24 | 2008-04-30 | 陈振铎 | Fire-proof material, fire retardant module and fire-proof plate prepared from the same |
| CN101134854A (en) * | 2007-10-08 | 2008-03-05 | 彭桦 | Tunnel fire-proof paint |
Non-Patent Citations (2)
| Title |
|---|
| 《Polymer International》 20001231 Heinrich Horacek et al. The importance of intumescent systems for fire protection of plastic materials 1106-1114 1－8 第49卷, * |
| 《建筑工业信息》 19880813 陈业明 以膨胀蛭石为基材的绝热材料 10 1－8 , * |
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| Publication number | Publication date |
|---|---|
| CN101985401B (en) | 2012-11-21 |
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Owner name: ZHEJIANG CHUANKE PREVENTING AND PROTECTING MATERIA Free format text: FORMER OWNER: YUAN XUEXIANG Effective date: 20130208 |
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Effective date of registration: 20130208 Address after: 312462, Shaoxing, Zhejiang, Shengzhou Province Economic Development Zone, Zhejiang branch of Sichuan Branch of protective materials development Co., Ltd. Patentee after: Zhejiang Chuanke Safety Material Development Co., Ltd. Address before: 312462 room four, unit 1, Taihe apartments, Shengzhou, Zhejiang 208, China Patentee before: Yuan Xuexiang |
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Granted publication date: 20121121 Termination date: 20150522 |
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