CN101914367A - Compound-type oil outflow round-up agent as well as preparation method and application thereof - Google Patents

Compound-type oil outflow round-up agent as well as preparation method and application thereof Download PDF

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CN101914367A
CN101914367A CN2010102704025A CN201010270402A CN101914367A CN 101914367 A CN101914367 A CN 101914367A CN 2010102704025 A CN2010102704025 A CN 2010102704025A CN 201010270402 A CN201010270402 A CN 201010270402A CN 101914367 A CN101914367 A CN 101914367A
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agent
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CN101914367B (en
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黄海清
黄振宏
黄晓梅
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GUANGDONG BIAOMEI SILICON AND FLUORIDE NEW MATERIALS CO Ltd
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Abstract

The invention discloses a compound-type oil outflow round-up agent as well as a preparation method and application thereof. The compound-type oil outflow round-up agent consists of the following materials in parts: 0-100 parts of fluorine-containing anon surface active agent, 1-100 parts of silicon compound non-ionic surface active agent, 10-50 parts of alcohol and 10-40 parts of water. The compound-type oil outflow round-up agent can be prepared by mixing, heating, refluxing, stirring and cooling the materials. The invention has larger oil round-up area and oil round-up amount and higher oil round-up speed, can effectively prevent diffusion of crude oil or oil product on the water level, ensures that the crude oil or oil product is rounded up for recycling and has great application value in the oil overflow treatment of water areas.

Description

A kind of compound oil spilling round-up agent and its production and application
Technical field
The present invention relates to petrochemical industry, be specifically related to a kind of compound oil spilling round-up agent and its production and application.
Background technology
In recent years, oil spilling, oil accident constantly take place in various countries, and all kinds of oil pollution incidents are in rising trend, caused immeasurable financial loss and environmental hazard.Statistics are arranged, annual oil and the petroleum products that leak into the ocean by all means accounts for 0.5% of world oil ultimate production, therefore, how to take new technology to solve the water pollution that oil liquid leakage causes, the precious resources such as oil that efficient recovery leaks become the significant problem that countries in the world are all paid attention to.
When the waters fluid takes place particularly during crude oil leakage, oil can diffusion rapidly on the water surface, influences more wider zones, and water environment and Biological resources are caused serious pollution, destruction.
Using oil-spill dispersant is one of main method of handling at present marine oil overflow.Oil-spill dispersant is dispersed into very little particulate with oil spilling emulsification, and particulate spreads out in the ocean with ocean current and morning and evening tides, and decomposes disappearance by action of microorganisms.But the oil-spill dispersant usage quantity is very big, is 10～30% of oil spillage.The partial concn of oil spilling oil spill dispersant is higher in blink, may of short duration the contact be arranged with the intravital biology of water, brings influence can for some biological development growth.And oil-spill dispersant enters food chain in the water after oil spilling is dispersed into particulate, and long-term accumulation in vivo finally will be detrimental to health.The oil spilling particulate is deposited to the seabed behind microbiological degradation, and density diminishes, and perhaps emulsifying effectiveness disappears, and all can float to the sea again, forms once more and pollutes.
Alleviating by the further diffusion of water surface fluid and causing in the bigger pollution, the oil film that the oil-collecting agent can make the water surface spread is assembled thickening, can change the dispersal direction of oil film at the water surface, reaches the purpose that reduces or control the water-surface oil film pollution damage.Change the oil film dispersal direction by the oil-collecting agent, make oil film assemble thickening, with other method recycling, can prevent or reduce oil spill then in a certain direction.
At present domestic having certain progress aspect the oil-collecting agent: Chinese patent CN1149612 discloses a kind of collecting oil agent composition, is used for the oil-collecting agent of diesel oil oil spilling, is made up of the alcohols or the kerosene organic solvent of mass percent 1～10% natural carboxylic acid and 90～99%; Be used for the oil-collecting agent of crude oil oil spilling, form by the above-mentioned organic solvent of mass percent 1～10% natural carboxylic acid and polyoxyethylene oleate and 90～99%.Chinese patent CN1473767 discloses a kind of composition of oil Film collecting agent on water.It comprises active ingredient and carrier.Active ingredient be in solid-state Fatty Alcohol(C12-C14 and C12-C18), solid-state aliphatic carboxylic acid, the sorbitan ester a kind of, two or three, carrier is C 2～C 8Fatty Alcohol(C12-C14 and C12-C18), aliphatic carboxylic acid or fat carboxylic ether.
All there is shortcoming and defect aspect many in but above existing patent of lifting in oil-collecting agent composition, consumption, effect etc.:
(1) use of the organic solvent of kerosene class has caused secondary pollution;
(2) oil-collecting amount and displacement of reservoir oil area are less;
(3) oil-collecting speed is slower.
Summary of the invention
The objective of the invention is to overcome the deficiency of existing oil-collecting agent aspect composition, consumption and effect, the agent of a kind of oil spilling round-up is provided, this compound oil spilling round-up agent can reduce seawater surface tension force greatly, stop crude oil or petroleum products on the water surface, to spread, sprawl, pasta is shunk to be concentrated, form the certain thickness oil reservoir, be convenient to rapid effective collection and handle.
The present invention also aims to provide the preparation method of a kind of described compound oil spilling round-up agent.
The present invention also aims to provide the application of described compound oil spilling round-up agent.
Above-mentioned purpose of the present invention is achieved by following technical solution:
The agent of a kind of compound oil spilling round-up, form by the following component of calculating by weight:
0～100 part in fluo anion type tensio-active agent;
1～100 part of silicone compound nonionic surface active agent;
10～50 parts of alcohol;
10～40 parts in water.
As a kind of preferred version, the agent of described compound oil spilling round-up, form by the following component of calculating by weight:
5～40 parts in fluo anion type tensio-active agent;
5～65 parts of silicone compound nonionic surface active agent;
10～50 parts of alcohol;
10～40 parts in water.
Described fluo anion type tensio-active agent is one or more the mixture in fluorinated sulfonate, fluorinated carboxylate salt or the fluorinated phosphate anion type tensio-active agent.
Described fluorinated sulfonate anionic type tensio-active agent has structure shown in formula I or formula II:
R fXArSO 3M
(Ⅰ)
R fSO 3M
(Ⅱ)
Wherein, R fFor containing the perfluoroalkyl of 1～20 carbon atom, thiazolinyl; X is oxygen or sulphur atom; Ar is an aromatic ring; M is a basic metal, a kind of in alkaline-earth metal, organic amine or the inorganic ammonium.
Described fluorinated carboxylate anion type tensio-active agent has structure shown in formula III:
R fCO 2M
(Ⅲ)
Wherein, R fBe perfluoroalkyl, thiazolinyl or the aryl that contains 1～20 carbon atom; M is a basic metal, a kind of in alkaline-earth metal or organic amine or the inorganic ammonium.
Described fluorinated phosphate anion type tensio-active agent has structure shown in formula IV:
Figure BSA00000253869500041
Wherein, R fBe perfluoroalkyl, thiazolinyl or the aryl that contains 1～20 carbon atom; R 1, R 2For independently containing alkyl, aryl or the hydrogen atom of 1 to 8 carbon atom separately.
Described silicone compound nonionic surface active agent has suc as formula structure shown in (V):
Wherein, R 1Be amino, hydroxyl or contain alkyl, haloalkyl, the thiazolinyl of 1～6 carbon atom; R 2Be hydrogen atom, amino, hydroxyl or contain alkyl, haloalkyl, the thiazolinyl of 1～6 carbon atom; R 3For phenyl or contain alkyl, the thiazolinyl of 1～4 carbon atom; Q is a hydrogen atom, hydroxyl or contain alkyl, the thiazolinyl of 1～4 carbon atom; W is hydrogen atom or the alkyl that contains 1～20 carbon atom; X=0～50, y=0～20, a=2～10, b=0～20, c=0～30 (x, y, a, b, c are integer).
Described alcohol is the alcohol that contains 1～4 carbon atom.
Described alcohol is preferably ethanol or propyl alcohol.
The present invention provides the preparation method of described compound oil spilling round-up agent simultaneously, comprises the steps:
Input table surface-active agent in the reaction vessel adds alcohol and water, reflux, and it is transparent evenly to be stirred to reaction solution; Be cooled to room temperature, obtain the agent of described compound oil spilling round-up.
The temperature of described reflux is 50～70 ℃, and described churning time is 2～4 hours.
Compound oil spilling round-up agent outward appearance of the present invention is brown or yellow clarified liq, and the pH value is 6.0～8.0, and relative density (25 ℃) is 0.90～1.10g/cm 3
The application of described compound oil spilling round-up agent in crude oil or the processing of petroleum products oil spilling.
Described compound oil spilling round-up agent is used, and specifically can be used for the ocean, lake, oil or other oils leakage processing such as river.When Oil spills, oil can spread, spread into quite big zone rapidly on the water surface, causes severe contamination to destroy to water surrounding and Biological resources.Add a small amount of this compound oil spilling round-up agent, can greatly reduce seawater surface tension force, stop crude oil on the water surface, to spread, sprawl, concentrate, form the certain thickness oil reservoir, be convenient to rapid collection and treatment and pasta is shunk.
Compared with prior art, the present invention has following beneficial effect:
(1) the compound oil spilling round-up of the present invention agent organic solvent of oiliness has not been avoided the secondary pollution that environment is caused;
(2) oil-collecting amount and displacement of reservoir oil area are bigger, compare with existing oil spilling oil-collecting agent, and when using the oil-collecting agent of identical or less amount, oil-collecting amount of the present invention and displacement of reservoir oil area are apparently higher than prior art; Total displacement of reservoir oil area of oil spilling round-up of the present invention agent can be up to 92%, and crude oil that overflows or Oil Recovery rate can be up to 90%; Adopt compound oil spilling round-up of the present invention agent that crude oil or the oil product that overflows reclaimed, can reduce the pollution that ecology is caused, economize on resources.
(3) displacement of reservoir oil speed is very fast, compares with existing oil spilling oil-collecting agent, and when using the oil-collecting agent of identical or less amount, displacement of reservoir oil speed is apparently higher than prior art; The displacement of reservoir oil speed of compound oil spilling round-up of the present invention agent can reach 10cm/s, can realize control pasta diffusion rapidly and efficiently.
Description of drawings
Fig. 1 is the oil-collecting effect comparison diagram of compound oil spilling round-up of the present invention agent and various surfactants.
Fig. 2 handles the effect synoptic diagram of oil spilling for existing dispersion agent.
Fig. 3 is the effect synoptic diagram that oil spilling is handled in compound oil spilling round-up agent of the present invention.
Embodiment
Further explain the present invention below in conjunction with the drawings and specific embodiments, but embodiment does not do any type of qualification to the present invention.
The verification method of described compound oil spilling round-up agent: 1. tank method: get long 80cm, wide 8cm, the degree of depth is to add seawater 4L in the tank of 10cm, the crude oil that adds 80g, treat it after the water surface is sprawled fully, inject oil spilling round-up agent 20 μ L, measure its displacement of reservoir oil time from end water-oil interface, round-up distance and round-up area, and calculate its round-up speed.With pump the oil that collects is reclaimed.2. circular groove method: get crude oil 80g, sprawling in diameter is in the circular groove of 35cm, adds seawater 4L.Inject oil spilling round-up agent 20 μ L from water-oil interface, measure its displacement of reservoir oil time, round-up distance and round-up area, and calculate its round-up speed.With pump the oil that collects is reclaimed.
Used reagent is commercial product among the contrast experiment, SDS (sodium lauryl sulphate): Dihua worker company limited is won in Tianjin; AEO-3 (dodecyl fatty alcohol-polyoxyethylene ether): auxiliary agent chemical plant, Guangzhou; OP-10 (octyl phenol polyoxy ethane ether): Hai'an, Jiangsu petroleum chemical plant; The tensio-active agent of fluo anion described in the embodiment: good fluorine silicon company limited is avenged in Harbin; Poly-silica nonionogenic tenside described in the embodiment: the industrial organosilicon novel material in Qingdao company limited.Also can adopt the like product of other producers.
Embodiment 1
Get 15 part of ten alkyl perfluorinated sulfonic acid sodium, 25 parts have the poly-silicon oxide compound shown in the following structural formula,
Figure BSA00000253869500071
With 30 parts of ethanol, 40 parts of water mix then, and 50 ℃ of reflux evenly stirred 4 hours, and are transparent to reaction solution, are cooled to room temperature, make product.Experimentize according to the described tank method of summary of the invention, displacement of reservoir oil top speed reaches 10cm/s, and ultimate range reaches 74cm, and total displacement of reservoir oil area reaches 92%, and the oil that uses pump to collect reclaims, and the rate of recovery reaches 90%.
Embodiment 2
Get 15 part of ten alkyl perfluorinated sulfonic acid sodium, 25 parts have the poly-silicon oxide compound shown in the following structural formula,
Figure BSA00000253869500072
With 30 parts of ethanol, 40 parts of water mix then, and 50 ℃ of reflux evenly stirred 4 hours, and are transparent to reaction solution, are cooled to room temperature, make product.Reach 94% according to the described disk method of the summary of the invention final total displacement of reservoir oil area that experimentizes, the oil that uses pump to collect reclaims, and the rate of recovery reaches 90%.
Embodiment 3
Get 20 parts of perfluor Sodium n-caproates, 40 parts have the poly-silicon oxide compound shown in the following structural formula,
Figure BSA00000253869500073
With 30 parts of ethanol, 40 parts of water mix then, and 50 ℃ of reflux evenly stirred 4 hours, and are transparent to reaction solution, are cooled to room temperature, make product.Experimentize according to the described tank method of summary of the invention, displacement of reservoir oil top speed reaches 9.0cm/s, and ultimate range reaches 72cm, and total displacement of reservoir oil area reaches 89%, and the oil that uses pump to collect reclaims, and the rate of recovery reaches 85%.
Embodiment 4
Get 30 parts of perfluoro hexyl Di-Sodium Phosphates, 70 parts have the poly-silicon oxide compound shown in the following structural formula,
Figure BSA00000253869500081
With 30 parts of ethanol, 40 parts of water mix then, and 70 ℃ of reflux evenly stirred 2 hours, and are transparent to reaction solution, are cooled to room temperature, make product.Experimentize according to the described tank method of summary of the invention, displacement of reservoir oil top speed reaches 8.5cm/s, and ultimate range reaches 64cm, and total displacement of reservoir oil area reaches 78%, and the oil that uses pump to collect reclaims, and the rate of recovery reaches 75%.
Embodiment 5
Get 15 part of ten alkyl perfluorinated sulfonic acid sodium, 65 parts have the poly-silicon oxide compound shown in the following structural formula,
Figure BSA00000253869500082
With 30 parts of ethanol, 40 parts of water mix then, and 70 ℃ of reflux evenly stirred 2 hours, and are transparent to reaction solution, are cooled to room temperature, make product.Experimentize according to the described tank method of summary of the invention, displacement of reservoir oil top speed reaches 8.8cm/s, and ultimate range reaches 69cm, and total displacement of reservoir oil area reaches 83%, and the oil that uses pump to collect reclaims, and the rate of recovery reaches 81%.
Embodiment 6
Get 15 part of ten alkyl perfluorinated sulfonic acid sodium, 25 parts have the poly-silicon oxide compound shown in the following structural formula,
Figure BSA00000253869500091
With 30 parts of ethanol, 40 parts of water mix then, and 70 ℃ of reflux evenly stirred 2 hours, and are transparent to reaction solution, are cooled to room temperature, make product.Experimentize according to the described tank method of summary of the invention, displacement of reservoir oil top speed reaches 9.1cm/s, and ultimate range reaches 70cm, and total displacement of reservoir oil area reaches 88%, and the oil that uses pump to collect reclaims, and the rate of recovery reaches 85%.
Embodiment 7
Get 15 part of ten alkyl perfluorinated sulfonic acid sodium, 90 parts have the poly-silicon oxide compound shown in the following structural formula,
Figure BSA00000253869500092
With 30 parts of ethanol, 40 parts of water mix then, and 60 ℃ of reflux evenly stirred 3 hours, and are transparent to reaction solution, are cooled to room temperature, make product.Experimentize according to the described tank method of summary of the invention, displacement of reservoir oil top speed reaches 9.4cm/s, and ultimate range reaches 73cm, and total displacement of reservoir oil area reaches 83%, and the oil that uses pump to collect reclaims, and the rate of recovery reaches 81%.
Embodiment 8
Get 25 parts and have the poly-silicon oxide compound shown in the following structural formula,
Figure BSA00000253869500093
With 30 parts of ethanol, 40 parts of water mix then, and 70 ℃ of reflux evenly stirred 2 hours, and are transparent to reaction solution, are cooled to room temperature, make product.Experimentize according to the described tank method of summary of the invention, displacement of reservoir oil top speed reaches 8.9cm/s, and ultimate range reaches 63cm, and total displacement of reservoir oil area reaches 73%, and the oil that uses pump to collect reclaims, and the rate of recovery reaches 72%.
Embodiment 9
Get 20 parts of perfluoro hexyl Di-Sodium Phosphates, 10 parts of perfluor Sodium n-caproates, 70 parts have the poly-silicon oxide compound shown in the following structural formula,
Figure BSA00000253869500101
With 30 parts of ethanol, 40 parts of water mix then, and 70 ℃ of reflux evenly stirred 2 hours, and are transparent to reaction solution, are cooled to room temperature, make product.Experimentize according to the described tank method of summary of the invention, displacement of reservoir oil top speed reaches 8.6cm/s, and ultimate range reaches 68cm, and total displacement of reservoir oil area reaches 85%, and the oil that uses pump to collect reclaims, and the rate of recovery reaches 80%.
Comparative Examples 1
Implement according to the described tank method of summary of the invention, contrast the oil-collecting effect of various tensio-active agents.
Embodiment 1 2.59s 4.96s 7.5s 74cm 92％
*Annotate: AEO-3 oil in 5 minutes has diffusion phenomena again.
From Comparative Examples and Fig. 1, we find out that the present invention and other tensio-active agent in displacement of reservoir oil speed, very big advantage is all arranged on distance and the area, and oil can not spread again.
Accompanying drawing 2 is the effect synoptic diagram of oil-spill dispersant.Oil-spill dispersant a large amount of (sump oil amounts 30%) joins and is subjected to oilysewage surface, by mechanical effect, oil spilling emulsification is dispersed into very little particulate.Particulate enters in the water and spreads with ocean current.
Accompanying drawing 3 is the effect synoptic diagram of oil spilling round-up of the present invention agent.Oil spilling round-up agent (ppm rank) joins and is subjected on the oilysewage surface, acts between the greasy dirt and the water surface.By changing the interfacial tension between the water surface and oil reservoir, make oil reservoir be driven fast and enrichment, make oil spilling become and be easy to reclaim.
From accompanying drawing 2 and accompanying drawing 3, find out that the present invention has tangible advantage in the processing that is subjected to oilysewage surface: can reclaim oil spilling effectively, can polluted-water, and the consumption much less.

Claims (10)

1. compound oil spilling round-up agent is characterized in that being made up of the following component of calculating by weight:
0～100 part in fluo anion type tensio-active agent;
1～100 part of silicone compound nonionic surface active agent;
10～50 parts of alcohol;
10～40 parts in water.
2. compound according to claim 1 oil spilling round-up agent is characterized in that being made up of the following component of calculating by weight:
5～40 parts in fluo anion type tensio-active agent;
5～65 parts of silicone compound nonionic surface active agent;
10～50 parts of alcohol;
10～40 parts in water.
3. as compound oil spilling round-up agent as described in any claim in claim 1 or 2, it is characterized in that described fluo anion type tensio-active agent is one or more the mixture in fluorinated sulfonate, fluorinated carboxylate salt or the fluorinated phosphate anion type tensio-active agent; Described alcohol is the alcohol that contains 1～4 carbon atom.
4. as compound oil spilling round-up agent as described in the claim 3, it is characterized in that described fluorinated sulfonate anionic type tensio-active agent, have structure shown in formula I or formula II:
R fXArSO 3M
(Ⅰ)；
R fSO 3M
(Ⅱ)；
Wherein, R fBe perfluoroalkyl, the thiazolinyl that contains 1～20 carbon atom; X is oxygen or sulphur atom; Ar is an aromatic ring; M is a kind of in basic metal, alkaline-earth metal or organic amine or the inorganic ammonium.
5. as compound oil spilling round-up agent as described in the claim 3, it is characterized in that described fluorinated carboxylate anion type tensio-active agent, have structure shown in formula III:
R fCO 2M
(Ⅲ)；
Wherein, R fBe perfluoroalkyl, thiazolinyl or the aryl that contains 1～20 carbon atom; M is a kind of in basic metal, alkaline-earth metal or organic amine or the inorganic ammonium.
6. as compound oil spilling round-up agent as described in the claim 3, it is characterized in that described fluorinated phosphate anion type tensio-active agent, have structure shown in formula IV:
Wherein, R fBe perfluoroalkyl, thiazolinyl or the aryl that contains 1～20 carbon atom; R 1, R 2For independently containing alkyl, aryl or the hydrogen atom of 1 to 8 carbon atom separately.
7. as compound oil spilling round-up agent as described in any claim in claim 1 or 2, it is characterized in that described silicone compound nonionic surface active agent, have suc as formula structure shown in (V):
Wherein, R 1Be amino, hydroxyl or contain alkyl, haloalkyl, the thiazolinyl of 1～6 carbon atom; R 2Be hydrogen atom, amino, hydroxyl or contain alkyl, haloalkyl, the thiazolinyl of 1～6 carbon atom; R 3For phenyl or contain alkyl, the thiazolinyl of 1～4 carbon atom; Q is a hydrogen atom, hydroxyl or contain alkyl, the thiazolinyl of 1～4 carbon atom; W is hydrogen atom or the alkyl that contains 1～20 carbon atom; X=0～50, y=0～20, a=2～10, b=0～20, c=0～30; Described x, y, a, b, c are integer.
8. preparation method as compound oil spilling round-up agent as described in any claim in claim 1 or 2 is characterized in that it being input table surface-active agent in the reaction vessel, adds alcohol and water, reflux, and it is transparent evenly to be stirred to reaction solution; Be cooled to room temperature, obtain the agent of described compound oil spilling round-up.
9. preparation method as claimed in claim 8, the temperature that it is characterized in that described reflux is 50～70 ℃; Described churning time is 2～4 hours.
10. the application of any described compound oil spilling round-up of claim agent in crude oil or the processing of oil product oil spilling in the claim 1 or 2.
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012028031A1 (en) * 2010-08-31 2012-03-08 广东标美硅氟新材料有限公司 A compounded oil outflow round-up agent, a reocess for its production and its use
CN102912775A (en) * 2012-08-06 2013-02-06 中国石油大学(华东) Processing technique for efficiently removing ocean oil spill
WO2013097167A1 (en) * 2011-12-27 2013-07-04 广东标美硅氟新材料有限公司 Silicone surfactant, and preparation method and use thereof
CN107384320A (en) * 2017-09-08 2017-11-24 广州理文科技有限公司 Application of the sulfonic fluoropolymer type compound as collection finish
CN107384321A (en) * 2017-09-08 2017-11-24 广州理文科技有限公司 Application of the fluorine-containing carboxylic acid type betaine compound as collection finish

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113603719A (en) * 2021-08-16 2021-11-05 新乡医学院 Difluoroalkyl substituted sulfur phosphate compound and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4235743A (en) * 1977-09-30 1980-11-25 Exxon Research & Engineering Co. Composition and method for suppressing vapor loss of volatile hydrocarbons
CN1867407A (en) * 2003-10-17 2006-11-22 3M创新有限公司 Surfactant composition having stable hydrophilic character

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3810835A (en) * 1971-02-25 1974-05-14 Chevron Res Process for treating oil slicks using chemical agents
GB2011901B (en) * 1978-01-03 1982-08-25 Ciba Geigy Ag Perfluoroalkyl-thioethyl ether derivatives
US4764285A (en) * 1986-03-15 1988-08-16 Exxon Research And Engineering Company Oil spill microemulsion dispersants
CN1055299C (en) * 1995-10-27 2000-08-09 山东大学 Collecting oil agent composition
US6261463B1 (en) * 1999-03-04 2001-07-17 U.S. Polychemical Marine Corp. Water based oil dispersant
CN101914367B (en) * 2010-08-31 2013-05-22 广东标美硅氟新材料有限公司 Compound-type oil outflow round-up agent as well as preparation method and application thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4235743A (en) * 1977-09-30 1980-11-25 Exxon Research & Engineering Co. Composition and method for suppressing vapor loss of volatile hydrocarbons
CN1867407A (en) * 2003-10-17 2006-11-22 3M创新有限公司 Surfactant composition having stable hydrophilic character

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
牟建海等: "氟表面活性剂在石油和消防领域的应用", 《化工科技市场》, vol. 26, no. 2, 31 December 2003 (2003-12-31), pages 5 - 7 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012028031A1 (en) * 2010-08-31 2012-03-08 广东标美硅氟新材料有限公司 A compounded oil outflow round-up agent, a reocess for its production and its use
WO2013097167A1 (en) * 2011-12-27 2013-07-04 广东标美硅氟新材料有限公司 Silicone surfactant, and preparation method and use thereof
CN102912775A (en) * 2012-08-06 2013-02-06 中国石油大学(华东) Processing technique for efficiently removing ocean oil spill
CN102912775B (en) * 2012-08-06 2015-02-11 中国石油大学(华东) Processing technique for efficiently removing ocean oil spill
CN107384320A (en) * 2017-09-08 2017-11-24 广州理文科技有限公司 Application of the sulfonic fluoropolymer type compound as collection finish
CN107384321A (en) * 2017-09-08 2017-11-24 广州理文科技有限公司 Application of the fluorine-containing carboxylic acid type betaine compound as collection finish

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Inventor after: Huang Zhenhong

Inventor after: Huang Haiqing

Inventor after: Huang Xiaomei

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