CN101959986B - Adhesive composition for trapping small organisms - Google Patents
Adhesive composition for trapping small organisms Download PDFInfo
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- CN101959986B CN101959986B CN2009801066484A CN200980106648A CN101959986B CN 101959986 B CN101959986 B CN 101959986B CN 2009801066484 A CN2009801066484 A CN 2009801066484A CN 200980106648 A CN200980106648 A CN 200980106648A CN 101959986 B CN101959986 B CN 101959986B
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- 239000000203 mixture Substances 0.000 title claims abstract description 90
- 239000000853 adhesive Substances 0.000 title description 41
- 230000001070 adhesive effect Effects 0.000 title description 41
- 229920001083 polybutene Polymers 0.000 claims abstract description 34
- -1 polyethylene Polymers 0.000 claims abstract description 24
- 239000013032 Hydrocarbon resin Substances 0.000 claims abstract description 20
- 229920006270 hydrocarbon resin Polymers 0.000 claims abstract description 20
- 229920000573 polyethylene Polymers 0.000 claims abstract description 20
- 239000007788 liquid Substances 0.000 claims abstract description 19
- 239000004698 Polyethylene Substances 0.000 claims abstract description 18
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims abstract description 13
- 229920001971 elastomer Polymers 0.000 claims description 26
- 239000005060 rubber Substances 0.000 claims description 26
- 150000002148 esters Chemical group 0.000 claims description 21
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical group CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 9
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- 238000006116 polymerization reaction Methods 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 241001465754 Metazoa Species 0.000 claims description 2
- 230000003712 anti-aging effect Effects 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims description 2
- 239000003921 oil Substances 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 239000004014 plasticizer Substances 0.000 claims description 2
- 235000013599 spices Nutrition 0.000 claims description 2
- 235000013311 vegetables Nutrition 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 35
- 238000000576 coating method Methods 0.000 abstract description 35
- 238000000034 method Methods 0.000 abstract description 16
- 239000000155 melt Substances 0.000 abstract description 7
- 239000007858 starting material Substances 0.000 abstract description 2
- 125000002723 alicyclic group Chemical group 0.000 abstract 1
- 229920005549 butyl rubber Polymers 0.000 abstract 1
- 238000002156 mixing Methods 0.000 description 25
- 229920002367 Polyisobutene Polymers 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 5
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229960001866 silicon dioxide Drugs 0.000 description 4
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 4
- 241001674044 Blattodea Species 0.000 description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 3
- 206010006514 bruxism Diseases 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 3
- 229920001195 polyisoprene Polymers 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 229920003355 Novatec® Polymers 0.000 description 2
- 241000283984 Rodentia Species 0.000 description 2
- 239000003377 acid catalyst Substances 0.000 description 2
- 229920006271 aliphatic hydrocarbon resin Polymers 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- RLAWWYSOJDYHDC-BZSNNMDCSA-N lisinopril Chemical compound C([C@H](N[C@@H](CCCCN)C(=O)N1[C@@H](CCC1)C(O)=O)C(O)=O)CC1=CC=CC=C1 RLAWWYSOJDYHDC-BZSNNMDCSA-N 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 238000007790 scraping Methods 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical group CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 101100460719 Mus musculus Noto gene Proteins 0.000 description 1
- 208000034189 Sclerosis Diseases 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C09J123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Catching Or Destruction (AREA)
- Paints Or Removers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
As a pressure-sensitive adhesive composition for trapping small organisms, use is made of a composition comprising: (A) 70 to 98% by mass of liquid polybutene having a number-average molecular weight of 200 to 1200; (B) 1.0 to 8.0% by mass of high-pressure method polyethylene having a melt index of 0.04 to 35; (C) 1.0 to 8.0% by mass of butyl rubber having a Mooney viscosity ML1+8 (at 125oC) of 30 to 60; and (D) 5 to 29% by mass of an alicyclic hydrocarbon resin. Thus, a pressure-sensitive adhesive composition for trapping small organisms, which has a high pressure-sensitive adhesiveness and good coating properties to an adherend, and in which the starting materials of the pressure-sensitive adhesive composition can be easily obtained and the pressure-sensitive composition can be producedat a good workability, is provided.
Description
Technical field
The present invention relates to be applicable to catch the adhesive composition of the atoms such as mouse, cockroach, fly.
Background technology
From the aspect of improving of living environment, the expeling of harmful atoms such as mouse, cockroach, fly is important problem.The infringement that is particularly caused by rodents is very large, and especially mouse not only causes damage to agricultural-food, food, and the lead pipe of also can breaking by the teeth causes gas leak, or lamp cord is exposed and initiation fire.Expelling method as these atoms, propose several different methods in the past and be committed to enforcement, wherein the easiest method has: have fusible trapping agent in the coating of the applied material such as ground paper, paperboard, plank, plastic film, sheet material, and it is arranged on method on the path of atom.At this moment, trapping agent must satisfy coating operability excellence and the also requirement of excellence of binding property.In addition, when in advance when applied material is coated with, avoid in preservation or its use in trapping agent from applied material flow out or be impregnated into the applied material after ooze out, thereby cause using or to pollute the floor.
As this atom trapping agent, disclose and for example comprised polybutene 86%, isoprene-isobutylene rubber 10%, and as the composition (patent documentation 1) of the paraffin 4% of Antidrip agent, comprise 80 parts of polybutene, 10 parts of isoprene-isobutylene rubbers and rosin, silica gel, polyethylene amounts to 40 parts composition (patent documentation 2), 80: 20 mixture, 100 mass parts with respect to polyisobutene (viscosity under 50 ℃ is 1000 pools) or polyisobutene and natural rubber, composition (the patent documentation 3 that has cooperated respectively organobentonite 2～40 mass parts or colloid silica 0.5～8 mass parts and obtained, patent documentation 4), comprise isoprene-isobutylene rubber 5 quality %, polybutene 35 quality %, and rosin ester, toluene, dimethylbenzene amounts to the composition (patent documentation 5) of 60 quality % etc.In addition, also disclose the composition (patent documentation 6) that comprises polybutene 80 quality %, isoprene-isobutylene rubber 16 quality % and polyethylene 4 quality %, and mixture 80～98 quality %, the viscosity-average molecular weight that comprise 2 kinds of different liquid polybutene of molecular weight are 1,000,000～2,500,000 polyisobutylene rubber 1～10 quality %, the composition (patent documentation 7) with high-pressure polyethylene 1～10 quality % of specific trait.
But these examples all can not satisfy all above-mentioned requirements.Particularly, about having used the composition of paraffin, the anti-effect that flows out is not enough when adding on a small quantity; On the other hand, if add enough amounts, along with the time lapse after the coating, the wax composition moves to the surface of bonding coat, so that bounding force decline, so capture ability significantly descends.About having used expensive organobentonite or the composition of silicon-dioxide, although good aspect anti-outflow effect and bounding force, these meal volumes are large, are involved in air during mixing, the labour of cost and time or cost aspect are considered during therefore from manufacturings such as mixed deaerations, and be not preferred.
In addition, comprise the composition of isoprene-isobutylene rubber, polybutene and rosin ester, toluene, dimethylbenzene owing to having used volatile aromatic solvent, therefore have the problem of foul smell.In addition, arrange be coated with this adhesive composition film to catch atom the time, through long-time, solvent evaporates, coated film sclerosis, thereby the problem that can't avoid capture ability to descend.In addition, comprise binding property and coating this two aspect of operability during operation that polybutene, isoprene-isobutylene rubber and poly composition can't satisfy adhesive composition simultaneously.
In addition, disclose the composition that uses polyisobutylene rubber among the Japanese kokai publication sho 2007-177104, although its bounding force is excellent, because the molecular weight of polyisobutylene rubber is very large, therefore had the long shortcoming of required time that is dissolved in the polybutene by mixing.And the supply source of polyisobutylene rubber is limited, and is not only expensive, and stable supplying also has problem.And 2 kinds of liquid polybutene of use etc. are also very bothersome in operation.
Patent documentation 1: Japanese Patent Publication 48-16617 communique
Patent documentation 2: Japanese kokai publication sho 52-105217 communique
Patent documentation 3: Japanese kokai publication sho 51-125123 communique
Patent documentation 4: Japanese Patent Publication 53-18586 communique
Patent documentation 5: Japanese kokai publication sho 52-98161 communique
Patent documentation 6: Japanese JP 2-57521 communique
Patent documentation 7: Japanese kokai publication sho 2007-177104 communique
Summary of the invention
Problem of the present invention is to provide a kind of pressure-sensitive adhesive composition for trapping small organisms, its have satisfy atom catch the binding property of usefulness excellent, when adhesive composition is made or the operability during the coating operation of the adhesive composition that makes is excellent and coating after adhesive composition the excellent properties of various requirement such as do not flow out, and starting material easily obtain and low price.
The present invention relates to a kind of pressure-sensitive adhesive composition for trapping small organisms, it is characterized in that, it comprises following compositions (integral body is made as 100 quality %):
(A) number-average molecular weight of 70～98 quality % is 200～1200 liquid polybutene,
(B) melting index of 1.0～8.0 quality % is 0.04～35 high-pressure polyethylene,
(C) the mooney viscosity ML of 1.0～8.0 quality %
1+8(125 ℃) are 30～60 isoprene-isobutylene rubber, and
(D) the ester ring type hydrocarbon resin of 5～29 quality %.
According to the present invention, by in the composition that comprises liquid polybutene, polyethylene, isoprene-isobutylene rubber, further adding the ester ring type hydrocarbon resin, following pressure-sensitive adhesive composition for trapping small organisms can be provided, it is compared with the existing composition that comprises polybutene, polyethylene, isoprene-isobutylene rubber, rosin or silica gel, binding property to atom is excellent, the excellences such as operability of the coating operation of the operability during manufacturing and adhesive composition, and do not have shortcomings such as adhesive composition outflow after the coating, cheap and have an excellent performance.
Embodiment
Below, illustrate in greater detail the present invention.
The number-average molecular weight of (A) liquid polybutene that the present invention uses is in 200～1200 scope.The scope of further preferred number-average molecular weight is 400～1200.This liquid state polybutene for example can decompose from petroleum naphtha and remove the butane-butylene fraction polymerization that obtains behind the divinyl the so-called C 4 fraction that produces and make.These polybutene are for example commercially available with the trade(brand)name of Nisseki Polybutene (Shin Nihon Oil Co., Ltd).When the number-average molecular weight of polybutene less than 200 the time because the point of ignition step-down, the security when therefore having when the manufacturing of this adhesive composition or in the kitchen etc. the place of pyrotechnics to use reduces.And the bounding force of the adhesive composition that obtains descends, thereby not preferred.In addition, when number-average molecular weight greater than 1200 the time because the melt viscosity of adhesive composition becomes excessive, thereby can't be coated with smoothly operation.
So-called high-pressure polyethylene refers to separately ethene or with ethene and other alkene (such as butylene, amylene, hexene etc.) polymerization and the polyethylene that obtains in method for high pressure polymerization, its density is 0.92～0.93.The melting index of (B) high-pressure polyethylene that the present invention uses is 0.04～35, is preferably 0.1～20.Melting index is dissolved in liquid polybutene less than 0.04 high-pressure polyethylene needs high temperature and long-time, can not obtain in addition anti-outflow effect and the anti-sufficient adhesive composition of effect that oozes out of binding property, trapping agent greater than the high-pressure polyethylene of this scope.High-pressure polyethylene for example can adopt commodity to be called Novatec LJ600 (Japanese Polyethylene Co., Ltd.).High-pressure polyethylene can use separately also and can multiplely use.
What is called (C) isoprene-isobutylene rubber that the present invention uses refers to mooney viscosity ML
1+8(125 ℃) be 30～60, be preferably 45～55 isoprene-isobutylene rubber.These isoprene-isobutylene rubbers are for example commercially available with the trade(brand)name of BUTYL268 (JSR Corp.'s system).As mooney viscosity ML
1+8(125 ℃) less than 30 o'clock, the bounding force of the adhesive composition that makes was not enough, to the catching property decline of atom.On the other hand, as mooney viscosity ML
1+8(125 ℃) greater than 60 o'clock, the dissolving required time was long in polybutene, and the melt viscosity of the adhesive composition that makes is very high, therefore was difficult to successfully coating on the face of applied material.
What is called (D) ester ring type hydrocarbon resin as the present invention's use, can enumerate the resin that uses acid catalyst that the alicyclic olefin compounds polymerization of cyclopentadiene or alkyl cyclopentadiene and so on is obtained, or examine hydrogenation after using acid catalyst with the alkenyl aromatic hydrocarbon polymerization, with aromatic ring and the resin that obtains etc.These ester ring type hydrocarbon resins can for example obtain with trade(brand)name Escorez 5300 (Exxon Mobil Chemical company system) from the market.
The mixing ratio of the liquid polybutene among the present invention is 70～98 quality % with respect to composition in its entirety, is preferably 75～85 quality %.If the mixing ratio of liquid polybutene is less than 70 quality %, then the extensibility of coated film descends, and has the deteriorated tendencies of coating processibility such as producing concave-convex surface.In addition, if, then there is the deteriorated tendency of anti-outflow of coated film greater than 98 quality % in the mixing ratio of liquid polybutene.
The mixing ratio of the high-pressure polyethylene among the present invention is 1.0～8.0 quality % with respect to composition in its entirety, is preferably 2.0～6.0 quality %, more preferably the scope of 3.0～4.5 quality %.If mixing ratio is less than 1.0 quality %, then the anti-outflow of coated film is deteriorated.On the other hand, if mixing ratio greater than 8.0 quality %, the formative of then filming descends, the processibility that produces the coated film such as concave-convex surface is deteriorated.
The mixing ratio of isoprene-isobutylene rubber is 1.0～8.0 quality % with respect to composition in its entirety, is preferably 2.0～6.0 quality %, more preferably the scope of 2.5～4.5 quality %.If mixing ratio then can't obtain sufficient bounding force less than 1.0 quality %; In addition, if mixing ratio greater than 8.0 quality %, then melt viscosity becomes greatly, the processibility during coating is deteriorated.
In the present invention, as its constituent, except above-mentioned three components, also must add the ester ring type hydrocarbon resin.By using the ester ring type hydrocarbon resin, the operability in the time of obtaining bounding force and coating is the adhesive composition of excellence all.When not making adhesive composition with the ester ring type hydrocarbon resin, if the composition of the operability excellence in the time of will obtaining being coated with then can only obtain the composition of poor adhesion.On the other hand, when not making the composition that can satisfy bounding force with the ester ring type hydrocarbon resin, the melt viscosity of said composition is very big, thus coating operability variation, thereby the two equal excellent adhesive composition of the operability all can't obtain the bounding force of target of the present invention and coating the time.The mixing ratio of ester ring type hydrocarbon resin is 5～29 quality % with respect to composition in its entirety, is preferably 7～20 quality %, more preferably the scope of 9～15 quality %.If mixing ratio is less than 5 quality %, then the melt viscosity of adhesive composition is too high, and coating goes wrong; If mixing ratio is greater than 29 quality %, then melt viscosity is excessively low, consequently, the anti-outflow variation of binding, thus not preferred.And the bounding force of coated film is low, and the acquisition performance of atom goes wrong.
Adhesive composition of the present invention can be by making (A)～(D) composition melting mixing.The method of melting mixing does not have particular restriction, can adopt known method to carry out.For example, can adopt under the temperature condition of (A)～(D) each composition melting, use mixing roll to carry out the methods such as mandatory stirring.As kneading device, can preferably use known still with agitating vane etc.
As compounding process, for example be preferably as follows method: will add successively or simultaneously therein other compositions as the liquid polybutene heating of principal constituent in advance, and carry out mixing.Preferred temperature range is 160 ℃～170 ℃ when carrying out this sequence of operations.Operating time can suitably be adjusted according to quantity, but is preferably 5～7 hours.
In addition, about be coated with the method for the adhesive composition that makes at base material, can preferably use the known either method such as the skill in using a kitchen knife in cookery, scraping blade method of scraping.The temperature of the adhesive composition during coating is preferably 160 ℃～170 ℃.
Composition of the present invention not with an organic solvent thereby does not have unusual foul smell, so mouse can not escape, and can not hinder the effect of attractive substance yet.In addition, owing to not using wilkinite or the such bulky weighting agent of silicon-dioxide, therefore in mixing operation, do not bubble the problem that makes manufacturing operation be difficult to continue.Adhesive composition of the present invention is not only effective to catching of the rodents atoms such as mouse, can be used for catching such as harmful atoms such as cockroaches in addition.
In addition, adhesive composition of the present invention can be according to applicable purposes, in not damaging its scope that requires performance, except above-mentioned necessary constituent, can also be as required suitably compounding practice finish, vegetable and animals oils, polymeric plasticizer, tenderizer, tinting material, oxidation inhibitor, antiaging agent, spices, attractive substance, feed etc.
Embodiment
Below, specify the present invention with embodiment, but the present invention is not limited to these embodiment.
＜embodiment 1～3 and comparative example 1～6 〉
Use material shown below, according to the mixing ratio shown in the table 1, prepared various adhesive compositions.
Isoprene-isobutylene rubber: the BUTYL268 processed of JSR company, mooney viscosity ML
1+8(125 ℃) 51
Polyisobutylene rubber: the Vistanex L-120 processed of Exxon Mobil Chemical company, weight-average molecular weight 1,660,000
High-pressure polyethylene: 108 ℃ of Japanese Polyethylene Co., Ltd. systems, Novatec LJ600, MFR5.5, density 0.93, fusing point (DSC method)
Liquid polybutene A: Nippon Petrochemicals Co., Ltd.'s system, Nisseki Polybutene HV-100, number-average molecular weight 980
Liquid polybutene B: Nippon Petrochemicals Co., Ltd.'s system, Nisseki Polybutene HV-300, number-average molecular weight 1400
105 ℃ of the ester ring type hydrocarbon resin A:Exxon Mobil Chemical Escorez 5300 processed of company, fusing points
100 ℃ of the aliphatic hydrocarbon resin B:Exxon Mobil Chemical Escorez 1304 processed of company, fusing points
The preparation method of adhesive composition is as described below.That is, in being heated to 170 ℃ liquid polybutene, add successively other composition, temperature is remained on 170 ℃, stir until each homogeneous chemical composition dissolving.Comparative example 4 is compositions of the disclosed use polyisobutylene rubber of Japanese kokai publication sho 2007-177104, although its bounding force is excellent, but because the molecular weight of polyisobutylene rubber is very large, therefore compare with other examples, by the mixing spended time phenomenal growth that is dissolved in the polybutene.Then, estimated the performance of melt viscosity and the bounding force of these adhesive compositions.Evaluation result is as shown in table 1.In addition, evaluation method is as described below.
＜evaluation method 〉
Melt viscosity: according to JIS-K7117, the melt viscosity under having measured 160 ℃.Operability when melt viscosity has influence on adhesive composition coated applied.Except the numerical value of melt viscosity, also put down in writing in the lump the evaluation of coating performance in the table.Evaluation is performed as follows.That is, use the stainless steel molding box of the specified dimension of making by punching, be coated with 170 ℃ adhesive composition on the surface of platform paper with thickness 2mm.Adhesive composition is really up to the mark and be coated with equably, and in the coating or the adhesive composition after the coating and do not flow out (being evaluated as zero).Adhesive composition is really up to the mark and be difficult to be coated with equably (being evaluated as *).Confirm to have in the coating operation or the adhesive composition outflow (being evaluated as △) after the coating.
Refer to touch viscosity: will point and the Surface Contact of coating the adhesive composition of coated face, and study finger and touched viscosity.
Estimate *: be attached to hardly finger.And without expansion, there is not caoutchouc elasticity.
△: although be attached to finger, the shortcoming caoutchouc elasticity.
Zero: be attached to finger, and expansion is arranged, caoutchouc elasticity is arranged.
Bounding force: according to probe tack method (JIS-Z0237 replenishes item), making adhesive composition and the diameter of coating coated face is the end contact of the metal column of 5mm, has used stretching test machine determinations under 23 ℃ metal column is pulled open required power from coated face.Bounding force affects the atom acquisition performance.
[table 1]
As shown in Table 1, comprise the adhesive composition of the present invention shown in the embodiment 1～3 of liquid polybutene, high-pressure polyethylene, isoprene-isobutylene rubber, ester ring type hydrocarbon resin and have suitable melt viscosity, refer to touch viscosity, bounding force is also good.That is this two aspect of operability when, the catching property of atom is with coating is all excellent.In addition, by embodiment 1～3 is compared, by regulating the mixing ratio of ester ring type hydrocarbon resin, can be adjusted to desirable bounding force and melt viscosity as can be known.
Relative therewith, for the comparative example 1 that does not cooperate the ester ring type hydrocarbon resin, although the operability when it is coated with is excellent, poor adhesion.For the mixing ratio that increases isoprene-isobutylene rubber and and make the consistent comparative example 2 of bounding force and embodiment 1, embodiment 2 with the large liquid polybutene of viscosity, although its bounding force excellence, melt viscosity is large, the operability during coating is poor.In addition, for using aliphatic hydrocarbon resin to replace the ester ring type hydrocarbon resin to be used as the comparative example 3 of hydrocarbon resin, although the operability during its coating is excellent, poor adhesion, and think strong from the foul smell of the binding of resin B.Comparative example 4 is present commercially available materials that are widely used as pressure-sensitive adhesive composition for trapping small organisms, and it has all real results of excellence of bounding force, coating operability.As seen from table, embodiment 1, embodiment 2 and embodiment 3 have bounding force and the coating operability no less than comparative example 4.In addition, the polyisobutylene rubber of comparative example 4 usefulness supra polymers replaces the application's isoprene-isobutylene rubber.Therefore, as shown in table 1, it is long that mixing thing reaches the required time of uniform state during mixing operation, the operability existing problems the during manufacturing of adhesive composition.And, also must use 2 kinds of liquid polybutene, manufacturing operation is miscellaneous in this.
In addition, the melt viscosity of the composition (comparative example 5) that the usage ratio of ester ring type hydrocarbon resin is very few is too high, coating operability existing problems.In addition, the coated face of the title complex (comparative example 6) that the usage ratio of ester ring type hydrocarbon resin is too much becomes really up to the mark, thereby does not have bounding force, and the catching property of atom is poor.And the viscosity during owing to melting is excessively low, and therefore broadening becomes excessive when the coating operation, is difficult to keep shape.
Relative therewith, among embodiment 1, embodiment 2 and the embodiment 3 illustrative adhesive composition of the present invention coating during operation operability and the atom acquisition performance this is all fine aspect two.And required time of the homogenization the during manufacturing of adhesive composition is also shorter, and the operability during manufacturing is also fine.In addition, the coated film after the coating of applied material is arranged on atom can not flow out when catching in the place, can not ooze out in applied material and can't use, and around also can not polluting, the keeping quality of coated film is also fine.
According to the present invention, can provide the adhesive composition that the grinding tooth atoms such as mouse is had excellent catching property.In addition, pressure-sensitive adhesive composition for trapping small organisms of the present invention is because the operability when making is excellent, thereby can make economically.In addition, this adhesive composition is because the coating operability is excellent, and therefore the coating operation on applied material also can be implemented economically.
Hence one can see that, pressure-sensitive adhesive composition for trapping small organisms of the present invention can be efficiently and is driven away economically the grinding tooth atom such as mouse, thereby can be economical and effectively prevent the agricultural-food or the infringement of food and the infringement of lead pipe or lamp cord that are caused by these grinding tooth atoms.
Claims (3)
1. a pressure-sensitive adhesive composition for trapping small organisms is characterized in that, it is become to be grouped into by following (A)～(D), and (A)～(D) composition adds up to 100 quality %,
(A) number-average molecular weight of 75～85 quality % is 200～1200 liquid polybutene,
(B) melting index of 1.0～8.0 quality % is 0.04～35 high-pressure polyethylene,
(C) the mooney viscosity ML under 125 of 1.0～8.0 quality % ℃
1+8Be 30～60 isoprene-isobutylene rubber, and
(D) the ester ring type hydrocarbon resin of 7～20 quality %, described ester ring type hydrocarbon resin are the resins that the ester ring type olefinic polymerization is obtained.
2. pressure-sensitive adhesive composition for trapping small organisms according to claim 1 is characterized in that, further is combined with operation finish, polymeric plasticizer, tenderizer, tinting material, oxidation inhibitor, antiaging agent, attractive substance.
3. pressure-sensitive adhesive composition for trapping small organisms according to claim 2 is characterized in that, as described attractive substance, is combined with vegetable and animals oils, spices or feed.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008050228A JP2009203446A (en) | 2008-02-29 | 2008-02-29 | Adhesive composition for capturing small creature |
| JP2008-050228 | 2008-02-29 | ||
| PCT/JP2009/053467 WO2009107687A1 (en) | 2008-02-29 | 2009-02-19 | Pressure-sensitive adhesive composition for trapping small organisms |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101959986A CN101959986A (en) | 2011-01-26 |
| CN101959986B true CN101959986B (en) | 2013-10-16 |
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| CN2009801066484A Active CN101959986B (en) | 2008-02-29 | 2009-02-19 | Adhesive composition for trapping small organisms |
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| Country | Link |
|---|---|
| JP (1) | JP2009203446A (en) |
| CN (1) | CN101959986B (en) |
| TW (1) | TWI449764B (en) |
| WO (1) | WO2009107687A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3601464A4 (en) * | 2017-03-31 | 2020-09-02 | 3M Innovative Properties Company | Adhesive comprising low molecular weight polyisobutylene polymer and styrene isobutylene block copolymer |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102850965B (en) * | 2012-08-13 | 2014-07-23 | 北京绿叶世纪日化用品有限公司 | Binder, preparation method of the binder and insect bonding plate coated with the binder |
| CN102850966A (en) * | 2012-08-13 | 2013-01-02 | 北京绿叶世纪日化用品有限公司 | Rat glue having attraction effects, preparation method of the rat glue and rat glue plate coated with the rat glue |
| CN103497711B (en) * | 2013-08-07 | 2015-11-11 | 佛山力得高科技有限公司 | Sticky mouse glue and preparation method thereof |
| CN103709977B (en) * | 2013-12-04 | 2017-07-11 | 浙江固特热熔胶有限公司 | The efficient Mouse adhering glue of environmental protection and public nuisance free and its production method |
| JP6984889B2 (en) * | 2018-03-30 | 2021-12-22 | 積水フーラー株式会社 | Hot melt composition |
| JP7430059B2 (en) | 2019-12-26 | 2024-02-09 | 積水フーラー株式会社 | hot melt composition |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52154781A (en) * | 1976-06-18 | 1977-12-22 | Nitto Electric Ind Co Ltd | Vermin adhesive collector |
| JPS5626968A (en) * | 1979-07-13 | 1981-03-16 | Nichiban Co Ltd | Adhesive tape for bundling raw vegetable of flower |
| JPS58180402A (en) * | 1982-04-16 | 1983-10-21 | Nippon Oil Co Ltd | Improved adhesive composition for capturing small life |
| JPS58180401A (en) * | 1982-04-16 | 1983-10-21 | Nippon Oil Co Ltd | Adhesive composition for capturing small life |
| JPH09143443A (en) * | 1995-11-22 | 1997-06-03 | Nitto Denko Corp | Tacky agent and tacky catching tool |
| CA2201258C (en) * | 1996-04-01 | 2005-12-06 | James A. Davis | Adhesive tape compositions and method for covering roofs |
| JP4146568B2 (en) * | 1999-03-18 | 2008-09-10 | 新田ゼラチン株式会社 | Adhesive composition for capturing small organisms and small organism capturing tool using the same |
| JP4969102B2 (en) * | 2005-12-28 | 2012-07-04 | Ｊｘ日鉱日石エネルギー株式会社 | Adhesive for capturing small organisms |
| JP4791821B2 (en) * | 2005-12-28 | 2011-10-12 | Ｊｘ日鉱日石エネルギー株式会社 | Adhesive composition for capturing small organisms |
-
2008
- 2008-02-29 JP JP2008050228A patent/JP2009203446A/en active Pending
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2009
- 2009-02-16 TW TW098104822A patent/TWI449764B/en active
- 2009-02-19 CN CN2009801066484A patent/CN101959986B/en active Active
- 2009-02-19 WO PCT/JP2009/053467 patent/WO2009107687A1/en active Application Filing
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3601464A4 (en) * | 2017-03-31 | 2020-09-02 | 3M Innovative Properties Company | Adhesive comprising low molecular weight polyisobutylene polymer and styrene isobutylene block copolymer |
Also Published As
| Publication number | Publication date |
|---|---|
| TW200936723A (en) | 2009-09-01 |
| TWI449764B (en) | 2014-08-21 |
| JP2009203446A (en) | 2009-09-10 |
| WO2009107687A1 (en) | 2009-09-03 |
| CN101959986A (en) | 2011-01-26 |
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