CN101942145A - Packaging adhesive film composition and application thereof - Google Patents
Packaging adhesive film composition and application thereof Download PDFInfo
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- CN101942145A CN101942145A CN2010102797265A CN201010279726A CN101942145A CN 101942145 A CN101942145 A CN 101942145A CN 2010102797265 A CN2010102797265 A CN 2010102797265A CN 201010279726 A CN201010279726 A CN 201010279726A CN 101942145 A CN101942145 A CN 101942145A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B10/00—Integration of renewable energy sources in buildings
- Y02B10/10—Photovoltaic [PV]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Abstract
The invention relates to a packaging adhesive film composition and application thereof. The composition mainly comprises the following components in parts by mass: 65-95 parts of ethylene-vinyl acetate copolymer, 2-20 parts of ethylene-octylene copolymer, 2-15 parts of medium molecular weight polyisobutylene, 0.1-3 parts of cross-linking agent, 0.05-2 parts of ultraviolet stabilizer and 0.05-2 parts of hindered amine antioxidant. The composition has the advantages of excellent aging resistance, high bonding strength with glass, high impact resistance modulus and easy processing, and is suitable for packaging a double-layer glass solar battery pack of BIPV or double-layer glass of decorative buildings in the aspects of tear strength and impact resistance modulus.
Description
(1) technical field
The present invention relates to a kind of packaging adhesive film composition and application thereof, the said composition transmittance is good, anti-impact modulus height and strong with the glass adhesive, is applicable to packaged material in solar cell photovoltaic assembly, double glazing encapsulation photovoltaic module or the laminated glass in building and the integrated photovoltaic.
(2) background technology
The building itself that makes solar electrical energy generation-architecture-integral (BIPV) has played the effect of energy resource supply, and solar module directly embeds in the building integral as roof or photovoltaic curtain wall integral part in the tool electricity generate function.As the part of material of construction, solar module will be kept the aesthetic of building structure main body, so the solar module that uses among the BIPV need encapsulate with front and back double glazing and transparent macromolecular material.Require solar module must satisfy the safety performance requirement of material of construction simultaneously, promptly solar module itself possesses characteristics such as basic insulation, anti-impact.
At present, two glass photovoltaic module encapsulation are polyvinyl butyral acetal ester (PVB) and ethylene-vinyl acetate copolymer (EVA) with the main flow material.PVB is the most widely used and selected the earliest packaged material between double glazing that is, PVB possesses higher penetration-resistant and better back fracture property, in Highrise buildings by widespread use.But the shaping cycle of PVB is long and necessary low temperature transportation stores, and uses not only to cost an arm and a leg but also be not suitable for general photovoltaic module laminating method at batch and processes.EVA was little with the cohesive strength of glass when EVA was used for the crystal silicon battery assembly of double glazing encapsulation, and shock strength can not satisfy the structural strength requirement of material of construction, so generally can not be used for as the main building material.
Vinyl olefins analog copolymer composition involved in the present invention has had required processing convenient feature and the resistance to compression anti-impact requirement of mechanical property, satisfied two glass assemblies or the laminated glass encapsulation user demand of the two glass assemblies of BIPV concurrently.
(3) summary of the invention
The object of the invention provides a kind of packaging adhesive film composition, possess excellent anti-aging property, anti-impact modulus height, easily processing and good, encapsulate with double glazing at the two glass solar modules or the decorative architecture that all are applicable to BIPV aspect tearing toughness and the anti-impact modulus with glass cementation intensity.
The technical solution used in the present invention is:
A kind of packaging adhesive film composition, form by the component that the quality proportioning is following:
65～95 parts of ethylene-vinyl acetate copolymers
2～20 parts of ethylene-octene copolymers
2～15 parts of middle molecular weight polyisoprene iso-butylenes
0.1～3 part of peroxide cross-linking agent
0.05～2 part of uv-absorbing agent
0.05～2 part of suffocated amine antioxidant.
The effect of described peroxide cross-linking agent is to increase the glued membrane temperature tolerance during high temperature out of doors, can be one of following or wherein two or more mixing: tert-butyl hydroperoxide-2-ethylhexanoate, the peroxybenzoic acid tert-pentyl ester, 1,1-bis(t-butylperoxy)-3,5, the 5-trimethyl-cyclohexane, 2, two (tert-pentyl the peroxide)-butane of 2-, tert butyl peroxy benzoate, the hot capric acid of tert-butyl hydroperoxide, tert-butyl hydroperoxide-2-ethylhexanoate, tert-butyl hydroperoxide-3,5,5-tri-methyl hexanoic acid ester, tert-butyl hydroperoxide-sec.-propyl carbonic ether, tert-butyl hydroperoxide-2-ethylhexyl carbonic ether, adjacent, neighbour-tertiary butyl-neighbour-sec.-propyl-list-peroxycarbonates, adjacent, neighbour-tertiary butyl-neighbour-(2-ethylhexyl)-list-peroxycarbonates, the neighbour, neighbour-tert-pentyl-neighbour-(2-ethylhexyl)-list-peroxycarbonates, two (tert-butyl hydroperoxide sec.-propyl) benzene.
Described uv-absorbing agent effect is to make glued membrane have uvioresistant performance, can be one of following or wherein two or more mixing: 2, and 2 '-tetramethylene two (3,1-benzoxazine-4-ketone), 2,8-dimethyl-4H, the 6H-benzo (1,2-d; 5; 4-d ') two (1; 3)-oxazines-4; the 6-diketone; 2-hydroxyl-4-methoxyl group-2 '-carboxyl benzophenone; 2; 2 '-dihydroxyl-4; 4 '-dimethoxy-benzophenone; 2-hydroxyl-4-benzoyl oxygen base benzophenone; 2; 2 '; 4; 4 '-tetrahydroxybenzophenone; 2; 2 '-dihydroxyl-4; 4 '-dimethoxy-benzophenone; 2-hydroxyl-5-chlorobenzophenone; 2-(2 '-hydroxyl-5 '-tert-butyl-phenyl) benzotriazole; 2-(2 '-hydroxyl-5 '-aminophenyl) benzotriazole; double acid double phenol A ester; 2-(2-hydroxyl-3; the 5-di-tert-pentyl-phenyl) benzotriazole; 2; 2 '-(1; the 4-phenylene) two-4H-3,1-benzoxazine-4-ketone; 2-(2 '-hydroxyl-3 ', 5 '-3,5-dimethylphenyl) benzotriazole; 2-(2 '-methyl-4 '-hydroxy phenyl) benzotriazole; two-(2-methoxyl group-4-hydroxyl-5-benzoyl phenyl) methane; 2-(2 '-hydroxy-5-methyl base phenyl) benzotriazole; 2-(2 '-hydroxy-5-methyl base phenyl)-5-carboxylic acid butyl ester benzotriazole.
The effect of described suffocated amine antioxidant is the weathering resistance that increases glued membrane, can be one of following or wherein two or more mixing: 2-hydroxyl-4-alkoxy benzophenone, 3,5-di-t-butyl-4-hydroxy-benzoic acid cetyl ester, three (1,2,2,6,6-pentamethyl--4-piperidyl) phosphorous acid ester, sebacic acid two-2,2,6,6-tetramethyl piperidine alcohol ester, Succinic Acid and 4-hydroxyl-2,2,6, the polymkeric substance of 6-tetramethyl--1-piperidines alcohol, N, N '-two (2,2,6,6-tetramethyl--4-piperidyl)-1,6-hexanediamine and 2,4-two chloro-6-(1,1,3, the 3-tetramethyl butyl) polymkeric substance of amino-1,3,5-triazines, N, N '-two (2,2,6,6-tetramethyl--4-piperidyl)-1,6-hexanediamine and 2,4-two chloro-6-(4-morpholinyl)-1,3, the polymkeric substance of 5-triazine, N, N '-two (1,2,2,6,6-pentamethyl--4-piperidyl)-1,6-hexanediamine and morpholine-2,4, the polymkeric substance of 6-three chloro-1,3,5-triazines, two (1,2,2,6,6-pentamethyl--4-piperidyl) sebate/methyl isophthalic acid, 2,2,6,6-pentamethyl--4-piperidyl sebate compound, 2,6 di tert butyl 4 methyl phenol, poly-[[6-1,1,3,3,-four-methyl butyl) amino]-S-triazine-2, the 4-double-basis], [[(2,2,6,6-tetramethyl--4-piperidyl) imino-]], 1,3,5-three (the 4-tertiary butyl-3-hydroxyl-2,6-dimethyl benzene methyl)-1,3,5-triazine-2,4,6-(1H, 3H, 5H)-triketone/two (2, the 4-dicumylphenyl) pentaerythritol diphosphites compound.
The vinyl acetate molar content is 15%～33% in the described ethylene-vinyl acetate copolymer, and described ethylene-vinyl acetate copolymer fusing point is 35 ℃～100 ℃, melting index 7～55, number-average molecular weight 5000～180000.Described ethylene-vinyl acetate copolymer can obtain by pressurization mass polymerization, letex polymerization, interfacial polymerization mode, and for improving the processibility of composition, EVA particle of the present invention can be the mixture that two or more meet the EVA of above-mentioned requirements.
The octene molar content is 20%～40% in the described ethylene-octene copolymer, and described ethylene-octene copolymer mooney viscosity is 3～35.For promoting the shock strength of this packaging adhesive film composition, can under high temperature fused state, form graft product by ethylene-octene copolymer with the polarity micromolecular compound such as maleic anhydride, the glycidyl methacrylate etc. that possess active group, small molecules percentage of grafting 0.1%～5%, preferred 0.2%～1.5%.
Molecular weight polyisoprene iso-butylene in described, viscosity-average molecular weight is 30000～120000, and the Si Taoding grid index is 15～60, and has stronger bounding force between the glass, battery sheet, more than 100N/cm.
When the present composition is applied to prepare the EVA glued membrane, also can increase some other supplementary additives, as some silane coupling agents that increases adhesive property, the dyestuff that improves the color outward appearance increases the functionalization purposes to increase color by adding part mineral filler such as glass fibre, fire retardant material etc.
The invention still further relates to described packaging adhesive film composition and be used for encapsulating the application of the EVA glued membrane of solar module in preparation.Packaging adhesive film described in the present invention by ethylene-vinyl acetate copolymer, ethylene-octene copolymer, middle molecular weight polyisoprene iso-butylene together with other auxiliary agents through batch mixings, melt extrude, casting film-forming and splitting winding make.
The invention still further relates to described packaging adhesive film composition and be used for encapsulating the application of the EVA glued membrane of double glazing in preparation.
The beneficial effect of packaging adhesive film composition of the present invention is mainly reflected in: composition mainly is made up of ethylene-vinyl acetate copolymer, ethylene-octene copolymer, middle molecular weight polyisoprene iso-butylene and other anti-aging auxiliary agents.Said composition has excellent anti-aging property,, anti-impact modulus height good with glass cementation intensity and easily processing, in the encapsulation with double glazing of the double glazing solar module that all is applicable to BIPV aspect tearing toughness and the anti-impact modulus or decorative architecture.
(4) embodiment
The present invention is described further below in conjunction with specific embodiment, but protection scope of the present invention is not limited in this:
Embodiment 1:
In massfraction, 95 parts of VA (vinyl acetate between to for plastic) mass content is in 33% the ethylene-vinyl acetate copolymer (du pont company PV 1200), add 2 parts of mooney viscosities and be 31 ethylene-octene copolymer (POE of Exxon Mobil company 5061), add 2 parts in molecular weight polyisoprene iso-butylene (German BASF
B15SFN), 0.05 part of uv-absorbing agent 2-(2-hydroxyl-3,5-di-tert-pentyl-phenyl) benzotriazole (UV-328 of U.S. Ciba company), 0.05 part is subjected to the histamine kind antioxidant to gather [[6-1,1,3,3,-four-methyl butyl) amino]-S-triazine-2, the 4-double-basis], [[(2,2,6,6-tetramethyl--4-piperidyl) imino-]] CHIMASSORB 944 (U.S. Ciba company), 1.5 parts of peroxide cross-linking agent t-butyl peroxy neodecanoic acids (
And mix TAPD).
Mixture is carried out blend extrude in forcing machine, temperature is controlled at 90 ℃, extrudate through curtain coating, cool off, cut, coiling process, promptly get the packaging adhesive film that thickness is 0.5mm, be designated as S-1.
Embodiment 2:
In massfraction, 65 parts of VA content is in 15% the ethylene-vinyl acetate copolymer (Elvax of Mitsui E.I.Du Pont Company 250), add 20 parts of mooney viscosities and be 5.0 ethylene-octene copolymer (POE of Exxon Mobil company 0210), add 9.5 parts in molecular weight polyisoprene iso-butylene (German BASF
B12N), add 2 parts of uv-absorbing agent 2-(2 '-hydroxy-5-methyl base phenyl) benzotriazole, 0.5 part oxidation inhibitor sebacic acid two-2,2,6,6-tetramethyl piperidine alcohol ester (Tinuvin 770), 3 parts of linking agent neighbours, neighbour-tert-pentyl-neighbour-(2-ethylhexyl)-list-peroxycarbonates (Akzo Nobel's superoxide company limited), and mix.
Mixture is carried out blend extrude in forcing machine, temperature is controlled at 90 ℃, extrudate through curtain coating, cool off, cut, coiling process, promptly get the packaging adhesive film that thickness is 0.5mm, be designated as S-2.
Embodiment 3:
In massfraction, 68 parts of VA content is in 15% the ethylene-vinyl acetate copolymer (Ube V215), add 17 parts of mooney viscosities and be 18.0 ethylene-octene copolymer (POE of Exxon Mobil company 5101), molecular weight polyisoprene iso-butylene in adding 12 parts (Zhejiang is along reaching macromolecular material company limited), 0.05 part uv-absorbing agent 2-(2 '-hydroxy-5-methyl base phenyl) benzotriazole, 2 parts of oxidation inhibitor 1,3,5-three (the 4-tertiary butyl-3-hydroxyl-2,6-dimethyl benzene methyl)-1,3,5-triazines-2,4,6-(1H, 3H, 5H)-triketone/two (2, the 4-dicumylphenyl) pentaerythritol diphosphites compound CYANOX 2777,1 part of linking agent neighbour, neighbour-tertiary butyl-neighbour-(2-ethylhexyl)-list-peroxycarbonates (
And mix TBEC).
Mixture is carried out blend extrude in forcing machine, temperature is controlled at 90 ℃, extrudate through curtain coating, cool off, cut, coiling process, promptly get the packaging adhesive film that thickness is 0.5mm, be designated as S-3.
Embodiment 4:
In massfraction, 75 parts of VA content is in 33% the ethylene-vinyl acetate copolymer (KA10 of Singapore TPC company), add 10 parts of mooney viscosities and be 18.0 ethylene-octene copolymer (POE of Exxon Mobil company 5101), 9.9 molecular weight polyisoprene iso-butylene in part (Zhejiang is along reaching macromolecular material company limited), 0.1 part uv-absorbing agent 2-(2 '-hydroxy-5-methyl base phenyl) benzotriazole, 2 parts of oxidation inhibitor 1,3,5-three (the 4-tertiary butyl-3-hydroxyl-2,6-dimethyl benzene methyl)-1,3,5-triazine-2,4,6-(1H, 3H, 5H)-triketone/two (2, the 4-dicumylphenyl) pentaerythritol diphosphites compound CYANOX 2777, two (tert-butyl hydroperoxide sec.-propyl) benzene of 3 parts of linking agents (
14S-f1), and mix.
Mixture is carried out blend extrude in forcing machine, temperature is controlled at 90 ℃, extrudate through curtain coating, cool off, cut, coiling process, promptly get the packaging adhesive film that thickness is 0.5mm, be designated as S-4.
Embodiment 5:
In massfraction, 95 parts of VA content is in 33% the ethylene-vinyl acetate copolymer (Elvax of Mitsui E.I.Du Pont Company 250), add 2 parts of mooney viscosities and be 18.0 ethylene-octene copolymer (POE of Exxon Mobil company 5101), molecular weight polyisoprene iso-butylene (Zhejiang is along reaching macromolecular material company limited) in 2 parts, 0.1 part of uv-absorbing agent sebacic acid two-2,2,6,6-tetramethyl piperidine alcohol ester (Tinuvin 770), 0.05 part of oxidation inhibitor 1,3,5-three (the 4-tertiary butyl-3-hydroxyl-2,6-dimethyl benzene methyl)-1,3,5-triazine-2,4,6-(1H, 3H, 5H)-triketone/two (2, the 4-dicumylphenyl) pentaerythritol diphosphites compound (CYANOX XS4), 1.5 parts of linking agents 1,1-bis(t-butylperoxy)-3,5, the 5-trimethyl-cyclohexane (
29-B90), and mix.
Mixture is carried out blend extrude in forcing machine, temperature is controlled at 90 ℃, extrudate through curtain coating, cool off, cut, coiling process, promptly get the packaging adhesive film that thickness is 0.5mm, be designated as S-5.
Embodiment 6
In massfraction, 95 parts of VA content is in 15% the ethylene-vinyl acetate copolymer (Ube V215), the POE (Anhui Bai Chen polymer novel material company limited) that adds 2 parts of maleic anhydride grafts, molecular weight polyisoprene iso-butylene in 2 parts (Zhejiang is along reaching macromolecular material company limited), 0.1 part uv-absorbing agent sebacic acid two-2,2,6,6-tetramethyl piperidine alcohol ester (Tinuvin770), 0.05 part oxidation inhibitor 1,3,5-three (the 4-tertiary butyl-3-hydroxyl-2,6-dimethyl benzene methyl)-1,3,5-triazine-2,4,6-(1H, 3H, 5H)-triketone/two (2, the 4-dicumylphenyl) pentaerythritol diphosphites compounds (CYANOX XS4), 1.5 part linking agent neighbour, neighbour-tert-pentyl-neighbour-(2-ethylhexyl)-list-peroxycarbonates (
And mix TAEC).
Mixture is carried out blend extrude in forcing machine, temperature is controlled at 90 ℃, extrudate through curtain coating, cool off, cut, coiling process, promptly get the packaging adhesive film that thickness is 0.5mm, be designated as S-6.
Embodiment 7:
In massfraction, 70 parts of VA content is in 28% the ethylene-vinyl acetate copolymer (the Taiwan platform gathers the associating chemical UE2818 of limited-liability company), add 14 parts of mooney viscosities and be 35.0 ethylene-octene copolymer (du pont company POE 8180), molecular weight polyisoprene iso-butylene in 15 parts (Zhejiang is along reaching macromolecular material company limited), 0.05 part uv-absorbing agent double acid double phenol A ester, 0.05 part oxidation inhibitor 1,3,5-three (the 4-tertiary butyl-3-hydroxyl-2,6-dimethyl benzene methyl)-1,3,5-triazines-2,4,6-(1H, 3H, 5H)-triketone/two (2, the 4-dicumylphenyl) pentaerythritol diphosphites compound (CYANOX 2777), 1 part of linking agent neighbour, neighbour-tertiary butyl-neighbour-(2-ethylhexyl)-list-peroxycarbonates (
And mix TBEC).
Mixture is carried out blend extrude in forcing machine, temperature is controlled at 90 ℃, extrudate through curtain coating, cool off, cut, coiling process, promptly get the packaging adhesive film that thickness is 0.5mm, be designated as S-7.
Embodiment 8:
In massfraction, 82 parts of VA content is in 28% the ethylene-vinyl acetate copolymer (the Taiwan platform gathers the associating chemical UE2818 of limited-liability company), add 2 parts of mooney viscosities and be 18.0 ethylene-octene copolymer (POE of Exxon Mobil company 5101), molecular weight polyisoprene iso-butylene in 15 parts (the Japanese ENEOS SN-U90-K of company), 0.05 part uv-absorbing agent 2,2 '-(1, the 4-phenylene) two-4H-3,1-benzoxazine-4-ketone, 0.05 part oxidation inhibitor 2, the 6-di-tert-butyl-4-methy phenol, 0.9 part linking agent neighbour, neighbour-tertiary butyl-neighbour-(2-ethylhexyl)-list-peroxycarbonates (
And mix TBEC).
Mixture is carried out blend extrude in forcing machine, temperature is controlled at 90 ℃, extrudate through curtain coating, cool off, cut, coiling process, promptly get the packaging adhesive film that thickness is 0.5mm, be designated as S-8.
Comparative example 1:
Do not add POE in mixture, additive method is identical with embodiment 1, obtains packaging adhesive film, is designated as C-1.
Comparative example 2:
Do not add the polyisobutene polymkeric substance in mixture, additive method is identical with embodiment 3, obtains packaging adhesive film, is designated as C-2.
By the packaging adhesive film that the foregoing description obtains, to estimate through following testing method, impact resistance performance evaluation the results are shown in table 1:
1, anti-collision performance
The exhibition national standard of testing method " building curtain wall " GB/T21086-2007 and " toughened glass " GB/T9963-1998 regulation impact resistance test method require to carry out.
Sample making: get the 3mm heavy sheet glass, packaging adhesive film and the 3mm heavy sheet glass that are of a size of 150mm * 150mm, put into vacuum laminator by glass/glued membrane/glass order, at 150 ℃, lamination solidified 15 minutes.
The steel ball that with diameter is 63.5mm (weight is 1040g) is that the distance of 1m is carried out the free-falling bump in vertical height, and whether the visual inspection test destroys, and the maximum bump of disruptive number of times does not take place record.
2, glass/packaging adhesive film cohesive strength
Testing method is with reference to standard GB/T2790 " 180 ° of peeling strength test methods of tackiness agent flexible material is to rigid material ".
Sample making: get the 3mm heavy sheet glass, packaging adhesive film and the TPT backboard that are of a size of 150mm * 150mm, put into vacuum laminator by glass/glued membrane/backboard order, at 150 ℃, lamination solidified 15 minutes.Glass/packaging adhesive film/glass vacuumizes in advance to heat in laminating machine and makes sample, back horizontal positioned after crosslinked.
On puller system, measure record tensile strength numerical value with 100mm/min speed.
3, wet and heat ageing resistant performance
Carry out the hydrothermal aging test by the GB/T2423.3 test method.
Test conditions :+85 ℃, relative humidity 85%, 2000h.
Test forward and backward to sample xanthochromia index (Δ YI) by National Standard plastics yellowness index test method " GB2409, analyze by ASTM by HunterLab ColorQuest color measurement instrument.
Table 1: embodiment and comparative example make the packaging adhesive film performance relatively
Through comparing, The above results vivo proved the present composition have concurrently outstanding shock resistance, with glassy bond performance and satisfy the long-term properties that photovoltaic module uses out of doors, the present composition can satisfy the characteristic of the required packaging adhesive film of BIPV photovoltaic module.
Claims (8)
1. packaging adhesive film composition, form by the component that the quality proportioning is following:
65～95 parts of ethylene-vinyl acetate copolymers
2～20 parts of ethylene-octene copolymers
2～15 parts of middle molecular weight polyisoprene iso-butylenes
0.1～3 part of peroxide cross-linking agent
0.05～2 part of uv-absorbing agent
0.05～2 part of suffocated amine antioxidant.
2. packaging adhesive film composition as claimed in claim 1, it is characterized in that described peroxide cross-linking agent is one of following or wherein two or more mixing: tert-butyl hydroperoxide-2-ethylhexanoate, the peroxybenzoic acid tert-pentyl ester, 1,1-bis(t-butylperoxy)-3,5, the 5-trimethyl-cyclohexane, 2, two (tert-pentyl the peroxide)-butane of 2-, the hot capric acid of tert-butyl hydroperoxide, tert butyl peroxy benzoate, tert-butyl hydroperoxide-2-ethylhexanoate, tert-butyl hydroperoxide-3,5,5-tri-methyl hexanoic acid ester, tert-butyl hydroperoxide-sec.-propyl carbonic ether, tert-butyl hydroperoxide-2-ethylhexyl carbonic ether, adjacent, neighbour-tertiary butyl-neighbour-sec.-propyl-list-peroxycarbonates, adjacent, neighbour-tertiary butyl-neighbour-(2-ethylhexyl)-list-peroxycarbonates, the neighbour, neighbour-tert-pentyl-neighbour-(2-ethylhexyl)-list-peroxycarbonates, two (tert-butyl hydroperoxide sec.-propyl) benzene.
3. packaging adhesive film composition as claimed in claim 1 is characterized in that described uv-absorbing agent is one of following or wherein two or more mixing: 2, and 2 '-tetramethylene two (3,1-benzoxazine-4-ketone), 2,8-dimethyl-4H, the 6H-benzo (1,2-d; 5; 4-d ') two (1; 3)-oxazines-4; the 6-diketone; 2-hydroxyl-4-methoxyl group-2 '-carboxyl benzophenone; 2; 2 '-dihydroxyl-4; 4 '-dimethoxy-benzophenone; 2-hydroxyl-4-benzoyl oxygen base benzophenone; 2; 2 '; 4; 4 '-tetrahydroxybenzophenone; 2; 2 '-dihydroxyl-4; 4 '-dimethoxy-benzophenone; 2-hydroxyl-5-chlorobenzophenone; 2-(2 '-hydroxyl-5 '-tert-butyl-phenyl) benzotriazole; 2-(2 '-hydroxyl-5 '-aminophenyl) benzotriazole; double acid double phenol A ester; 2-(2-hydroxyl-3; the 5-di-tert-pentyl-phenyl) benzotriazole; 2; 2 '-(1; the 4-phenylene) two-4H-3,1-benzoxazine-4-ketone; 2-(2 '-hydroxyl-3 ', 5 '-3,5-dimethylphenyl) benzotriazole; 2-(2 '-methyl-4 '-hydroxy phenyl) benzotriazole; two-(2-methoxyl group-4-hydroxyl-5-benzoyl phenyl) methane; 2-(2 '-hydroxy-5-methyl base phenyl) benzotriazole; 2-(2 '-hydroxy-5-methyl base phenyl)-5-carboxylic acid butyl ester benzotriazole.
4. packaging adhesive film composition as claimed in claim 1 is characterized in that described suffocated amine antioxidant is one of following or wherein two or more mixing: 2-hydroxyl-4-alkoxy benzophenone, 3,5-di-t-butyl-4-hydroxy-benzoic acid cetyl ester, three (1,2,2,6,6-pentamethyl--4-piperidyl) phosphorous acid ester, sebacic acid two-2,2,6,6-tetramethyl piperidine alcohol ester, Succinic Acid and 4-hydroxyl-2,2,6, the polymkeric substance of 6-tetramethyl--1-piperidines alcohol, N, N '-two (2,2,6,6-tetramethyl--4-piperidyl)-1,6-hexanediamine and 2,4-two chloro-6-(1,1,3, the 3-tetramethyl butyl) polymkeric substance of amino-1,3,5-triazines, N, N '-two (2,2,6,6-tetramethyl--4-piperidyl)-1,6-hexanediamine and 2,4-two chloro-6-(4-morpholinyl)-1,3, the polymkeric substance of 5-triazine, N, N '-two (1,2,2,6,6-pentamethyl--4-piperidyl)-1,6-hexanediamine and morpholine-2,4, the polymkeric substance of 6-three chloro-1,3,5-triazines, two (1,2,2,6,6-pentamethyl--4-piperidyl) sebate/methyl isophthalic acid, 2,2,6,6-pentamethyl--4-piperidyl sebate compound, 2,6 di tert butyl 4 methyl phenol, poly-[[6-1,1,3,3,-four-methyl butyl) amino]-S-triazine-2, the 4-double-basis], [[(2,2,6,6-tetramethyl--4-piperidyl) imino-]], 1,3,5-three (the 4-tertiary butyl-3-hydroxyl-2,6-dimethyl benzene methyl)-1,3,5-triazine-2,4,6-(1H, 3H, 5H)-triketone/two (2, the 4-dicumylphenyl) pentaerythritol diphosphites compound.
5. packaging adhesive film composition as claimed in claim 1, it is characterized in that the vinyl acetate molar content is 15%～33% in the described ethylene-vinyl acetate copolymer, described ethylene-vinyl acetate copolymer fusing point is 35 ℃～100 ℃, melting index 7～55, number-average molecular weight 5000～180000.
6. packaging adhesive film composition as claimed in claim 1 is characterized in that the octene molar content is 20%～40% in the described ethylene-octene copolymer, and described ethylene-octene copolymer mooney viscosity is 3～35.
7. packaging adhesive film composition as claimed in claim 1 is used for encapsulating the application of the EVA glued membrane of solar module in preparation.
8. packaging adhesive film composition as claimed in claim 1 is used for encapsulating the application of the EVA glued membrane of double glazing in preparation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102797265A CN101942145B (en) | 2010-09-13 | 2010-09-13 | Packaging adhesive film composition and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2010102797265A CN101942145B (en) | 2010-09-13 | 2010-09-13 | Packaging adhesive film composition and application thereof |
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| CN102399500A (en) * | 2011-12-22 | 2012-04-04 | 庄晓曦 | Packaging adhesive film for solar photovoltaic component |
| CN102585731A (en) * | 2011-12-28 | 2012-07-18 | 广州鹿山新材料股份有限公司 | Novel polyolefin packaging glue film composite and application thereof |
| CN102660203A (en) * | 2012-03-30 | 2012-09-12 | 苏州福斯特光伏材料有限公司 | Heat-conducting weatherable solar cell packaging material |
| CN102936464A (en) * | 2011-08-16 | 2013-02-20 | 核工业西南物理研究院 | Ultraviolet-absorbed adhesive coating material |
| CN103173145A (en) * | 2013-03-19 | 2013-06-26 | 广州鹿山新材料股份有限公司 | EVA (Ethylene Vinyl-Acetate) glue film special for packaging double glass solar assembly and preparation method thereof |
| CN103975446A (en) * | 2011-12-05 | 2014-08-06 | 大日本印刷株式会社 | Sealing material sheet for solar cell modules |
| CN104380481A (en) * | 2012-06-19 | 2015-02-25 | 三井化学东赛璐株式会社 | Solar cell sealing material and solar cell module |
| CN106753059A (en) * | 2016-12-28 | 2017-05-31 | 杭州福斯特光伏材料股份有限公司 | A kind of pair of glass photovoltaic module hot melt butyl sealant and preparation method |
| CN107170851A (en) * | 2017-06-05 | 2017-09-15 | 合肥嘉仕诚能源科技有限公司 | A kind of solar cell package material and preparation method thereof |
| CN107266777A (en) * | 2017-07-25 | 2017-10-20 | 合肥华盖光伏科技有限公司 | A kind of photovoltaic encapsulation material and preparation method thereof |
| CN107501706A (en) * | 2017-09-01 | 2017-12-22 | 泰州隆基乐叶光伏科技有限公司 | A kind of p-type double-side cell packaging adhesive film |
| CN109362809A (en) * | 2018-11-28 | 2019-02-22 | 冯占亭 | The insecticide of one planting fruit-trees disease prevention |
| CN111303790A (en) * | 2020-04-03 | 2020-06-19 | 惠州保均玻璃材料有限公司 | Glue film and back plate integrated packaging material and processing technology thereof |
| CN111479862A (en) * | 2017-12-15 | 2020-07-31 | 阿科玛法国公司 | Use of mixtures of organic peroxides for crosslinking polyolefin elastomers |
| CN113930169A (en) * | 2021-11-01 | 2022-01-14 | 南京工程学院 | Heat-resistant EVA (ethylene vinyl acetate) adhesive film and preparation method thereof |
| CN115368831A (en) * | 2021-05-18 | 2022-11-22 | 杭州福斯特应用材料股份有限公司 | Packaging adhesive film and preparation method thereof |
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| CN102936464A (en) * | 2011-08-16 | 2013-02-20 | 核工业西南物理研究院 | Ultraviolet-absorbed adhesive coating material |
| CN102936464B (en) * | 2011-08-16 | 2014-03-05 | 核工业西南物理研究院 | Ultraviolet-absorbed adhesive coating material |
| CN103975446A (en) * | 2011-12-05 | 2014-08-06 | 大日本印刷株式会社 | Sealing material sheet for solar cell modules |
| CN103975446B (en) * | 2011-12-05 | 2016-08-24 | 大日本印刷株式会社 | Solar module sealing material sheet |
| CN102399500A (en) * | 2011-12-22 | 2012-04-04 | 庄晓曦 | Packaging adhesive film for solar photovoltaic component |
| CN102585731A (en) * | 2011-12-28 | 2012-07-18 | 广州鹿山新材料股份有限公司 | Novel polyolefin packaging glue film composite and application thereof |
| CN102660203A (en) * | 2012-03-30 | 2012-09-12 | 苏州福斯特光伏材料有限公司 | Heat-conducting weatherable solar cell packaging material |
| CN102660203B (en) * | 2012-03-30 | 2014-11-05 | 苏州福斯特光伏材料有限公司 | Heat-conducting weatherable solar cell packaging material |
| CN104380481A (en) * | 2012-06-19 | 2015-02-25 | 三井化学东赛璐株式会社 | Solar cell sealing material and solar cell module |
| CN104380481B (en) * | 2012-06-19 | 2017-05-03 | 三井化学东赛璐株式会社 | Solar cell sealing material and solar cell module |
| CN103173145A (en) * | 2013-03-19 | 2013-06-26 | 广州鹿山新材料股份有限公司 | EVA (Ethylene Vinyl-Acetate) glue film special for packaging double glass solar assembly and preparation method thereof |
| CN103173145B (en) * | 2013-03-19 | 2015-01-14 | 广州鹿山新材料股份有限公司 | EVA (Ethylene Vinyl-Acetate) glue film special for packaging double glass solar assembly and preparation method thereof |
| CN106753059A (en) * | 2016-12-28 | 2017-05-31 | 杭州福斯特光伏材料股份有限公司 | A kind of pair of glass photovoltaic module hot melt butyl sealant and preparation method |
| CN106753059B (en) * | 2016-12-28 | 2019-01-22 | 杭州福斯特应用材料股份有限公司 | A kind of double glass photovoltaic modulies hot melt butyl sealant and preparation method |
| CN107170851A (en) * | 2017-06-05 | 2017-09-15 | 合肥嘉仕诚能源科技有限公司 | A kind of solar cell package material and preparation method thereof |
| CN107266777A (en) * | 2017-07-25 | 2017-10-20 | 合肥华盖光伏科技有限公司 | A kind of photovoltaic encapsulation material and preparation method thereof |
| CN107501706A (en) * | 2017-09-01 | 2017-12-22 | 泰州隆基乐叶光伏科技有限公司 | A kind of p-type double-side cell packaging adhesive film |
| CN107501706B (en) * | 2017-09-01 | 2020-07-28 | 泰州隆基乐叶光伏科技有限公司 | P-type double-sided battery packaging adhesive film |
| CN111479862A (en) * | 2017-12-15 | 2020-07-31 | 阿科玛法国公司 | Use of mixtures of organic peroxides for crosslinking polyolefin elastomers |
| CN111479862B (en) * | 2017-12-15 | 2022-05-31 | 阿科玛法国公司 | Use of mixtures of organic peroxides for crosslinking polyolefin elastomers |
| CN109362809A (en) * | 2018-11-28 | 2019-02-22 | 冯占亭 | The insecticide of one planting fruit-trees disease prevention |
| CN111303790A (en) * | 2020-04-03 | 2020-06-19 | 惠州保均玻璃材料有限公司 | Glue film and back plate integrated packaging material and processing technology thereof |
| CN115368831A (en) * | 2021-05-18 | 2022-11-22 | 杭州福斯特应用材料股份有限公司 | Packaging adhesive film and preparation method thereof |
| CN115368831B (en) * | 2021-05-18 | 2024-02-20 | 杭州福斯特应用材料股份有限公司 | Packaging adhesive film and preparation method thereof |
| CN113930169A (en) * | 2021-11-01 | 2022-01-14 | 南京工程学院 | Heat-resistant EVA (ethylene vinyl acetate) adhesive film and preparation method thereof |
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