CN101973148B - Arc protection fabric, manufacturing method and application thereof - Google Patents

Arc protection fabric, manufacturing method and application thereof Download PDF

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Publication number
CN101973148B
CN101973148B CN201010260286.9A CN201010260286A CN101973148B CN 101973148 B CN101973148 B CN 101973148B CN 201010260286 A CN201010260286 A CN 201010260286A CN 101973148 B CN101973148 B CN 101973148B
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fire
retardant
fabric
layer
protection
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CN101973148A (en
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钟洲
胡祖明
陈蕾
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Super Gomez new materials Limited by Share Ltd
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SRO ARAMID FIBER (JIANGSU) Co Ltd
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Abstract

The invention relates to an arc protection fabric, a manufacturing method and application thereof. The invention is characterized in that: the arc protection fabric comprises three mutually independent layers, namely a flame-retardant outer layer 1, a heat-insulation layer 2 and a flame-retardant inner layer 3, and the flame-retardant outer layer and the heat-insulation layer and the heat-insulation layer and the flame-retardant inner layer are alternatively compounded so as to manufacture an interweaved double-layer composite tube fabric; two pipe layers complement each other, the protection performance is multiplied, and protection dead corners are avoided. For the fabric of the invention, the raw materials of the three independent single layers can be selected reasonably according to different arc-resistant levels and needed protection levels; and the fabric can be manufactured by using raw material fibers alone or by blending various raw material fibers,.

Description

A kind of arc protection fabric, preparation method and application thereof
Technical field
The present invention relates to a kind of heat-resisting and fire-retardant arc protection fabric, preparation method and application of multilayer, a kind of fabric that utilizes resistance to TRANSIENT HIGH TEMPERATURE and insulation characterisitic specifically, for the making of arc protection clothes and fire-entry suit.
Background technology
Electric arc accident is a kind of uncertain accident.Every day, there is thousands of worker to be exposed among the danger of electric arc.This huge crowd not only comprises power worker, is also included in the employee of petrochemical industry, chemical engineering industry, combustion gas, Running-water Company, oil plant and some other large and medium-sized enterprise.
Arc protection and fire-retardant clothes generally wear uncomfortable, because wherein add protective fibers to there is bad moisture transmission, general arc protection and fire-retardant clothes, all that post processing adds protective fibers or protective coating, the arc protection performance that fabric itself has not possessed or be not permanent arc protection flame-retardant textile, and heavy wearing, limitation of activity.
So the present invention intends providing the top-weight fabric of a kind of heat-resistant combustion and arc protection, uses it for single protective garment or protective garment outer, can increase sense comfortable and easy to wear, can accomplish arc protection and heat-resistant combustion from raw material, can directly contact skin, and fabric be frivolous, mechanical performance is strong, movable convenient.
Summary of the invention
The object of the invention is to provide a kind of arc protection fabric, preparation method and application thereof, can adapt under the particular surroundings such as potential electric arc threat, high temperature or danger and use.
Arc protection fabric of the present invention is that adjacent two individual layers are alternately compound successively, obtain composite tube type fabric by three layers of individual layer independently.Fabric of the present invention just obtains two-layer supplementary cast air layer mutually, can improve the arc protection effect of fabric.
Arc protection fabric of the present invention is composited by special method successively by following three layers: described arc protection fabric can arc protection grade as required artificially be selected different material combinations, and described arc protection fabric is outer for single protective garment or protective garment.
Fabric of the present invention is comprised of fire-retardant outer 1, thermal insulation layer 2, fire-retardant internal layer 3, and described fire-retardant outer 1 and thermal insulation layer 2, thermal insulation layer 2 and fire-retardant internal layer 3 are alternately compound successively, obtain composite tube type fabric.Can be compound by braiding, quilt, stitching and the method such as bonding in precalculated position; Adjacent two individual layers are alternately compound in precalculated position can obtain two-layer independently pipe layer, and this two-layer pipe layer complements one another.
Described fire-retardant outer 1 is that fire resistance fibre is the woven fabric of main body.Be generally to take meta-aromatic polyamide fiber as main component, can adopt the X-FIPER of commercially available prod ,Ru Yuhe company.If require in addition degree of protection high, also available use p-aromatic polyamide fiber, polyimide fiber, PBI fibre and polyparaphenylene's benzene two oxazole fibers.If degree of protection is lower, can also use flame-retardant acrylic fibre fiber and FRC etc.
The nonwoven heat insulation felt that described thermal insulation layer 2 is main component for fire resistance fibre.Generally take meta-aromatic polyamide fiber as raw material, junior also available flame-retardant acrylic fibre fiber or FRC.
The woven fabric that described fire-retardant internal layer 3 is one or more fire resistance fibres.Fire resistance fibre comprises flame-retardant acrylic fibre fiber, FRC or pre-oxidized fibers.If protective garment class requirement is very high, also can adopt meta-aromatic polyamide fiber.
Fire-retardant outer 1, thermal insulation layer 2, fire-retardant internal layer 3 can be made for a kind of raw fibre is single, can be also plurality of raw materials fiber blend system.For example fire-retardant outer 1 can be between the blending product of position Fanglun 1313 and contraposition poly.
Arc protection fabric of the present invention can independently be used, and makes arc protection clothes or fire-entry suit, also can increase in inside waterproof ventilative layer and comfort liner and use.
Arc protection fabric of the present invention fire-retardant outer 1 and thermal insulation layer 2, thermal insulation layer 2 and fire-retardant internal layer 3 are alternately compound successively, obtain composite tube type fabric, see Fig. 1.Complex method is by can be by braiding, quilt, stitching and bonding etc.The width of multiple tube is 5-30mm, and wherein optimum size is 10mm.
Under normal operation, arc protection fabric is when room temperature, and 1,2,3 treble cloths are pressed close to each other, and fabric is in flat structure, as broad as long with multilayer common fabric.The in the situation that of TRANSIENT HIGH TEMPERATURE, fire-retardant outer 1 is exposed under high temperature, air expanded by heating, and pipe layer sticks out, and obtains outer layer insulation gas-bearing formation 4 and primary insulation gas-bearing formation 5, sees Fig. 2.Due to this special construction, in the situation that exposing, heat can form double-deck air heat insulation structural, and fabric of the present invention is not increased in the situation of fabric proportion, barrier propterty increases.This fabric can be used separately, also can be used as the outermost layer in common protective garment.It is fire-retardant and heat-proof quality is good.
Fabric of the present invention has double hyer insulation system when high temperature, from Fig. 1,2.Fabric safeguard function of the present invention does not have dead angle, and barrier propterty is multiplied.
Described arc protection fabric comprises three layers of independent individual layer, fire-retardant outer 1 and fire-retardant internal layer 3 all there is independently warp thread and weft systems, yarn can be single thread, multiple yarn or covering yarn.Thermal insulation layer 2 is nonwoven heat insulation felt independently.Each interlayer seam zygonema can be used high-tenacity suture, has improved so again the mechanical performance of protective garment.
Described arc protection fabric comprises three layers of independent individual layer, fire-retardant outer 1 and fire-retardant internal layer 3 all there is independently warp thread and weft systems, its yarn comprises single thread, twisted yarn and hybrid yams etc.
The protective garment that the fabric that arc protection provided by the invention is good is made is light and thin, but has good fire-retardant and heat-proof quality, and manufacture method is relatively simple, and indices just can reach industry standard.
Arc protection fabric of the present invention can also install filler yarn additional in pipe layer, increases needed barrier propterty.Filler yarn can be an aromatic polyamide fibre, p-aromatic polyamide fiber, flame-retardant acrylic fibre and anti-flaming viscose etc.
Arc protection clothes comprises at least one deck arc protection fabric of the present invention, also can in inside, increase comfort liner and waterproof ventilative layer, makes fire-entry suit.
In sum, arc protection fabric provided by the invention can choose reasonable form three independently raw materials of individual layer according to different resistance to electric arc grades.Fabric of the present invention can be made for a kind of raw fibre is single, can be also plurality of raw materials fiber blend.Can be different according to required degree of protection, choose reasonable forms the raw material of independent individual layer.
Accompanying drawing explanation
Fig. 1 is the sectional view of fabric of the present invention;
Fig. 2 is that fabric of the present invention runs into outside moment high temperature sectional view.
The specific embodiment
Embodiment 1:
Fire-retardant skin: take meta-aromatic polyamide fiber as primary raw material, adopt the X-FIPER of Yu He company, grammes per square metre 150g/m 2
Thermal insulation layer: take meta-aromatic polyamide fiber as primary raw material, adopt the X-FIPER of Yu He company, grammes per square metre 100g/m 2
Fire-retardant internal layer: anti-flaming viscose, grammes per square metre 80g/m 2
It is compound that adjacent two layers adopts the method for quilt to carry out, and pipe layer width is 10mm
Certain one deck with upper fabric or combination layer are carried out to following quantitative measurement:
Fire-retardant skin: ultimate strength is tested according to GB3923.1-1997
Tearing brute force is tested according to GB3917.3-1997
Thermal stability is tested according to GA10-2002
Fire resistance is tested according to GB/T5455-1997
Thermal insulation layer: stability is tested according to GA10-2002
Fire resistance is tested according to GB/T5455-1997
Whole fabric: overall thermal barrier propterty is tested according to GA10-2002
In following examples as do not have specified otherwise also will test fabric according to embodiment 1 physical test method.
The individual layer of table 1 arc protection fabric provided by the invention or the performance test results of whole fabric.
Table 1
Figure BSA00000239875900041
Embodiment 2
Fire-retardant skin: take meta-aromatic polyamide fiber as primary raw material, adopt the X-FIPER of Yu He company, grammes per square metre 150g/m 2
Thermal insulation layer: take meta-aromatic polyamide fiber as primary raw material, adopt the X-FIPER of Yu He company, grammes per square metre 100g/m 2
Fire-retardant internal layer: anti-flaming viscose, grammes per square metre 80g/m 2
It is compound that adjacent two layers adopts the method for quilt to carry out, and pipe layer width is 20mm
As test in embodiment 1, this cloth is tested, result is as table 2.
Table 2
Figure BSA00000239875900051
Embodiment 3
Fire-retardant skin: take meta-aromatic polyamide fiber as primary raw material, adopt the X-FIPER of Yu He company, grammes per square metre 150g/m 2
Thermal insulation layer: FRC is primary raw material, grammes per square metre 100g/m 2
Fire-retardant internal layer: FRC, grammes per square metre 80g/m 2
It is compound that adjacent two layers adopts the method for quilt to carry out, and pipe layer width is 10mm
As test in embodiment 1, this cloth is tested, result is as table 3.
Table 3
Figure BSA00000239875900052
Embodiment 4
Fire-retardant skin: take flame-retardant acrylic fibre fiber as primary raw material, grammes per square metre 150g/m 2
Thermal insulation layer: take flame-retardant acrylic fibre fiber as primary raw material, grammes per square metre 100g/m 2
Fire-retardant internal layer: anti-flaming viscose, grammes per square metre 80g/m 2
It is compound that adjacent two layers adopts the method for quilt to carry out, and pipe layer width is 10mm
As test in embodiment 1, this cloth is tested, result is as table 4.
Table 4
Figure BSA00000239875900061
Embodiment 5
Fire-retardant skin: take meta-aromatic polyamide fiber as primary raw material, adopt the X-FIPER of Yu He company, grammes per square metre 150g/m 2
Thermal insulation layer: take meta-aromatic polyamide fiber as primary raw material, adopt the X-FIPER of Yu He company, grammes per square metre 100g/m 2
Fire-retardant internal layer: take meta-aromatic polyamide fiber as primary raw material, adopt the X-FIPER of Yu He company, grammes per square metre 100g/m 2
It is compound that adjacent two layers adopts the method for quilt to carry out, and pipe layer width is 10mm
As test in embodiment 1, this cloth is tested, result is as table 5.
Table 5
Figure BSA00000239875900062

Claims (8)

1. an electric arc fabric, it is characterized in that described fabric comprises independently individual layer of three of fire-retardant skin, thermal insulation layer and fire-retardant internal layers, and fire-retardant skin and thermal insulation layer, thermal insulation layer two individual layers adjacent with fire-retardant internal layer are alternately compound in precalculated position, obtain intersecting two-layer compound cast fabric; Described adjacent two individual layers alternately obtain two independently pipe layers pre-determined bit is compound, and this two pipes layer complements one another.
2. by fabric claimed in claim 1, it is characterized in that:
A) fire-retardant skin is the woven fabric that comprises that the fire resistance fibre of meta-aromatic polyamide fiber is main body;
B) described thermal insulation layer is to take the nonwoven heat insulation felt that meta-aromatic polyamide fiber is Main Ingredients and Appearance at interior fire resistance fibre;
C) described fire-retardant internal layer is the woven fabric at one or more interior fire resistance fibres with flame-retardant acrylic fibre fiber, FRC or pre-oxidized fibers.
3. by the fabric described in claim 1 or 2, it is characterized in that described fire-retardant skin, thermal insulation layer or fire-retardant internal layer are that a kind of fiber is made, or make for multiple fiber blend.
4. by the fabric described in claim 1 or 2, it is characterized in that three independently individual layer according to different resistance to electric arc grades, select different raw fibres:
Fire-retardant outer p-aromatic polyamide fiber, polyimide fiber, PBI fibre or the polyparaphenylene Ben Bing bis-oxazole fiber of using when a) degree of protection is high; Fire-retardant outer flame-retardant acrylic fibre fiber or the FRC of using when degree of protection is lower;
When b) degree of protection is lower, thermal insulation layer is used flame-retardant acrylic fibre fiber or FRC;
When c) degree of protection is high, fire-retardant internal layer is used meta-aromatic polyamide fiber.
5. prepare the method for fabric as claimed in claim 1, it is characterized in that fire-retardant skin, thermal insulation layer and fire-retardant internal layer replace successively compound by braiding, quilt, stitching or adhesive bonding method enforcement, fabric is in flat structure, wherein fire-retardant skin and fire-retardant internal layer have independently warp thread and weft systems, and thermal insulation layer is nonwoven heat insulation felt independently.
6. by method claimed in claim 5, it is characterized in that:
1. the yarn of described warp thread or weft systems is single thread, multiple yarn or covering yarn;
2. each interlayer seam zygonema is high-tenacity suture.
7. by the application of arc protection fabric claimed in claim 1, it is characterized in that making separately protection electric arc clothes, fire-entry suit or as the outermost layer in common protective garment; Overall thermal barrier propterty TPP is 30-40cal/cm 2.
8. by application claimed in claim 7, it is characterized in that:
1. in the pipe layer being alternately compounded to form at adjacent two individual layers, install filler yarn additional, improve barrier propterty, described filler yarn is position aromatic polyamide fibre, p-aromatic polyamide fiber, flame-retardant acrylic fibre or anti-flaming viscose;
2. arc protection clothes comprises at least one deck arc protection fabric of the present invention, in pipe layer, increases comfort liner or waterproof ventilative layer.
CN201010260286.9A 2010-08-20 2010-08-20 Arc protection fabric, manufacturing method and application thereof Active CN101973148B (en)

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US20140026303A1 (en) * 2012-07-27 2014-01-30 E I Du Pont De Nemours And Company Fiber blends, yarns, fabrics, and garments for arc and flame protection
CN104256943B (en) * 2014-09-11 2015-11-11 张矢超 A kind of arc protection clothes and preparation method thereof
CN105671792B (en) * 2016-01-18 2018-01-19 东华大学 A kind of preparation method of the bowl-shape raised fire-entry suit insulating layer material of band
CN105506829B (en) * 2016-01-28 2016-10-26 杭州启澄科技有限公司 A kind of insulant of power equipment maintaining protective garment
CN107160751B (en) * 2017-05-08 2019-01-25 常熟市宝沣特种纤维有限公司 A kind of aramid fabric of the anti-metal drop of fire-retardant fireproof
CN107252146A (en) * 2017-06-26 2017-10-17 周敏 A kind of arc protection knitted gloves
CN110284339A (en) * 2019-05-23 2019-09-27 康帝雅高档面料(苏州)有限公司 A kind of fire-retardant arc protection composite material
CN113201845B (en) * 2021-05-18 2022-11-04 陕西元丰纺织技术研究有限公司 Single-layer three-dimensional structure arc-proof fabric and preparation method thereof
CN114261149A (en) * 2021-12-29 2022-04-01 江苏先诺新材料科技有限公司 Polyimide arc-proof garment fabric and arc-proof garment

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CN1705445A (en) * 2002-10-21 2005-12-07 纳幕尔杜邦公司 Multilayered, breathable textile fabric
CN1829832A (en) * 2003-08-06 2006-09-06 纳幕尔杜邦公司 Lightweight protective apparel
CN1930334A (en) * 2004-03-18 2007-03-14 纳幕尔杜邦公司 Modacrylic/cotton/aramid fiber blends for arc and flame protection

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