CN101979448B - Starflower aesthetical paint and preparation and using methods thereof - Google Patents
Starflower aesthetical paint and preparation and using methods thereof Download PDFInfo
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- CN101979448B CN101979448B CN 201010531401 CN201010531401A CN101979448B CN 101979448 B CN101979448 B CN 101979448B CN 201010531401 CN201010531401 CN 201010531401 CN 201010531401 A CN201010531401 A CN 201010531401A CN 101979448 B CN101979448 B CN 101979448B
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Abstract
The invention relates to a starflower aesthetical paint, which consists of the following components in percentage by mass: 40 to 50 percent of film-forming resin, 12 to 25 percent of coloring pigment, 3 to 8 percent of cosolvent, 10 to 20 percent of diluent, 8 to 15 percent of polypropylene resin color masterbatch particle and 1 to 1.5 percent of aid, wherein the polypropylene resin color masterbatch particles are solid particles in various colors with the grain size of 10-2,000 mu m. The starflower aesthetical paint is convenient to manufacture and construct, a starflower-texture decorative and protective coating can be formed, and simultaneously the coated workpieces are highly protected.
Description
Technical field
The present invention relates to a kind of star flower novelty finish and preparation and method of use, belong to and to spend texture and to have the novelty finish technical field of protection decoration function by the formation star on surfaces such as various household electrical appliance, toy, instrument, hardware appliance, auto parts machineries.
Background technology
In people's daily life and production field; There is the outward appearance of many articles for use only need not protect with paint with defencive function; But also need carry out application with novelty finish with protection, decoration both; Improve the aesthetic image of product appearance with this, increase value-added content of product and competitive power.Novelty finish is according to the paint performance; Use speciality tool; On various sundries surface, imitate out natural colored and natural pattern; Be the paint kind that constitutes by special material, this lacquer liquid covered with paint, lacquer, colour wash, etc. when sundries are surperficial that the nature of filming forms multiple patterns such as mallear stria, wrinkle, crackle, frost flower with special usefulness.For the frost flower novelty finish mainly by varnish, take off floating aluminium powder, YLENE, turps and rosin and mix; But take off floating aluminium powder by toluene, YLENE and rosin constitute take off floating agent and aluminium powder constitutes, and the pigment of aluminium powder to be ice making spend base utilizes argentine pigment, the quality of aluminium powder light; The characteristics of buoyancy height, strong covering power and good stability; On enamelled coating, play the reflected light performance, after the film forming, give object decoration sense attractive in appearance especially.Since the existence of aluminium powder make the formed frost flower pattern of enamelled coating have that stereoscopic sensation is strong, color is unusual, bright like mirror, cover the coarse effect of object plane.But when making the frost flower novelty finish; By mass percentage the rosin of 30% toluene, 57% YLENE and 13% is processed and taken off floating agent; Again by weight than 1: 5～7 with aluminium powder with take off floating agent and process and take off floating aluminium powder, but make when taking off floating aluminium powder, not only the tired lock of operation; And be prone to cause that to take off floating good aluminium powder oxidized, make the novelty finish quality that makes be difficult for guaranteeing.Moreover this novelty finish is in construction process, earlier to being handled by the lacquer object plane; Then object plane is brushed white alkyd ready-mixed paint twice, treat thorough drying after, frost flower lacquer is coated on the object plane; Aluminium powder in frost flower lacquer is deposited to the end fully, and surface smoothing is in the time of also can seeing thread, point-like; Just form the frost flower base, after forming the frost flower base, dipped in the lacquer liquid of transferring rare frost flower lacquer with brush again; And on the object plane that coated with lacquer, carry out random drip, it is netted to let the lines of drip become, and the gap of lines is not excessive.After dripping off, pull out some lines with chicken feather in rare slightly gap, after about 20 minutes, sleet decorative pattern in different poses and with different expressions promptly occurs at once.But contain YLENE in the above-mentioned novelty finish, and YLENE there is hormesis to eye and respiratory tract, environment and human beings'health have been brought certain harm.And adopt above-mentioned frost flower lacquer in coating process, not only complicated operation, and having relatively high expectations to operator.
Summary of the invention
The object of the invention provides a kind of manufacturing, easy construction, can form star flower texture and decorate supercoat, simultaneously to being coated with star flower novelty finish and preparation and the method for use that workpiece also has strong provide protection.
The present invention is that the technical scheme that achieves the above object is: a kind of star flower novelty finish, and it is characterized in that: its raw material is formed by having following component by mass percent:
Film-forming resin 40-50%;
Tinting pigment 12-25%;
True solvent 3-8%;
Thinner 10-20%;
Acrylic resin look female particulate 8-15%;
Auxiliary agent 1.0-1.5%;
Described Vestolen PP 7052 look female particulate is shades of colour, the particle diameter solid particulate at the 10-2000 mu m range.
Wherein: described film-forming resin is the wherein a kind of of resol, Synolac, aminoresin, epoxy resin, urethane resin, vinyl resin and fluorocarbon resin, or any two kinds mixture.
Described tinting pigment be white titanium pigment, zinc sulfide white, carbon black, red, medium chrome yellow medium yellow, phthalein blue or green blue, phthalein is dark green, iron oxide red powder, iron oxide yellow powder wherein a kind of, or two or more mixture.
Described true solvent is hexone solvent or dibasic acid esters high boiling solvent.
Described thinner is fat hydrocarbon solvent, terpenes solvent, esters solvent or the two or more mixed solvent of alcoholic solvent.
Described auxiliary agent is siccative and dispersion agent and anti-settling agent or skimmer.
The preparation method of star flower novelty finish of the present invention; It is characterized in that: by mass percentage; The auxiliary agent of the thinner of the film-forming resin of the tinting pigment of 12-25%, 40-50%, 10-20%, 1.0-1.5% dropped in the proportion container stir, grind masher with high speed mixture is dispersed to fineness≤30 μ m, stir after adding the true solvent of 3-8% again; Add the female particulate of acrylic resin look of the 8-15% of required color at last, and stir and promptly process star flower novelty finish.
The method of use of star flower novelty finish of the present invention; It is characterized in that: spend novelty finish to be coated on the star that makes with the form of construction work of aerial spraying or electrostatic spraying and be coated with on the workpiece; Wet-film thickness is controlled at 120-300 μ m; Stationary indoors surface drying 15-30 minute; To be coated with workpiece again and be placed in the 70-100 ℃ of far infrared baking oven baking and take out after 40-100 minute, and make being coated with and form hard firm Vestolen PP 7052 look female particulate on the workpiece after true solvent part swelling and produce and be the color fine arts paint film of star pattern.
The present invention has the following advantages after adopting the art technical scheme:
The female particulate of the acrylic resin look that the present invention selects for use is that particle diameter is the solid particulate of 10-2000 μ m; And wet-film thickness is controlled at 120-300 μ m; Make the particle diameter of acrylic resin look female particulate obviously spend the novelty finish build, decorate supercoat so can form unique star flower texture greater than star.2, the true solvent of being selected for use in the star of the present invention flower novelty finish can be with acrylic resin look female particulate swelling at short notice; In system lacquer process; Through control thinner consumption, can make solvent system only be dissolved into film resin, and can not cause swelling acrylic resin look female particulate; Thereby guarantee star flower novelty finish between staging life acrylic resin look female particulate swelling does not take place; And after the construction spraying, because the thinner evaporation rate faster than true solvent, makes true solvent strength in film process, have one to improve process gradually; The final acrylic resin look female particulate that produces is formed unique star flower texture and decorates supercoat by the swelling phenomenon.3, star flower novelty finish of the present invention only need be through after the spraying; Adopt 70-100 ℃ temperature to force heat drying; To promote acrylic resin look female particulate generation secondary aggregation to form bigger acrylic resin look female particle aggregate; And then under the true solvent action on the coating interface, make the female particulate generation of the acrylic resin look swelling on the aggregate coating interface, finally make a large amount of acrylic resin looks female particulate fully by adhered to one another on enamelled coating; After the solvent of taking seriously all volatilizees; Be coated on the workpiece and form hard firm Vestolen PP 7052 look female particulate after true solvent part swelling and the peculiar color fine arts of star pattern that are that produce are filmed, not only have excellent decoration property, also had stronger provide protection being coated with workpiece; The surface of the star flower fine arts decoration of hardness height, strong adhesion can be obtained, the protection decoration function of star flower texture can be formed on surfaces such as various household electrical appliance, toy, instrument, hardware appliance, auto parts machineries.
Embodiment
Star flower novelty finish of the present invention, its raw material is formed by having following component by mass percent:
Film-forming resin 40-50%;
Tinting pigment 12-25%;
True solvent 3-8%;
Thinner 10-20%;
Acrylic resin look female particulate 8-15%;
Auxiliary agent 1-1.5%;
Above-mentioned Vestolen PP 7052 look female particulate is shades of colour, the particle diameter solid particulate at the 10-2000 mu m range; As adopt colored masterbatch such as black, white, redness, yellow, imitative gold, imitative copper, imitative silver; And film-forming resin is the wherein a kind of of resol, Synolac, aminoresin, epoxy resin, urethane resin, vinyl resin and fluorocarbon resin or any two or more mixture; This resol can adopt pure phenolic resin or modified phenolic resins, and modified phenolic resins adopts the modification of flax oil rosin phenolic resin; Synolac can adopt common Synolac or modified alkyd resin; Modified alkyd resin such as drying-type styrene alkyd resin or acrylic-modified Synolac or tertiary monocarboxylic acid modified alkyd resin etc.; This epoxy resin adopts E-20 (601), E-12 (604) or E-06 (607) etc.; And urethane resin adopts the blocked polyurethane resin, and vinyl resin can adopt thermoplastic acrylic resin or thermal-curable acrylic resin, and fluorocarbon resin can adopt FEVE fluorine resin etc.Tinting pigment of the present invention be white titanium pigment, zinc sulfide white be lithopone, carbon black, red, medium chrome yellow medium yellow, phthalein blue or green blue, phthalein is dark green, iron oxide red powder, iron oxide yellow powder wherein a kind of, or two or more mixture respectively is modulated into required color through each pigment.True solvent of the present invention is that hexone solvent or dibasic acid esters high boiling solvent are DBE etc.; Thinner of the present invention is fat hydrocarbon solvent, terpenes solvent, esters solvent or the two or more mixed solvent of alcoholic solvent; This fat hydrocarbon solvent is like No. 120 solvent oils or 100-3 solvent wet goods; Terpenes solvent such as turps; Esters solvent such as N-BUTYL ACETATE etc., alcoholic solvent such as ethanol, Virahol or propyl carbinol etc.; Auxiliary agent of the present invention is siccative and dispersion agent and anti-settling agent or skimmer; Can adopt cobaltic drier, manganic drier or zirconium driers etc. like siccative; Its dispersion agent adopts titanate coupling agent such as organic titanate composite dispersing agent etc., and anti-settling agent adopts organic bentonite, polyolefin-wax particulate etc., and skimmer is selected the free and unfettered infusion of modified organic silicon class for use; Like modest 5500 skimmers of moral, can prepare as requested.
Star flower concrete component of novelty finish of the present invention and quality proportion by subtraction are seen table 1
Table 1
The resol of film-forming resin adopts the modification of flax oil rosin phenolic resin in the foregoing description 2, and dispersion agent is selected the organic titanate composite dispersing agent for use, can make phenolic aldehyde star flower novelty finish.When gathering aminoresin and select butyl ether melamino-formaldehyde aminoresin and Synolac for use in the film-forming resin, make alkyd one amino star flower novelty finish among the embodiment 3 through above-mentioned component.And the vinyl resin among the embodiment 5 adopts thermal-curable acrylic resin, and urethane resin adopts butyl ether melamino-formaldehyde aminoresin, can make vinylformic acid-amino star flower novelty finish.
The present invention presses the mass percent of table 1; Tinting pigment, film-forming resin, thinner, auxiliary agent are dropped in the proportion container and stir, and are under 0 ℃-50 ℃ in temperature, disperse speed to grind with 6000-20000rpm to mixture with grinding masher at a high speed; Mixture is dispersed to fineness≤30 μ m; Stir after adding true solvent again, add the female particulate of acrylic resin look of required color at last, and stir and promptly process star flower novelty finish.
The method of use of star flower novelty finish of the present invention; Spending novelty finish to be coated on the star that makes with the form of construction work of aerial spraying or electrostatic spraying is coated with on the workpiece; Wet-film thickness is controlled at 120-300 μ m; Stationary indoors surface drying 15-30 minute will be coated with workpiece again and be placed in the 70-100 ℃ of far infrared baking oven baking and take out after 40-100 minute, make being coated with and form hard firm Vestolen PP 7052 look female particulate on the workpiece after true solvent part swelling and produce and be the color fine arts paint film of star pattern; This fine arts paint film not only has excellent decoration property, is also had stronger provide protection to being coated with workpiece simultaneously.
Claims (5)
1. a star is spent novelty finish, and it is characterized in that: its raw material is formed by having following component by mass percent:
Film-forming resin 40-50%;
Tinting pigment 12-25%;
True solvent 3-8%;
Thinner 10-20%;
Acrylic resin look female particulate 8-15%;
Auxiliary agent 1.0-1.5%;
Described Vestolen PP 7052 look female particulate is shades of colour, the particle diameter solid particulate at the 10-2000 mu m range; Described film-forming resin is the wherein a kind of of resol, Synolac, aminoresin, epoxy resin, urethane resin, vinyl resin and fluorocarbon resin; Or any two kinds mixture; Described true solvent is hexone solvent or dibasic acid esters high boiling solvent, and described thinner is fat hydrocarbon solvent, terpenes solvent, esters solvent or the two or more mixed solvent of alcoholic solvent.
2. star according to claim 1 flower novelty finish is characterized in that: described tinting pigment be white titanium pigment, zinc sulfide white, carbon black, red, medium chrome yellow medium yellow, phthalein blue or green blue, phthalein is dark green, iron oxide red powder, iron oxide yellow powder wherein a kind of, or two or more mixture.
3. star flower novelty finish according to claim 1, it is characterized in that: described auxiliary agent is siccative and dispersion agent and anti-settling agent or skimmer.
4. spend the preparation method of novelty finish according to the said star of claim 1; It is characterized in that: by mass percentage; The auxiliary agent of the thinner of the film-forming resin of the tinting pigment of 12-25%, 40-50%, 10-20%, 1.0-1.5% dropped in the proportion container stir; With grinding masher is dispersed to fineness≤30 μ m with mixture at a high speed; Stir after adding the true solvent of 3-8% again, add the acrylic resin look female particulate of the 8-15% of required color at last, and stir and promptly process star flower novelty finish.
5. according to the method for use of claim 1 or 4 described stars flower novelty finishes; It is characterized in that: spend novelty finish to be coated on the star that makes with the form of construction work of aerial spraying or electrostatic spraying and be coated with on the workpiece; Wet-film thickness is controlled at 120-300 μ m; Stationary indoors surface drying 15-30 minute; To be coated with workpiece again and be placed in the 70-100 ℃ of far infrared baking oven baking and take out after 40-100 minute, and make being coated with and form hard firm Vestolen PP 7052 look female particulate on the workpiece after true solvent part swelling and produce and be the color fine arts paint film of star pattern.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201010531401 CN101979448B (en) | 2010-10-27 | 2010-10-27 | Starflower aesthetical paint and preparation and using methods thereof |
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| CN 201010531401 CN101979448B (en) | 2010-10-27 | 2010-10-27 | Starflower aesthetical paint and preparation and using methods thereof |
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| CN101979448A CN101979448A (en) | 2011-02-23 |
| CN101979448B true CN101979448B (en) | 2012-12-12 |
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Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102898914A (en) * | 2012-10-29 | 2013-01-30 | 龚维德 | Acrylic acid hammer paint and preparation method thereof |
| CN103992699A (en) * | 2014-05-19 | 2014-08-20 | 安徽嘉木橡塑工业有限公司 | White fluorocarbon coating |
| CN104017450B (en) * | 2014-06-26 | 2017-05-17 | 立邦工业涂料(上海)有限公司 | Acrylic polyurethane finish paint and preparation method thereof |
| CN106280900A (en) * | 2016-08-29 | 2017-01-04 | 安徽宇腾真空电气有限责任公司 | A kind of special bright face, high-voltage switch gear surface paint |
| CN107177292A (en) * | 2017-07-27 | 2017-09-19 | 太仓市科教新城琉璃艺术策划中心 | A kind of coloured glaze red phenolic resin coating |
| CN107365519A (en) * | 2017-08-09 | 2017-11-21 | 新乡学院 | A kind of water proof type gouache pigment formula and preparation method |
| CN107523114A (en) * | 2017-08-11 | 2017-12-29 | 新乡学院 | A kind of quick-dry type oil colour formula and preparation method |
| CN111808487A (en) * | 2020-07-06 | 2020-10-23 | 昆山金百辰金属科技有限公司 | Ice flower paint |
Citations (4)
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|---|---|---|---|---|
| CN1102194A (en) * | 1993-10-28 | 1995-05-03 | 付守成 | Stereoscopic multicolor paint |
| CN1123298A (en) * | 1994-11-18 | 1996-05-29 | 郭静峰 | Stereo-glitter multi-colour coatings and producing method thereof |
| CN1380366A (en) * | 2002-04-22 | 2002-11-20 | 潘治平 | UV solidified intaglio printing decorative ink |
| CN101014647A (en) * | 2004-07-27 | 2007-08-08 | 伊凯普彩点股份公司 | Pigment preparation for colouring polymers |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7812085B2 (en) * | 2005-06-24 | 2010-10-12 | Exxonmobil Chemical Patents Inc. | Functionalized propylene copolymer adhesive composition |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1102194A (en) * | 1993-10-28 | 1995-05-03 | 付守成 | Stereoscopic multicolor paint |
| CN1123298A (en) * | 1994-11-18 | 1996-05-29 | 郭静峰 | Stereo-glitter multi-colour coatings and producing method thereof |
| CN1380366A (en) * | 2002-04-22 | 2002-11-20 | 潘治平 | UV solidified intaglio printing decorative ink |
| CN101014647A (en) * | 2004-07-27 | 2007-08-08 | 伊凯普彩点股份公司 | Pigment preparation for colouring polymers |
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| CN101979448A (en) | 2011-02-23 |
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Address after: 678 Yulong North Road, Xinbei District, Changzhou City, Jiangsu Province Patentee after: CHANGZHOU GUANGHUI CHEMICAL Co.,Ltd. Address before: 213016, 505, three Fort Street, bell tower, Jiangsu, Changzhou Patentee before: CHANGZHOU GUANGHUI CHEMICAL Co.,Ltd. |