CN101942954A - Negative pressure type hollow glass capable of monitoring, regulating and restoring pressure value in cavity - Google Patents
Negative pressure type hollow glass capable of monitoring, regulating and restoring pressure value in cavity Download PDFInfo
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- CN101942954A CN101942954A CN2009101572454A CN200910157245A CN101942954A CN 101942954 A CN101942954 A CN 101942954A CN 2009101572454 A CN2009101572454 A CN 2009101572454A CN 200910157245 A CN200910157245 A CN 200910157245A CN 101942954 A CN101942954 A CN 101942954A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/24—Structural elements or technologies for improving thermal insulation
- Y02A30/249—Glazing, e.g. vacuum glazing
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B80/00—Architectural or constructional elements improving the thermal performance of buildings
- Y02B80/22—Glazing, e.g. vaccum glazing
Abstract
The invention relates to negative pressure type hollow glass capable of monitoring, regulating and restoring the pressure value in a cavity, two glass sheets are stacked and combined into a basic component, then the hollow glass with higher isolation performance is formed by combination, support bodies are uniformly distributed and arranged between the adjacent two glass sheets, a pressure monitoring coating belt is arranged between the two glass sheets, a bleeder valve is arranged on the glass sheet on one side, and the edges of the adjacent glass sheets are compounded to a structural semi-rigid sealing and blocking system by adopting a compound material through a sealing valve for joint coupling the upper part with the lower part and a coupling agent. The negative pressure type hollow glass can solve the problems that the existing vacuum glass and the negative pressure type hollow glass can not detect the vacuum degree and the negative pressure status in the glass cavity at random, the vacuum glass produces the stress concentration phenomenon during the manufacturing process, the concentrated stress can not be eliminated, the cost is too high, the quality is unstable and uncontrollable and the like, further greatly improve the service life and the quality of a product and realize the purpose of keeping the high efficiency and the energy conservation of the product for a long time.
Description
Technical field
The present invention relates to a kind of hollow glass structure, particularly relate to a kind of suction type hollow glass of monitoring and regulating the thermal insulation sound insulation of repairing cavity internal pressure value.
Background technology
At present, by vast scientific and technical personnel's further investigation, various solutions and method have all been proposed for the method for making vacuum or hollow glass.Its key technology mainly concentrates on the problem with the preparation method method of putting of the supporter that relates between the glassy layer.And (continue to keep the vacuum of vacuum glass) aspect the isolation performance that how to keep vacuum or hollow glass relating to, improve the sealing performance aspect of hollow glass, and how to monitor the situation of change of the pressure in the hollow glass internal cavities and problems such as negative pressure value how to recover inner chamber, because the genetic prerequisites such as the close performance of matter of glass self determine, any vacuum tank (as thermos flask used in everyday) can not keep the negative pressure performance of vacuum for a long time because of the constraint of aspects such as material and process manufacturing technology and cost, thereby the sealing isolation performance of product is descended, lost efficacy until its isolation performance, and the isolation performance of goods such as door and window for building and curtain wall and sunlight room often requires to need the property retention phase of quite growing (more than the 10-80), innovation and creation that relate to this type of technology that such performance requirement is present and invention technology, all still do not propose basic solution, remain to continue further investigation in the functional configuration and the manufacture method of thermal insulation sound insulation combination glass.
Summary of the invention
For remedying above-mentioned defective, the purpose of this invention is to provide a kind of new thermal insulation sound insulation and can monitor the suction type hollow glass that adjustable trimming makes sustainable its isolation performance of maintenance again, a kind of suction type hollow glass of monitoring and regulating reparation cavity internal pressure value of the present invention has long-term isolation performance hold facility and better semi-rigid construction sealing performance, thereby and reach long-acting effects of energy conservation and environmental protection, improve product application life, realized the saving of resource.
The present invention is a kind of, and to monitor and regulate the technical scheme of the suction type hollow glass of repairing cavity internal pressure value as follows: a kind ofly monitor and regulate the suction type hollow glass of repairing cavity internal pressure value, stack by two layers of glass plate and to be combined as elementary cell, with described elementary cell is that the higher combination hollow glass of isolation performance is carried out being combined into more than one group or two groups in the basis, between adjacent sheets of glass, be provided with that equally distributed weather resistant with certain elastic characteristic is printed or the supporter of making by rigid material of sinter molding, on external surface one side glass plate, has the several sealed aspirating hole, by sealant adhesion seal valve, described by the bonding seal valve of sealant, by upper-lower seal idol part, sealed valve core seals even part with being arranged on, lower seal idol part, sealing ring between the sealed valve core is formed, edge in adjacent sheets of glass, also have the edge voids filled up and coat the metallic composite structure sealing system of the negative-pressure type glass edge made of metallic composite of two combination glass edges, realize the effect of semi-rigid edge sealing, and the work in-process of invention before having solved and invention vacuum glass and use in concentrate the phenomenon that bursts that causes because of variations in temperature produces stress, the invention can be avoided in processing by the metallic composite structure sealing system of the negative-pressure type glass edge that adopts metallic composite and make and the generation of stress concentration phenomenon in using in real time.
When the present invention can monitor and regulate the suction type hollow glass practical application of repairing the chamber pressure value, the banded coating bar of making at each bight coating useful pressure developer of closed inner chamber of two sheet glass combinations of isometric L type is realized the display performance of force value, when in use as the banded coating bar of isometric L type that closed inner chamber pressure changes this coating pressure developer takes place to illustrate closed inner chamber to have extraneous gas to infiltrate by change in color, along with the change color of pressure developer illustrates the pressure in the closed inner chamber to increase and the reduction degree, then prompting need be adjusted recovery with force value to closed inner chamber pressure.
When the present invention can monitor and regulate the suction type hollow glass practical application of repairing the chamber pressure value, when the change value of pressure of closed inner chamber arrives the isolation performance minimum, can the force value of closed inner chamber be returned to the qualified level of isolation performance by the opening encapsulation spool and by the special gas draw-out device.
When the present invention can monitor and regulate the suction type hollow glass glass practical application of repairing the chamber pressure value, can be by two sheet glass for being combined into elementary cell, carry out based on this two layers or more than be combined into the higher suction type hollow glass of isolation performance, print around the upper glass edge or depression that sintering curing adheres to and projection and having to print the depression of adhering to and projection around frame up and down, the sealing four directions glass edge of certain width and the sealing four directions frame of certain width is arranged be that mutual chimeric mode makes up mutually, both printed on the glass combination bonding surface up and down or the square of sintering curing projection, trapezoidal, mutual chimeric, both concavo-convex chimeric of semicircle or special-shaped closed frame.
A kind of suction type hollow glass of monitoring and regulating reparation cavity internal pressure value of the present invention, wherein said supporter is that matrix form distributes.
The present invention is a kind of to monitor and regulates the suction type hollow glass of repairing cavity internal pressure value, and wherein said supporter is printed by weather resistant and weather resistant with certain elastic characteristic (can realize elastic characteristic by deformable structure) or the supporter of being made by rigid material of sinter molding.
The present invention is a kind of to monitor and regulates the suction type hollow glass of repairing cavity internal pressure value, and wherein said supporter is hemispherical, cylindrical, annulated column shape or polygon cylindricality etc.
A kind of suction type hollow glass of monitoring and regulating reparation cavity internal pressure value of the present invention, wherein the supporter between the glass plate adopts the form of structure with certain elastic performance and location printing or sintering curing mode, two glass sheets are in use because temperature changes the variation of the clearance space that phenomenon produced that expands with heat and contract with cold that causes repeatedly about enabling to resist and regulate, to keep the interval support function of glass plate, alleviate the repeatedly active force of thermal stresses, improve the effective performance of edge sealing glass plate edge sealing place.Adopt the replaceable seal valve of (or more than) simultaneously from close formula structure, the gas that constantly permeates by glass plate can regularly can be extracted, can repeat to take out the gas that infiltrates closed inner chamber, gas extract device in can the various removable portable on-the-spot glass of supporting use, to solve in use because the negative pressure value between the glass plate that a variety of causes causes descends this inevitable problem that occurs.Use printing curing or sintering curing to constitute the seal construction that dense material is formed the mosaic structure at glass plate edge at last, its external margin is used metal and rubber-like encapsulant again, gas molecule had the adhesive tape that the bonding adhesive of high blocking ability is made, carry out the seal construction of secondary packaging type for metal and rubber-like encapsulant single face composite compact material, again by the C type of metal and macromolecular material compound extrusion forming or the semi-rigid composite material of approximate shapes, with build-in sealing around the negative-pressure type hollow glass edge, form many places malleation and the miniature balance chamber of negative pressure, play the effect that intercepts the gas infiltration, the seal failure phenomenon that the phenomenon of expanding with heat and contract with cold that can reduce or avoid temperature because of long-term natural environment to change caused material self repeatedly causes, thereby improved the sealing performance of glass edge greatly, made the edge sealing performance of glass be higher than the anti-gas osmosising performance of the material of glass own.Comprehensive, the rigid material that the present invention is a kind of to monitor and regulated the suction type hollow glass of repairing cavity internal pressure value owing to adopted and have certain elasticity (or realize elastic characteristic by deformable structure) is made the braced structures system to keep the support effect when the vacuum degree between seal glass changes, the edge seal construction of impermeabilisation, to keep sealing performance to greatest extent, each bight is coated with the banded coating bar of isometric L type and shows what the negative pressure value of closed inner chamber changed by the pressure developer, has the variation that to monitor the closed inner chamber negative pressure value and by having the sealing extraction valve that can repeat gas bleeding, having solved present vacuum glass and hollow glass exists and can not monitor and can not repair the present situation that can't keep isolation performances such as its thermal insulation sound insulation for a long time, solved building doors and windows, the lasting maintenance problem of the thermal insulation sound insulation value of the long timeliness of building such as curtain wall and sunlight room, the application life and the quality of product have been improved greatly, reduce upright product at no damage state based replacing number of times, saved a large amount of energy and resource.
Description of drawings
Fig. 1 monitors and regulates the front view of a certain unit of a kind of embodiment of suction type hollow glass of repairing cavity internal pressure value for the present invention is a kind of;
Fig. 2 shows the vertical view of L shaped coating bar, edge configuration sealing system for supporter, seal valve, pressure among Fig. 1;
Fig. 3 is the generalized section of Fig. 1 seal valve in I-shaped boring on glass;
Fig. 4 monitors and regulates the enlarged diagram of the suction type hollow glass seal valve of repairing cavity internal pressure value for the present invention is a kind of;
Fig. 5 monitors and regulates the suction type hollow glass pressure of repairing cavity internal pressure value and shows the enlarged diagram that L shaped coating is overlooked for the present invention is a kind of
Fig. 6 is to be the generalized section of metal and rubber-like encapsulant single face composite compact clad material in Fig. 1 edge seal system;
The metal of the metal of the sealing usefulness that Fig. 7 coats at home and abroad for edge seal system and C shape that macromolecular material is composited or approximate shapes and the composite material generalized section of macromolecular material.
Fig. 8 is the generalized section of the peripheral multiple-sealed structure mutual alignment relation of edge seal system.
The specific embodiment
For further specifying the present invention, specifically set forth with the following Examples:
Embodiment 1;
The present invention is a kind of to monitor and regulates the suction type hollow glass of repairing cavity internal pressure value, can be according to following processing step production:
1) with reference to figure 1, at first two (or more than) glass plates 1 are bored (or more than) two-way glass orifice 3, cleaning, the drying that step is arranged on the glass sheets therein by the cutting of specific product dimensional requirement, boring, this glass sheets is called closes sheet, closes sheet under another sheet is called;
2) with reference to figure 2, under close on the sheet to distribute with matrix form and paste several supporters 2 according to the uniform principle of stress distribution, supporter 2 is made by the rigid material of the certain elastic characteristic of having of weather resistant (or by deformable structure realization elastic characteristic), as forming with one deck steel disc one deck rubber multilayer stack combinations, can be hemispherical, annulated column shape or polygon cylindricality, this example is polygon cylindricality, as shown in Figure 2, technological requirement support 2 fixedly secures and is closing up and down on the inner chamber table plane of sealing on the glass sheets;
3) with reference to figure 1, have and print or the structure band 5 of the double-coated sealant of sintering curing mosaic sealing is solidificated in the zone, edge of glass plate closing the glass sheets edge up and down, the shape of structure band 61 conforms to the space between glass edge, can be according to the variation of concrete suction type hollow glass product size, the section of the structure band 61 in this example is lenticular structure, it is chimeric mutually when two sheet glass close sheet to close the lenticular structure of sheet up and down, as shown in Figure 1, structure band 61 is printed by nonmetals and is solidified or the sintering curing moulding;
4) with reference to figure 1, the upper-lower seal of seal valve idol part is fixed on the form that is spirally connected to be had I-shaped drill hole in the combination glass and is sealed;
5) with reference to figure 1, with on close sheet and make up the adjacent edge chamfer place of glass with closing down the sheet combination and stick to the encapsulant of high obstructing performance, it is filled and led up sealing;
6) coated with reference to the low rigidity band symmetry of the figure 1 usefulness coupling agent flexibility that metal and macromolecular material is compound at the stile edge that closes sheet glass up and down, and the coating scope close up and down on the sheet glass around the lower plane more than or equal to 3 to 4 times to used thickness of glass size range, and be the closed-loop structure that forms sealing;
7) with reference to the figure 1 extension form that to be wrapped in its section profile of closed profiles frame of the metal with certain rigidity of combination glass edge and macromolecular material composite molding be C type or approximate form of fracture;
8) with reference to figure 1, have by the sealant adhesion and can repeat to take out the seal valve 4 of body function of degassing, even part 41 is with following even part 42 and with its sealing that is spirally connected on elder generation's arrangement sealed valve body, using the on-the-spot gas that will make up in the glass cavity to extract by the negative pressure ventilation device or with moving portable air extractor, under negative pressure, removable sealed core 43 put into simultaneously the closed hole fit sealing that is spirally connected, cover seal cover 45 at last and make secondary seal, on the sealed valve body even part 41 and down even part 42 its each other and and the glass contact face between complete after some sealing rings 44 and adhesive material sealing are set.
The present invention compares with prior art has following progress;
1) strong point displacement that causes of the distortion that can guarantee to be produced when glass in use changes because of variations in temperature and internal negative pressure degree of the supporter 2 with elastic recovery capability is effectively controlled, and is beneficial to the maintenance of the negative pressure value of inner chamber;
2) adopt inner chamber that the chamber pressure display unit is set, solved present vacuum glass and negative-pressure type hollow glass and can't monitor the performance of the isolation performance of product intuitively and monitor blank in real time at the negative-pressure type hollow glass;
3) adopt the seal valve 4 to repeat to take out the body that degass to solve the problem that existing vacuum glass and hollow glass cause the decline of negative pressure value to cause the isolation performance of vacuum glass or negative-pressure type hollow glass to reduce or lost efficacy because of the reason of gas infiltration, and can guarantee the maintenance of the long-term isolation performance of product, favourable economizing on resources;
The edge of negative-pressure type hollow glass is to adopt multiple tracks structural formula sealing means to be combined into sealing system to realize reliable sealing system, thereby improve the sealing performance of product greatly, than the low-melting glass welding manner of vacuum glass eliminated because of the glass under hot environment welding be the problem that the thermal stresses that produces can't be eliminated;
4) solved the form that the normal pressure hollow glass only relies on macromolecular material to seal, and its hermetic barrier performance when negative pressure value surpasses certain negative two atmospheric pressure that produces can not realize blocking the order ground of gas molecule infiltration, the steady quality of more effective assurance product and unfailing performance with regard to degradation failure.
Above-described embodiment is described preferred implementation of the present invention; be not that scope of the present invention is limited; design under the prerequisite of spirit not breaking away from the present invention; various distortion and improvement that the common engineers and technicians in this area make technical scheme of the present invention all should fall in the definite protection domain of claims of the present invention.
Claims (10)
1. can monitor and regulate the suction type hollow glass of repairing cavity internal pressure value for one kind, its special Zheng is: stacked by two layers of glass plate (1) and be combined as basic module, with described basic module unit is that the higher combination suction type hollow glass of isolation performance is carried out being combined into more than one group or two groups in the basis, between adjacent sheets of glass, be provided with that the weather resistant with certain elastic deformation characteristic of evenly arranging according to matrix-style according to the principle of bearing capacity uniform distribution is printed or the rigid support (2) of sinter molding, on the glass plate of the outside, boring (3) and the sealing of disposing the I-shaped or approximate shapes of or above several cylinders shape or the circle terraced steps seal valve that even part is formed of bleeding, by the bonding seal valve of sealant, described seal valve (4) is by the even part of last sealing (41), lower seal idol part (42), sealed valve core (43) and be arranged on the sealing even part (41), lower seal idol part (42), sealing ring (44) between the sealed valve core (43), the even part lid of last sealing (45) is formed; Around the inboard of last or lower-glass combination interlayer cavity edge structure sealing system (61), apply certain-length and width and can show the L type coating bar (5) that sealing back cavity internal pressure changes, adopt at the edge of two glass basic modules that stack up and down that to have metal material and macromolecular material be that the compound semi-rigid hermetic barrier of the structural formula system (6) that becomes of coupling agent is by printing the depression of adhering to and projection and have on the sealing four directions frame of certain width (61) around the upper glass edge, by printing the depression of adhering to and projection around the chimeric lower-glass edge of correspondence dislocation and the sealing four directions frame (62) of certain width being arranged, stick at the triangle zone of the edging chamfering at glass edge near side (ns) place up and down and to have the die fluid sealant bonding adhesive abnormity band (63) of body molecule performance of high resistant, be coated in two sheet glass stile all around and all and up and down expose the coupling agent (64) that the plane has certain width, stick on up and down stile around the glass of two or above multi-disc and all and up and down expose the adhesive tape (65) that metal that the plane has certain width and thickness and the high blocking-up type bonding adhesive of rubber-like sealing gas molecule are made, be wrapped in the metal with certain rigidity of combination glass edge and the closed profiles frame (66) of macromolecular material composite molding.
2. according to (3) in the claim 1 described a kind of suction type hollow glass of repairing cavity internal pressure value of monitoring and regulate, it is characterized in that: the cylindrical or I-shaped boring of circle terraced steps.
3. a kind of suction type hollow glass of repairing cavity internal pressure value of monitoring and regulate according to claim 4 is characterized in that described supporter (2) prints curing moldings such as available light and sintering by the rigid material of weather resistant.
4. according to (2) in the claim 1 described a kind of suction type hollow glass of repairing cavity internal pressure value of monitoring and regulate, it is characterized in that: described supporter (2) is hemispherical, cylindrical, annulated column shape, trapezoidal or polygon cylindricality etc.
5. according to (5) in the claim 1 described a kind of suction type hollow glass of repairing cavity internal pressure value of monitoring and regulate, it is characterized in that: the coating bar (5) that can show the cavity internal pressure variation of sealing back that has certain-length and width when corner's coating around the inboard of last or lower-glass combination interlayer cavity edge structure sealing system (61), both on combination glass inner chamber or on the lower-glass inner surface, the edge seals corner in the concavo-convex coating sealing frame, applies equilateral L type pressure and changes show bar (5).
6. according to the described a kind of suction type hollow glass of repairing cavity internal pressure value of monitoring and regulate in (61) in the claim 1 and (62), it is characterized in that: print the depression of adhering to and projection around the upper glass edge and have print around (61) and lower-glass edge on the sealing four directions frame of certain width or depression that sinter molding is adhered to projection and there is the sealing four directions frame (62) of certain width to make up mutually in mutual chimeric mode, both printed on the glass combination bonding surface up and down or the square of the projection of sinter molding, semicircle or abnormity or have mutual chimeric, both concavo-convex chimeric of the closed frame of dentelation.
7. according to (63) in the claim 1 described a kind of compound semi-rigid hermetic barrier of structural formula system that becomes of suction type hollow glass of repairing cavity internal pressure value that monitors and regulate, it is characterized in that: stick at the triangle zone of the edging chamfering at glass edge near side (ns) place up and down and have die fluid sealant bonding adhesive abnormity band (63) sealing of body molecule performance of high resistant.
8. according to (64) in the claim 1 described a kind of compound semi-rigid hermetic barrier of structural formula system that becomes of suction type hollow glass of repairing cavity internal pressure value that monitors and regulate, it is characterized in that: coated around two sheet glass stile after the combination all and up and down expose the plane greater than 3 to 4 times to used thickness of glass size range width, towards can the be coupled coupling agent of metal material and glass material of having of center of glass direction.
9. according to (65) in the claim 1 described a kind of suction type hollow glass of repairing cavity internal pressure value of monitoring and regulate, it is characterized in that: the adhesive tape that the high blocking-up type bonding adhesive of metal and rubber-like gas molecule is made is that metal and rubber type of material single face are compound, the metal exposed face will with the coating coupling agent the glass outer surface close-coupled.
10. according to (66) in the claim 1 described a kind of suction type hollow glass of repairing cavity internal pressure value of monitoring and regulate, it is characterized in that: being wrapped in the metal with certain rigidity of combination glass edge and its section profile of closed profiles frame of macromolecular material composite molding is the extension form of C type or approximate above-mentioned form of fracture.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2009101572454A CN101942954A (en) | 2009-07-03 | 2009-07-03 | Negative pressure type hollow glass capable of monitoring, regulating and restoring pressure value in cavity |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2009101572454A CN101942954A (en) | 2009-07-03 | 2009-07-03 | Negative pressure type hollow glass capable of monitoring, regulating and restoring pressure value in cavity |
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| CN101942954A true CN101942954A (en) | 2011-01-12 |
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| CN2009101572454A Pending CN101942954A (en) | 2009-07-03 | 2009-07-03 | Negative pressure type hollow glass capable of monitoring, regulating and restoring pressure value in cavity |
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Cited By (20)
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| CN103015863A (en) * | 2012-12-19 | 2013-04-03 | 新乡职业技术学院 | Molecular sieve division bar with baffles for manufacturing hollow glass |
| CN104986968A (en) * | 2015-07-15 | 2015-10-21 | 平凉市老兵科技研发有限公司 | Vacuum glass |
| CN106285341A (en) * | 2016-11-14 | 2017-01-04 | 朱小菊 | Vacuum sound insulation glass |
| CN106285340A (en) * | 2016-11-14 | 2017-01-04 | 仲炳华 | Electrical cycle sound control glass |
| CN109665725A (en) * | 2018-11-29 | 2019-04-23 | 中国科学院微电子研究所 | A kind of vacuum glass that examining vacuum degree and system |
| WO2020118667A1 (en) * | 2018-12-11 | 2020-06-18 | 淄博环能海臣环保技术服务有限公司 | Vacuum-regulated thermal insulation glass plate provided with roller-press support double-adhesive sealed glass spacer cavity |
| WO2020118675A1 (en) * | 2018-12-11 | 2020-06-18 | 淄博环能海臣环保技术服务有限公司 | Adjustable vacuum heat insulating glass having protective frame, rolled support frame and metal brazed sandwich |
| WO2020118678A1 (en) * | 2018-12-11 | 2020-06-18 | 淄博环能海臣环保技术服务有限公司 | Insulating glass panels regulated by vacuum in cavity between spaced glass and sealed by two sealants |
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Cited By (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
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| CN104986968A (en) * | 2015-07-15 | 2015-10-21 | 平凉市老兵科技研发有限公司 | Vacuum glass |
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