CN101962917A - Printing raw paste capable of improving reactive printing fineness of real silk fabrics - Google Patents
Printing raw paste capable of improving reactive printing fineness of real silk fabrics Download PDFInfo
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Abstract
The invention discloses a printing raw paste capable of improving reactive printing fineness of real silk fabrics, belonging to the technical field of reactive dye printing of the real silk fabrics. The printing raw paste comprises water, a waster softening agent, an antireducer, urea and an alkali agent. The printing raw paste is characterized by comprising a composite paste, wherein the mass percent of the composite paste is 4-5 percent and the mass percent of the urea is 2-5 percent. By changing the traditional sodium alga acid reactive printing system, the invention obviously improves the fineness of the reactive printing of the real silk fabrics, and thoroughly solves the problem of dispersion of the reactive printing of real silks and blending or interweaving fabrics thereof. It has been found that the invention solves the technical difficulty of puzzling the industry for many years.
Description
Technical field
The present invention relates to the former paste of a kind of stamp, particularly a kind of former paste of stamp that is used for the silk like lining belongs to the technical field of silk like lining printing with reactive dye.
Background technology
For many years, the real silk fabric stamp adopts acidity, neutral dye stamp mostly, and its chromatogram is complete, and the flower type is meticulous, is subjected to many consumers' favor.But along with the raising of people's living standard, the consumer is more and more higher to the requirement of COLOR FASTNESS, and COLOR FASTNESS acid, neutral dye does not far satisfy the requirement in market; And the heavy metal environmental issue of neutral dye also causes people's attention.Therefore, the stamp of REACTIVE DYES on real silk and blending and interwoven fabric will progressively replace acidity, neutral dye stamp.
The comparison of acid, neutral stamp and reactive printing
| Acid, neutral stamp | Reactive printing | |
| Used printing gum | Guar gum | Sodium alginate |
| Steaming time | 30-60 minute | 7-15 minute |
| The temperature of soaping | 40-60 |
100℃ |
| Soaping fastness | Low | High |
| Flower type fineness | Good | Difference |
As can be seen from the above table, acid, neutral dye stamp is to soap through 40-60 ℃, and therefore in the fastness more than 60 ℃ detected, its fastness was very low; And dyestuff and fiber be by the ionic bond combination, so fastness is lower.REACTIVE DYES and fiber be by covalent bonds, and soap by high temperature boiling water, so COLOR FASTNESS is very high.Simultaneously, well-known because acid, neutral dye is to make the former paste of stamp with guar gum, guar gum contains a large amount of-OH base has the splendid water-based of embracing, and is therefore acid, neutral dye stamp flower type fineness is good.And REACTIVE DYES has reactive group because of it, can't make former paste with guar gum, otherwise a large amount of-OH radical reaction on REACTIVE DYES and the guar gum causes feel rough, and COLOR FASTNESS is very poor.Therefore REACTIVE DYES is mainly done former paste with sodium alginate, and the greatest problem of sodium alginate on real silk is that the imbibition of flower type is fuzzy, particularly wetOnwet.Obvious especially on real silk and cotton interwoven fabric, not imbibition on the cotton direction, only imbibition on the real silk direction.
Generally speaking, imbibition problem has seriously hindered the stamp of REACTIVE DYES on real silk fabric and has used.Capture its fineness problem, profound significance is arranged, huge market potential is arranged.
Summary of the invention
Goal of the invention of the present invention provides a kind of former paste of stamp that improves silk like lining reactive printing fineness.
For achieving the above object, the technical solution used in the present invention is: this can improve the former paste of stamp of silk like lining reactive printing fineness, comprise water, water softener, anti-reductant, urea and alkaline agent, it is characterized in that: also comprise compound thickener, the quality percentage composition of described compound thickener is 4～5%, and the quality percentage composition of described urea is 2～5%.
Further, the present invention also comprises high waterborne polymeric and/or the white kerosene embraced, and the quality percentage composition that described height is embraced waterborne polymeric is 10～20%, described white kerosene the quality percentage composition be 8～12%.
Further, compound thickener of the present invention is the mixture of acrylic polymer dispersion and natural seaweed acid sodium.
Further, height of the present invention is embraced the copolymer that waterborne polymeric is butyl acrylate and methyl methacrylate.
Further, compound thickener of the present invention is replaced with sodium alginate.
Compared with prior art, the invention has the beneficial effects as follows: (1) traditional silk like lining reactive printing be with sodium alginate as the former paste of stamp, the imbibition of ubiquity flower type is serious, fineness is poor; The present invention passes through with compound thickener (for example mixture of acrylic polymer dispersion and natural seaweed acid sodium) as the former paste of stamp, and the quality percentage composition of controlling compound thickener is 4～5%, the urea quality percentage composition is 2～5%, has improved the fineness of silk like lining reactive printing.(2) the present invention is that 10～20% height is embraced waterborne polymeric and/or the quality percentage composition is the white kerosene of 8-12% by add the quality percentage composition in the former paste of stamp, has further improved the fineness of silk like lining reactive printing.(3) the present invention is by the traditional sodium alginate reactive printing of change system, obviously improved the fineness of silk like lining reactive printing, thoroughly solve the imbibition problem of real silk and blending or interwoven fabric reactive printing, facts have proved, the invention solves puzzlement industry technical barrier for many years.
Description of drawings
Fig. 1 is the rheological characteristic comparison diagram of compound thickener and the former paste of sodium alginate;
Fig. 2 is the storage stability comparison diagram of compound thickener and the former paste of sodium alginate;
Fig. 3 is the colored type design sketch that uses the former paste of sodium alginate and the stamp production procedure lining identical with embodiment 1-16 with technology in the prior art;
Fig. 4 is the colored type design sketch of embodiment 1;
Fig. 5 is the colored type design sketch of embodiment 2;
Fig. 6 is the colored type design sketch of embodiment 3;
Fig. 7 is the colored type design sketch of embodiment 4;
Fig. 8 is the colored type design sketch of embodiment 5;
Fig. 9 is the colored type design sketch of embodiment 6;
Figure 10 is the colored type design sketch of embodiment 7;
Figure 11 is the colored type design sketch of embodiment 8;
Figure 12 is the colored type design sketch of embodiment 9;
Figure 13 is the colored type design sketch of embodiment 10;
Figure 14 is the colored type design sketch of embodiment 11;
Figure 15 is the colored type design sketch of embodiment 12;
Figure 16 is the colored type design sketch of embodiment 13;
Figure 17 is the colored type design sketch of embodiment 14;
Figure 18 is the colored type design sketch of embodiment 15;
Figure 19 is the colored type design sketch of embodiment 16;
Figure 20 (a) is the colored type design sketch of the former paste of stamp of the embodiment of the invention 17;
Figure 20 (b) is the colored type design sketch that uses the identical lining of the former paste of sodium alginate and stamp production procedure and technology and embodiment 17 in the prior art.
Wherein, among Fig. 1 and Fig. 2 ... representative " compound thickener ",---representative " the former paste of sodium alginate ".
The specific embodiment
Print paste is made up of former paste, dyestuff, auxiliary agent.Wherein the former paste of stamp is the carrier of dyestuff and auxiliary agent, and it directly affects the quality of stamp product: comprise colored type definition, and the piece face uniformity, tinctorial yield, fabric feeling is printed operation stability etc.Therefore further investigate the performance of various printing gums: rheological characteristic, thixotropy, saturating net is embraced water-based, and storage stability is taken off paste property or the like, is the important step that printer author must fully grasp.Only in this way, printer author could be in face of the various stamp problems that occur, and correct the analysis solves panoramic printing quality problem flexibly, thereby produces exquisite stamp product.
Sodium alginate is a reactive printing thickener the most frequently used in the prior art.Its chemical composition is β-1,4D-mannuronic acid (M type) and β-1, the heteropolymer of 4L-guluronic acid (G type).The easy hydrolysis of sodium alginate paste, the print paste after hydrolysis imbibition especially easily.Hydrolysis be exactly at ordinary times everybody often run into in summer, the former paste of sodium alginate is subjected to the invasion and attack (urea in the mill base has promoted hydrolysis more) of bacterium, cause the macromolecule fracture, thereby cause former paste hydrolysis, cause colored pattern paste, tinctorial yield decline, coloured light poor reproducibility, waste a series of problems such as big.And the viscosity of hydrolysis and sodium alginate self is relevant, the easier hydrolysis that viscosity is low.Therefore the preservative agent that adds different plug azoles quinoline ketone derivatives in mill base is necessary.
The rheological characteristic of mill base and thixotropy are very important performance parameters.It depends primarily on the performance of former paste.Rheological characteristic is meant former paste under the effect of shearing force, its viscosity change characteristic.General stamp viscosity index (VI) PVID commonly used represents the rheological characteristic of the former paste of stamp.That is: the PVID=viscosity 1 (60r/min) of former paste/viscosity 2 (6r/min), the PVID of sodium alginate is generally between 0.6-0.8.Rheological characteristic is exactly in the stamp process, and mill base is subjected to the shear action of scraper or bar magnet, the degree that its viscosity descends, thus influence the saturating net rate of mill base.After thixotropy is meant that shearing force discharges, the speed that mill base viscosity is replied.Thixotropy is exactly after mill base is imprinted on the fabric in actual production, the speed that its viscosity is replied.Its influences the definition of the type of blossoming, the uniformity.The water-based of embracing of thickener is one of factor of influence flower type definition.In mill base, water exists with three kinds of forms: bound water, obvolvent water, free water.Wherein free water is the principal element that causes colored type poor definition.Certainly, after free water is imprinted on the fabric, understand forming bound water between some and the fiber rapidly.Therefore the fabric difference spends the type definition also different.As: the mill base that the former paste of sodium alginate is done in cotton, fiber crops, on the cellulose fibres such as viscose glue, definition is better, but on real silk fabric, definition is just very poor.Although mainly be because the real silk water imbibition is very strong, and its amount in conjunction with free water is limited, therefore the flower type just thickens.Armful water-based of guar gum thickener is better than sodium alginate paste, and therefore acid stamp specific activity printing clearness will be got well.When doing the silk reactive printing, preferably select low viscous sodium alginate for use.
Compound thickener of the present invention is the mixture of acrylic polymer dispersion and natural seaweed acid sodium.Its PVID is between 0.4-0.6.Well more a lot of than sodium alginate rheological characteristic.As shown in Figure 1: compound thickener is under the effect of scraper or bar magnet shearing force, and mill base viscosity sharply descends, and the decline of sodium alginate paste viscosity is less, and therefore the saturating net of compound thickener mill base is good.After shearing force discharged, after promptly mill base was imprinted on the fabric, its viscosity was apparently higher than sodium alginate paste, and therefore compound thickener tinctorial yield height spends the type definition good, the cloth cover good evenness.
Because the rheological characteristic of compound thickener, thixotropy obviously is better than sodium alginate paste, so the saturating net rate of its mill base height, and viscosity is replied fast, and back side infiltration is few, apparent tinctorial yield height.General compound thickener tinctorial yield is than the high 10-40% of sodium alginate paste.
The thixotropy of compound thickener and an armful water-based are better than sodium alginate, and therefore flower type definition is better than sodium alginate, and particularly wet-wet stamp is more obvious.And the bulk face uniformity is also good than sodium alginate.Even fabric pentration difference is big, also have spreadability preferably.
As can be seen from Figure 2: compound thickener mill base of the present invention is placed after 12 days viscosity and is changed very for a short time, and that sodium alginate mill base viscosity descends is very big.
Therefore, the present invention can select for use Hensel to step the compound thickener LYOPRINT of both sexes (can the print) RD-HT 01 of weaving dying (China) Co., Ltd, and it is the mixture of acrylic polymer dispersion and natural seaweed acid sodium.The compound thickener of these both sexes has the characteristic of two class thickeners, has condensed the elite of natural paste and synthetic thickener two worlds.Its hydrolytic resistance can obviously improve, and rheological characteristic, thixotropy obviously are better than the sodium alginate thickener.To improving silk like lining reactive printing fineness good effect is arranged.
Amount of urea is excessive, can quicken the hydrolysis of sodium alginate and REACTIVE DYES on the one hand, causes the imbibition when printing serious; The hygroscopic capacity increase is excessive in the process of evaporating on the other hand, also can aggravate imbibition.Therefore wanting strict control amount of urea is 2-5% with respect to the quality percentage composition of the former paste of stamp.
Find through a large amount of tests: the present invention is if add an amount of white kerosene in thickener, when the stamp look fall be imprinted on the fabric after, the rapid imbibition of kerosene, thereby the oily interface of the dyestuff imbibition that around the flower type, form to stop, seal the imbibition of dyestuff, thereby obtained meticulous colored type.
In addition, the present invention can increase the water absorption of cocoon fiber if add an amount of water-based better polymerization thing of embracing in thickener, thereby stoped the imbibition of REACTIVE DYES behind seal and the imbibition during decatize, find that through a large amount of contrast tests its flower type fineness obviously improves.
Therefore, the present invention is by the synergy of compound thickener and an amount of urea, or they and the synergy of white kerosene, high armful waterborne polymeric, can realize the high-fineness stamp of REACTIVE DYES on the silk like lining.
Below further specify the present invention with specific embodiment.
Embodiment 1:
The former paste prescription of stamp:
In the above-mentioned prescription, calgon is a water softener; Reservehao S is anti-reductant; Sodium bicarbonate is alkaline agent.
By above prescription calgon, reservehao S and sodium bicarbonate are dissolved in the warm water, add LYOPRINT RD-HT 01 while stirring, high-speed stirred added urea and cold water after 30 minutes, stirred.
The production procedure and the production technology of carrying out stamp on lining are:
Size mixing → stamp → oven dry → 102 ℃ saturated vapor decatize 8 minutes → soap → dry
Specific as follows: as in former paste, to add black P-GR 50 grams of REACTIVE DYES Nowe clone, stir, prepare black color paste; In former paste, add the REACTIVE DYES Nowe and clone yellow P-6GS 30 grams, stir, prepare yellow mill base.Adopt the flat screen printing machine stamp.Elder generation's printing black lines, rewetting cover wet and print flower type of the yellow full end, dry 2 minutes in 120 ℃ hot blast drying room then; The ventilative moisture regain of PRINTED FABRIC after the oven dry 10 minutes is on link formula continuous steaming machine, with 102 ℃ of saturated vapor decatizes 8 minutes, at last, the PRINTED FABRIC after the decatize is soaped on open soaper: first cold water spray, the 1st, 2 lattice flat wash trough cold wash, 50 ℃ of hot water wash of the 3rd lattice, 70 ℃ of hot water wash of the 4th lattice, the 5th, 6 lattice add 95 ℃ of hot water wash of 2g/l industrial washing clothes powder, the 7th lattice cold wash, and the 8th lattice add the neutralization of 0.5g/l glacial acetic acid, the 9th lattice cold wash, oven dry at last gets final product.
Fig. 3 is for using the printing effect of the former paste of sodium alginate, and Fig. 4 is the printing effect of the compound former paste of embodiment 1, and through contrast as can be known, the compound former paste of embodiment 1 increases than the former dextrin fineness of sodium alginate.
Embodiment 2:
The former paste prescription of stamp:
In the above-mentioned prescription, calgon is a water softener; Reservehao S is anti-reductant; Sodium bicarbonate is alkaline agent.
By above prescription calgon, reservehao S, sodium bicarbonate are dissolved in the warm water, add LYOPRINT RD-HT 01 while stirring, high-speed stirred added urea and cold water after 30 minutes, stirred.
On lining, carry out the production procedure of stamp and production technology with embodiment 1.
Fig. 5 is the former paste printing effect of embodiment 2, by Fig. 5 and Fig. 3 contrast can be found that embodiment 2 former pastes increase than the former dextrin fineness of the sodium alginate of prior art.And by Fig. 5 and Fig. 4 contrast can be found that embodiment 2 also slightly improves than embodiment 1 fineness, promptly LYOPRINT RD-HT 01 consumption increases, and fineness also can improve.
Embodiment 3:
The former paste prescription of stamp:
In the above-mentioned prescription, calgon is a water softener; Reservehao S is anti-reductant; Sodium bicarbonate is alkaline agent.
By above prescription calgon, reservehao S, sodium bicarbonate are dissolved in the warm water, add LYOPRINT RD-HT 01 while stirring, high-speed stirred added urea and cold water after 30 minutes, stirred.
On lining, carry out the production procedure of stamp and production technology with embodiment 1.
Fig. 6 is embodiment 3 former paste printing effects, by Fig. 6 and Fig. 3 contrast can be found that embodiment 3 former pastes increase than the former dextrin fineness of sodium alginate.And by Fig. 6 and Fig. 5 contrast can be found that embodiment 3 also slightly improves than embodiment 2 finenesses, promptly LYOPRINT RD-HT 01 consumption increases, and fineness also can improve.If but LYOPRINT RD-HT 01 consumption is excessive, mill base viscosity is too big, and operation easier is big during printing, is difficult for scraping slurry, so LYOPRINT RD-HT 01 quality percentage composition is controlled at 4-5%.
Embodiment 4:
The former paste prescription of stamp:
In the above-mentioned prescription, calgon is a water softener; Reservehao S is anti-reductant; Sodium bicarbonate is alkaline agent.
With calgon, reservehao S, sodium bicarbonate are dissolved in the warm water, add LYOPRINT RD-HT 01 while stirring by above prescription, and high-speed stirred added urea and cold water after 30 minutes, stirred.
On lining, carry out the production procedure of stamp and production technology with embodiment 1.
Fig. 7 is embodiment 4 former paste printing effects, by Fig. 7 and Fig. 3 contrast can be found that embodiment 4 former pastes increase than the former dextrin fineness of sodium alginate.
Embodiment 5:
The former paste prescription of stamp:
In the above-mentioned prescription, calgon is a water softener; Reservehao S is anti-reductant; Sodium bicarbonate is alkaline agent.
With calgon, reservehao S, sodium bicarbonate are dissolved in the warm water, add LYOPRINT RD-HT 01 while stirring by above prescription, and high-speed stirred added urea and cold water after 30 minutes, stirred.
On lining, carry out the production procedure of stamp and production technology with embodiment 1.
Fig. 8 is embodiment 5 former paste printing effects, by Fig. 8 and Fig. 3 contrast can be found that embodiment 5 former pastes increase than the former dextrin fineness of sodium alginate.And by Fig. 8 and Fig. 7 contrast can be found that embodiment 5 also slightly improves than embodiment 4 finenesses, promptly amount of urea reduces, and fineness also can improve.This mainly is that hygroscopic capacity descends when decatize because amount of urea is few, thereby reduces the imbibition of dyestuff.
Embodiment 6:
The former paste prescription of stamp:
In the above-mentioned prescription, calgon is a water softener; Reservehao S is anti-reductant; Sodium bicarbonate is alkaline agent.
With calgon, reservehao S, sodium bicarbonate are dissolved in the warm water, add LYOPRINT RD-HT 01 while stirring by above prescription, and high-speed stirred added urea and cold water after 30 minutes, stirred.
On lining, carry out the production procedure of stamp and production technology with embodiment 1.
Fig. 9 is embodiment 6 former paste printing effects, by Fig. 9 and Fig. 3 contrast can be found that embodiment 6 former pastes increase than the former dextrin fineness of sodium alginate.And by Fig. 9 and Fig. 8 contrast can be found that embodiment 6 also slightly improves than embodiment 5 finenesses, promptly amount of urea reduces, and fineness also can improve.But amount of urea very little, can reduce the fixation of REACTIVE DYES, so the urea quality percentage composition is controlled at 2-5%.
Embodiment 7:
The former paste prescription of stamp:
In the above-mentioned prescription, calgon is a water softener; Reservehao S is anti-reductant; Sodium bicarbonate is alkaline agent.
With calgon, reservehao S, sodium bicarbonate are dissolved in the warm water, add LYOPRINT RD-HT 01 while stirring by above prescription, and high-speed stirred is after 30 minutes, add urea and cold water, stir, and add white kerosene at last and stir and get final product.
On lining, carry out the production procedure of stamp and production technology with embodiment 1.
Figure 10 is embodiment 7 former paste printing effects, by Figure 10 and Fig. 3 contrast can be found that embodiment 7 former pastes obviously improve than the former dextrin fineness of sodium alginate.And, the fineness of stamp is further improved by Figure 10 and Fig. 8 contrast can be found that embodiment 7 obviously improves than embodiment 5 finenesses, makes the adding of kerosene clear.This mainly is because when printing, and white kerosene is prior to water flushing around the flower type rapidly, thereby formed " moat " around the flower type, stoped REACTIVE DYES to around imbibition.
Embodiment 8:
The former paste prescription of stamp:
In the above-mentioned prescription, calgon is a water softener; Reservehao S is anti-reductant; Sodium bicarbonate is alkaline agent.
With calgon, reservehao S, sodium bicarbonate are dissolved in the warm water, add LYOPRINT RD-HT01 while stirring, and high-speed stirred is after 30 minutes, add urea and cold water, stir, and add white kerosene at last and stir and get final product.
On lining, carry out the production procedure of stamp and production technology with embodiment 1.
Figure 11 is embodiment 8 former paste printing effects, by Figure 11 and Fig. 3 contrast can be found that embodiment 11 former pastes obviously improve than the former dextrin fineness of sodium alginate.And by Figure 11 and Figure 10 contrast being found that embodiment 8 slightly improves than embodiment 7 finenesses, illustrate to increase white kerosene, the fineness of stamp improves.
Embodiment 9:
The former paste prescription of stamp:
In the above-mentioned prescription, calgon is a water softener; Reservehao S is anti-reductant; Sodium bicarbonate is alkaline agent.
With calgon, reservehao S, sodium bicarbonate are dissolved in the warm water, add LYOPRINT RD-HT01 while stirring, and high-speed stirred is after 30 minutes, add urea and cold water, stir, and add white kerosene at last and stir and get final product.
On lining, carry out the production procedure of stamp and production technology with embodiment 1.
Figure 12 is embodiment 9 former paste printing effects, by Figure 12 and Fig. 3 contrast can be found that embodiment 12 former pastes obviously improve than the former dextrin fineness of sodium alginate.And by Figure 12 and Figure 11 contrast being found that embodiment 9 slightly improves than embodiment 8 finenesses, illustrate to increase white kerosene, the fineness of stamp improves.But it is too many that white kerosene adds, and can increase the cleaning burden, and therefore white kerosene quality percentage composition should be controlled at 8-12%.
Embodiment 10:
The former paste prescription of stamp:
In the above-mentioned prescription, calgon is a water softener; Reservehao S is anti-reductant; Sodium bicarbonate is alkaline agent.
Wherein, embracing aqueous polymer FW for the Ningbo card steps Corvidae skill limited company product, is the copolymer of butyl acrylate and methyl methacrylate.
With calgon, reservehao S, sodium bicarbonate are dissolved in the warm water, add LYOPRINT RD-HT01 while stirring, and high-speed stirred is after 30 minutes, add urea and cold water, stir, and add polymer FW at last and stir and get final product.
On lining, carry out the production procedure of stamp and production technology with embodiment 1.
Figure 13 is embodiment 10 former paste printing effects, by Figure 13 and Fig. 3 contrast can be found that embodiment 13 former pastes obviously improve than the former dextrin fineness of sodium alginate.And, high adding of embracing waterborne polymeric is described by Figure 13 and Fig. 8 contrast can be found that embodiment 10 obviously improves than embodiment 5 finenesses, the moisture in the print paste is held firmly by this polymer after printing, thereby reduced the imbibition of dyestuff; When decatize, it also can hold moisture simultaneously, the imbibition phenomenon when having reduced decatize, thereby the obvious raising of realization fineness.
Embodiment 11:
The former paste prescription of stamp:
In the above-mentioned prescription, calgon is a water softener; Reservehao S is anti-reductant; Sodium bicarbonate is alkaline agent.
Wherein, embrace aqueous polymer FW and step Corvidae skill limited company product for the Ningbo card.It is the copolymer of butyl acrylate and methyl methacrylate.
With calgon, reservehao S, sodium bicarbonate are dissolved in the warm water, add LYOPRINT RD-HT01 while stirring, and high-speed stirred is after 30 minutes, add urea and cold water, stir, and add polymer FW at last and stir and get final product.
On lining, carry out the production procedure of stamp and production technology with embodiment 1.
Figure 14 is embodiment 11 former paste printing effects, by Figure 14 and Fig. 3 contrast can be found that embodiment 14 former pastes obviously improve than the former dextrin fineness of sodium alginate.And by Figure 14 and Figure 13 contrast can be found that embodiment 11 increases than embodiment 10 finenesses.The consumption that increases the water conservation polymer is described, fineness can further improve.
Embodiment 12:
The former paste prescription of stamp:
In the above-mentioned prescription, calgon is a water softener; Reservehao S is anti-reductant; Sodium bicarbonate is alkaline agent.
Wherein, embracing aqueous polymer FW for the Ningbo card steps Corvidae skill limited company product, is the copolymer of butyl acrylate and methyl methacrylate.
With calgon, reservehao S, sodium bicarbonate are dissolved in the warm water, add LYOPRINT RD-HT01 while stirring, and high-speed stirred is after 30 minutes, add urea and cold water, stir, and add polymer FW at last and stir and get final product.
On lining, carry out the production procedure of stamp and production technology with embodiment 1.
Figure 15 is embodiment 12 former paste printing effects, by Figure 15 and Fig. 3 contrast can be found that embodiment 12 former pastes obviously improve than the former dextrin fineness of sodium alginate.And by Figure 15 and Figure 14 contrast can be found that embodiment 12 increases than embodiment 11 finenesses.The consumption that increases the water conservation polymer is described, fineness can further improve.If but the water conservation polymer volume is excessive, may cause and remove difficulty, thereby can influence fabric feeling, so water conservation polymer quality percentage composition is controlled at 10-20%.
Embodiment 13:
The former paste prescription of stamp:
In the above-mentioned prescription, calgon is a water softener; Reservehao S is anti-reductant; Sodium bicarbonate is alkaline agent.
Wherein, embracing aqueous polymer FW for the Ningbo card steps Corvidae skill limited company product, is the copolymer of butyl acrylate and methyl methacrylate.
With calgon, reservehao S, sodium bicarbonate are dissolved in the warm water, add LYOPRINT RD-HT01 while stirring, and high-speed stirred added urea and cold water after 30 minutes, stirred, and added polymer FW at last, white kerosene, and stirring gets final product.
On lining, carry out the production procedure of stamp and production technology with embodiment 1.
Figure 16 is embodiment 13 former paste printing effects, by Figure 16 and Fig. 3 contrast can be found that embodiment 13 former pastes obviously improve than the former dextrin fineness of sodium alginate.And by Figure 16 and Figure 11 and Figure 14 contrast can be found, embodiment 13 is than embodiment 8 and implement 11 finenesses and obviously improve.The cooperative effect of high water conservation polymer and white kerosene is described, makes fineness reach best.
Embodiment 14:
The former paste prescription of stamp:
In the above-mentioned prescription, calgon is a water softener; Reservehao S is anti-reductant; Sodium bicarbonate is alkaline agent.
Wherein, embracing aqueous polymer FW for the Ningbo card steps Corvidae skill limited company product, is the copolymer of butyl acrylate and methyl methacrylate.
With calgon, reservehao S, sodium bicarbonate are dissolved in the warm water, add sodium alginate while stirring, and high-speed stirred is after 2 hours, add urea and cold water, stir, and add polymer FW at last and stir and get final product.
On lining, carry out the production procedure of stamp and production technology with embodiment 1.
Figure 17 is embodiment 14 former paste printing effects, by Figure 17 and Fig. 3 contrast can be found that embodiment 14 former pastes obviously improve than the former dextrin fineness of the sodium alginate of prior art.
Embodiment 15:
The former paste prescription of stamp:
In the above-mentioned prescription, calgon is a water softener; Reservehao S is anti-reductant; Sodium bicarbonate is alkaline agent.
With calgon, reservehao S, sodium bicarbonate are dissolved in the warm water, add sodium alginate while stirring, and high-speed stirred is after 2 hours, add urea and cold water, stir, and add white kerosene at last and stir and get final product.
On lining, carry out the production procedure of stamp and production technology with embodiment 1.
Figure 18 is embodiment 15 former paste printing effects, by Figure 18 and Fig. 3 contrast can be found that embodiment 15 former pastes obviously improve than the former dextrin fineness of the sodium alginate of prior art.
Embodiment 16:
The former paste prescription of stamp:
In the above-mentioned prescription, calgon is a water softener; Reservehao S is anti-reductant; Sodium bicarbonate is alkaline agent.
Wherein, embracing aqueous polymer FW for the Ningbo card steps Corvidae skill limited company product, is the copolymer of butyl acrylate and methyl methacrylate.
With calgon, reservehao S, sodium bicarbonate are dissolved in the warm water, add LYOPRINT RD-HT01 while stirring, and high-speed stirred added urea and cold water after 30 minutes, stirred, and added polymer FW at last, and white kerosene stirs and gets final product.
On lining, carry out the production procedure of stamp and production technology with embodiment 1.
Figure 19 is embodiment 16 former paste printing effects, by Figure 19 and Fig. 3 contrast can be found that embodiment 16 former pastes obviously improve than the former dextrin fineness of the sodium alginate of prior art.The cooperative effect that water conservation polymer and white kerosene are described is suitable for the former paste of sodium alginate equally.
Embodiment 17:
The former paste prescription of stamp:
In the above-mentioned prescription, calgon is a water softener; Reservehao S is anti-reductant; Sodium bicarbonate is alkaline agent.
Wherein, embrace aqueous polymer FW and step Corvidae skill limited company product for the Ningbo card.It is the copolymer of butyl acrylate and methyl methacrylate.
With calgon, reservehao S, sodium bicarbonate are dissolved in the warm water, add LYOPRINT RD-HT01 while stirring, and high-speed stirred added urea and cold water after 30 minutes, stirred, and added polymer FW at last, white kerosene, and stirring gets final product.
On lining, carry out the production procedure and the production technology of stamp:
Size mixing → stamp → oven dry → 102 ℃ saturated vapor decatize 8 minutes → soap → dry
In former paste, add black P-GR 60 grams of REACTIVE DYES Nowe clone, stir, prepare black color paste; Add the REACTIVE DYES Nowe and clone yellow P-6GS 7 grams in former paste, black P-SG 3.6 grams stir, and prepare green mill base; Add the REACTIVE DYES Nowe and clone red P-BN 9 grams in former paste, black P-SG 0.5 gram prepares the pink colour mill base; In former paste, add the REACTIVE DYES Nowe and clone yellow P-2RN 4 grams, prepare yellow mill base.Adopt the flat screen printing machine stamp.First printing black lines, wet green mill base, pink colour shading mill base, the yellow mill base printed of wet successively again cover dried 2 minutes in 120 ℃ hot blast drying room then; The ventilative moisture regain of PRINTED FABRIC after the oven dry 10 minutes is on link formula continuous steaming machine, with 102 ℃ of saturated vapor decatizes 8 minutes, at last, the PRINTED FABRIC after the decatize is soaped on open soaper: first cold water spray, the 1st, 2 lattice flat wash trough cold water, 50 ℃ of hot water wash of the 3rd lattice, 70 ℃ of hot water wash of the 4th lattice, the 5th, 6 lattice add 95 ℃ of hot water wash of 2g/l industrial washing clothes powder, the 7th lattice cold wash, and the 8th lattice add the neutralization of 0.5g/l glacial acetic acid, the 9th lattice cold wash, oven dry at last gets final product.
Figure 20 (a) is that the former paste of the embodiment of the invention 17 is printed the flower type, and Figure 20 (b) spends type for the former paste of sodium alginate that uses prior art and according to the production procedure identical with embodiment 17 with the lining that production technology is printed.Can find from Figure 20 (b), because this flower type black lines has been printed three times by green, pink colour, the wet pressing of the wet cover of yellow mill base, and the water-retaining property of the former paste of sodium alginate is very poor, add that the thin lining suction of real silk slurry amount is very limited, therefore the flower type is very fuzzy, and fineness is very poor.Can find that from Figure 20 (a) former paste of the present invention has obviously improved repeatedly wetOnwet flower type by the cooperative effect of compound thickener, amount of urea, white kerosene, water conservation polymer, the stamp fineness on silk fabric does not almost have the imbibition phenomenon.
At present, raising along with people's living standard, flower type design pursuing individualityization, therefore the flower type becomes increasingly complex, nearly all colored type all is repeatedly a wetOnwet, and silk like lining suction slurry amount is very limited, so reactive printing flower type is generally very fuzzy, has seriously hindered the development of the reactive printing of silk like lining.Use the former paste of stamp of the present invention, thoroughly solved the colored type imbibition problem of silk like lining reactive printing existence for a long time, thereby make reactive printing thoroughly replace acidity, neutral dye stamp to become possibility, can realize high fastness, high-fineness, not contain the reactive printing of heavy metal.
Claims (5)
1. former paste of stamp that can improve silk like lining reactive printing fineness, comprise water, water softener, anti-reductant, urea and alkaline agent, it is characterized in that: also comprise compound thickener, the quality percentage composition of described compound thickener is 4～5%, and the quality percentage composition of described urea is 2～5%.
2. the former paste of stamp that improves silk like lining reactive printing fineness according to claim 1, it is characterized in that: also comprise high waterborne polymeric and/or the white kerosene embraced, the quality percentage composition that described height is embraced waterborne polymeric is 10～20%, described white kerosene the quality percentage composition be 8～12%.
3. the former paste of stamp that improves silk like lining reactive printing fineness according to claim 1 and 2 is characterized in that: described compound thickener is the mixture of acrylic polymer dispersion and natural seaweed acid sodium.
4. the former paste of stamp that improves silk like lining reactive printing fineness according to claim 2, it is characterized in that: described height is embraced the copolymer that waterborne polymeric is butyl acrylate and methyl methacrylate.
5. the former paste of stamp that improves silk like lining reactive printing fineness according to claim 2, it is characterized in that: described compound thickener is replaced with sodium alginate.
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| CN2010102953225A CN101962917B (en) | 2010-09-27 | 2010-09-27 | Printing raw paste capable of improving reactive printing fineness of real silk fabrics |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102634998A (en) * | 2012-04-01 | 2012-08-15 | 浙江嘉欣兴昌印染有限公司 | Printing gum for polyester fabrics and novel low-gum printing method |
| CN102720059A (en) * | 2012-06-20 | 2012-10-10 | 浙江华泰丝绸有限公司 | Pretreatment method for numerical printing of silk |
| CN104628886A (en) * | 2014-12-25 | 2015-05-20 | 山东洁晶集团股份有限公司 | Process method for improving rheological properties of printing and dyeing level sodium alginate |
| CN104894895A (en) * | 2015-05-29 | 2015-09-09 | 济南正骐生物科技有限公司 | Pure cotton fabric coating paste and preparation method thereof |
| CN105113296A (en) * | 2015-09-16 | 2015-12-02 | 太仓市国峰纺织印染有限责任公司 | Printing paste and preparation method thereof |
| CN105696379A (en) * | 2016-03-29 | 2016-06-22 | 湖南工程学院 | Reactive dye printing paste as well as preparation method and application thereof |
| CN106283740A (en) * | 2016-09-19 | 2017-01-04 | 上海雅运纺织助剂有限公司 | A kind of reactive printing composite paste material and its preparation method and application |
| CN106978738A (en) * | 2017-04-28 | 2017-07-25 | 山东轻工职业学院 | A kind of Dyeing with Disperse/Reactive Graft versus host disease composite paste material and its printing technology |
| CN109056374A (en) * | 2018-08-01 | 2018-12-21 | 淄博大染坊丝绸集团有限公司 | A kind of wide cut silk glues the printing technology of satin |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN88102788A (en) * | 1988-05-10 | 1988-12-07 | 安徽省地矿局测试中心 | Concave-convex clay rod printing and dyeing slurry modulation method |
| CN101096823A (en) * | 2007-07-03 | 2008-01-02 | 浙江理工大学 | Real silk fabric coloring agent printing decoration light water developing and printing flowers method |
| CN101684618A (en) * | 2008-09-23 | 2010-03-31 | 山东滨州亚光毛巾有限公司 | Composite printing paste and preparation method thereof |
-
2010
- 2010-09-27 CN CN2010102953225A patent/CN101962917B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN88102788A (en) * | 1988-05-10 | 1988-12-07 | 安徽省地矿局测试中心 | Concave-convex clay rod printing and dyeing slurry modulation method |
| CN101096823A (en) * | 2007-07-03 | 2008-01-02 | 浙江理工大学 | Real silk fabric coloring agent printing decoration light water developing and printing flowers method |
| CN101684618A (en) * | 2008-09-23 | 2010-03-31 | 山东滨州亚光毛巾有限公司 | Composite printing paste and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 《印染》 20020420 范秀芝等 混合糊料在活性染料平网印花中的应用 第19页 1-5 , 第4期 2 * |
| 《印染助剂》 20050620 唐增荣 纺织品印花助剂综述 1-9 1-5 第22卷, 第6期 2 * |
Cited By (11)
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| CN102634998A (en) * | 2012-04-01 | 2012-08-15 | 浙江嘉欣兴昌印染有限公司 | Printing gum for polyester fabrics and novel low-gum printing method |
| CN102720059A (en) * | 2012-06-20 | 2012-10-10 | 浙江华泰丝绸有限公司 | Pretreatment method for numerical printing of silk |
| CN104628886A (en) * | 2014-12-25 | 2015-05-20 | 山东洁晶集团股份有限公司 | Process method for improving rheological properties of printing and dyeing level sodium alginate |
| CN104894895A (en) * | 2015-05-29 | 2015-09-09 | 济南正骐生物科技有限公司 | Pure cotton fabric coating paste and preparation method thereof |
| CN105113296A (en) * | 2015-09-16 | 2015-12-02 | 太仓市国峰纺织印染有限责任公司 | Printing paste and preparation method thereof |
| CN105696379A (en) * | 2016-03-29 | 2016-06-22 | 湖南工程学院 | Reactive dye printing paste as well as preparation method and application thereof |
| CN105696379B (en) * | 2016-03-29 | 2018-02-09 | 湖南工程学院 | A kind of printing paste with active dye and its preparation method and application |
| CN106283740A (en) * | 2016-09-19 | 2017-01-04 | 上海雅运纺织助剂有限公司 | A kind of reactive printing composite paste material and its preparation method and application |
| CN106978738A (en) * | 2017-04-28 | 2017-07-25 | 山东轻工职业学院 | A kind of Dyeing with Disperse/Reactive Graft versus host disease composite paste material and its printing technology |
| CN109056374A (en) * | 2018-08-01 | 2018-12-21 | 淄博大染坊丝绸集团有限公司 | A kind of wide cut silk glues the printing technology of satin |
| CN109652982A (en) * | 2018-10-22 | 2019-04-19 | 广州德宇祥服装有限公司 | A kind of processing method of dry and comfortable slurry and dry and comfortable antibacterial sportswear fabric |
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