CN101953364A - Electric heating sanitary perfumed slice and application thereof - Google Patents
Electric heating sanitary perfumed slice and application thereof Download PDFInfo
- Publication number
- CN101953364A CN101953364A CN2010105418129A CN201010541812A CN101953364A CN 101953364 A CN101953364 A CN 101953364A CN 2010105418129 A CN2010105418129 A CN 2010105418129A CN 201010541812 A CN201010541812 A CN 201010541812A CN 101953364 A CN101953364 A CN 101953364A
- Authority
- CN
- China
- Prior art keywords
- electric heating
- scented tea
- heating health
- tributyl citrate
- acetyl tributyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005485 electric heating Methods 0.000 title claims abstract description 48
- -1 fatty alcohol ester Chemical class 0.000 claims abstract description 22
- 150000001875 compounds Chemical class 0.000 claims abstract description 13
- 241000238631 Hexapoda Species 0.000 claims abstract description 10
- 239000002728 pyrethroid Substances 0.000 claims abstract description 5
- 241001122767 Theaceae Species 0.000 claims description 47
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 22
- 239000000843 powder Substances 0.000 claims description 12
- RDOFJDLLWVCMRU-UHFFFAOYSA-N Diisobutyl adipate Chemical compound CC(C)COC(=O)CCCCC(=O)OCC(C)C RDOFJDLLWVCMRU-UHFFFAOYSA-N 0.000 claims description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 239000000049 pigment Substances 0.000 claims description 7
- 229920006395 saturated elastomer Polymers 0.000 claims description 7
- 235000013599 spices Nutrition 0.000 claims description 7
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 6
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 6
- OCQDPIXQTSYZJL-UHFFFAOYSA-N 1,4-bis(butylamino)anthracene-9,10-dione Chemical group O=C1C2=CC=CC=C2C(=O)C2=C1C(NCCCC)=CC=C2NCCCC OCQDPIXQTSYZJL-UHFFFAOYSA-N 0.000 claims description 5
- 241000255925 Diptera Species 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 5
- 230000003078 antioxidant effect Effects 0.000 claims description 5
- 239000012752 auxiliary agent Substances 0.000 claims description 5
- 239000003381 stabilizer Substances 0.000 claims description 5
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 4
- 150000004056 anthraquinones Chemical class 0.000 claims description 4
- DKMROQRQHGEIOW-UHFFFAOYSA-N Diethyl succinate Chemical compound CCOC(=O)CCC(=O)OCC DKMROQRQHGEIOW-UHFFFAOYSA-N 0.000 claims description 3
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 3
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 3
- GYWCVOZDFNTGAV-UHFFFAOYSA-N 10-octoxy-10-oxodecanoic acid Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(O)=O GYWCVOZDFNTGAV-UHFFFAOYSA-N 0.000 claims description 2
- SPSPIUSUWPLVKD-UHFFFAOYSA-N 2,3-dibutyl-6-methylphenol Chemical group CCCCC1=CC=C(C)C(O)=C1CCCC SPSPIUSUWPLVKD-UHFFFAOYSA-N 0.000 claims description 2
- IKEHOXWJQXIQAG-UHFFFAOYSA-N 2-tert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1 IKEHOXWJQXIQAG-UHFFFAOYSA-N 0.000 claims description 2
- HBTAOSGHCXUEKI-UHFFFAOYSA-N 4-chloro-n,n-dimethyl-3-nitrobenzenesulfonamide Chemical compound CN(C)S(=O)(=O)C1=CC=C(Cl)C([N+]([O-])=O)=C1 HBTAOSGHCXUEKI-UHFFFAOYSA-N 0.000 claims description 2
- WJNDHRGXEXGVCO-UHFFFAOYSA-N C(C)(C)NC(C)C1=CC=C(C=2C(C3=CC=CC=C3C(C12)=O)=O)NC(C)C Chemical compound C(C)(C)NC(C)C1=CC=C(C=2C(C3=CC=CC=C3C(C12)=O)=O)NC(C)C WJNDHRGXEXGVCO-UHFFFAOYSA-N 0.000 claims description 2
- XTJFFFGAUHQWII-UHFFFAOYSA-N Dibutyl adipate Chemical compound CCCCOC(=O)CCCCC(=O)OCCCC XTJFFFGAUHQWII-UHFFFAOYSA-N 0.000 claims description 2
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- QMGGFHSAUPCGLF-UHFFFAOYSA-N NC1=CC=CC=2C(C3=CC=CC=C3C(C12)=O)=O.C(C)C1=CC(=CC(=C1)C)CC Chemical compound NC1=CC=CC=2C(C3=CC=CC=C3C(C12)=O)=O.C(C)C1=CC(=CC(=C1)C)CC QMGGFHSAUPCGLF-UHFFFAOYSA-N 0.000 claims description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 2
- 239000012965 benzophenone Substances 0.000 claims description 2
- 239000012964 benzotriazole Substances 0.000 claims description 2
- 239000001055 blue pigment Substances 0.000 claims description 2
- 235000019282 butylated hydroxyanisole Nutrition 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 229940031769 diisobutyl adipate Drugs 0.000 claims description 2
- 229940031578 diisopropyl adipate Drugs 0.000 claims description 2
- MSQKMFXJFBXZNQ-UHFFFAOYSA-N dipropan-2-yl pentanedioate Chemical compound CC(C)OC(=O)CCCC(=O)OC(C)C MSQKMFXJFBXZNQ-UHFFFAOYSA-N 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- WEAPVABOECTMGR-UHFFFAOYSA-N triethyl 2-acetyloxypropane-1,2,3-tricarboxylate Chemical compound CCOC(=O)CC(C(=O)OCC)(OC(C)=O)CC(=O)OCC WEAPVABOECTMGR-UHFFFAOYSA-N 0.000 claims description 2
- 125000003354 benzotriazolyl group Chemical group N1N=NC2=C1C=CC=C2* 0.000 claims 1
- 239000004480 active ingredient Substances 0.000 abstract description 5
- 239000003039 volatile agent Substances 0.000 abstract 3
- VXRUADVCBZMFSV-UHFFFAOYSA-N 2-acetyloxypropane-1,2,3-tricarboxylic acid Chemical compound CC(=O)OC(CC(O)=O)(CC(O)=O)C(O)=O VXRUADVCBZMFSV-UHFFFAOYSA-N 0.000 abstract 1
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 230000001066 destructive effect Effects 0.000 abstract 1
- QYMFNZIUDRQRSA-UHFFFAOYSA-N dimethyl butanedioate;dimethyl hexanedioate;dimethyl pentanedioate Chemical compound COC(=O)CCC(=O)OC.COC(=O)CCCC(=O)OC.COC(=O)CCCCC(=O)OC QYMFNZIUDRQRSA-UHFFFAOYSA-N 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 29
- 239000000463 material Substances 0.000 description 17
- 238000005303 weighing Methods 0.000 description 8
- 241000607479 Yersinia pestis Species 0.000 description 7
- 241000257159 Musca domestica Species 0.000 description 4
- 229920005830 Polyurethane Foam Polymers 0.000 description 4
- 230000000749 insecticidal effect Effects 0.000 description 4
- 239000011496 polyurethane foam Substances 0.000 description 4
- ZDQWESQEGGJUCH-UHFFFAOYSA-N Diisopropyl adipate Chemical class CC(C)OC(=O)CCCCC(=O)OC(C)C ZDQWESQEGGJUCH-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000008029 eradication Effects 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- MIZYPRIEDMSCAC-UHFFFAOYSA-N (2-methyl-4-oxo-3-prop-2-enylcyclopent-2-en-1-yl) 2,2,3,3-tetramethylcyclopropane-1-carboxylate Chemical compound CC1=C(CC=C)C(=O)CC1OC(=O)C1C(C)(C)C1(C)C MIZYPRIEDMSCAC-UHFFFAOYSA-N 0.000 description 2
- 241000256186 Anopheles <genus> Species 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- LTMQQEMGRMBUSL-UHFFFAOYSA-N Metoxadiazone Chemical compound O=C1OC(OC)=NN1C1=CC=CC=C1OC LTMQQEMGRMBUSL-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229960005286 carbaryl Drugs 0.000 description 2
- CVXBEEMKQHEXEN-UHFFFAOYSA-N carbaryl Chemical compound C1=CC=C2C(OC(=O)NC)=CC=CC2=C1 CVXBEEMKQHEXEN-UHFFFAOYSA-N 0.000 description 2
- UISUNVFOGSJSKD-UHFFFAOYSA-N chlorfluazuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC(C=C1Cl)=CC(Cl)=C1OC1=NC=C(C(F)(F)F)C=C1Cl UISUNVFOGSJSKD-UHFFFAOYSA-N 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- QQQYTWIFVNKMRW-UHFFFAOYSA-N diflubenzuron Chemical compound FC1=CC=CC(F)=C1C(=O)NC(=O)NC1=CC=C(Cl)C=C1 QQQYTWIFVNKMRW-UHFFFAOYSA-N 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 239000000077 insect repellent Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 1
- WITMXBRCQWOZPX-UHFFFAOYSA-N 1-phenylpyrazole Chemical class C1=CC=NN1C1=CC=CC=C1 WITMXBRCQWOZPX-UHFFFAOYSA-N 0.000 description 1
- 241000256111 Aedes <genus> Species 0.000 description 1
- 241000256118 Aedes aegypti Species 0.000 description 1
- APHGYLSVTBJZHJ-UHFFFAOYSA-N C(C)(C)N(C(C)C)CCC1=CC=CC=2C(C3=CC=CC=C3C(C12)=O)=O Chemical compound C(C)(C)N(C(C)C)CCC1=CC=CC=2C(C3=CC=CC=C3C(C12)=O)=O APHGYLSVTBJZHJ-UHFFFAOYSA-N 0.000 description 1
- 0 CCC(Cl)=C[C@@]1C(C)(C)C1C(OCc1c(CC)c(F)c(*C*)c(F)c1F)=O Chemical compound CCC(Cl)=C[C@@]1C(C)(C)C1C(OCc1c(CC)c(F)c(*C*)c(F)c1F)=O 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000256054 Culex <genus> Species 0.000 description 1
- 241000256113 Culicidae Species 0.000 description 1
- LVZWSLJZHVFIQJ-UHFFFAOYSA-N Cyclopropane Chemical compound C1CC1 LVZWSLJZHVFIQJ-UHFFFAOYSA-N 0.000 description 1
- 239000005891 Cyromazine Substances 0.000 description 1
- 239000005893 Diflubenzuron Substances 0.000 description 1
- 241000255582 Drosophilidae Species 0.000 description 1
- YUGWDVYLFSETPE-JLHYYAGUSA-N Empenthrin Chemical compound CC\C=C(/C)C(C#C)OC(=O)C1C(C=C(C)C)C1(C)C YUGWDVYLFSETPE-JLHYYAGUSA-N 0.000 description 1
- DNXHEGUUPJUMQT-CBZIJGRNSA-N Estrone Chemical compound OC1=CC=C2[C@H]3CC[C@](C)(C(CC4)=O)[C@@H]4[C@@H]3CCC2=C1 DNXHEGUUPJUMQT-CBZIJGRNSA-N 0.000 description 1
- 239000005912 Lufenuron Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920001131 Pulp (paper) Polymers 0.000 description 1
- ISRUGXGCCGIOQO-UHFFFAOYSA-N Rhoden Chemical compound CNC(=O)OC1=CC=CC=C1OC(C)C ISRUGXGCCGIOQO-UHFFFAOYSA-N 0.000 description 1
- 241001519528 Telenomus Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- OASZCUUPKKGVSG-UHFFFAOYSA-N [O].NC(O)=N Chemical compound [O].NC(O)=N OASZCUUPKKGVSG-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229930014345 anabasine Natural products 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 1
- 229940125904 compound 1 Drugs 0.000 description 1
- LVQDKIWDGQRHTE-UHFFFAOYSA-N cyromazine Chemical compound NC1=NC(N)=NC(NC2CC2)=N1 LVQDKIWDGQRHTE-UHFFFAOYSA-N 0.000 description 1
- 229950000775 cyromazine Drugs 0.000 description 1
- 229940019503 diflubenzuron Drugs 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- DIRFUJHNVNOBMY-UHFFFAOYSA-N fenobucarb Chemical compound CCC(C)C1=CC=CC=C1OC(=O)NC DIRFUJHNVNOBMY-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- RGNPBRKPHBKNKX-UHFFFAOYSA-N hexaflumuron Chemical compound C1=C(Cl)C(OC(F)(F)C(F)F)=C(Cl)C=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F RGNPBRKPHBKNKX-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229960000521 lufenuron Drugs 0.000 description 1
- PWPJGUXAGUPAHP-UHFFFAOYSA-N lufenuron Chemical compound C1=C(Cl)C(OC(F)(F)C(C(F)(F)F)F)=CC(Cl)=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F PWPJGUXAGUPAHP-UHFFFAOYSA-N 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- SMKRKQBMYOFFMU-UHFFFAOYSA-N prallethrin Chemical compound CC1(C)C(C=C(C)C)C1C(=O)OC1C(C)=C(CC#C)C(=O)C1 SMKRKQBMYOFFMU-UHFFFAOYSA-N 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides an electric heating sanitary perfumed slice, containing active ingredient, volatile agent and a carrier; wherein the active ingredient is pyrethroid compound the structure of which is shown as formula (1); the volatile agent is compounded by low grade fatty alcohol ester of acetyl citric acid and C4-C20 aliphatic dibasic ester; and each carrier contains 22-200mg of active ingredient and 50-1000mg of volatile agent. The electric heating sanitary perfumed slice of the invention can effectively prevent and kill off flying sanitary destructive insects such as flies for a long time.
Description
Technical field
The present invention relates to a kind of product of preventing and treating sanitary insect pest, be specifically related to a kind of electric heating health scented tea and application thereof.
Background technology
Electric mosquito repellent tablet is that an effective insecticidal constituent remains on the goods in cellulosic or the porous carrier, be often used in about 130 ~ 200 ℃ and heat sanitary insect pests such as preventing and kill off mosquitos and flies down, but in actual use, open wide or open environment, use electric mosquito repellent tablet very undesirable the fly type pests effect half.
At present on the Chinese market control fly type pests mainly also to be to use with cholrempenthrin be the fly eradication line spices of effective insecticidal constituent, have stronger penetrating odor but also exist, use the shortcoming of not enough safety and environmental protection.
Research through the inventor, the saturated binary fatty acid ester of finding lower aliphatic alcohol ester by preferred acetyl tributyl citrate and C4 ~ C20 is re-dubbed waves diffusing solvent, can promote the pyrethroid compound shown in the dissolution type (1), keep good fluidization property simultaneously, obtained the desinsection electricity sheet dropping liquid of high-load, the electric heating health scented tea that is mixed with thus demonstrates has 8 ~ 12 hours long preventing efficiencies to sex hygiene insects that circles in the air such as fly classes.
Summary of the invention
The purpose of this invention is to provide a kind of electric heating health scented tea, can prevent and treat the sex hygiene insects that circle in the air such as fly class effectively, enduringly.
Above-mentioned purpose of the present invention is achieved through the following technical solutions:
A kind of electric heating health scented tea is provided, contains active component, wave powder and carrier; Wherein, described active component is the pyrethroid compound (compound 1) of structure shown in the formula (1); Described composite the forming of saturated binary fatty acid ester of waving powder by the lower aliphatic alcohol ester and the C4 ~ C20 of acetyl tributyl citrate; Contain active component 22 ~ 200mg on the every carrier, contain and wave powder 50 ~ 1000 mg.
The weight ratio of the lower aliphatic alcohol ester of described acetyl tributyl citrate and the saturated binary fatty acid ester of C4 ~ C20 is preferably 2:8 ~ 8:2.
The mixture of one or more in the ternary ester that the preferred acetyl tributyl citrate of lower aliphatic alcohol ester of described acetyl tributyl citrate and the alcohol of C1 ~ C4 form.
The mixture of one or more in the preferred acetyl tributyl citrate trimethyl of the lower aliphatic alcohol ester of described acetyl tributyl citrate, ATEC, acetyl tributyl citrate three n-propyls, acetyl tributyl citrate three isopropyl esters, ATBC or acetyl tributyl citrate three isobutyl esters.
The mixture of one or more in the preferred diethyl succinate of saturated binary fatty acid ester, glutaric acid diisopropyl ester, Di-n-butyl Adipate, diisobutyl adipate, diisopropyl adipate, octyl sebacate or the dibutyl sebacate of described C4 ~ C20.
Described active component and the preferred 40 ~ 80:300 of weight ratio ~ 800 of waving powder.
Described compound (1) can be the raceme of structure compound as the formula (1), perhaps can be a kind of or mixture of its any stereoisomer.Described stereoisomer comprises because of the caused stereoisomer of asymmetric carbon atom on the cyclopropane.
The instantiation of compound (1) can comprise:
2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester;
2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester;
2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, trans-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester;
Or,
2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, cis-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester.
Above-mentioned particular compound all is a compound known, perhaps can prepare by known method.
Described carrier can be cellulosic carrier or porous carrier.
Described cellulosic carrier can be selected from native fiber such as paper pulp, cellulose, cotton, synthetic fibers such as polyester, acrylic compounds, inorfils such as glass fibre, asbestos etc.; Described porous carrier can be selected from porous matter resins such as porous matter magnetisable materials such as porous matter inorganic substances, biques such as diatomite or polyurethane foam, polypropylene foam etc.
Electric heating health scented tea of the present invention can also further contain other auxiliary agents.
Described auxiliary agent can be one or more the mixture in pigment, spices, antioxidant or the stabilizing agent.
Described pigment can be selected from 1,4-dibutylamino anthraquinone, 1,4-diisopropylaminoethyl anthraquinone, 1, and anthraquinones such as the adjacent toluidino anthraquinone of 4-two (2,6-diethyl-4-methylbenzene amino) anthraquinone or 1-methylamino-4-are blue pigment.These pigments both may be used alone, can also be two or more kinds in combination, or other pigments different with color mix use.
Described antioxidant can be selected from dibutyl hydroxy toluene, butylated hydroxyanisole (BHA), 2, phenolic antioxidants such as 2-methylene two (4-methyl-6-tert butyl phenol) or 2,6 di tert butyl 4 methyl phenol.
Described stabilizing agent can be selected from benzotriazole ultraviolet absorber or benzophenone ultraviolet absorber.
Electric heating health scented tea of the present invention can also further suitably contain other active insecticidal components or avoid and keep away active component etc., can expect further to improve its effectiveness thus.
Described other active insecticidal components can be selected from terallethrin (Terallethrin), Prallethrin pyrethroid compounds such as (Empenthrin), chlopyrifos organic phosphorus compounds such as (Chloropyrifos), unden (Propoxur), carbaryl (Carbaryl), metoxadiazone (Metoxadiazone); Osbac carbamate compounds such as (Fenobucarb); the fluorine third oxygen urea (Lufenuron); UC 62644 (Chlorfluazuron); fluorine bell urea (Hexaflumuron); TH-6040 (Diflubenzuron); the material that fly eradication amine (Cyromazine) etc. stop chitin to form; anabasine (neonicotinoido) compounds, or one or more the mixture in the N-Phenylpyrazole compounds.
Electric heating health scented tea of the present invention can be by described active component, wave powder and other auxiliary agents mixes the solution impregnation that obtains and prepares to carrier.
The common specification of electric heating health scented tea of the present invention is every wide 2.2cm; Long 3.5cm; Thick 0.15 ~ 0.4cm, but be not specially limited in this shape, and can suitably adjust the ratio of composition with the variation of scented tea shape.
In the present invention, the scented tea of per 1 2.2cm * 3.5cm * 0.15 ~ 0.4cm contains compound (1) 22 ~ 200mg usually, contains and waves powder 50 ~ 1000 mg, when needing, can further contain the pigment of 0.1-4mg, the stabilizing agent of 1-20mg and the spices of 1-20mg.
Electric heating health scented tea of the present invention can be heated to 130-200 ℃ by the ordinary electronic kill mosquito worm device of band heater and come prevent and kill off insect pests.
Described insect mainly is housefly (Musca domestica), telenomus (Muscaina stabulans), fruit bat Nuscidae insects such as (Drosophilidae), can hold concurrently anti-culex (Culex), yellow-fever mosquito (Aedes), anopheles Dulicidae Diptera pests such as (Anopheles).
Embodiment
Explain technical scheme of the present invention and effect in detail with the form of embodiment below, but the present invention is not limited to following examples.Below said umber be weight portion if no special instructions.
Embodiment 1
Take by weighing 26 part 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, 36 parts of ATBCs, 36 parts of diethyl succinates, 1 part of 1,4-dibutylamino anthraquinone, 1 part of 2,6 di tert butyl 4 methyl phenol mix and are mixed with electric sheet dropping liquid.
Get this dropping liquid of 100mg and be impregnated in the cellulosic carrier that constitutes by the pulp material of 2.2cm * 3.5cm * 0.28cm and velveteen, obtain electric heating health scented tea 1 of the present invention, contain effective composition 26mg, wave powder 72mg.
Get this dropping liquid of 150mg and be impregnated in the porous carrier that is made of the diatomite of 2.2cm * 3.5cm * 0.28cm, obtain electric heating health scented tea 2 of the present invention, active ingredient 39mg waves powder 108mg.
Get this dropping liquid of 200mg and be impregnated in the cellulosic carrier that is made of the pulp material of 2.2cm * 3.5cm * 0.30cm and velveteen, obtain electric heating health scented tea 3 of the present invention, active ingredient 52mg waves powder 144mg.
Embodiment 2
Take by weighing 14.8 part 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, trans-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, 50 parts of ATECs, 35 parts of diisopropyl adipates, 0.2 part of 1,4-dibutylamino anthraquinone mix and are mixed with electric sheet dropping liquid.
Get this dropping liquid of 300mg and be impregnated in the cellulosic carrier that constitutes by the pulp material of 2.2cm * 3.5cm * 0.28cm and velveteen, obtain electric heating health scented tea 4 of the present invention.
Get this dropping liquid of 400mg and be impregnated in the cellulosic carrier that constitutes by the pulp material of 2.2cm * 3.5cm * 0.28cm and velveteen, obtain electric heating health scented tea 5 of the present invention.
Get this dropping liquid of 400mg and be impregnated in the porous carrier that constitutes by the polyurethane foam of 2.2cm * 3.5cm * 0.28cm, obtain electric heating health scented tea 6 of the present invention.
Embodiment 3
Take by weighing 14.8 part 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, cis-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, 50 parts of ATECs, 35 parts of diisopropyl adipates, 0.2 part of 1,4-dibutylamino anthraquinone mix and are mixed with electric sheet dropping liquid.
Get this dropping liquid of 300mg and be impregnated in the cellulosic carrier that constitutes by the pulp material of 2.2cm * 3.5cm * 0.28cm and velveteen, obtain electric heating health scented tea 7 of the present invention.
Get this dropping liquid of 400mg and be impregnated in the cellulosic carrier that constitutes by the pulp material of 2.2cm * 3.5cm * 0.28cm and velveteen, obtain electric heating health scented tea 8 of the present invention.
Get this dropping liquid of 400mg and be impregnated in the porous carrier that constitutes by the polyurethane foam of 2.2cm * 3.5cm * 0.28cm, obtain electric heating health scented tea 9 of the present invention.
Embodiment 4
Take by weighing 20 part 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, trans-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, 20 parts of acetyl tributyl citrate three isobutyl esters, 60 parts of diisobutyl adipates mix and are mixed with electric sheet dropping liquid.
Get this dropping liquid of 300mg and be impregnated in the cellulosic carrier that constitutes by the pulp material of 2.2cm * 3.5cm * 0.28cm and velveteen, obtain electric heating health scented tea 10 of the present invention.
Get this dropping liquid of 300mg and be impregnated in the cellulosic carrier that is made of the pulp material of 2.2cm * 3.5cm * 0.28cm and velveteen, drip 0.2mg blue dyes 1 again, 4-diisopropylaminoethyl anthraquinone obtains electric heating health scented tea 11 of the present invention.
Get this dropping liquid of 400mg and be impregnated in the porous carrier that constitutes by the polyurethane foam of 2.2cm * 3.5cm * 0.28cm, obtain electric heating health scented tea 12 of the present invention.
Embodiment 5
Take by weighing 30 part 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, trans-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, 40 parts of acetyl tributyl citrate three isobutyl esters, 30 parts of diisobutyl adipates mix and are mixed with electric sheet dropping liquid.
Get this dropping liquid of 200mg and be impregnated in the cellulosic carrier that constitutes by the pulp material of 2.2cm * 3.5cm * 0.28cm and velveteen, obtain electric heating health scented tea 13 of the present invention.
Get this dropping liquid of 300mg and be impregnated in the cellulosic carrier that constitutes by the pulp material of 2.2cm * 3.5cm * 0.28cm and velveteen, obtain electric heating health scented tea 14 of the present invention.
Get this dropping liquid of 500mg and be impregnated in the cellulosic carrier that constitutes by the pulp material of 2.2cm * 3.5cm * 0.28cm and velveteen, obtain electric heating health scented tea 15 of the present invention.
Embodiment 6
Take by weighing 12 part 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, trans-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, 60 parts of acetyl tributyl citrate trimethyls, 28 parts of diisobutyl adipates mix and are mixed with electric sheet dropping liquid.
Get this dropping liquid of 1000mg and be impregnated in the cellulosic carrier that constitutes by the pulp material of 2.2cm * 3.5cm * 0.40cm and velveteen, obtain electric heating health scented tea 16 of the present invention.
Get this dropping liquid of 1000mg and be impregnated in the cellulosic carrier that constitutes by the glass fibre of 2.2cm * 3.5cm * 0.40cm, obtain electric heating health scented tea 17 of the present invention.
Embodiment 7
Take by weighing 20 part 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, cis-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, 20 parts of acetyl tributyl citrate three isobutyl esters, 60 parts of diisobutyl adipates mix and are mixed with electric sheet dropping liquid.
Get this dropping liquid of 300mg and be impregnated in the cellulosic carrier that constitutes by the pulp material of 2.2cm * 3.5cm * 0.28cm and velveteen, obtain electric heating health scented tea 18 of the present invention.
Get this dropping liquid of 300mg and be impregnated in the cellulosic carrier that constitutes by the pulp material of 2.2cm * 3.5cm * 0.28cm and velveteen, drip 2mg antioxidant 2,6 di tert butyl 4 methyl phenol again, obtain electric heating health scented tea 19 of the present invention.
Embodiment 8
Take by weighing 25 part 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester, 30 parts of acetyl tributyl citrate three isobutyl esters, 22.5 parts of diisobutyl adipates, 22.5 parts of diisopropyl adipates mix and are mixed with electric sheet dropping liquid.
Get this dropping liquid of 250mg and be impregnated in the cellulosic carrier that constitutes by the pulp material of 2.2cm * 3.5cm * 0.28cm and velveteen, obtain electric heating health scented tea 20 of the present invention.
Test case 1
With electric heating health scented tea 5,6,8,9,10,11 of the present invention and 20 and at present commercially available the most frequently used 0.8% cholrempenthrin fly perfume (or spice) (contrast fragrant 1) carry out evaluation of pesticide effectiveness contrast with reference to the standard of GBT 13917.10-2009 to housefly, adopt 28m
3Simulation room device.Detailed process is as follows.With each electric heating scented tea sample energising preheating 1h, 2h, 4h, 8h, 12h draws 100 boss flies, in the simulation room, accurate smoked kill 60min, housefly of per 10 minutes records is knocked down number, finally knocks down 50% examination worm (KT according to result's statistics
50) required time, the results are shown in table 1:
Table 1.
By the result of table 1 as seen, electric heating health scented tea of the present invention can be in a long time with good effect control fly class sanitary insect pest, and being better than the leading fly eradication product in existing market in effect---in the 0.8% cholrempenthrin fly perfume (or spice), the consumption of active compound component significantly is lower than 0.8% cholrempenthrin fly perfume (or spice).
Claims (10)
1. an electric heating health scented tea contains active component, waves powder and carrier; It is characterized in that: described active component is the pyrethroid compound of structure shown in the formula (1); Described composite the forming of saturated binary fatty acid ester of waving powder by the lower aliphatic alcohol ester and the C4 ~ C20 of acetyl tributyl citrate; Contain active component 22 ~ 200mg on the every carrier, contain and wave powder 50 ~ 1000 mg
2. the described electric heating health of claim 1 scented tea, it is characterized in that: the weight ratio of the lower aliphatic alcohol ester of described acetyl tributyl citrate and the saturated binary fatty acid ester of C4 ~ C20 is 2:8 ~ 8:2.
3. the described electric heating health of claim 1 scented tea is characterized in that: the lower aliphatic alcohol ester of described acetyl tributyl citrate is one or more the mixture in the ternary ester that forms of the alcohol of acetyl tributyl citrate and C1 ~ C4.
4. the described electric heating health of claim 1 scented tea is characterized in that: the lower aliphatic alcohol ester of described acetyl tributyl citrate is selected from one or more the mixture in acetyl tributyl citrate trimethyl, ATEC, acetyl tributyl citrate three n-propyls, acetyl tributyl citrate three isopropyl esters, ATBC or acetyl tributyl citrate three isobutyl esters.
5. the described electric heating health of claim 1 scented tea is characterized in that: the saturated binary fatty acid ester of described C4 ~ C20 is selected from one or more the mixture in diethyl succinate, glutaric acid diisopropyl ester, Di-n-butyl Adipate, diisobutyl adipate, diisopropyl adipate, octyl sebacate or the dibutyl sebacate.
6. the described electric heating health of claim 1 scented tea, it is characterized in that: described active component is 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester; 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, trans-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester or 2,3,5,6-tetrafluoro-4-methoxyl methyl benzyl-1R, cis-3-(2, the 2-dichloroethylene)-2,2-dimethyl cyclopropane carboxylic acid ester.
7. the described electric heating health of claim 1 scented tea, it is characterized in that: described carrier is cellulosic carrier or porous carrier.
8. the described electric heating health of claim 1 scented tea, it is characterized in that: described electric heating health scented tea also further contains other auxiliary agents; Described auxiliary agent is one or more the mixture in pigment, spices, antioxidant or the stabilizing agent.
9. the described electric heating health of claim 8 scented tea, it is characterized in that: described pigment is selected from 1,4-dibutylamino anthraquinone, 1,4-diisopropylaminoethyl anthraquinone, 1, the anthraquinone of the adjacent toluidino anthraquinone of 4-two (2,6-diethyl-4-methylbenzene amino) anthraquinone or 1-methylamino-4-is one or more the mixture in the blue pigment; Described antioxidant is selected from dibutyl hydroxy toluene, butylated hydroxyanisole (BHA), 2,2-methylene two (4-methyl-6-tert butyl phenol) or 2,6 di tert butyl 4 methyl phenol; Described stabilizing agent is selected from benzotriazole ultraviolet absorber or benzophenone.
10. the application of the described electric heating health of claim 1 scented tea is characterized in that: described electric heating health scented tea is heated to 130-200 ℃ prevents and treats diptera Nuscidae insect.
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| CN103168791A (en) * | 2011-12-26 | 2013-06-26 | 江苏扬农化工股份有限公司 | Meperfluthrin-containing compound insecticidal composition and application thereof |
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