CN101915723A - Method and device for measuring total organic carbon in water body - Google Patents

Method and device for measuring total organic carbon in water body Download PDF

Info

Publication number
CN101915723A
CN101915723A CN 201010237328 CN201010237328A CN101915723A CN 101915723 A CN101915723 A CN 101915723A CN 201010237328 CN201010237328 CN 201010237328 CN 201010237328 A CN201010237328 A CN 201010237328A CN 101915723 A CN101915723 A CN 101915723A
Authority
CN
China
Prior art keywords
water body
voltage signal
organic carbon
total organic
area value
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN 201010237328
Other languages
Chinese (zh)
Other versions
CN101915723B (en
Inventor
程岩
任国兴
张虹斌
马然
高杨
汤永佐
尤小华
张颖
刘东彦
张颖颖
王洪亮
石小梅
曹煊
刘岩
孙继昌
侯广利
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oceanographic Instrumentation Research Institute Shandong Academy of Sciences
Original Assignee
Oceanographic Instrumentation Research Institute Shandong Academy of Sciences
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oceanographic Instrumentation Research Institute Shandong Academy of Sciences filed Critical Oceanographic Instrumentation Research Institute Shandong Academy of Sciences
Priority to CN2010102373287A priority Critical patent/CN101915723B/en
Publication of CN101915723A publication Critical patent/CN101915723A/en
Application granted granted Critical
Publication of CN101915723B publication Critical patent/CN101915723B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)

Abstract

本发明提供一种水体中总有机碳的测量方法及装置。水体中总有机碳的测量方法，包括：对实验池中的水体进行检测，以获得水体中的有机碳对应的电压信号；对电压信号进行积分处理，以得到电压信号对应的面积值；根据面积值和预设的浓度公式，计算水体中的总有机碳的浓度，其中，预设的浓度公式为浓度与面积值之间的线性关系公式。通过对实验池中水体中进行检测，以获得不同时刻水体中的有机碳对应的电压信号；然后，将电压信号进行积分以得到电压信号对应的面积值；最后，将面积值带入浓度公式便可以准确可靠的获得水体中总有机碳的浓度。由于检测到的电压信号无需假定为平稳的或时不变的，提高了水体中总有机碳的测量方法的可靠性。

Figure 201010237328

The invention provides a method and device for measuring total organic carbon in a water body. The method for measuring the total organic carbon in the water body includes: detecting the water body in the experimental pool to obtain the voltage signal corresponding to the organic carbon in the water body; integrating the voltage signal to obtain the area value corresponding to the voltage signal; value and a preset concentration formula to calculate the concentration of total organic carbon in the water body, wherein the preset concentration formula is a linear relationship formula between the concentration and the area value. By detecting the water body in the experimental pool, the voltage signal corresponding to the organic carbon in the water body at different times is obtained; then, the voltage signal is integrated to obtain the area value corresponding to the voltage signal; finally, the area value is brought into the concentration formula. The concentration of total organic carbon in water can be obtained accurately and reliably. Since the detected voltage signal does not need to be assumed to be stationary or time-invariant, the reliability of the method for measuring the total organic carbon in the water body is improved.

Figure 201010237328

Description

The measuring method of total organic carbon in waterbody and device
Technical field
The present invention relates to field of measuring technique, relate in particular to a kind of measuring method and device of total organic carbon in waterbody.
Background technology
At present, total organic carbon (Total OrganicCarbon in the water body (for example: ocean, lake or rivers), be designated hereinafter simply as: the overall target that TOC) is organic pollutants in water body, it is one of most important project of marine environmental monitoring, because TOC is an overall target of representing organic substance total amount in the water body with the content of carbon, so TOC more can directly reasonably represent in the water body by the degree of organic pollutants.In the prior art, the measuring technique of TOC is normally carried out on the platform of laboratory in the water body, is specially: the signal of the TOC correspondence of supposition in the water body be steadily or the time constant, then, according to the content of TOC in the detected calculated signals water body.
As from the foregoing, because the structure and the concentration of water body organism are influenced greatly by space-time, majority is in interrelated, interactional state, and in the prior art signal of the TOC correspondence in the measuring method of the TOC supposition water body be stably or the time constant, the result's of measurement accuracy and representativeness will be under suspicion.Therefore, the reliability of the measuring method of TOC is relatively poor in the prior art.
Summary of the invention
The invention provides a kind of measuring method and device of total organic carbon in waterbody,, realize the reliability of the measuring method of raising total organic carbon in waterbody in order to solve the relatively poor defective of measuring method reliability of total organic carbon in waterbody in the prior art.
The invention provides a kind of measuring method of total organic carbon in waterbody, comprising:
Water body in the experiment pool is detected, to obtain the voltage signal of the organic carbon correspondence in the described water body;
Described voltage signal is carried out Integral Processing, to obtain the area value of described voltage signal correspondence;
According to described area value and default concentration formula, calculate the concentration of the total organic carbon in the described water body, wherein, described default concentration formula is the linear relationship formula between described concentration and the described area value.
The present invention also provides a kind of measurement mechanism of total organic carbon in waterbody, comprising:
Detection module is used for the water body of experiment pool is detected, to obtain the voltage signal of the organic carbon correspondence in the described water body;
The Integral Processing module is used for described voltage signal is carried out Integral Processing, to obtain the area value of described voltage signal correspondence;
Computing module is used for calculating the concentration of the total organic carbon in the described water body according to described area value and default concentration formula, and wherein, described default concentration formula is the linear relationship formula between described concentration and the described area value.
The measuring method of total organic carbon in waterbody provided by the invention and device are by to detecting in the water body in the experiment pool, to obtain the voltage signal of the organic carbon correspondence in the different water bodys constantly; Then, voltage signal is carried out integration to obtain the area value of voltage signal correspondence; At last, area value is brought into the concentration that the concentration formula just can obtain total organic carbon in waterbody accurately and reliably.Because detected voltage signal need not to be assumed to stably or the time is constant, thereby can detect the concentration of total organic carbon in waterbody in real time accurately, improve the reliability of the measuring method of total organic carbon in waterbody.
Description of drawings
In order to be illustrated more clearly in the embodiment of the invention or technical scheme of the prior art, to do one to the accompanying drawing of required use in embodiment or the description of the Prior Art below introduces simply, apparently, accompanying drawing in describing below is some embodiments of the present invention, for those of ordinary skills, under the prerequisite of not paying creative work, can also obtain other accompanying drawing according to these accompanying drawings.
Fig. 1 is the process flow diagram of the measuring method embodiment one of total organic carbon in waterbody of the present invention;
Fig. 2 is the process flow diagram of the measuring method embodiment two of total organic carbon in waterbody of the present invention;
Fig. 3 is the process flow diagram of step 1 among the measuring method embodiment two of total organic carbon in waterbody of the present invention;
Fig. 4 is the process flow diagram of step 3 among the measuring method embodiment two of total organic carbon in waterbody of the present invention;
Fig. 5 is the measurement mechanism example structure synoptic diagram of total organic carbon in waterbody of the present invention.
Embodiment
For the purpose, technical scheme and the advantage that make the embodiment of the invention clearer, below in conjunction with the accompanying drawing in the embodiment of the invention, technical scheme in the embodiment of the invention is clearly and completely described, obviously, described embodiment is the present invention's part embodiment, rather than whole embodiment.Based on the embodiment among the present invention, those of ordinary skills belong to the scope of protection of the invention not making the every other embodiment that is obtained under the creative work prerequisite.
Fig. 1 is the process flow diagram of the measuring method embodiment one of total organic carbon in waterbody of the present invention.As shown in Figure 1, the measuring method of present embodiment total organic carbon in waterbody comprises:
Step 1, the water body in the experiment pool is detected, to obtain the voltage signal of the organic carbon correspondence in the water body.Concrete, by the water body in the experiment pool is detected, can obtain the voltage signal of the organic carbon correspondence in the different water bodys constantly, thereby the voltage signal that need not to suppose the organic carbon correspondence in the water body be stable or the time constant, thereby can obtain the voltage signal of organic carbon correspondence accurately.
Step 2, voltage signal is carried out Integral Processing, to obtain the area value of voltage signal correspondence.Concrete, can obtain the voltage signal and the formed two-dimensional curve of time of different organic carbon correspondences constantly by step 1, carry out Integral Processing by step 2 pair voltage signal, can obtain the size of the area of voltage signal and time span formation, promptly obtain the area value of voltage signal correspondence.
Step 3, according to area value and default concentration formula, calculate the concentration of the total organic carbon in the water body, wherein, default concentration formula is the linear relationship formula between concentration and the area value.Concrete, the concentration of the total organic carbon in the water body area value corresponding with voltage signal is linear, can be brought in the default concentration formula by the area value of step 3 with acquisition in the step 2, accurately to calculate the concentration of the total organic carbon in the water body.
The measuring method of present embodiment total organic carbon in waterbody is by to detecting in the water body in the experiment pool, to obtain the voltage signal of the organic carbon correspondence in the different water bodys constantly; Then, voltage signal is carried out integration to obtain the area value of voltage signal correspondence; At last, area value is brought into the concentration that the concentration formula just can obtain total organic carbon in waterbody accurately and reliably.Because detected voltage signal need not to be assumed to stably or the time is constant, thereby can detect the concentration of total organic carbon in waterbody in real time accurately, improve the reliability of the measuring method of present embodiment total organic carbon in waterbody.
Fig. 2 is the process flow diagram of the measuring method embodiment two of total organic carbon in waterbody of the present invention.As shown in Figure 2, the measuring method of present embodiment total organic carbon in waterbody based on the measuring method embodiment one of above-mentioned total organic carbon in waterbody, includes step 1-step 3, and its difference is: also comprised before step 1:
Step 1 ', in experiment pool, inject ozone, so that the organic carbon in ozone and water body reaction is luminous.Concrete, the pairing voltage signal of organic carbon in the acquisition water body for convenience, step 1 in the present embodiment ' ozone is injected in the water body in the experiment pool, ozone will react with organic carbon and luminous, and the big more light intensity of the concentration of total organic carbon in waterbody is just strong more.
Step 1 is specially: the light that the water body in the experiment pool is sent detects, and light is converted to voltage signal.Concrete, by step 1 ' light that the water body in the experiment pool is sent, the light intensity that step 1 is sent the water body in test experience pond, and be voltage signal with detected smooth corresponding conversion, thereby the pairing voltage signal of organic carbon in the water body can be obtained easily.
Further, carry out Integral Processing, before the area value that obtains the voltage signal correspondence, also comprise at step 2 pair voltage signal:
Step 2 ', voltage signal is removed the processing of making an uproar.Concrete, because in the water body to experiment pool detects with the process that obtains voltage signal, the process of detecting can be subjected to extraneous influence of various factors, thereby need remove the processing of making an uproar to detected voltage signal, for example, can handle voltage signal by one-dimensional wavelet transform, effectively voltage signal is removed the processing of making an uproar.
The measuring method of present embodiment total organic carbon in waterbody, by ozone being injected in the water body so that ozone and organic carbon reaction are luminous, light intensity by sending in the test experience pond easily, and be voltage signal, thereby can obtain the voltage signal of organic carbon correspondence in the water body easily with phototransformation.In addition, by the voltage signal that obtains is removed the processing of making an uproar, can effectively weaken extraneous factor to the influence that detected voltage signal causes, make voltage signal more accurate, more help improving the reliability of the measuring method of present embodiment total organic carbon in waterbody.
Based on technique scheme, optionally, as shown in Figure 3, the step 1 in the present embodiment comprises following concrete steps:
Step 11, judge that voltage signal is whether stable.Concrete, judge by step 11 pair detected voltage signal, determine whether voltage signal is in steady state (SS).For example: the relative standard deviation that can calculate continuous a plurality of voltage signals; If relative standard deviation, determines then that voltage signal is in steady state (SS) less than default standard deviation.In a period of time scope, can detect different corresponding constantly voltage signals, calculate the relative standard deviation of continuous a plurality of voltage signals then, relative standard deviation that calculates and the standard deviation of presetting are compared, if relative standard deviation can determine then that less than default standard deviation detected voltage signal is in steady state (SS).
Step 12, if voltage signal be in steady state (SS), in experiment pool, do not continuing under the situation of injection water body, detect first voltage signal of the organic carbon correspondence in the water body, until the ratio of first voltage signal and the mean value of the voltage signal that is in steady state (SS) less than pre-set threshold value.Concrete, after judging voltage signal and being in steady state (SS), then stop in experiment pool, to continue to inject water body, and begin first voltage signal of the organic carbon correspondence in the detection record water body simultaneously.Because continue in the experiment pool to inject ozone, the content of the organic carbon in the water body reduces gradually, the light intensity that the water body of experiment pool sends also dies down gradually, thereby causes the magnitude of voltage of detected first voltage signal to reduce gradually.When the ratio of first voltage signal and the mean value of the voltage signal that is in steady state (SS) during less than pre-set threshold value, detected all magnitudes of voltage are first voltage signal.
Step 13, after the ratio of the magnitude of voltage of first voltage signal and the mean value of the voltage signal that is in steady state (SS) is less than pre-set threshold value, in experiment pool, continuing to inject under the situation of water body, detect second voltage signal of the organic carbon correspondence in the water body, mxm. appears until detecting second voltage signal, the size of the magnitude of voltage of obtained previous moment when wherein, mxm. is detected second voltage signal magnitude of voltage that occurs previous moment for the first time greater than constantly magnitude of voltage of back one.Concrete, after the ratio of the magnitude of voltage of first voltage signal and the mean value of the voltage signal that is in steady state (SS) is less than pre-set threshold value, will continues to inject water body again in the experiment pool, and begin second voltage signal of the organic carbon correspondence in the detection record water body simultaneously.Owing to injected new water body in the experiment pool, the content of the organic carbon in the experiment pool is increased, the light intensity that the water body of experiment pool sends is grow gradually also, thereby causes the magnitude of voltage of detected second voltage signal to increase gradually.In detecting the process of second voltage signal, when the magnitude of voltage that detected previous moment occurs for the first time during greater than constantly magnitude of voltage of back one, as mxm., detected all magnitudes of voltage are second voltage signal with the magnitude of voltage of this previous moment.
And the step 2 in the present embodiment is specially: first voltage signal and second voltage signal are carried out Integral Processing.Concrete, the area value that obtains in the step 2 comprises two parts, i.e. the area value sum of the area value of the first voltage signal correspondence and the second voltage signal correspondence.
The measuring method of present embodiment total organic carbon in waterbody, by after obtaining voltage signal in judgement and being in steady state (SS), detect the voltage signal of the organic carbon correspondence in the water body in the different time sections again, can obtain the area value of voltage signal correspondence more accurately and effectively, thereby can obtain the concentration of total organic carbon in waterbody more accurately, more help improving the reliability of the measuring method of present embodiment total organic carbon in waterbody.
Based on technique scheme, optionally, present embodiment step 1 is specially: according to default sample frequency the water body in the experiment pool is detected, wherein, sample frequency is the relative standard deviation frequency values hour of continuous a plurality of voltage signals.
Particularly, in the process that the water body in the experiment pool is detected, can detect according to default sample frequency, wherein, this employing frequency is a pairing frequency values when the numerical value of the relative standard deviation of detected voltage signal is minimum value.By adopting default sample frequency that the voltage signal of the organism correspondence in the experiment pool is detected, can obtain the voltage signal of organic carbon correspondence more accurately; And, can more accurately be easy to calculate the area value of voltage signal correspondence owing to adopt default sample frequency to detect.
Further, the measuring method of present embodiment total organic carbon in waterbody both can the continuous detection experiment pool in the concentration of total organic carbon, can also adopt the concentration of total organic carbon in the discontinuous mode test experience pond.When adopting discontinuous mode, step 1 will detect the water body in the experiment pool according to default sample frequency, concrete, above-mentioned steps 12 and step 13 can adopt following method to obtain: according to default sample frequency the water body in the experiment pool is carried out the interval and detect, to obtain a plurality of voltage signals, wherein, the number of voltage signal is the default number of times that detects.Concrete, the interval detection can be configured in advance and number of times will be detected, detect the voltage signal of correspondence in the different time sections then at interval according to default sample frequency.Step 2 in the present embodiment is specially: each voltage signal is carried out Integral Processing, to obtain the area value of each voltage signal correspondence.Concrete, the voltage signal in each time period is carried out Integral Processing, thereby can obtain each voltage signal corresponding area value in the time period at place separately.
Further again, the step 3 in the present embodiment can be specially:
Maximum area value and minimum area value in step 31, the removal area value;
Step 32, remaining area value is averaged, to obtain the average area value;
Step 33, according to average area value and default concentration formula, calculate the concentration of the total organic carbon in the water body.Concrete, behind the area value by each voltage signal correspondence of step 2 acquisition, maximum area value and minimum area value are removed; Then, can calculate residual area value sum, in the hope of the average area value of above-mentioned area value; At last, the average area value is brought into the concentration formula, just can calculates the concentration of the total organic carbon in the water body.
Further, default concentration formula in the present embodiment can adopt the formula that configures in advance, also can carry out the scene and set in the process of primary detection voltage signal.Particularly, in order to set default concentration formula in advance, the measuring method of present embodiment total organic carbon in waterbody also comprised before step 33:
Step 33 ', set default concentration formula, be specially:, obtain default concentration value and the linear relationship between the average area value, with the concentration formula that obtains presetting according to average area value and default concentration value.Concrete, can be complementary with default concentration value by calculating the average area value that obtains, make the average area value corresponding one by one, thereby can obtain the concentration value preset and the linear relationship between the average area value easily with the concentration value of presetting.For example: can detect the average area value twice, twice average area value will be distinguished corresponding different default concentration values, then, according to two groups of average area values and default concentration value, calculate default concentration formula.
The measuring method of present embodiment total organic carbon in waterbody detects the water body in the experiment pool by adopting default sample frequency, can obtain the voltage signal of organic carbon correspondence more accurately; And, can more accurately be easy to calculate the area value of voltage signal correspondence owing to adopt default sample frequency to detect.By setting default concentration formula, can set the concentration formula easily according to actual needs, thereby make the concentration value of the total organic carbon that calculates more accurate, more help improving the reliability of the measuring method of present embodiment total organic carbon in waterbody.
One of ordinary skill in the art will appreciate that: all or part of step that realizes said method embodiment can be finished by the relevant hardware of programmed instruction, aforesaid program can be stored in the computer read/write memory medium, this program is carried out the step that comprises said method embodiment when carrying out; And aforesaid storage medium comprises: various media that can be program code stored such as ROM, RAM, magnetic disc or CD.
Fig. 5 is the measurement mechanism example structure synoptic diagram of total organic carbon in waterbody of the present invention.As shown in Figure 5, the measurement mechanism of present embodiment total organic carbon in waterbody comprises: detection module 10, Integral Processing module 20 and computing module 30.
Detection module 10 is used for the water body of experiment pool is detected, to obtain the voltage signal of the organic carbon correspondence in the water body.
Integral Processing module 20 is used for voltage signal is carried out Integral Processing, to obtain the area value of voltage signal correspondence.
Computing module 30 is used for calculating the concentration of the total organic carbon in the water body according to area value and default concentration formula, and wherein, the concentration formula is the linear relationship formula between concentration and the area value.
Particularly, the detection module 10 in the present embodiment, Integral Processing module 20 and the computing module 30 concrete courses of work can not repeat them here referring to the record of the measuring method embodiment of total organic carbon in waterbody of the present invention.
The measurement mechanism of present embodiment total organic carbon in waterbody is by to detecting in the water body in the experiment pool, to obtain the voltage signal of the organic carbon correspondence in the different water bodys constantly; Then, voltage signal is carried out integration to obtain the area value of voltage signal correspondence; At last, area value is brought into the concentration that the concentration formula just can obtain total organic carbon in waterbody accurately and reliably.Because detected voltage signal need not to be assumed to stably or the time is constant, thereby can detect the concentration of total organic carbon in waterbody in real time accurately, improve the reliability of the measuring method of present embodiment total organic carbon in waterbody.
It should be noted that at last: above embodiment only in order to technical scheme of the present invention to be described, is not intended to limit; Although with reference to previous embodiment the present invention is had been described in detail, those of ordinary skill in the art is to be understood that: it still can be made amendment to the technical scheme that aforementioned each embodiment put down in writing, and perhaps part technical characterictic wherein is equal to replacement; And these modifications or replacement do not make the essence of appropriate technical solution break away from the spirit and scope of various embodiments of the present invention technical scheme.

Claims (10)

1.一种水体中总有机碳的测量方法，其特征在于，包括：1. a method for measuring total organic carbon in a water body, characterized in that, comprising: 对实验池中的水体进行检测，以获得所述水体中的有机碳对应的电压信号；Detecting the water body in the experimental pool to obtain a voltage signal corresponding to the organic carbon in the water body; 对所述电压信号进行积分处理，以得到所述电压信号对应的面积值；Integrate the voltage signal to obtain an area value corresponding to the voltage signal; 根据所述面积值和预设的浓度公式，计算所述水体中的总有机碳的浓度，其中，所述预设的浓度公式为所述浓度与所述面积值之间的线性关系公式。Calculate the concentration of total organic carbon in the water body according to the area value and a preset concentration formula, wherein the preset concentration formula is a linear relationship formula between the concentration and the area value. 2.根据权利要求1所述的水体中总有机碳的测量方法，其特征在于，在所述对实验池中的水体进行检测之前，还包括：2. the measuring method of total organic carbon in the water body according to claim 1, is characterized in that, before the water body in the described experiment pool is detected, also comprises: 向所述实验池中注入臭氧，以使所述臭氧与所述水体中的有机碳反应发光；Injecting ozone into the experimental pool, so that the ozone reacts with the organic carbon in the water body to emit light; 所述对实验池中的水体进行检测，具体为：对所述实验池中的水体发出的光进行检测，并将所述光转换为所述电压信号。The detecting the water body in the experimental pool specifically includes: detecting the light emitted by the water body in the experimental pool, and converting the light into the voltage signal. 3.根据权利要求2所述的水体中总有机碳的测量方法，其特征在于，在所述对所述电压信号进行积分处理，以得到所述电压信号对应的面积值之前，还包括：对所述电压信号进行除噪处理。3. the measuring method of total organic carbon in the water body according to claim 2, is characterized in that, before described voltage signal is carried out integral processing, to obtain the area value corresponding to described voltage signal, also comprises: The voltage signal is subjected to noise removal processing. 4.根据权利要求1-3任一所述的水体中总有机碳的测量方法，其特征在于，所述对实验池中的水体进行检测具体为：4. according to the measuring method of the total organic carbon in the arbitrary described water body of claim 1-3, it is characterized in that, the described water body in the test pond is detected specifically as: 判断所述电压信号是否稳定；judging whether the voltage signal is stable; 若所述电压信号处于稳定状态，在不向所述实验池中继续注入水体的情况下，检测所述水体中的有机碳对应的第一电压信号，直至所述第一电压信号与处于稳定状态的电压信号的平均值之比小于预设阀值；If the voltage signal is in a stable state, without continuing to inject water into the experimental pool, detect the first voltage signal corresponding to the organic carbon in the water until the first voltage signal is in a stable state. The ratio of the average value of the voltage signal is less than the preset threshold; 在所述第一电压信号的电压值与处于稳定状态的电压信号的平均值之比小于预设阀值后，在向所述实验池中继续注入水体的情况下，检测所述水体中的有机碳对应的第二电压信号，直至检测到所述第二电压信号出现最高值，其中，所述最高值为检测到的所述第二电压信号第一次出现前一时刻的电压 值大于后一时刻的电压值时所取得前一时刻的电压值的大小；After the ratio of the voltage value of the first voltage signal to the average value of the voltage signal in a steady state is less than the preset threshold value, when the water body continues to be injected into the experimental pool, the organic matter in the water body is detected. carbon corresponding to the second voltage signal until the highest value of the second voltage signal is detected, wherein the highest value is greater than the detected voltage value at the moment before the first appearance of the second voltage signal The voltage value at the moment is the magnitude of the voltage value obtained at the previous moment; 所述对所述电压信号进行积分处理，具体为：对所述第一电压信号和所述第二电压信号进行积分处理。The performing integration processing on the voltage signal specifically includes: performing integration processing on the first voltage signal and the second voltage signal. 5.根据权利要求4所述的水体中总有机碳的测量方法，其特征在于，所述判断所述电压信号是否稳定具体为：5. the measuring method of total organic carbon in the water body according to claim 4, is characterized in that, whether described voltage signal of described judgment is stable is specially: 计算连续的多个所述电压信号的相对标准偏差；calculating the relative standard deviation of a plurality of consecutive voltage signals; 若所述相对标准偏差小于预设的标准偏差，则确定所述电压信号处于稳定状态。If the relative standard deviation is smaller than a preset standard deviation, it is determined that the voltage signal is in a stable state. 6.根据权利要求1-3任一所述的水体中总有机碳的测量方法，其特征在于，所述对实验池中的水体进行检测，具体为：6. according to the measuring method of the total organic carbon in the arbitrary described water body of claim 1-3, it is characterized in that, the described water body in the test pool is detected, specifically: 根据预设的采样频率对所述实验池中的水体进行检测，其中，所述采样频率为连续的多个所述电压信号的相对标准偏差最小时的频率值。The water body in the experimental pool is detected according to a preset sampling frequency, wherein the sampling frequency is a frequency value at which the relative standard deviation of a plurality of consecutive voltage signals is the smallest. 7.根据权利要求6所述的水体中总有机碳的测量方法，其特征在于，所述根据预设的采样频率对所述实验池中的水体进行检测，具体为：7. the measuring method of total organic carbon in the water body according to claim 6, is characterized in that, described according to preset sampling frequency, the water body in the described experiment pool is detected, specifically: 根据预设的采样频率对所述实验池中的水体进行间隔检测，以获得多个所述电压信号，其中，所述电压信号的个数为预设检测次数；The water body in the experimental pool is detected at intervals according to a preset sampling frequency to obtain a plurality of voltage signals, wherein the number of the voltage signals is a preset number of times of detection; 对所述电压信号进行积分处理，具体为：对各个所述电压信号进行积分处理，以得到各个所述电压信号对应的面积值。Performing integral processing on the voltage signals is specifically: performing integral processing on each of the voltage signals to obtain an area value corresponding to each of the voltage signals. 8.根据权利要求7所述的水体中总有机碳的测量方法，其特征在于，所述根据所述面积值和预设的浓度公式，计算所述水体中的总有机碳的浓度，具体为：8. the measuring method of total organic carbon in the water body according to claim 7, is characterized in that, described according to described area value and preset concentration formula, calculate the concentration of the total organic carbon in described water body, be specifically : 去除所述面积值中的最大面积值和最小面积值；removing the largest area value and the smallest area value among the area values; 对剩余的所述面积值求平均值，以得到平均面积值；averaging the remaining said area values to obtain an average area value; 根据所述平均面积值和预设的浓度公式，计算所述水体中的总有机碳的浓度。 Calculate the concentration of total organic carbon in the water body according to the average area value and a preset concentration formula. the 9.根据权利要求8所述的水体中总有机碳的测量方法，其特征在于，在所述根据所述平均面积值和预设的浓度公式之前，还包括：设定预设的浓度公式，具体为：根据所述平均面积值和预设的浓度值，获得所述预设的浓度值与所述平均面积值之间的线性关系，以得到预设的浓度公式。9. the measuring method of total organic carbon in water body according to claim 8, is characterized in that, before described according to described average area value and preset concentration formula, also comprises: setting preset concentration formula, Specifically, according to the average area value and the preset concentration value, obtain a linear relationship between the preset concentration value and the average area value, so as to obtain a preset concentration formula. 10.一种水体中总有机碳的测量装置，其特征在于，包括：10. A measuring device for total organic carbon in a water body, characterized in that it comprises: 检测模块，用于对实验池中的水体进行检测，以获得所述水体中的有机碳对应的电压信号；The detection module is used to detect the water body in the experimental pool, so as to obtain the voltage signal corresponding to the organic carbon in the water body; 积分处理模块，用于对所述电压信号进行积分处理，以得到所述电压信号对应的面积值；An integral processing module, configured to perform integral processing on the voltage signal to obtain an area value corresponding to the voltage signal; 计算模块，用于根据所述面积值和预设的浓度公式，计算所述水体中的总有机碳的浓度，其中，所述预设的浓度公式为所述浓度与所述面积值之间的线性关系公式。 A calculation module, configured to calculate the concentration of total organic carbon in the water body according to the area value and a preset concentration formula, wherein the preset concentration formula is the difference between the concentration and the area value Linear relationship formula. the
CN2010102373287A 2010-07-21 2010-07-21 Method and device for measuring total organic carbon in waterbody Expired - Fee Related CN101915723B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2010102373287A CN101915723B (en) 2010-07-21 2010-07-21 Method and device for measuring total organic carbon in waterbody

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2010102373287A CN101915723B (en) 2010-07-21 2010-07-21 Method and device for measuring total organic carbon in waterbody

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN2012100831970A Division CN102621046A (en) 2010-07-21 2010-07-21 Method for measuring total organic carbon in water body

Publications (2)

Publication Number Publication Date
CN101915723A true CN101915723A (en) 2010-12-15
CN101915723B CN101915723B (en) 2012-09-05

Family

ID=43323285

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2010102373287A Expired - Fee Related CN101915723B (en) 2010-07-21 2010-07-21 Method and device for measuring total organic carbon in waterbody

Country Status (1)

Country Link
CN (1) CN101915723B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102288643A (en) * 2011-08-01 2011-12-21 山东省科学院海洋仪器仪表研究所 Method and device for measuring organic matter of soil

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2570774Y (en) * 2002-09-28 2003-09-03 武汉元素科技发展有限公司 Closed cycle total organic carbon analytical equipment
JP2005305328A (en) * 2004-04-22 2005-11-04 Toshiba Corp Water treatment controlling system
CN1737541A (en) * 2005-08-29 2006-02-22 山东省科学院海洋仪器仪表研究所 Utilize the method for chemiluminescence measurement water body total organic carbon in the ozone oxidation process
CN1963472A (en) * 2006-11-03 2007-05-16 山东省科学院海洋仪器仪表研究所 Method for examining deposit or organic matter content in soil by ozone oxidation
CN101004386A (en) * 2007-01-15 2007-07-25 山东省科学院海洋仪器仪表研究所 Method for measuring chemical oxygen demand and total organic carbon by mode of oxidizing floating injected ozone
CN101673098A (en) * 2009-09-29 2010-03-17 北京安控科技股份有限公司 Control system used for total organic carbon (TOC) on-line monitor
US20100159602A1 (en) * 2007-09-05 2010-06-24 Conway Gregory B Carbon measurement in aqueous samples using oxidation at elevated temperatures and pressures

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2570774Y (en) * 2002-09-28 2003-09-03 武汉元素科技发展有限公司 Closed cycle total organic carbon analytical equipment
JP2005305328A (en) * 2004-04-22 2005-11-04 Toshiba Corp Water treatment controlling system
CN1737541A (en) * 2005-08-29 2006-02-22 山东省科学院海洋仪器仪表研究所 Utilize the method for chemiluminescence measurement water body total organic carbon in the ozone oxidation process
CN1963472A (en) * 2006-11-03 2007-05-16 山东省科学院海洋仪器仪表研究所 Method for examining deposit or organic matter content in soil by ozone oxidation
CN101004386A (en) * 2007-01-15 2007-07-25 山东省科学院海洋仪器仪表研究所 Method for measuring chemical oxygen demand and total organic carbon by mode of oxidizing floating injected ozone
US20100159602A1 (en) * 2007-09-05 2010-06-24 Conway Gregory B Carbon measurement in aqueous samples using oxidation at elevated temperatures and pressures
CN101673098A (en) * 2009-09-29 2010-03-17 北京安控科技股份有限公司 Control system used for total organic carbon (TOC) on-line monitor

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
《International Journal of Radiation Biology》 19851231 Henglein A,et al Scavenger of OH radicals produced in the sonolysis of water 251-258 1-10 第48卷, 2 *
《海洋技术》 20090331 刘岩,等 海水总有机碳（TOC）分析技术研究 66-69 1-10 第28卷, 第1期 2 *
《环境科学与技术》 20100331 刘岩,等 利用发光技术测量海水总有机碳（TOC）技术研究 123-126 1-10 第33卷, 第3期 2 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102288643A (en) * 2011-08-01 2011-12-21 山东省科学院海洋仪器仪表研究所 Method and device for measuring organic matter of soil
CN102288643B (en) * 2011-08-01 2013-01-09 山东省科学院海洋仪器仪表研究所 Method and device for measuring organic matter of soil

Also Published As

Publication number Publication date
CN101915723B (en) 2012-09-05

Similar Documents

Publication Publication Date Title
CN106770559B (en) A kind of quiet spy combined type geochemistry microelectrode probe system
WO2007106810A3 (en) Nmr method of detecting precipitants in a hydrocarbon stream
DE60126756D1 (en) METHOD FOR DETECTING AN ANALYTE THROUGH FLUORESCENCE
CN203772850U (en) Real-time tilapia cultivation water quality monitoring and pre-alarming integrated device
IL181131A0 (en) USE OF C3a AND DERIVATIVES THEREOF AS A BIOMARKER FOR COLORECTAL ADEMONA AND/OR CARCINOMA; DIAGNOSIS METHOD AND TEST SYSTEM USING THE SAME
WO2009001862A1 (en) Method of evaluating visceral fat accumulation
CN109031265B (en) Sewage discharge traceability positioning system and method
Delwiche et al. A novel optical sensor designed to measure methane bubble sizes in situ
CN109751043B (en) Pressure pulse coding and decoding system and method for formation pressure measurement while drilling tool
ATE456853T1 (en) METHOD AND DEVICE FOR MONITORING SWITCHING DEVICES IN ELECTRICAL SWITCHGEARS
CN109554452A (en) Method and device based on solid nano hole detection super low concentration molecular marker
CN101915723A (en) Method and device for measuring total organic carbon in water body
WO2010068653A3 (en) Combined optical and resistance measuring apparatus and method
CN115825183A (en) Seabed carbon dioxide leakage monitoring equipment, method and system and storage medium
CN104198538A (en) Shipborne cruising dissolved inorganic carbon observation device and method
WO2008090941A1 (en) Method of evaluating ibd, amino acid data processor, amino acid data processing method, amino acid data processing system, amino acid data processing program and recording medium
MX2022011822A (en) System and method for analyte monitoring and predictive modeling.
CN103616365B (en) Flow injection Fluorimetric Quenching Method measures pick-up unit plumbous in water and method
CN102809558B (en) Method for measuring polycyclic aromatic hydrocarbons (PAHs) of sea water in flow injection chemiluminescence way
CN206248166U (en) A kind of water-level measuring post of portable type measuring level of ground water
CN202141716U (en) Automatic alarm device for water pollution in rivers and lakes
WO2009054350A1 (en) Method for evaluation of impaired glucose tolerance
CN106560711B (en) Drinking water source monitoring and pre-warning system and method
CN102621046A (en) Method for measuring total organic carbon in water body
CN106556682A (en) Animal farm wastewater treatment effect method of real-time

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120905

Termination date: 20130721