CN101973671B - Method for realizing SBR nitrosation-denitrosation at low temperature by optimally controlling aeration time - Google Patents
Method for realizing SBR nitrosation-denitrosation at low temperature by optimally controlling aeration time Download PDFInfo
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- CN101973671B CN101973671B CN201010508419XA CN201010508419A CN101973671B CN 101973671 B CN101973671 B CN 101973671B CN 201010508419X A CN201010508419X A CN 201010508419XA CN 201010508419 A CN201010508419 A CN 201010508419A CN 101973671 B CN101973671 B CN 101973671B
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Abstract
The invention discloses a control method for realizing nitrosation-denitrosation of ammonia nitrogen wastewater at a low temperature by a sequencing batch reactor (SBR) method. Based on the conventional facultative anaerobic-aerobic intermittent activated sludge method, pH, oxidation-reduction potential (ORP) and dissolved oxygen (DO) are used as real-time monitoring parameters to establish an automatic control system in the method. The oxidation of nitrite is suppressed by controlling concentration of free ammonia (FA) in a reactor system at the temperature of between 10 and 18 DEG C, or the aeration time is optimally controlled according to an ammonia valley point on a pH real-time curve, so that high-concentration ammonia nitrogen wastewater is treated by nitrosation-denitrosation. By the method, the nitrosation rate can reach 80 percent, and the removal rates of TN, NH3-N and chemical oxygen demand (COD) reach over 95 percent, 99 percent and 90 percent respectively.
Description
Technical field
The present invention relates to SBR method (sequencing batch active sludge) realization high ammonia-nitrogen wastewater nitrosification-anti-nitrosifying method under a kind of low temperature.
Background technology
Constantly tightening up of sewage drainage standard is the general development trend of present countries in the world; Reduction to control nitrogen, phosphorus removal and related process energy consumption that eutrophication is a purpose has become important research direction.Traditional biological process adopts complete nitrification-denitrification process denitrogenation usually; Be that aerobic unit is by ammonia oxidation bacteria (Ammonia Oxidizing Bacteria; AOB) ammonia nitrogen is oxidized to nitrite nitrogen after, (Nitrite Oxidizing Bacteria NOB) is oxidized to nitric nitrogen by nitrifier again; Hold concurrently and restore into nitrogen after oxygen (anaerobism) unit then becomes nitrite nitrogen with the nitrate-nitrogen reduction that generates.This is in practical application, and particularly in the treating processes to high ammonia nitrogen, low ratio of carbon to ammonium waste water, aeration and nitre nitrogen that ammonia nitrogen is oxidized to nitre nitrogen are reduced into replenishing of the required external carbon source of nitrogen and all can produce too high running cost.Therefore, the denitrogenation novel process of research and development optimization ability (money) source consumption seems very necessary.1998, Hellinga C etc. utilized that ammonia oxidation bacteria is shorter than nitrifier generation time under 35 ℃ of conditions, selected suitable sludge retention time (SRT) to eliminate nitrifier and kept ammonia oxidation bacteria; Thereby the nitrosification-anti-nitrosification process that in single reactor drum, has at first realized, promptly ammonia nitrogen directly is reduced into nitrogen (Hellinga C, Schellen AAJC after being oxidized to nitrite nitrogen; Mulder JW; Van Loosdrecht MCM, Heijen, JJ; 1998.The SHARON Process:an innovative method for nitrogen removal from ammonium-rich wastewater.Water Sci.Technol.37,135-142).Relative complete nitrification-the denitrification of this technology can be saved 25% aeration rate at most, 40% external carbon source, and reduce by 40% biological increment.This causes the countries in the world extensive concern, and follow-up research work is intended to widen nitrosification-anti-nitrosifying range of application or reduces its requirement to operational conditions.Blackburne R through dissolved oxygen (DO) is controlled at the lower concentration level (＜0.5mg/L); Utilize ammonia oxidation bacteria to the affinity of dissolved oxygen greater than nitrifier; (19 ℃～23 ℃) are realized nitrosification-anti-nitrosification (Blackburne R at ambient temperature; Yuan ZG, Keller be nitrification to nitrite using low dissolved oxygen concentration as the main selection factor.Biodegradation.19:303-312 J.2008.Partial).Aslan S etc. under 21 ℃ of conditions with biological film fluidized bed processing high ammonia-nitrogen wastewater; The nitrosification rate reaches 72% (Alan S, Dahab be and denitritation of ammonium-rich wastewater using fluidized-bed biofilm reactors.J.Hazardous Materials.156:56-63 M.2008.Nitritation).In addition; Bae W etc. discovers when free ammonia concentration is greater than 4mg/L in the system; Can produce obvious suppression (Bae W to the oxidation of nitrite nitrogen; Baek S, Chung JW, Lee be operation factors for nitrite accumulation in batch reactors.Biodegradation.12:359-366 Y.2002.Optimal).
More than the research common ground is, although the new relative complete nitrification-denitrification of process is energy-conservation, needs heating equipment reaction system is maintained middle high temperature (20 ℃～35 ℃), and the energy that heat supply consumed is higher; So can not in the actual treatment of waste water, realize real saving energy and reduce the cost.Therefore, manage to reduce temperature of reaction and become the key of promoting this technology.And through the controlled accumulation of free ammonia concentration, perhaps according to pH continuous monitoring curve real-time optimization aeration time, (10 ℃～18 ℃) realize that high ammonia-nitrogen wastewater nitrosification-anti-nitrosifying method does not have report under coldcondition.
Summary of the invention
The purpose of this invention is to provide and adopt SBR method (sequencing batch active sludge) treatment of high concentration ammonia nitrogen waste water under a kind of coldcondition, efficiently remove nitrogen and COD through nitrosification-anti-nitrosification approach, and the control method that cuts down the consumption of energy.
In order to achieve the above object, the present invention proposes two kinds of modes, realizes that complete nitrification-denitrification changes to short distance nitration-denitrification (nitrosification-anti-nitrosification) under the low temperature, specifically is respectively:
A) optimize the aeration time method:
After SBR method complete nitrification-denitrification denitrogenation is stable; At every round-robin aerobic unit of taking turns; " ammonia valley point " according on the pH continuous monitoring curve controlled aerobic unitary duration in real time; That is: adopt suitable aeration flow to continue aeration earlier, when pH continuous monitoring curve occurs stopping aeration immediately behind " ammonia valley point " (ammonia valley).Through optimizing aeration time gradually reducing the oxidation of nitrite nitrogen, thereby make denitrification process change short-cut nitrification and denitrification into by complete nitrification-denitrification gradually, the nitrosification rate can continue to increase and finally reach 80%.
B) the controlled accumulative of free ammonia:
Behind SBR complete nitrification-denitrification denitrogenation effect stability; Make free ammonia concentration (Free ammonia in the reaction system through reducing the aeration flow; FA) be increased to more than or equal to 20mg/L; Then the aeration flow is returned to the lasting aeration of suitable aeration flow and reach more than 80%, recover normal Inlet and outlet water cycle of treatment afterwards again, realize nitrosification-anti-nitrosification that ammonia nitrogen waste water is handled up to the nitrosification rate.
SBR method complete nitrification-denitrification denitrogenation described in the present invention is stable, all is meant the stable NH of making of SBR method
3-N clearance reaches 80%, and NO in the water outlet
3-N/TN is greater than 70%.
Above-mentioned a) described in " ammonia valley point " be meant when the ammonia nitrogen oxidation finishes, dpH/dt by negative value change on the occasion of the time pH value (the V point among Fig. 2).
B) reducing the aeration flow described in is that the aeration flow is reduced to 1/10～1/15 of suitable aeration flow.
Said suitable aeration flow rate calculation experimental formula is following:
Q=q * MLSS * In * 10
-9(formula 1)
Wherein, the aeration flow that Q-is suitable, unit are L/min;
MLSS-mixed liquor suspended solids (mixed solution concentration of suspension): be used for representing activated sludge concentration, unit is mgL
-1The value of MLSS is confirmed according to practical situation, but for the handled high ammonia-nitrogen wastewater of the present invention, the MLSS value is generally at 7000～12000mg/L.
The In-NH of intaking
3-N concentration, unit is mgL
-1
Q-empirical Calculation constant comes from experiment.For suitable aeration flow, its value is 200～400, and unit is (ml
3Mg
-2Min
-1), be the air capacity of the influent ammonia nitrogen unit of the offering concentration active sludge of oxidation unit's concentration in the representation unit time.
Method is through optimizing the aeration time of reactor drum aerobic unit, realizing that complete nitrification changes to nitrosification a); Method b) is through inhibited reaction device nitrite oxidation function, realizes nitrosification-anti-nitrosification.This dual mode can separately use, and also can be bonded to together to use.
Combine when using, can adopt " the controlled accumulation of free ammonia " earlier, adopt the method for " optimization aeration time " again.Concrete combination controlling method step is following: 1) behind SBR method complete nitrification-denitrification denitrogenation effect stability, make through reducing the aeration flow that free ammonia concentration is increased to more than or equal to 20mg/L in the reaction system; 2) after step 1); Control the aerobic unit duration at the every round-robin aerobic unit of taking turns of SBR method in real time according to the ammonia valley point on the pH continuous monitoring curve; That is: adopt earlier suitable aeration flow to continue aeration, when pH continuous monitoring curve occurs stopping aeration behind the ammonia valley point, system is changed to nitrosification-anti-nitrosification rapidly by the controlled accumulation of free ammonia; When stablizing the nitrosification denitrogenation, water outlet NO
2-N/TN reaches more than 80%, thereby realizes nitrosification-anti-nitrosification that ammonia nitrogen waste water is handled.
Also can adopt " optimization aeration time " earlier, adopt the method for " the controlled accumulation of free ammonia " again.The main purpose of this combining method is the performance for further inhibited reaction device oxidation nitrite nitrogen, improves the nitrosification rate.For example: its condition of application is, when " optimization aeration time " makes the complete nitrification denitrification when short-cut nitrification and denitrification changes, transition process is slow (such as greater than 30 days or 5 hydraulic detention times); Or change back nitrosification rate lower (such as being lower than 50%); In this case, can adopt " the controlled accumulative means of free ammonia ", reactor drum is suppressed the nitrite-oxidizing ability; Make the oxidation of ammonia nitrogen rest on this step of nitrite nitrogen, thereby improve the nitrosification rate.
Concrete combination controlling method step is following: after 1) SBR method complete nitrification-denitrification denitrogenation is stablized; Aerobic unit adopts suitable aeration rate in the SBR circulation; And after the ammonia valley point appears in pH continuous monitoring curve, stop aeration immediately, be increased to 30%～60% gradually until the nitrosification rate; (the SBR cycle number of this process experience is by the decision of nitrosification rate rising speed, generally within 1～5 hydraulic detention time); 2) the SBR system is through after the step 1); Make through reducing the aeration flow that free ammonia concentration is increased to more than or equal to 20mg/L in the reaction system; Immediately the aeration flow is returned to suitable aeration flow then and continue aeration, complete nitrification-denitrification is able to accelerate, reaches more than 80% until the nitrosification rate to nitrosification-anti-nitrosification transformation; According to the normal Inlet and outlet water cycle of treatment of SBR method, can realize ammonia nitrogen waste water nitrosification-anti-nitrosification processing afterwards.
In the method for the invention, low temperature indication TR is 10 ℃～18 ℃.
NH in the said ammonia nitrogen waste water
3-N concentration is greater than 500mg/L.Specifically be meant: waste water of livestock poultry, percolate, anaerobic sludge digestion liquid and buck.
The effect of present method is, under 10 ℃～18 ℃ coldcondition, realizes that nitrosification-anti-nitrosification approach handles low C/N ratio wastewater (the nitrosification rate reaches 80%), guarantees that reactor drum efficiently removes nitrogen (about 95%TN, about 99%NH
3-N) and COD (about 92%), reduce aeration energy consumption, and save external carbon source.
Description of drawings
Fig. 1 is the structural representation of the used reactive system of the present invention.
Fig. 2 optimizes aeration time according to " ammonia valley point " on the pH real-time curve under 15 ℃ among the embodiment 1 to realize nitrosification-anti-nitrosifying synoptic diagram.
Fig. 3 is 15 ℃ of nitrosification-anti-nitrosification service charts of controlling free ammonia concentration down among the embodiment 2.
Fig. 4 be among the embodiment 3 under 10 ℃ according to the pH real-time curve on " ammonia valley point " optimize the nitrosification-anti-nitrosification service chart of aeration time.
Embodiment
Through specific embodiment method of the present invention is described below, but the present invention is not limited thereto.
Experimental technique described in the following embodiment like no specified otherwise, is ordinary method; Said reagent and material like no specified otherwise, all can obtain from commercial sources.
" sequencing batch activated sludge reactor " that the present invention adopted be (SBR) for known technology, and it is every takes turns circulation and be made up of water inlet, the oxygen (anaerobism) of holding concurrently, aerobic, deposition and 5 unit of water outlet.The present invention sets up real-time control system to strengthen the process control to reactor drum on this basis, and the structural representation of reactive system is seen Fig. 1.As shown in Figure 1, adopt pH, DO (dissolved oxygen) and ORP (redox potential) electrode pair reactor drum to carry out continuous monitoring, its signal is input to computingmachine and is write down and calculate; Computingmachine adds the start and stop of pump, aerator and agitator motor, thereby controls hocketing of each reaction member in real time according to time variable control turnover water pump, the carbon source set.In addition, regulate aerobic unitary aeration flow through under meter: suitable aeration flow calculates according to influent load confirms that low excessively flow then is about the former 1/10.
The present invention realizes the nitrosification-anti-nitrosification of high ammonia-nitrogen wastewater under the SBR method low temperature through following two kinds of modes.
Mode is a): select suitable aeration flow for use at aerobic unit; Judge the pH real-time curve when robot control system(RCS) and occur stopping aeration immediately behind the minimum point (" ammonia valley point "), thereby the optimal control aeration time is progressively to realize the transformation of complete nitrification to short distance nitration (being nitrosification).
Mode b), selected low aeration flow earlier for use, so that free ammonia (FA) is not produced controlled continuous rising by complete oxidation at aerobic unit in the system for the function of inhibited reaction device nitrite oxidation.When FA concentration in the system surpasses 20mg/L, use suitable aeration flow immediately instead and continue aeration, be increased to more than 80% up to the nitrosification rate.Further specify the present invention by embodiment below.
When among the following embodiment buck, anaerobic sludge digestion liquid, percolate being handled, the denitrifying carbon source of employing is industrial methyl alcohol.And being treated to of waste water of livestock poultry practiced thrift running cost employing feces of livestock and poultry underflow (Manure Slurry) as denitrifying carbon source.Feces of livestock and poultry underflow preparation method is: pig manure is ground the back (10 order) of sieving be diluted with water to the underflow shape, its COD is 50000～100000mg/L.
Suitable aeration flow among the following embodiment all adopts formula 1 to calculate according to influent load and confirms.MLSS is controlled at about 10000mg/L in the SBR operational process among the following embodiment.
Embodiment adopts the SBR method to realize the nitrosification-anti-nitrosification of percolate down for 1,15 ℃
Handle certain percolate (water-quality guideline is seen table 1) with real-time control SBR system, it is 15 ± 0.5 ℃ that temperature of reactor is controlled at.This embodiment adopts mode of the present invention a) to realize nitrosification-anti-nitrosification.(working cycle comprises 5 unit, water inlet-oxygen (anaerobism)-aerobic-deposition-water outlet of holding concurrently) nitrogen transformation and corresponding real-time curve are as shown in Figure 2 in the circulation.NH in the reactor system
3-N and TN follow into that water rises to, and the oxygen stage of holding concurrently is replenished external carbon source in system, thus the NO that last round of circulation aerobic unit is produced
2-N and NO
3-N Restore All becomes N
2System gets into aerobic unit subsequently; Adopt suitable aeration flow (about 3.5L/min adopts formula 1 to calculate according to influent load and confirms) to continue aeration, local minimum point (the V point shown in the figure occurs up to pH continuous monitoring curve; I.e. " ammonia valley point ") after, aeration stopped immediately.In the aeration process, dissolved oxygen concentration maintains the lower level of 0～3.5mg/L; Ammonia nitrogen rate of oxidation (about 15.1mgNh
-1L
-1) much larger than nitrite nitrogen rate of oxidation (about 2.8mgNh
-1L
-1), reactor drum water outlet NO
2-N level (about 50mg/L) is apparently higher than NO
3-N (about 10mg/L) and NH
3-N (＜3mg/L), the nitrosification rate is about 83%.
Among the embodiment 1, SBR calculates according to the ORP continuous monitoring value that computingmachine reads in every circulation oxygen unit of holding concurrently of taking turns, with judge system whether need replenish external carbon source (if dORP/dt＜5 o'clock, with the pulse mode supplementary carbon source up to d
2ORP/dt
2=0 o'clock, stop supplementary carbon source, stop to replenish when the K point among Fig. 2 promptly occurring).Aerobic unit then calculates dpH/dt according to the pH continuous monitoring value that computingmachine reads; Change on the occasion of judging the pH real-time curve by negative value according to dpH/dt and local minimum point (" ammonia valley point ") to occur; And put with this and to be this unitary end time, thereby in time stop aeration in order to avoid nitrite nitrogen further is oxidized to nitric nitrogen.Inlet and outlet water Pollutant levels and clearance are seen table 1.
Percolate nitrosification-anti-nitrosification operation result under table 1, the 15 ℃ of conditions
ND: do not detect
Embodiment adopts the SBR method to realize the nitrosification-anti-nitrosification of breeding wastewater down for 2,15 ℃
Handle certain intensive culture waste water (water-quality guideline is seen table 2) with real-time control SBR system, the temperature of reactor drum is controlled at 15 ± 0.5 ℃, and this embodiment adopts mode b of the present invention) realize that complete nitrification-denitrification changes to nitrosification-anti-nitrosification.Inlet and outlet water nitrogen pollutant concentration is as shown in Figure 3.Reactor drum moves preceding 18 days water outlet NH
3-N and NO
2-N maintains the lower concentration level, and NO
3-N accounts for more than the TN80%.The 19th day to the 32nd day, the aeration flow was contracted to 0.3L/min from 3.0L/min, NH in the system
3-N raises gradually, and NO
3-N then reduces most 0mg/L rapidly.Free ammonia concentration is increased to about 36.3mg/L (NH in system
3-N ≈ 205mg/L; PH=8.8), immediately aeration rate is returned to the 3.0L/min continuous aeration.NH
3-N dropped to not enough 5mg/L in 6 days subsequently; In this process, system NO
2Significantly accumulation takes place in-N, is up to about 170mg/L, and NO
3-N only is increased to 30mg/L.After this was illustrated in control FA (free ammonia) rising, reactor drum obviously was suppressed the oxidation susceptibility of nitrite nitrogen.After this, replenish corresponding carbon source, water outlet NO through real-time control
2-N and NO
3-N descends, but NO
2-N (average out to 39mg/L) concentration is still apparently higher than NO
3-N (average out to 7.5mg/L).The nitrosification rate that reactor drum moved in 5 months continuously is up to 85%.Inlet and outlet water Pollutant levels and clearance are seen table 2.This embodiment controls the nitrosification-anti-nitrosification service chart of free ammonia concentration and sees Fig. 3.
Waste water of livestock poultry nitrosification-anti-nitrosification operation result under table 2, the 15 ℃ of conditions
ND: do not detect
Its concentration of FA (free ammonia) is typically expressed as mgNH in the above-described embodiments
3/ L, its value calculates (down together) at the ionization equilibrium of aqueous phase by following formula according to ammonia usually:
FA------Free ammonia, unit are mgNH
3/ L;
TAN------Total ammonia as nitrogen, total ammonia nitrogen concentration measures, and unit is mgNH
3-N/L;
The T------centigradetemperature, unit is ℃.
Embodiment adopts the SBR method to realize the nitrosification-anti-nitrosification of waste water of livestock poultry down for 3,10 ℃
A) realize that the complete nitrification denitrification is to the transformation of short-cut nitrification and denitrification in the livestock breeding wastewater processing with mode of the present invention.The reactor drum water inlet is identical with embodiment 2, and temperature then is controlled at 10 ± 0.5 ℃.Fig. 4 is SBR 6 months a denitrification effect of operation continuously.Preceding 13 days, reactor drum aerobic unit aeration time was fixed as 4.5h, and the aeration flow is 3.2L/min.This water outlet in period NO
3-N is far above NO
2-N.Since the 14th day, reactor drum adopted control (sequence of control is identical with embodiment 1) in real time at aerobic unit, and as the aeration terminal point, the time of aerobic unit is shortened the (2.7h～3.4h) to average 3.1h with " ammonia valley point " on the pH real-time curve.In subsequently 8 days, reactor drum water outlet NH
3-N maintains lower concentration level, NO all the time
2-N then gradually by＜1mg/L is increased to 31.6mg/L, and NO
3-N drops to 7.6mg/L gradually by 40.8mg/L.This shows reactor drum under identical aeration flow, realizes that through the optimal control aeration time complete nitrification is to nitrosifying transformation.Reactor drum is at the nitrosification rate average out to 81% of operation in 5 months subsequently.Inlet and outlet water Pollutant levels and clearance are seen table 3.This embodiment sees Fig. 4 according to nitrosification-anti-nitrosification service chart that aeration time is optimized in " ammonia valley point " on the pH real-time curve.
Waste water of livestock poultry nitrosification-anti-nitrosification operation result under table 3, the 10 ℃ of conditions
ND: do not detect
Embodiment adopts the SBR method to realize the nitrosification-anti-nitrosification of sludge digestion liquid down for 4,10 ℃
Control the SBR system in real time with the present invention and handle certain sludge of sewage treatment plant Digestive system, temperature of reactor is controlled to be 10 ± 0.5 ℃.This case study on implementation combine mode a) and b) realize the steady running of nitrosification denitrogenation under the coldcondition.At first adopt mode b), promptly control FA concentration and raise gradually: preceding 9 days reactor drum water outlet NO to realize that complete nitrification changes to nitrosification
3-N accounts for TN and maintains more than 90%, to the 20th day reactor drum aeration flow is contracted to about 0.3L/min by 2.8L/min on the 10th day, and free ammonia concentration is increased to 20.1mg/L (NH by about 0.3mg/L thereupon in the system
3-N is increased to 219.6mg/L by about 2.0mg/L; PH=8.9), subsequently the aeration flow is recalled to the continuous aeration to 3.5L/min, up to NO
2/ (NO
2+ NO
3) reach more than 80%.Be accompanied by the oxidation of ammonia nitrogen, NO
2-N is increased to 175mg/L, far above NO
3-N (the highest 40mg/L that is merely).After controlled accumulation took place FA, the aerobic unit of reactor drum adopted mode a) to optimize aeration time, the nitrosification rate average out to 82% that moved continuously in 6 months.Inlet and outlet water Pollutant levels and clearance are seen table 4.
Sludge digestion liquid nitrosification-anti-nitrosification operation result under table 4, the 10 ℃ of conditions
ND: do not detect
Embodiment adopts the SBR method to realize the nitrosification-anti-nitrosification of sludge digestion liquid down for 5,10 ℃
Control the SBR system in real time with the present invention and handle certain sludge of sewage treatment plant Digestive system, temperature of reactor is controlled to be 10 ± 0.5 ℃, and the reactor drum influent quality is identical with embodiment 4.Present case adopts earlier optimizes aeration, combines the controlled accumulation of free ammonia again, realizes that the denitrogenation path is reached more than 80% by the transformation and the nitrosification rate of whole process to short distance.SBR reaches nitrated stable (NH behind 2 hydraulic detention times
3-N clearance reaches 93%, and water outlet NO
3-N/TN reaches 90%, and in two hydraulic detention times subsequently, every circulation aerobic unit of taking turns a) is optimized aeration time according to mode, and promptly every the wheel circulates in the pH continuous curve and occur stopping aeration immediately behind the ammonia valley point, water outlet NO
3-N/TN drops to 47% gradually, and NO
2-N/TN rises to 40% by 10% gradually.After this, the aeration flow of reactor drum is reduced to 0.3L/min by 2.5L/min, makes the free ammonia in the system produce controlled continuous rising.The free ammonia concentration of reactor system is increased to greater than behind the 20mg/L by not enough 1mg/L gradually, immediately with aeration return back to 2.5L/min continue aeration until free ammonia concentration less than 5mg/L below.This post-reactor water outlet NO
2-N/TN also reaches 80%, nitrosification rate (NO
2-N/NO
2-N+NO
3-N) also be stabilized in more than 82%.
Sludge digestion liquid nitrosification-anti-nitrosification operation result under table 5, the 10 ℃ of conditions
ND: do not detect
Claims (7)
1. the SBR method realizes ammonia nitrogen waste water nitrosification-anti-nitrosifying method under the low temperature, comprises the steps:
After SBR method complete nitrification-denitrification denitrogenation reaches and stablizes; At every round-robin aerobic unit of taking turns; Control aerobic unitary duration in real time according to the ammonia valley point on the pH continuous monitoring curve, that is: adopt suitable aeration flow to continue aeration earlier, when pH continuous monitoring curve occurs stopping aeration behind the ammonia valley point; Through progressively optimizing aeration time reducing the oxidation of nitrite nitrogen, thereby realize that complete nitrification changes to nitrosification;
Described SBR method complete nitrification-denitrification denitrogenation is stable, is meant the stable NH of making of SBR method
3-N clearance reaches 80%, and NO in the water outlet
3-N/TN is greater than 70%;
Said ammonia valley point is meant when the ammonia nitrogen oxidation finishes, dpH/dt by negative value change on the occasion of the time the pH value;
Said suitable aeration flow is that 1 calculating is confirmed according to the following equation:
Q=q * MLSS * In * 10
-9(formula 1)
Wherein, the aeration flow that Q-is suitable, unit are L/min;
MLSS-mixed solution concentration of suspension is used for representing activated sludge concentration, and unit is mgL
-1
The In-NH of intaking
3-N concentration, unit is mgL
-1
Q-empirical Calculation constant is the influent ammonia nitrogen of oxidation unit's concentration in the representation unit time, and the air capacity of the unit's of offering concentration active sludge; Its value is 200～400, and unit is ml
3Mg
-2Min
-1Said low temperature is 10 ℃～18 ℃.
2. method according to claim 1 is characterized in that: NH in the said ammonia nitrogen waste water
3-N concentration is greater than 500mg/L.
3. method according to claim 2 is characterized in that: said ammonia nitrogen waste water be selected from following any one: livestock breeding wastewater, percolate, sludge digestion liquid and buck.
4. the SBR method realizes ammonia nitrogen waste water nitrosification-anti-nitrosifying method under the low temperature, comprises the steps:
1) after SBR method complete nitrification-denitrification denitrogenation was stablized, the aerobic unit in the SBR circulation adopted suitable aeration rate to continue aeration, and occurs stopping aeration behind the ammonia valley point at pH continuous monitoring curve, is increased to 30%～60% until the nitrosification rate; Said ammonia valley point is meant when the ammonia nitrogen oxidation finishes, dpH/dt by negative value change on the occasion of the time the pH value;
2) the SBR system is through after the step 1); Make through reducing the aeration flow that free ammonia concentration is increased to more than or equal to 20mg/L in the reaction system; Then the aeration flow is returned to suitable aeration flow; Continue aeration and reach more than 80%, recover the normal Inlet and outlet water cycle of treatment of SBR method afterwards again, can realize ammonia nitrogen waste water nitrosification-anti-nitrosification processing until the nitrosification rate;
Described SBR method complete nitrification-denitrification denitrogenation is stable, is meant the stable NH of making of SBR method
3-N clearance reaches 80%, and NO in the water outlet
3-N/TN is greater than 70%;
Said low temperature is 10 ℃～18 ℃; Said suitable aeration flow is that 1 calculating is confirmed according to the following equation:
Q=q * MLSS * In * 10
-9(formula 1)
Wherein, the aeration flow that Q-is suitable, unit are L/min;
MLSS-mixed solution concentration of suspension is used for representing activated sludge concentration, and unit is mgL
-1
The In-NH of intaking
3-N concentration, unit is mgL
-1
Q-empirical Calculation constant is the air capacity of the influent ammonia nitrogen unit of the offering concentration active sludge of oxidation unit's concentration in the representation unit time; Its value is 200～400, and unit is ml
3Mg
-2Min
-1
5. method according to claim 4 is characterized in that: step 2) described in to reduce the aeration flow be that the aeration flow is reduced to 1/10～1/15 of said suitable aeration flow.
6. according to claim 4 or 5 described methods, it is characterized in that: NH in the said ammonia nitrogen waste water
3-N concentration is greater than 500mg/L.
7. method according to claim 6 is characterized in that: said ammonia nitrogen waste water be selected from following any one: livestock breeding wastewater, percolate, sludge digestion liquid and buck.
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| CN102701441B (en) * | 2012-05-16 | 2013-07-24 | 北京工业大学 | Method for regulating and controlling nitrogen proportion of partial nitrosation effluent of low-ammonia-nitrogen continuous stirred-tank reactor (CSTR) at normal temperature |
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