CN101909583A - Water-in-oil type preparation for hiding pores - Google Patents

Water-in-oil type preparation for hiding pores Download PDF

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Publication number
CN101909583A
CN101909583A CN200880122854XA CN200880122854A CN101909583A CN 101909583 A CN101909583 A CN 101909583A CN 200880122854X A CN200880122854X A CN 200880122854XA CN 200880122854 A CN200880122854 A CN 200880122854A CN 101909583 A CN101909583 A CN 101909583A
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quality
powder
water
oil
glycylglycine
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CN101909583B (en
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石松孝之
高桥淳
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Shiseido Co Ltd
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Shiseido Co Ltd
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Dermatology (AREA)
  • Dispersion Chemistry (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)

Abstract

Provided is a water-in-oil type preparation for hiding pores, said preparation containing glycylglycine, which has a parakeratosis inhibiting action, in a stable state, and having having both an outstanding pore hiding effect and good usability. The preparation contains; (a) 0.001 to 20 mass % of glycylglycine, (b) 0.5 to 2.5 mass % of a crosslinked polyether modified organopolysiloxane polymer, (c) a powder and (d) 6 to 10 mass % ethanol, wherein the (c) powder is titanium dioxide or a composite powder with titanium dioxide as the core having an average particle diameter of 0.2 to 0.5 mu m, which may be hydrophobilized, and is included at a proportion of 0.5 to 1.5 mass% relative to the entire mass of the preparation.

Description

Water-in-oil type preparation for hiding pores
Technical field
The present invention relates to water-in-oil type preparation for hiding pores, in more detail, the present invention relates to keep pore skin on every side normal; Suppress highlighting of pore hole hole shape structure; And the water-in-oil type preparation for hiding pores that usability such as ductility, moistening is good.
Background technology
In recent years, with young woman the center particularly, the worry that highlights for pore increases, and expectation always is used to improve the cosmetics that this pore highlights.But,, utilize astringent lotion usually or remove keratotic plug and deal with pore and highlight because the mechanism that causes pore to highlight it be unclear that.Perhaps seek visual improvement with foundation cream mostly.
But, be example with the astringent lotion, its objective is the tension skin, it is by temporarily making skin surface temperature and descend or making protein coagulating realize acting on organic acid etc. with ethanol.Therefore the burden of skin is big, and can not solve the problem that pore highlights at all, and its effect is also unsatisfactory.
In addition, removing keratotic plug is will be blocked in the method that the keratotic plug in the pore is removed by physical method, for example known have utilize keratotic plug remover (for example referring to patent documentation 1), the cosmetics (for example referring to patent documentation 2) that contain the water-insoluble cyclodextrin contain macromolecular compound with salt forming group, contain the above viscosity of 50 quality % be the keratotic plug removal of 5mPa～80mPas/25 ℃ oil content apply some make up (for example referring to patent documentation 3) wait the method for removing keratotic plug.In the method for removing keratotic plug like this, physical property external force causes skin impaired sometimes, has the problem that skin is had side effect.In addition, its effect also is temporary transient, and pore becomes greatly on the contrary after may having generated keratotic plug soon again or having removed keratotic plug, and its effect is also not necessarily satisfactory.
The mechanism that highlights about pore, it is one of reason of highlighting of pore that the applicant has separated the caused parakeratosis of bright reason owing to sebum, therefore, by improving the parakeratosis of pore part, the area of identifiable pore will be reduced, thereby improve highlighting of pore, based on these understanding, the applicant has found a kind of parakeratosis inhibitor and shrinking pore agent (referring to patent documentation 4～6) of novelty.
Patent documentation 1: Japanese kokai publication hei 5-97627 communique
Patent documentation 2: Japanese kokai publication hei 5-105619 communique
Patent documentation 3: TOHKEMY 2002-241260 communique
Patent documentation 4: TOHKEMY 2004-2289 communique
Patent documentation 5: TOHKEMY 2005-179342 communique
Patent documentation 6: TOHKEMY 2005-179343 communique
Summary of the invention
For these situations, the inventor furthers investigate repeatedly, found that, to have the inhibiting glycylglycine of parakeratosis when making the water-in-oil type preparation with specific prescription, obtained stably to cooperate glycylglycine, had excellent pore covering effect and the good water-in-oil type preparation for hiding pores of usability, thereby finished the present invention.
The present invention relates to a kind of water-in-oil type preparation for hiding pores, it is characterized in that, it contains (a) glycylglycine of 0.001 quality %～20 quality %, 0.5 the polyether-modified organopolysiloxane polymer of (b) cross-linking type of quality %～2.5 quality %, (c) (d) ethanol of powder and 6 quality %～10 quality %, wherein, as (c) powder, with respect to the cosmetics total amount, the mean diameter that contains 0.5 quality %～1.5 quality % be 0.2 μ m～0.5 μ m through hydrophobization also handle can titanium dioxide or with also handle through hydrophobization can titanium dioxide be the composite granule of nuclear.
By the present invention, can make and stably be combined with glycylglycine; Has excellent pore covering effect; And the water-in-oil type preparation for hiding pores that usability such as ductility, moistening is also good.
The specific embodiment
Below the specific embodiment of the present invention is described.
((a) glycylglycine)
Among the present invention, glycylglycine is (a) composition, known its shown in following structural formula (1), have the parakeratosis inhibitory action.This glycylglycine is the crystallinity base, so when being used for preparation, water is neccessary composition, but when making usability good emulsifying preparation, exists low temperature to cause emulsifying to destroy and produces the shortcoming of low-temperature stability differences such as piece.Among the present invention,, can make the water-in-oil type preparation for hiding pores that is combined with glycylglycine and good stability by adopting specific prescription.
This glycylglycine cooperates 0.001 quality %～20 quality %, is preferably 1 quality %～3 quality % in the water-in-oil type preparation for hiding pores total amount.When the use level of glycylglycine was very few, the pore covering effect was insufficient; When the use level of glycylglycine is too much, bad stability.
(the polyether-modified organopolysiloxane polymer of (b) cross-linking type)
Among the present invention, the polyether-modified organopolysiloxane polymer of cross-linking type is (b) composition, and it is following such material.
The polyether-modified organopolysiloxane polymer of the cross-linking type that uses among the present invention (composition (b)) is with the polymer of composition shown in general formula (3) and/or the general formula (4) as neccessary composition in the combination of the organopolysiloxane shown in polyoxyalkylene shown in organic hydrogen containing siloxane shown in organic hydrogen containing siloxane shown in the following general formula (1) and/or the following general formula (2) and the general formula (3) and/or the general formula (4).
R 2aR 3bHcSiO (4-a-b-c)/2...(1)
In the formula (1), R 2Represent that carbon number of the same race or not of the same race is 1～18 nothing replaces or band replaces alkyl, aryl, aralkyl or halogenation alkyl, R 3Be general formula CtH2tO (C 2H 4O) d (C 3H 6O) eR 4[wherein, R 4Expression hydrogen atom or carbon number be 1～10 representative examples of saturated aliphatic alkyl or-(CO)-R 5Shown group, d are represented 2～200 integer, and e represents 0～200 integer, and d+e represents that 3～200 integer, t represent 2～6, R 5The expression carbon number is 1～5 representative examples of saturated aliphatic alkyl] shown in polyoxyalkylenes, a satisfies 1.0≤a≤2.5, b satisfies 0.001≤b≤1.0, c satisfies 0.001≤c≤1.0;
R 2fHgSiO (4-f-g)/2...(2)
In the formula (2), R 2Same as described above, f satisfies 1.0≤f≤3.0, and g satisfies 0.001≤g≤1.5;
C sH 2s-1O(C 2H 4O)h(C 3H 6O)iC sH 2s-1...(3)
In the formula (3), h represents 2～200 integer, and i represents 0～200 integer, and h+i represents 3～200 integer, and s represents 2～6;
R 2jR 6kSiO (4-j-k)/2...(4)
In the formula (4), R 2Same as described above, R 6The terminal carbon number with aliphatic unsaturated group of expression is 2～10 1 valency alkyl, and j satisfies 1.0≤j≤3.0, and k satisfies 0.001≤k≤1.5.
As the polyether-modified organopolysiloxane polymer of the cross-linking type that uses among the present invention, for example can enumerate KSG-210 (chemical industry society of SHIN-ETSU HANTOTAI makes, and contains the 6cs dimethyl silscone of have an appointment 25 quality % cross-linking type polyether modified silicone, about 75 quality %), KSG-240,310,320,330,340 (more than be chemical industry society of SHIN-ETSU HANTOTAI make), KSG-21 (the polyether-modified organopolysiloxane of cross-linking type is 22%～32%, methyl polysiloxane be 68%～78%) (manufacturing of chemical industry society of SHIN-ETSU HANTOTAI).These can be used singly or in combination.
The addition of the polyether-modified organopolysiloxane polymer of cross-linking type is 0.5 quality %～2.5 quality %, preferred 1 quality %～2 quality %.When the addition of the polyether-modified organopolysiloxane polymer of cross-linking type is less than 0.5 quality %, bad stability then; During greater than 2.5 quality %, then need firmly extend, usability is poor.
((c) powder)
The powder that the present invention uses contain mean diameter be 0.2 μ m～0.5 μ m through hydrophobization also handle can titanium dioxide or with also handle through hydrophobization can titanium dioxide be the composite granule (below be called the titanium oxide based powder) of nuclear, this titanium oxide based powder belongs to the pigment-level titanium oxide.
The titanium oxide based powder can directly use, and also can handle the back use by hydrophobization.In addition, can also carry out hydrophobization in the manufacturing process of cosmetics handles.Handle as hydrophobization, can enumerate the processing of fatty acid dextrin, silicone-treated, alkyl-modified silicone-treated, polydimethylsiloxane and handle, use the silicon dioxide covering handled through polydimethylsiloxane, fatty acid dextrin-titanium processing, fatty acid treatment etc., but be not limited to these.Specifically can enumerate the method powder handled with Dextrin palmitate, n-octyl triethoxysilane, handle the method that handle with 14 (carbon) alkene the back with tetramethyl-ring tetrasiloxane.
Among the present invention, preferred use is the composite granule of nuclear with the titanium dioxide of handling through hydrophobization.By titanium oxide based powder and glycylglycine are share, can improve the pore covering effect synergistically.
As preferred titanium oxide based powder, can enumerate OTS-2TRONOX R-KB-2 (through the mica titanium of n-octyl triethoxysilane processing, mean diameter 0.5 μ m, big east changes into industrial society and makes), EPI-WR-6 is (through 1,3,5, the mica titanium that the 7-tetramethyl-ring tetrasiloxane is handled, mean diameter 0.3 μ m～0.4 μ m, the Japan society that refines makes), Bayer titanium R-KB-1 (Titanium Dioxide Rutile Top grade, mean diameter 0.3 μ m～0.4 μ m, Bayer society makes) etc.
The addition of titanium oxide based powder is 0.5 quality %～1.5 quality %, is preferably 0.7 quality %～1 quality %.When the addition of titanium oxide based powder was very few, the pore covering effect was insufficient; In the time of too much, the usability variation.
Powder of the present invention also contains poly-methyl silsesquioxane lining cross-linking type silicone elastomer powder when preferably containing above-mentioned titanium oxide based powder.
Poly-methyl silsesquioxane lining cross-linking type silicone elastomer powder is the organic siliconresin lining silicone rubber powder that silicone rubber is obtained with the organic siliconresin lining, as commercially available product, can enumerate for example KSP100, KSP101, KSP105 (manufacturing of chemical industry society of SHIN-ETSU HANTOTAI) etc.
The addition of poly-methyl silsesquioxane lining cross-linking type silicone elastomer powder is preferably 6 quality %～10 quality %, more preferably 7 quality %～9 quality %.By adding poly-methyl silsesquioxane lining cross-linking type silicone elastomer powder, usability is improved.In addition, also have the light scattering effect that improves above-mentioned titanium oxide based powder, the effect that improves the pore covering effect.
Among the present invention,, except above-mentioned powder, can also contain other powder as (c) powder composition.
As described powder composition, for example can enumerate inorganic powder (for example Talcum, Kaolin, Muscovitum, silk Muscovitum (sericite), white mica, phlogopite, synthetic mica, rubellan, biotite, Vermiculitum, magnesium carbonate, calcium carbonate, aluminium silicate, barium silicate, calcium silicates, magnesium silicate, strontium silicate, wolframic acid slaine, magnesium, silicon dioxide, zeolite, barium sulfate, Gypsum Fibrosum preparata (bassanite), calcium phosphate, fluor-apatite, hydroxyapatite, ceramics, metallic soap (for example Grillocin P 176, calcium palmitate, calcium stearate, aluminium stearate), boron nitride etc.); Organic dust (for example polyamide powder (nylon powder), polyethylene powders, polymethyl methacrylate powder, polystyrene powder, styrene and acrylic acid copolymer resin powder, benzoguanamine resin powder, polytetrafluorethylepowder powder, cellulose powder etc.); Inorganic Chinese white (for example zinc oxide etc.); Inorganic red series pigments (for example ferrum oxide (iron oxide red), iron titanate etc.); Inorganic brown series pigments (for example, gamma-iron oxide etc.); Inorganic yellow series pigments (for example yellow ferric oxide, loess etc.); Inorganic black series pigments (for example Black Rouge etc.); Inorganic violet pigment (for example manganese violet, cobalt violet etc.); Inorganic green series pigments (for example chromium oxide, chromic oxide gel, cobalt titanate etc.); Inorganic blue series pigments (for example ultramarine, barba hispanica etc.); Pearl pigment (for example, Bismuth Oxychloride, guanin etc.); Metallic powdery pigment (for example aluminium powder, copper powder etc.); Zirconium, organic pigments such as barium or aluminum color lake (for example red No. 201, red No. 202, red No. 204, red No. 205, red No. 220, red No. 226, red No. 228, red No. 405, orange No. 203, orange No. 204, yellow No. 205, organic pigments such as yellow No. 401 and blue No. 404, red No. 3, red No. 104, red No. 106, red No. 227, red No. 230, red No. 401, red No. 505, orange No. 205, yellow No. 4, yellow No. 5, yellow No. 202, yellow No. 203, green No. 3 and blue No. 1 etc.); Natural pigment (for example chlorophyll, beta-carotene etc.) etc.The total addition level of powder composition is preferably 7 quality %～13 quality %.
((d) ethanol)
(d) ethanol that the present invention uses is set at specific addition, has kept the stability of system thus.Its addition is 6 quality %～10 quality %, is preferably 4 quality %～8 quality %.When alcoholic acid addition is very few, emulsifying takes place easily destroy bad stability.In addition, when alcoholic acid addition was too much, glycylglycine can be separated out, and in this case, stability is variation also.
((e) polyether modified silicone)
Among the present invention,, preferably when containing above-mentioned (b) composition, also contain (e) polyether modified silicone as emulsifying agent in order to improve stability.Need to prove that polyether modified silicone can have alkyl chain, side chain.
As polyether modified silicone, for example can enumerate KF-6028, KF-6017, KF-6019 (polyoxyethylene-methyl polysiloxane copolymer, the manufacturing of chemical industry society of SHIN-ETSU HANTOTAI), TS polymer 50-D5 (poly-(ethylene oxide-propylene oxide) methyl polysiloxane copolymer-decamethylcyclopentaandoxane solution, east Li Daokangningshe manufacturing), ABIL EM 90 (methyl polysiloxane-cetyl methyl polysiloxane-poly-(ethylene oxide-propylene oxide) methyl polysiloxane copolymer, DEGUSSA society makes), preferred especially KF-6028.
(e) addition of composition is preferably 0.01 quality %～5 quality %.
(oil content)
Water-in-oil type preparation for hiding pores of the present invention can also contain the oil content that comprises polar oil.
Wherein, as polar oil, can enumerate intramolecularly and have side chain; The oil content of hydroxyl, carboxyl, carbonyl isopolarity base.
Specifically can enumerate senior alcohols such as oleyl alcohol, iso stearyl alcohol; Senior fatty acid such as oleic acid, isostearic acid; Ester oil classes such as myristic acid isopropyl esters, Palmic acid isopropyl esters, didecyl acid propylene glycol ester, two capric acid DOPCP, myristic acid octyl group dodecyl ester, tricaprylin, glycerol triethyl group alkyl caproate (three 2 ethyl hexanoic acid glyceride), two isostearic acid polyglycerol esters, three isostearic acid polyglycerol esters, Palmic acid octyl group ester; Olive oil, Oleum Ricini, Jojoba oil, macadimia nut wet goods oils etc. can use in these materials one or more.
Among these, preferred especially ester oil, wherein, from improving the angle of stability, preferred isooctyl acid cetyl ester.
In addition, as the oil content beyond the polar oil,, can enumerate American Avocado Tree oil, Camellia oil, macadimia nut oil, ermine oil, olive oil, Oleum Ricini, Jojoba oil, triglycerin, tricaprylin etc. for example as liquid fat; As hydrocarbon, can enumerate liquid paraffin, squalane, alkane, ceresine, Squalene etc.; As higher fatty acids, can enumerate lauric acid, myristic acid, Palmic acid, stearic acid, behenic acid, oleic acid, 12-hydroxy stearic acid, isostearic acid, linoleic acid, linolenic acid etc.; As higher alcohol, can enumerate dodecyl alcohol, cetyl alcohol, stearyl alcohol, docosyl alcohol, oleyl alcohol, single stearyl glycerin ether, single palmityl glycerin ether, cholesterol, plant sterol, isooctadecanol etc.; As ester oil, can enumerate myristic acid isopropyl esters, sad cetyl ester, isooctyl acid cetyl ester, myristic acid octyl group dodecyl ester, stearic acid butyl ester, oleic acid decyl ester, Ethylene glycol dicaprylate, malic acid two iso stearyl esters, three sad trihydroxy methyl propyl ester, three isostearic acid trihydroxy methyl propyl ester, Pentaerythrityl tetraoctanoate, tricaprylin, three glyceryl isostearates, ethyl acetate, butyl acetate, pentyl acetate etc.; As silicone, can enumerate organic siliconresin, silicone rubber of dimethyl polysiloxane, methyl phenyl silicone, methyl hydrogen containing siloxane, decamethylcyclopentaandoxane, octamethylcy-clotetrasiloxane, formation tridimensional network etc.
In addition, can also contain pertroleum waxes such as hard paraffin, microwax; Mineral such as paraffin, ceresine are wax; Native paraffin such as Carnauba wax, candelilla wax; In wax.
These oil contents can be selected a kind of or two or more water-in-oil type preparation for hiding pores of the present invention that are used for arbitrarily.
The total addition level of oil content is advisable with 10 quality %～50 quality %.When being less than 10 quality %, bad stability; During greater than 50 quality %, the water of inner phase becomes very few, the usability variation.
In addition, consider that the ester oil of 3 quality %～20 quality % that preferably contains the cosmetics total amount is as oil content from stable aspect.
Water-in-oil type preparation for hiding pores of the present invention can use the composition that is generally used for cosmetics beyond the mentioned component according to purpose in the scope amount of not damaging effect of the present invention, matter, for example can add medicament beyond beauty treatment composition, the glycylglycines such as antiseptic, plant extracts such as polyhydric alcohol, chelating agen, inorganic salt, UV absorbent, water soluble polymer, P-hydroxybenzoic acid derivant, phenoxyethanol, spice etc.
As the polyhydric alcohol that is generally used for cosmetics based on adjusting purpose such as sense of touch, antiseptic, wetting agent, for example can enumerate propylene glycol, 1,3-butanediol, dipropylene glycol, Polyethylene Glycol, glycerol, diglycerol, poly-glycerine etc., these materials can use one or more in water-in-oil type preparation for hiding pores of the present invention.Water-in-oil type preparation for hiding pores of the present invention contains under the situation of these polyhydric alcohol, and the content of these polyhydric alcohol is preferably 1%～30%.
Form for water-in-oil type preparation for hiding pores of the present invention has no particular limits, from the angle of usability, and forms such as preferred emulsion shape, white shape, gel.In addition, the water-in-oil type preparation for hiding pores of the present invention pore that can use before makeup hides use in material, the beautifying liquid etc.
Embodiment
Enumerate embodiment below the present invention is described in more detail, but the present invention is not subjected to any restriction of these embodiment.If no special instructions, addition is represented with quality %.
Test example 1 (white shape beautifying liquid)
With the prescription shown in the following table 1,2, prepare white shape beautifying liquid by usual way, and measure pore covering effect, usability and stability by following method.Its result sums up and lists in table 1,2.
(1) assay method of pore covering effect
Special judge's (パ ネ Le) on skin, utilizes following standard to whether feeling that pore hides sense and estimates sample coating.
(evaluation criterion)
◎: feel that obviously pore hides sense.
Zero: feel that pore hides sense.
Zero △: feel that a little pore hides sense.
△: feel that few pore hides sense.
*: imperceptible pore hides sense.
(2) assay method of usability
Special judge on skin, utilizes following standard to whether feeling that wetness sensation, moisture feeling estimate sample coating.
(evaluation criterion)
Zero: feel wetness sensation, moisture feeling.
Zero △: feel wetness sensation, moisture feeling a little.
△: feel extremely slight wetness sensation, moisture feeling.
*: imperceptible wetness sensation, moisture feeling.
(3) Wen Dingxing assay method
With sample 50 ℃ place 1 month after, observe by outward appearance, utilize following standard, the separation of whether observing liquid phase (oil phase or water) is estimated.
(evaluation criterion)
Zero: do not see separation fully.
Zero △: do not see separation.
△: almost do not see separation.
*: the separation of liquid phase (oil phase or water) appears.
[table 1]
The test example 1 2 3 4 5 6 7 8 9 10 11 12
Ethanol - - 4 4 5 6 7 7 8 8 9 10
Dipropylene glycol 5 5 5 5 5 5 5 5 5 5 5 5
Glycerol 4 4 4 4 4 4 4 4 4 4 4 4
The polyether-modified organopolysiloxane polymer ※ 1 of cross-linking type 0.75 0.9 0.6 0.8 1 1.5 0.75 0.9 0.6 0.8 1 2
Prop up chain polyether modified silicone ※ 2 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9
The isooctyl acid cetyl ester 5 5 5 5 5 5 5 5 5 5 5 5
Decamethylcyclopentaandoxane 20 20 20 20 20 20 20 20 20 20 20 20
Dimethyl polysiloxane ※ 3 2 2 2 2 2 2 2 2 2 2 2 2
Glycylglycine - 1.6 1.6 1.6 1.6 1.6 1.6 1.6 1.6 1.6 1.6 1.6
The n-octyl triethoxysilane is handled mica titanium ※ 4 - - - 0.1 0.25 0.5 0.75 0.8 0.9 1 1.2 1.5
Poly-methyl silsesquioxane lining cross-linking type silicone elastomer powder ※ 5 8 8 8 8 8 8 8 8 8 8 8 8
EDTA-3Na.2H2O 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05
Sal 0.6 0.6 0.6 0.6 0.6 0.6 0.6 0.6 0.6 0.6 0.6 0.6
Phenoxyethanol 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4
Spice 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03
Water Surplus Surplus Surplus Surplus Surplus Surplus Surplus Surplus Surplus Surplus Surplus Surplus
The pore covering effect × × × △ △ ○△ ○ ◎ ◎ ◎ ○ ○
Usability × × △ △ △ ○ ○ ○ ○ ○△ △ △
Stability ○ × △ △ ○△ ○ ○ ○ ○ ○ ○ ○
[table 2]
The test example 13 14 15 16 17 18 19 20 21
Ethanol 8 8 7 7 7 7 7 7 7
Dipropylene glycol 5 5 5 5 5 5 5 5 5
Glycerol 4 4 4 4 4 4 4 4 4
The polyether-modified organopolysiloxane polymer ※ 1 of cross-linking type 0.5 4 0.75 0.9 0.6 0.8 0.75 0.9 0.6
Prop up chain polyether modified silicone ※ 2 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9
The isooctyl acid cetyl ester 5 5 5 5 5 5 5 5 5
Decamethylcyclopentaandoxane 20 20 15 20 20 20 20 20 20
Dimethyl polysiloxane ※ 3 2 2 2 2 2 2 2 2 2
Glycylglycine 1 2 - 1 5 2 2 2 2
The n-octyl triethoxysilane is handled mica titanium ※ 4 0.9 0.9 0.8 0.8 0.8 0.8 0.8 0.8 0.8
Poly-methyl silsesquioxane lining cross-linking type silicone elastomer powder ※ 5 8 8 8 8 8 1 3 5 10
?EDTA-3Na.2H2O 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05
Sal 0.6 0.6 0.6 0.6 0.6 0.6 0.6 0.6 0.6
Phenoxyethanol 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4
Spice 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03 0.03
Water Surplus Surplus Surplus Surplus Surplus Surplus Surplus Surplus Surplus
The pore covering effect ◎ ◎ ◎ ◎ ◎ △ ○△ ○ ◎
Usability ○ △ ○ ○ ○ ○ ○ ○ ○
Stability ○△ ○ × ○ ○ ○ ○ ○ △
※ 1:KSG-210 (chemical industry society of SHIN-ETSU HANTOTAI makes for the polyether-modified organopolysiloxane polymer of cross-linking type, about 25 quality % cross-linking type polyether modified silicone-Yue 75 quality %6cs dimethyl silscones)
※ 2:KF-6028 (polyoxyethylene-methyl polysiloxane copolymer, chemical industry society of SHIN-ETSU HANTOTAI makes)
※ 3:KF-96A-6T (dimethyl polysiloxane, chemical industry society of SHIN-ETSU HANTOTAI makes)
(the n-octyl triethoxysilane is handled mica titanium to ※ 4:OTS-2TRONOX R-KB-2, and big east changes into industrial society and makes mean diameter: 0.5 μ m)
※ 5:KSP100 (poly-methyl silsesquioxane lining cross-linking type silicone elastomer powder, chemical industry society of SHIN-ETSU HANTOTAI make)
In the table, though test example 15 does not add glycylglycine, its stability is also poor.Its reason is that the prerequisite of prescription of the present invention is the glycylglycine that adds poor stability in the common prescription, forms stabilizing formulation, so do not add under the situation of glycylglycine, balance has been destroyed, and stability is variation on the contrary.
Embodiment 1 emulsion form beautifying liquid
Composition addition (quality %)
(1) dimethyl polysiloxane 3.0
(2) the isooctyl acid cetyl ester 3.5
(3) decamethylcyclopentaandoxane 22.0
(4) glycerol 5.0
(5) dipropylene glycol 3.0
(6) the cross-linking type polyether modified silicone 1.2
(7) polyether modified silicone 0.4
(8) ethanol 8.0
(9) poly-methyl silsesquioxane lining cross-linking type silicone elastomer powder 9.0
(10) the n-octyl triethoxysilane is handled mica titanium 0.9
(11) phenoxyethanol 0.2
(12) menthol 0.01
(13)EDTA-3Na 0.01
(14) glycylglycine 2.0
(15) spice 0.05
(16) Purified Water surplus
Embodiment 2 emulsion form beautifying liquids
Composition addition (quality %)
(1) the phenyl methyl polysiloxanes 2.0
(2) Palmic acid octyl group ester 4.0
(3) decamethylcyclopentaandoxane 18.0
(4) glycerol 8.0
(5) 1,3 butylene glycol 7.0
(6) the cross-linking type polyether modified silicone 0.75
(7) polyether modified silicone 0.7
(8) ethanol 9.0
(9) poly-methyl silsesquioxane lining cross-linking type silicone elastomer powder 6.0
(10) the n-octyl triethoxysilane is handled mica titanium 1.0
(11) phenoxyethanol 0.2
(12) sodium carboxy methyl cellulose 0.2
(13) glycylglycine 1.0
(14) spice 0.07
(15) Purified Water surplus
Embodiment 3 emulsion form beautifying liquids
Composition addition (quality %)
(1) dimethyl polysiloxane 3.0
(2) glycerol triethyl group alkyl caproate 3.5
(3) decamethylcyclopentaandoxane 20.0
(4) glycerol 8.0
(5) dipropylene glycol 5.0
(6) Polyethylene Glycol-400 0.5
(7) the cross-linking type polyether modified silicone 0.9
(8) polyether modified silicone 0.8
(9) ethanol 8.0
(10) poly-methyl silsesquioxane lining cross-linking type silicone elastomer powder 5.0
(11) Titanium Dioxide Rutile Top grade 0.9
(12) phenoxyethanol 0.2
(13) xanthan gum 0.05
(14) sodium chloride 0.5
(15) glycylglycine 2.0
(16) spice 0.05
(17) Purified Water surplus
Embodiment 4 frosts
Composition addition (quality %)
(1) methyl phenyl silicone 3.0
(2) myristic acid octyl group dodecyl ester 3.5
(3) microwax 0.5
(4) decamethylcyclopentaandoxane 6.0
(5) 1,3 butylene glycol 3.0
(6) the cross-linking type polyether modified silicone 1.8
(7) polyether modified silicone 1.5
(8) Polyethylene Glycol-150 1.0
(9) ethanol 6.0
(10) poly-methyl silsesquioxane lining cross-linking type silicone elastomer powder 6.0
(11) tetramethyl-ring tetrasiloxane is handled mica titanium 0.5
(12) phenoxyethanol 0.4
(13) glycylglycine 5.0
(14) spice 0.1
(15) Purified Water surplus
Embodiment 5W/O type oil-in-water type foundation cream
Composition addition (quality %)
(1) dimethyl polysiloxane 10.0
(2) isostearic acid 3.0
(3) the cross-linking type polyether modified silicone 0.9
(4) polyether modified silicone 3.0
(5) propylene glycol 2.5
(6) ethanol 6.0
(7) Nipagin ester 0.1
(8) poly-methyl silsesquioxane lining cross-linking type silicone elastomer powder 6.0
(9) the n-octyl triethoxysilane is handled mica titanium 0.8
(10) the silicone-treated titanium oxide 2.5
(11) the silicone-treated Muscovitum 2.5
(12) the silicone-treated Talcum 1.5
(13) the silicone-treated ferrum oxide 4.5
(14) antioxidant 0.2
(15) glycylglycine 3.0
(16) spice 0.05
(17) Purified Water surplus
Embodiment 6UV interleaving agent
Composition addition (quality %)
(1) methyl phenyl silicone 2.0
(2) decamethylcyclopentaandoxane 25.0
(3) the isooctyl acid cetyl ester 4.0
(4) glycerol 4.0
(5) 1,3 butylene glycol 0.5
(6) the cross-linking type polyether modified silicone 1.5
(7) polyether modified silicone 0.1
(8) ethanol 9.0
(9) poly-methyl silsesquioxane lining cross-linking type silicone elastomer powder 10.0
(10) the n-octyl triethoxysilane is handled mica titanium 1.5
(11) particulate titanium dioxide 5.0
(11) p-methoxycinnamic acid octyl group ester 5.0
(12) glycylglycine 1.0
(13) spice 0.1
(14) Purified Water surplus
Utilizability on the industry
By the present invention, can provide stably to cooperate pore covering effect and the good water-in-oil type preparation for hiding pores of usability that has the inhibiting glycylglycine of parakeratosis, has excellence.

Claims (4)

1. a water-in-oil type preparation for hiding pores is characterized in that, described cosmetics contain:
0.001 (a) glycylglycine of quality %～20.0 quality %,
0.5 the polyether-modified organopolysiloxane polymer of (b) cross-linking type of quality %～2.5 quality %,
(c) powder and
(d) ethanol of 6 quality %～10 quality %,
Wherein, as (c) powder, the mean diameter that described cosmetics contain the 0.5 quality %～1.5 quality % of cosmetics total amount is the titanium dioxide of handling or handling without hydrophobization through hydrophobization of 0.2 μ m～0.5 μ m; Or be the composite granule of nuclear with the titanium dioxide of handling through hydrophobization or handling without hydrophobization.
2. water-in-oil type preparation for hiding pores as claimed in claim 1 is characterized in that, as (c) powder, described cosmetics also contain poly-methyl silsesquioxane lining cross-linking type silicone elastomer powder.
3. water-in-oil type preparation for hiding pores as claimed in claim 1 is characterized in that, as oil content, described cosmetics contain the ester oil of the 3 quality %～10 quality % of cosmetics total amount.
4. water-in-oil type preparation for hiding pores as claimed in claim 1 is characterized in that, it also contains (e) polyether modified silicone of 0.01 quality %～5 quality %.
CN200880122854XA 2007-12-27 2008-12-09 Water-in-oil type preparation for hiding pores Active CN101909583B (en)

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JP2007-335813 2007-12-27
JP2007335813A JP2009155274A (en) 2007-12-27 2007-12-27 Water-in-oil type cosmetic for pore-masking use
PCT/JP2008/003668 WO2009084156A1 (en) 2007-12-27 2008-12-09 Water-in-oil type preparation for hiding pores

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Cited By (1)

* Cited by examiner, † Cited by third party
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CN105963159A (en) * 2015-03-13 2016-09-28 信越化学工业株式会社 Gel paste composition and cosmetic using the gel paste composition

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010063762A (en) * 2008-09-12 2010-03-25 Yoshiharu Masui Antibacterial deodorant
JP2013043847A (en) * 2011-08-23 2013-03-04 Kao Corp Water-in-oil emulsified cosmetic
JP6262995B2 (en) * 2013-10-31 2018-01-17 株式会社コーセー Unevenness correction cosmetic
KR102526135B1 (en) * 2015-01-30 2023-04-26 주식회사 엘지생활건강 Make-up cosmetic composition having immediate effect
JP6708371B2 (en) * 2015-05-29 2020-06-10 花王株式会社 Water-in-oil emulsion cosmetic
JP6923338B2 (en) * 2016-03-31 2021-08-18 株式会社コーセー Water-in-oil emulsified cosmetics
WO2018221174A1 (en) * 2017-05-30 2018-12-06 信越化学工業株式会社 Water-breaking cosmetic material
WO2019004048A1 (en) * 2017-06-29 2019-01-03 信越化学工業株式会社 Water break-type sunscreen cosmetic product
US11166888B2 (en) 2017-08-31 2021-11-09 Shiseido Company, Ltd. Water-in-oil emulsion cosmetic
JP7108127B2 (en) 2018-08-21 2022-07-27 ザ プロクター アンド ギャンブル カンパニー How to identify pore color
KR20220156034A (en) 2020-05-08 2022-11-24 더 프록터 앤드 갬블 캄파니 How to identify dendritic pores
JP2023175309A (en) * 2022-05-30 2023-12-12 日信化学工業株式会社 Cellulose-siloxane composite particles, method for producing the same, and cosmetic
CN115487100A (en) * 2022-09-23 2022-12-20 诺斯贝尔化妆品股份有限公司 Cosmetic composition and cosmetic with effects of controlling oil and refining pores

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003113033A (en) * 2001-09-28 2003-04-18 Kose Corp Water-in-oil type cosmetic
JP2003226615A (en) * 2002-01-31 2003-08-12 Kose Corp Water-in-oil emulsified cosmetic
JP2003238356A (en) * 2002-02-15 2003-08-27 Kose Corp Cosmetic
JP3821785B2 (en) * 2002-05-14 2006-09-13 株式会社コーセー Water-containing powder cosmetic
JP2004269362A (en) * 2003-03-05 2004-09-30 Kose Corp Cosmetic
MXPA05013590A (en) * 2003-06-19 2006-03-09 Procter & Gamble Polyol-in-silicone emulsions.
JP4073389B2 (en) * 2003-10-31 2008-04-09 株式会社資生堂 Water-in-oil emulsion composition
KR101165288B1 (en) * 2003-11-27 2012-07-19 가부시키가이샤 시세이도 Parakeratosis inhibitor
JP5241058B2 (en) * 2003-11-27 2013-07-17 株式会社 資生堂 Keratinization inhibitor and pore-reducing agent
JP2006001918A (en) * 2004-06-17 2006-01-05 Kanebo Cosmetics Inc Water-in-oil type emulsion cosmetic
JP4993983B2 (en) * 2005-09-28 2012-08-08 信越化学工業株式会社 Organopolysiloxane surface treatment agent system, powder surface-treated with the treatment agent system, and cosmetics containing the powder

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105963159A (en) * 2015-03-13 2016-09-28 信越化学工业株式会社 Gel paste composition and cosmetic using the gel paste composition
US11020327B2 (en) 2015-03-13 2021-06-01 Shin-Etsu Chemical Co., Ltd. Gel paste composition and cosmetic using the gel paste composition

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CN101909583B (en) 2012-11-14
JP2009155274A (en) 2009-07-16
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KR20100100902A (en) 2010-09-15
HK1145637A1 (en) 2011-04-29
WO2009084156A1 (en) 2009-07-09

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