CN101928527A - Environmental-friendly protection film for automobile - Google Patents
Environmental-friendly protection film for automobile Download PDFInfo
- Publication number
- CN101928527A CN101928527A CN2010102657522A CN201010265752A CN101928527A CN 101928527 A CN101928527 A CN 101928527A CN 2010102657522 A CN2010102657522 A CN 2010102657522A CN 201010265752 A CN201010265752 A CN 201010265752A CN 101928527 A CN101928527 A CN 101928527A
- Authority
- CN
- China
- Prior art keywords
- protective membrane
- eco
- protection film
- friendly car
- environmental
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005266 casting Methods 0.000 claims abstract description 3
- 239000012528 membrane Substances 0.000 claims description 21
- 230000001681 protective effect Effects 0.000 claims description 21
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 229920001971 elastomer Polymers 0.000 claims description 4
- 239000003208 petroleum Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 3
- 239000000806 elastomer Substances 0.000 claims description 3
- 229920001179 medium density polyethylene Polymers 0.000 claims description 3
- 239000004701 medium-density polyethylene Substances 0.000 claims description 3
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 239000006096 absorbing agent Substances 0.000 claims description 2
- 229920001684 low density polyethylene Polymers 0.000 claims description 2
- 239000004702 low-density polyethylene Substances 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 239000004594 Masterbatch (MB) Substances 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000007790 scraping Methods 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract description 2
- 210000003608 fece Anatomy 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract description 2
- 230000002265 prevention Effects 0.000 abstract 6
- 239000003513 alkali Substances 0.000 abstract 1
- 239000000428 dust Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 description 9
- 239000010410 layer Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 4
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 3
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- VHOQXEIFYTTXJU-UHFFFAOYSA-N Isobutylene-isoprene copolymer Chemical group CC(C)=C.CC(=C)C=C VHOQXEIFYTTXJU-UHFFFAOYSA-N 0.000 description 1
- 206010040844 Skin exfoliation Diseases 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000012296 anti-solvent Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229950002083 octabenzone Drugs 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
The invention provides an environmental-friendly protection film for an automobile. The environmental-friendly protection film is produced by co-extruding and casting an external layer, a middle layer and a bonding layer according to a certain thickness proportion to obtain a white protection film with the thickness of 40 to 100 micron. The environmental-friendly protection film mainly has the functions of dust prevention, mechanical damage prevention, ultraviolet prevention, bird dung pollution prevention, scraping prevention, oil pollution prevention, acid and alkali corrosion resistance, solvent corrosion resistance and the like.
Description
Technical field
The present invention relates to the automobile environment-protection field, be specifically related to a kind of eco-friendly car protective membrane.
Background technology
Protection film for automobile is mainly used in automobile assembling, the transportation protection to automotive paints surface and component surface.At present; on the market there be much with protective membrane commercial automobile; mostly be foreign brands; for example: Tesa protective membrane, the Poli-film protective membrane of Germany, the western card protection film of Switzerland, the 3M protective membrane of the U.S.; they produce by two procedures; first procedure is produced polyolefine protective membrane base material earlier, and second operation work is coating binder on base material, and oven dry forms again.Domestic protective membrane patent; for example application number is the autoadhesion protective membrane of mentioning in 200410034833.6 the patent in order to temporary protection vehicle lacquer painting, and just the autoadhesion that is coated with again to comprise isoprene-isobutylene rubber by substrate (being made of the polylefin thermoplatic film) becomes to be grouped into.The protective membrane of this coating gluing, tackiness agent are passed in time and are existed glue-line to shift the risk of peeling off, and cause protected surface contamination, are difficult to clean; Contain organic solvent in the tackiness agent of coating, have dissolvent residual in various degree, cause environmental pollution; And this protective membrane need produce through the twice manufacturing procedure, and the process for processing cost increases undoubtedly.
The present invention is directed to the problems referred to above; design a kind of eco-friendly car protective membrane; with the polyolefin plastics particle by three-layer co-extruded casting method production; the time processing moulding; need not buy expensive automatic double surface gluer and carry out second glue spreading processing, no solvent residue can not cause environmental pollution; production technique is simple, low production cost.
Summary of the invention
The invention provides a kind of eco-friendly car protective membrane; and the production and processing method of this protective membrane, this automobile mainly contains functions such as dustproof, anti-physical abuse, antiultraviolet, anti-birds droppings pollution, anti-scraping, anti-greasy dirt, acid-alkali-corrosive-resisting, anti-solvent corrosion with protective membrane.
Technical scheme of the present invention is as follows:
The major function of layer structure is anti-scraping, absorbs ultraviolet ray, easy uncoiling that the protection car surface is avoided destroying, in order to avoid influence outward appearance.If the surface needs printing figure message, need carry out corona treatment.
The major function of interlayer structure is that the functional layer of film provides a supporting role, and titanium dioxide provides certain hiding rare support.
The major function of adhesive structure is for providing stable bond properties, and the cohesive force size can be not in time, the variation of light radiation and changing, and can not take place that glue-line shifts, obscission.The cohesive force size can be regulated, and needs big cohesive force, can increase the shared ratio of hydrogenated petroleum resin.
Advantage of the present invention is:
1, bonding coat is made of macromolecular materials such as vinylbenzene inlay and break copolymer, hydrogenated petroleum resin, propenyl special elastomers, these macromolecular materials itself are exactly the polyolefins material, so the bonding force in bonding coat and middle layer is strong more than the bonding force of coating process, do not exist adhesive layer to peel off, shift risk.
2, the polyolefine material itself of outer, middle layer and bonding coat has resistance to chemical attack, acid and alkali-resistance, performance such as ageing-resistant, the protective membrane product of making under Exposure to Sunlight, severe environment such as drench with rain, long service life, good weatherability.
3, adhesion-layer materials has excellent oxidation-resistance, weathering resistance, thermostability, processing stability, and is viscosity stabilized, and passing fluctuation in time is very little.
Embodiment
Example 1:
Main raw material(s):
1, SP4030, medium-density polyethylene, density degree 0.934.
2, RF401, Co-polypropylene.
3, FD0270, new LDPE (film grade)
4, UV-531, UV light absorber, composition is an Octabenzone.
5, dispersion agent, composition are macromolecule wax.
6, MD2311, the vinylbenzene inlay and break copolymer.
7, C-115W, hydrogenated petroleum resin.
8, VM6102, the propenyl special elastomer.
9, PE7024, white master material.
Outer: 79%SP4030+20%RF401+1%UV-531 accounts for 15% of bed thickness ratio;
The middle layer: the 39.8%SP4030+39.8%FD0270+20%PE7024+0.4% dispersion agent accounts for 70% of bed thickness ratio;
Bonding coat: 85%MD2311+10%C-115W+5%VM6102 accounts for 15% of bed thickness ratio;
According to actual requirement, the material rate of skin, middle layer, bonding coat and bed thickness ratio can be done slightly inching.
Claims (5)
1. an eco-friendly car protective membrane is characterized in that three-decker is respectively: skin, middle layer, bonding coat, the bed thickness ratio of three-decker: outer 5%-30%, middle layer 40%-90%, bonding coat 5%-30%.
2. eco-friendly car protective membrane according to claim 1 is characterized in that adopting three-layer co-extruded casting method production, and the technological process of production is: spice-three-layer co-extruded-thickness measuring-corona treatment-side cut-rolling-cut-pack.
3. eco-friendly car protective membrane according to claim 1 is characterized in that the mass percent of described outer raw material is: medium-density polyethylene 50-100%, Co-polypropylene 10-50%, anti masterbatch 5-10%, UV light absorber 0.5-2%; The mass percent of middle layer raw material is: medium-density polyethylene 30-60%, titanium dioxide 10-30%, dispersion agent 0.1-0.5%, new LDPE (film grade) 25-55%; The mass percent of bonding coat raw material is: vinylbenzene inlay and break copolymer 50-100%, hydrogenated petroleum resin 0-50%, propenyl special elastomer 0-20%.
4. eco-friendly car protective membrane according to claim 1 is characterized in that its thickness range 40-100 micron.
5. eco-friendly car protective membrane according to claim 1 is characterized in that its color is white.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010265752 CN101928527B (en) | 2010-08-26 | 2010-08-26 | Environmental-friendly protection film for automobile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010265752 CN101928527B (en) | 2010-08-26 | 2010-08-26 | Environmental-friendly protection film for automobile |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101928527A true CN101928527A (en) | 2010-12-29 |
| CN101928527B CN101928527B (en) | 2013-07-31 |
Family
ID=43367967
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010265752 Expired - Fee Related CN101928527B (en) | 2010-08-26 | 2010-08-26 | Environmental-friendly protection film for automobile |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101928527B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104131674A (en) * | 2014-07-10 | 2014-11-05 | 安徽双津实业有限公司 | Environment-friendly metal adhesive film and manufacturing method thereof |
| CN104844910A (en) * | 2015-06-03 | 2015-08-19 | 苏州靖羽新材料有限公司 | Anti-oil film material and preparation method thereof |
| CN105643853A (en) * | 2016-04-05 | 2016-06-08 | 昆山久庆塑胶有限公司 | Electrical adhesive tape processing method |
| CN105820767A (en) * | 2016-04-05 | 2016-08-03 | 昆山久庆塑胶有限公司 | Production process of PVC electrical adhesive tape |
| CN106833407A (en) * | 2016-12-21 | 2017-06-13 | 安徽双津实业有限公司 | A kind of IT product high-temperature resistant self-adhesive diaphragm |
| CN107383812A (en) * | 2017-07-26 | 2017-11-24 | 合肥梵腾环保科技有限公司 | A kind of environmental protection protective film |
| CN107868415A (en) * | 2017-12-03 | 2018-04-03 | 山东天野生物降解新材料科技有限公司 | Complete biodegradable protection film for automobile and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0580037A1 (en) * | 1992-07-20 | 1994-01-26 | BASF Aktiengesellschaft | Use of an adhesive surface protection film for the transport of automobiles |
| CN1918003A (en) * | 2001-10-22 | 2007-02-21 | 埃克森美孚化学专利公司 | Protective films |
| CN1919899A (en) * | 2006-08-29 | 2007-02-28 | 唐新国 | One-time forming non-gelatinizing cool-adhesion protective membrane |
| CN201525162U (en) * | 2009-05-31 | 2010-07-14 | 安徽省宁国双津(集团)实业有限公司 | Glass protective film |
-
2010
- 2010-08-26 CN CN 201010265752 patent/CN101928527B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0580037A1 (en) * | 1992-07-20 | 1994-01-26 | BASF Aktiengesellschaft | Use of an adhesive surface protection film for the transport of automobiles |
| CN1918003A (en) * | 2001-10-22 | 2007-02-21 | 埃克森美孚化学专利公司 | Protective films |
| CN1919899A (en) * | 2006-08-29 | 2007-02-28 | 唐新国 | One-time forming non-gelatinizing cool-adhesion protective membrane |
| CN201525162U (en) * | 2009-05-31 | 2010-07-14 | 安徽省宁国双津(集团)实业有限公司 | Glass protective film |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104131674A (en) * | 2014-07-10 | 2014-11-05 | 安徽双津实业有限公司 | Environment-friendly metal adhesive film and manufacturing method thereof |
| CN104844910A (en) * | 2015-06-03 | 2015-08-19 | 苏州靖羽新材料有限公司 | Anti-oil film material and preparation method thereof |
| CN105643853A (en) * | 2016-04-05 | 2016-06-08 | 昆山久庆塑胶有限公司 | Electrical adhesive tape processing method |
| CN105820767A (en) * | 2016-04-05 | 2016-08-03 | 昆山久庆塑胶有限公司 | Production process of PVC electrical adhesive tape |
| CN106833407A (en) * | 2016-12-21 | 2017-06-13 | 安徽双津实业有限公司 | A kind of IT product high-temperature resistant self-adhesive diaphragm |
| CN107383812A (en) * | 2017-07-26 | 2017-11-24 | 合肥梵腾环保科技有限公司 | A kind of environmental protection protective film |
| CN107868415A (en) * | 2017-12-03 | 2018-04-03 | 山东天野生物降解新材料科技有限公司 | Complete biodegradable protection film for automobile and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101928527B (en) | 2013-07-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| C53 | Correction of patent of invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 242300 No. 1 West Antarctic Road, Anhui, Ningguo Applicant after: ANHUI SHUANGJIN Co.,Ltd. Address before: 242300 No. 1 West Antarctic Road, Anhui, Ningguo Applicant before: Anhui Ningguo Shuangjin (Group) Industrial Co.,Ltd. |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: ANHUI NINGGUO DOUBLE-JIN (GROUP) CO., LTD. TO: ANHUI SHUANGJIN CO., LTD. |
|
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130731 |