CN101921445B - Production formulation of HIPS (High Impact Polystyrene) foaming material and making method thereof - Google Patents
Production formulation of HIPS (High Impact Polystyrene) foaming material and making method thereof Download PDFInfo
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- CN101921445B CN101921445B CN2010102657170A CN201010265717A CN101921445B CN 101921445 B CN101921445 B CN 101921445B CN 2010102657170 A CN2010102657170 A CN 2010102657170A CN 201010265717 A CN201010265717 A CN 201010265717A CN 101921445 B CN101921445 B CN 101921445B
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- Extrusion Moulding Of Plastics Or The Like (AREA)
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Abstract
The invention discloses a production formulation of an HIPS (High Impact Polystyrene) foaming material and a making method thereof. The material consists of high impact polystyrene resin (HIPS resin, primary recycled material), polystyrene resin (PS resin, primary recycled material), SBS (Styrene-But) resin, ultrafine talcum powders, azodicarbonamide (AC foaming agent), zinc oxide, calcium stearate, sodium bicarbonate, citric acid, phosphite ester, antimonous oxide, tetrabromobisphemol A, antioxidant, UV (ultraviolet) absorbers, toner, turpentine and white oil. Plates or foaming sectional materials made of the materials have the characteristics of light weight, water resistance, corrosion resistance, aging resistance and inflaming retarding and can be sawed and dug without paint and can be widely used as floor boards or used for manufacturing furniture or leisure chairs used in public places, and the like.
Description
Affiliated technical field
The invention belongs to chemical technology field, relate to a kind of HIPS foam material production formula and preparation method thereof.
Background technology
At present, produce the material that furniture uses on the market and be generally timber and steel, also need further to paint processing, do not only polluting the environment like this, and production cost is also very high with the furniture of these material produce.For this reason, utilize a kind of HIPS foam material of waste and old HIPS material produce to be used for the furniture manufacturing crucial meaning is just arranged.
Summary of the invention:
The purpose of this invention is to provide production formula of a kind of HIPS foam material and preparation method thereof.
In order to achieve the above object, a kind of HIPS foam material production formula of the present invention is by high-impact polystyrene resin (HIPS resin, the one-level feed back), polystyrene resin (PS resin, the one-level feed back), the SBS resin, superfine talcum powder, Cellmic C 121 (AC whipping agent), zinc oxide, calcium stearate, sodium bicarbonate, citric acid, phosphorous acid ester, antimonous oxide, tetrabromo-bisphenol, oxidation inhibitor, UV absorption agent, toner, turps and white oil are formed, the weight percent that its prescription is formed is: HIPS one-level feed back resin 30%～50%, PS one-level feed back resin 15%～30%, SBS resin 3%～15%, superfine talcum powder 1%～15%, Cellmic C 121 3%～15%, zinc oxide 0.5%～2%, calcium stearate 0.3%～1%, sodium bicarbonate 0.5%～0.9%, citric acid 0.1%～0.3%, phosphorous acid ester 0.5%～5%, antimonous oxide 1%～5%, tetrabromo-bisphenol 3%～6%, oxidation inhibitor 0.1%～0.3%, UV absorption agent 0.1～0.3%, toner 0.01%～0.3%, turps 0.1%～0.3%, white oil 0.1%～0.3%.
Oxidation inhibitor in the above-mentioned materials is antioxidant 1010 or oxidation inhibitor 168 or is the compound of the two that the UV absorption agent is UV-234 or UV-360 or is the compound of the two.
The specific embodiment of the present invention is:
1, produces the HIPS foaming plate
A, be poured in the little basin of stainless steel after toner weighed up in proportion, add turps then in little basin, stir with stainless steel bar, treat to add white oil again in little basin after the toner dissolving, this starches stand-by for toner.
B, with HIPS one-level feed back resin, PS one-level feed back resin, SBS resin, Cellmic C 121, zinc oxide, calcium stearate, sodium bicarbonate, citric acid, phosphorous acid ester, antimonous oxide, tetrabromo-bisphenol, oxidation inhibitor, UV absorption agent and toner slurry add in the high-speed mixer successively, open high-speed mixer, high-speed mixing was emitted material after 30 minutes, material was sent in the loading hopper of sheet material forcing machine then.
The rotating speed of c, control sheet material forcing machine is 300～350r/min, the temperature of control barrel front portion, middle part, rear portion and head is respectively: 200～210 ℃, 195～205 ℃, 190～200 ℃, 210～220 ℃, above-mentioned materials is extruded into certain width and certain thickness sheet material.
2, produce the HIPS foamed profile
A, be poured in the little basin of stainless steel after toner weighed up in proportion, add turps then in little basin, stir with stainless steel bar, treat to add white oil again in little basin after the toner dissolving, this starches stand-by for toner.
B, with HIPS one-level feed back resin, PS one-level feed back resin, SBS resin, Cellmic C 121, zinc oxide, calcium stearate, sodium bicarbonate, citric acid, phosphorous acid ester, antimonous oxide, tetrabromo-bisphenol, oxidation inhibitor, UV absorption agent and toner slurry add in the high-speed mixer successively, open high-speed mixer, high-speed mixing was emitted material after 30 minutes, material was sent in the loading hopper of twin screw extruder then.
C, open system HIPS foaming molding mold according to the shape of foamed profile.
The rotating speed of d, control twin screw extruder is 330～380r/min, the temperature of control barrel front portion, middle part, rear portion and head is respectively: 200～210 ℃, 195～205 ℃, 190～200 ℃, 210～220 ℃, material in the twin screw extruder is got in the HIPS foaming molding mold, pressurize 1 minute is treated to take out HIPS foaming spare after the mold cools down.
The invention has the beneficial effects as follows, HIPS foaming plate or foamed profile have in light weight, water-fast, corrosion-resistant, ageing-resistant and fire-retardant characteristics, material foamings in twin screw extruder or in the sheet material forcing machine such as HIPS resin, the density of its product is identical with density of wood, it can be sawed, can dig, exempt from paint, can be widely used as timber floor or as the sheet material of furniture manufacturing usefulness or be used to make the leisure chaise longue used the public place etc., foamed profile can be made table leg, the chair leg, footpost etc., its disposal molding does not have scrap stock, and its production cost is low, make a silk purse out of a sow's ear, the HIPS waste and scrap that factory is difficult to utilize has changed into product.
Embodiment 1 (producing the HIPS foaming plate)
(1), phthalocyanine blue 0.1% (weight percent, below identical) is poured in the little basin of stainless steel, add turps 0.1% then in little basin, stir with stainless steel bar, treat to add white oil 0.1% again after the toner dissolving in little basin, this starches stand-by for toner.
(2), with HIPS one-level feed back resin 40%, PS one-level feed back resin 20%, SBS resin 5%, superfine talcum powder 10%, Cellmic C 121 10%, zinc oxide 1%, calcium stearate 0.3%, sodium bicarbonate 0.7%, citric acid 0.3%, phosphorous acid ester 3%, antimonous oxide 4%, tetrabromo-bisphenol 5%, oxidation inhibitor 168 0.2%, UV-360 0.2% and toner slurry add in the high-speed mixer successively, open high-speed mixer, high-speed mixing was emitted material after 30 minutes, material was sent in the loading hopper of sheet material forcing machine then.
(3), the rotating speed of control sheet material forcing machine is 350r/min, the temperature of control barrel front portion, middle part, rear portion and head is respectively: 200 ℃, 195 ℃, 190 ℃, 210 ℃, it is 1500mm that material is extruded into width through the sheet material forcing machine, and thickness is the blue foaming plate of 3mm.
Embodiment 2 (producing the HIPS foamed profile)
(1), lemon yellow 0.1% (weight percent, below identical) poured in the little basin of stainless steel, add turps 0.1% then in little basin, stir with stainless steel bar, treat to add white oil 0.1% again after the toner dissolving in little basin, this starches stand-by for toner.
(2), with HIPS one-level feed back resin 40%, PS one-level feed back resin 25%, SBS resin 5%, superfine talcum powder 5%, Cellmic C 121 10%, zinc oxide 1%, calcium stearate 0.3%, sodium bicarbonate 0.7%, citric acid 0.3%, phosphorous acid ester 3%, antimonous oxide 4%, tetrabromo-bisphenol 5%, antioxidant 1010 0.2%, UV-234 0.2% and toner slurry add in the high-speed mixer successively, open high-speed mixer, high-speed mixing was emitted material after 30 minutes, material was sent in the loading hopper of twin screw extruder then.
(3), open system seat leg foaming molding mold.
(4), the rotating speed of control twin screw extruder is 380r/min, the temperature of control barrel front portion, middle part, rear portion and head is respectively: 210 ℃, 205 ℃, 200 ℃, 220 ℃, material in the twin screw extruder is got in the seat leg foaming molding mold, pressurize 1 minute is treated to take out seat leg foaming spare after the mold cools down.
Claims (3)
1. HIPS foam material, the weight percent that it is characterized in that this Material formula makeup is: HIPS one-level feed back resin 30%～50%, PS one-level feed back resin 15%～30%, SBS resin 3%～15%, superfine talcum powder 1%～15%, Cellmic C 121 3%～15%, zinc oxide 0.5%～2%, calcium stearate 0.3%～1%, sodium bicarbonate 0.5%～0.9%, citric acid 0.1%～0.3%, phosphorous acid ester 0.5%～5%, antimonous oxide 1%～5%, tetrabromo-bisphenol 3%～6%, oxidation inhibitor 0.1%～0.3%, UV absorption agent 0.1～0.3%, toner 0.01%～0.3%, turps 0.1%～0.3%, white oil 0.1%～0.3%.
2. the making method of a kind of HIPS foam material according to claim 1, when it is characterized in that making with HIPS one-level feed back, PS one-level feed back, the SBS resin, Cellmic C 121, zinc oxide, calcium stearate, sodium bicarbonate, citric acid, phosphorous acid ester, antimonous oxide, tetrabromo-bisphenol, oxidation inhibitor, UV absorption agent and toner slurry add in the high-speed mixer successively, open high-speed mixer, high-speed mixing was emitted material after 30 minutes, then material is sent in the loading hopper of twin screw extruder, the rotating speed of control twin screw extruder is 330～380r/min, control barrel front portion, the middle part, the temperature of rear portion and head is respectively: 200～210 ℃, 195～205 ℃, 190～200 ℃, 210～220 ℃, material in the twin screw extruder is got in the HIPS foaming molding mold, pressurize 1 minute, treat to take out HI PS foaming spare after the mold cools down, the making method of toner slurry is to be poured in the little basin of stainless steel after toner is weighed up in proportion, in little basin, add turps then, stir with stainless steel bar, treat in little basin, to add white oil again after the toner dissolving.
3. the making method of a kind of HI PS foam material according to claim 2 is characterized in that the HIPS foam material is sheet material or section bar, and the working method of its section bar is that the HIPS foam material is got in the HIPS section bar mould by twin screw extruder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102657170A CN101921445B (en) | 2010-08-17 | 2010-08-17 | Production formulation of HIPS (High Impact Polystyrene) foaming material and making method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102657170A CN101921445B (en) | 2010-08-17 | 2010-08-17 | Production formulation of HIPS (High Impact Polystyrene) foaming material and making method thereof |
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| Publication Number | Publication Date |
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| CN101921445A CN101921445A (en) | 2010-12-22 |
| CN101921445B true CN101921445B (en) | 2011-10-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2010102657170A Expired - Fee Related CN101921445B (en) | 2010-08-17 | 2010-08-17 | Production formulation of HIPS (High Impact Polystyrene) foaming material and making method thereof |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104231463A (en) * | 2014-10-17 | 2014-12-24 | 苏州市涵信塑业有限公司 | Plastic particle employing SBS (Styrene Butadiene Styrene) modified waste polystyrene |
| CN106398077A (en) * | 2016-09-19 | 2017-02-15 | 吴中心 | Micro-foaming material with single layer structure |
| KR101945603B1 (en) | 2016-12-30 | 2019-02-07 | 롯데첨단소재(주) | Thermoplastic resin composition and article produced therefrom |
| CN108530786B (en) * | 2018-04-29 | 2021-06-11 | 宁波灿烨塑业有限公司 | Anti-aging HIPS foamed plastic and preparation method thereof |
| KR102164729B1 (en) * | 2019-08-05 | 2020-10-14 | 강현식 | A process for preparing co-extruded lamination sheet for packing tray |
| CN110511522B (en) * | 2019-08-19 | 2022-04-29 | 南通佳景健康科技股份有限公司 | Halogen-free flame-retardant HIPS (high impact polystyrene) foam material and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US7214739B2 (en) * | 2003-04-22 | 2007-05-08 | General Electric Company | Composition and method for improving the surface adhesion of resin compositions to polyurethane foam |
| US7354990B2 (en) * | 2003-08-26 | 2008-04-08 | General Electric Company | Purified polymeric materials and methods of purifying polymeric materials |
| US20060178543A1 (en) * | 2005-02-08 | 2006-08-10 | Krupinski Steven M | Foamed sheet containing a styrenic copolymer |
| KR100700078B1 (en) * | 2005-04-06 | 2007-03-28 | 허정도 | Compositions and manufacturing methods of bitumen modifiers having complex functionality |
| JP5199590B2 (en) * | 2007-03-01 | 2013-05-15 | 帝人化成株式会社 | Thermoplastic resin composition |
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Effective date of registration: 20131217 Address after: 226300 Jiangsu city of Nantong province Tongzhou District Chuan Jiang Zhen Jiang Zhang No. 88 Patentee after: JIANGSU DAHAI PLASTIC CO., LTD. Address before: 225300 Jiangsu Province, Taizhou City Hailing District eight Bridge Street 3 building 503 room Patentee before: Wang Chonggao |
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