CN101908533A - Bilaterally displayed OLED (Organic Light-emitting Device) and preparation method thereof - Google Patents
Bilaterally displayed OLED (Organic Light-emitting Device) and preparation method thereof Download PDFInfo
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- CN101908533A CN101908533A CN2009100849826A CN200910084982A CN101908533A CN 101908533 A CN101908533 A CN 101908533A CN 2009100849826 A CN2009100849826 A CN 2009100849826A CN 200910084982 A CN200910084982 A CN 200910084982A CN 101908533 A CN101908533 A CN 101908533A
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/10—OLED displays
- H10K59/12—Active-matrix OLED [AMOLED] displays
- H10K59/128—Active-matrix OLED [AMOLED] displays comprising two independent displays, e.g. for emitting information from two major sides of the display
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K59/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
- H10K59/80—Constructional details
- H10K59/87—Passivation; Containers; Encapsulations
- H10K59/873—Encapsulations
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K71/00—Manufacture or treatment specially adapted for the organic devices covered by this subclass
- H10K71/50—Forming devices by joining two substrates together, e.g. lamination techniques
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Electroluminescent Light Sources (AREA)
Abstract
The invention relates to a bilaterally displayed OLED (Organic Light-emitting Device) and a preparation method thereof. The bilaterally displayed OLED comprises a first substrate, a second substrate and a packaging piece, wherein a first OLED is arranged on the first substrate; the second substrate is arranged opposite to the first substrate, and a second OLED is arranged on the second substrate; and the packaging piece is positioned between the first OLED and the second OLED and respectively bonded with the first substrate and the second substrate through packaging glue. The bilaterally displayed OLED of the invention has the characteristics that two light-emitting surfaces can carry out completely independent light-emitting display and can not interact.
Description
Technical field
The present invention relates to field of optoelectronic devices, relate in particular to OLED device of a kind of double-sided display and preparation method thereof.
Technical background
Organic electroluminescence device (OLED) has lot of advantages and possesses extremely strong competitiveness as a kind of new display spare and existing main flat-panel monitor liquid crystalline phase ratio.The general structure of organic electroluminescence device comprises successively: matrix, anode, organic layer, negative electrode, organic function layer comprises emission layer (EML) again, can also comprise hole injection layer (HIL) and/or hole transmission layer (HTL) between anode and emission layer, and electron transfer layer between emission layer and negative electrode (ETL) and/or electron injecting layer (EIL), can also comprise hole blocking layer (HBL) between emission layer and electron transfer layer etc.
Present OLED product substantially all is to be used for common light emitting display, realizes that by drive independence is luminous if OLED can satisfy the two sides simultaneously, then can improve the practical value of OLED display products greatly.
In the prior art, be two luminous components of preparation on same device substrate as CN200610004422.1, CN200610036679.5, luminous to different directions respectively; As CN200510022930.8, CN200510052900.1 then is to prepare two OLED devices respectively in the both sides of same device substrate, and the direction outside substrate is luminous separately; All be to adopt the polarized material realization luminous also just like CN1589075, CN1575073.
More than these patents substantially all realized the OLED that preparation has the double-side function to a certain extent, but these products or structure are too thick and heavy, perhaps preparation technology is quite complicated, thereby cost is higher.
Therefore, research and develop and a kind ofly can realize the double-side function, the New O LED device that does not increase preparation cost again has very big meaning.
Technology contents
The objective of the invention is to overcome the defective of above-mentioned prior art, a kind of OLED device that can realize double-sided display is provided, provide simultaneously that a kind of cost is low, the simple preparation method of technology.
For achieving the above object, technical scheme of the present invention is:
A kind of double side display organic electroluminescence light emitting device comprises: one first substrate, and first organic electroluminescence device is arranged on this first substrate; One second substrate is oppositely arranged with first substrate, and second organic electroluminescence device is arranged on this second substrate; A case chip, between above-mentioned two organic electroluminescence devices, and bonding respectively by packaging plastic and above-mentioned two substrates.
Above-mentioned first organic electroluminescence device and second organic electroluminescence device are respectively by two driving device controls.
Above-mentioned case chip can all be provided with groove on relative with two organic electroluminescence devices respectively face, be placed with drier in the groove.
Perhaps above-mentioned case chip also can be provided with at least one groove on the face relative with first organic electroluminescence device, be placed with drier in the groove, and case chip is provided with at least one hole.
Above-mentioned first substrate of the present invention and second substrate are transparent, and case chip is transparent or opaque.
First organic electroluminescence device of the present invention is as the light source display device, and second organic electroluminescence device is as matrix display spare.
Two organic electroluminescence devices perhaps of the present invention are all as the light source display device.Two organic electroluminescence devices perhaps of the present invention are all as matrix display spare.
The present invention also proposes a kind of preparation method of double side display organic electroluminescence light emitting device, comprises that step is as follows:
One first substrate is provided, first organic electroluminescence device is prepared on first substrate; Case chip is prepared on first substrate to encapsulate first organic electroluminescence device by the packaging plastic bonding; One second substrate is provided, second organic electroluminescence device is prepared on second substrate; Assemble this first substrate and second substrate, the another side of case chip is bonding to encapsulate second organic electroluminescence device by the packaging plastic and second substrate.
The beneficial effect of double-side display device of the present invention is:
(1) two light-emitting area can independent fully luminous demonstration, not influence mutually.
The performance index of (2) two light-emitting area devices (brightness, efficient, life-span etc.) are in full accord with the single face individual devices.
Description of drawings
Fig. 1 is the device architecture schematic diagram of embodiment 1;
Fig. 2 is the device architecture schematic diagram of embodiment 2;
Detailed description of main elements:
11 is that first substrate, 12 is that first organic electroluminescence device, 13 is that first drier, 14 is the first contact conductor district; 21 is that second substrate, 22 is that second organic electroluminescence device, 23 is that second drier, 24 is the second contact conductor district; 30 is that case chip, 31 is that packaging plastic, 32 is the hole on the case chip.
Embodiment
Double-sided display OLED device of the present invention adopts two organic electroluminescence devices to be prepared from.
Substrate can be glass or flexible substrate, and flexible substrate adopts a kind of material in polyesters, the polyimides compounds; First electrode layer (anode layer) of organic electroluminescence device, can adopt inorganic material or organic conductive polymer, inorganic material is generally the higher metals of work function such as metal oxides such as ITO, zinc oxide, zinc tin oxide or gold, copper, silver, the optimized ITO that is chosen as, organic conductive polymer are preferably polythiophene/polyvinylbenzenesulfonic acid sodium (hereinafter to be referred as PEDOT: PSS), a kind of material in the polyaniline (hereinafter to be referred as PANI); The second electrode lay (cathode layer, metal level), the general alloy that adopts the lower metal of work functions such as lithium, magnesium, calcium, strontium, aluminium, indium or they and copper, gold, silver, or the electrode layer that alternately forms of metal and metal fluoride, the present invention is preferably Mg:Ag alloy-layer, Ag layer and LiF layer successively, Al layer successively.
Organic light emitting medium mainly includes organic electroluminescent layer (EML), the general small molecule material that adopts, can be fluorescent material, as metal organic complex (as Alq3, Gaq3, Al (Saph-q) or Ga (Saph-q)) compounds, can be doped with dyestuff in this small molecule material, doping content is the 0.01wt%~20wt% of small molecule material, dyestuff is generally aromatic condensed ring class (as rubrene), Coumarins is (as DMQA, C545T) or two pyrans class (as DCJTB, DCM) a kind of material in the compound, perhaps be that anthracene derivative (as ADN) perylene analog derivative is (as 2,5,8, uncle 11-4-Ding Ji perylene (TBPe)) the luminescent layer material also can adopt carbazole derivates as 4,4 '-N, N '-two carbazoles-biphenyl (CBP), polyvinylcarbazole (PVK), but Doping Phosphorus photoinitiator dye in this material are as three (2-phenylpyridine) iridium (Ir (ppy) 3), two (2-phenylpyridine) (acetylacetone,2,4-pentanedione) iridium (Ir (ppy) 2 (acac)), octaethylporphyrin platinum (PtOEP) etc.;
Can also comprise electron transfer layer, hole injection layer and hole transmission layer in the above-mentioned device architecture, electron transfer layer (ETL) adopts oxine aluminium (Alq3) usually; The host material of hole injection layer (HIL) can adopt copper phthalocyanine (CuPc), 4,4 ' 4 " (N-3-aminomethyl phenyl-N-phenyl-amino)-triphenylamine (m-MTDATA), 4-three, 4 ' 4 "-three (N-2-naphthyl-N-phenyl-amino)-triphenylamines (2-TNATA); The host material of hole transmission layer (HTL) can adopt the low molecular material of the arylamine class and the branch polymer same clan, is preferably N, N '-two-(1-naphthyl)-N, N '-diphenyl-1,1 '-xenyl-4,4 '-diamines (NPB);
The present invention is further detailed explanation below in conjunction with the drawings and specific embodiments.
Embodiment 1:
In conjunction with Fig. 1 is the structural representation of present embodiment 1, and double side display organic electroluminescence light emitting device comprises that first substrate 11, first organic electroluminescence device 12 are arranged on this first substrate; Second substrate 21, second organic electroluminescence device 22 are arranged on this first substrate; The packaging plastic 31 that case chip 30 and being used for bonds case chip respectively with first substrate and second substrate respectively, in the face relative of case chip, all be provided with groove, in groove, place first drier 13 and second drier 23 respectively with two organic electroluminescence devices.
The material of first substrate 11 and second substrate 21 can be light transmission good glass or plastic material.
It is micromolecule light-emitting diode (OLED) or based on the polymer LED (PLED) of polymer that first organic electroluminescence device 12 and second organic electroluminescence device 22 can independently be selected for use respectively, and the lighting function material in two luminescent devices can independently be selected for use to fluorescent material respectively or be phosphor material.
Picture that first organic electroluminescence device 12 is shown and information can be similar and different in second organic electroluminescence device 22 shown picture or information.
First organic electroluminescence device 12 can be used as the light source display device, and second organic electroluminescence device 22 is as matrix display spare simultaneously.Two organic electroluminescence devices also can be used as the light source display device simultaneously.Two organic electroluminescence devices also can be used as matrix display spare simultaneously.
First organic electroluminescence device 12 and second organic electroluminescence device 22 can all adopt the passive type driving method.Two organic electroluminescence devices also can adopt active formula driving method simultaneously.Perhaps two organic electroluminescence devices adopt active formula and passive type driving method respectively.
The preparation method of double side display organic electroluminescence light emitting device of the present invention as shown in Figure 1 is as follows: one first substrate 11 is provided, first organic electroluminescence device 12 is prepared on first substrate 11; Then first drier 13 is placed in the groove of case chip 30, by packaging plastic 31 case chip 30 bondings is prepared on first substrate 11 again, to reach the purpose of encapsulation first organic electroluminescence device 12.
One second substrate 21 then is provided, second organic electroluminescence device 22 is prepared on second substrate 21;
Assemble this first substrate 11 and second substrate 21 at last: second drier 23 is placed in the groove of another side (that promptly relative face) of case chip 30 with second substrate, again that the another side of case chip 30 is bonding by the packaging plastic 31 and second substrate 21, to encapsulate second organic electroluminescence device 22.
First organic electroluminescence device is a blue-light device, and the organic material of its device architecture and employing is:
ITO/m-MTDATA(100nm)/NPB(20nm)/ADN:TBPe(20nm:3%)/Alq
3(50nm)/LiF(0.5nm)/Al(150nm)
With the ITO electro-conductive glass substrate of the good special pattern of etching as substrate, substrate is placed on the deionized water for ultrasonic ripple that contains cleaning fluid to be cleaned, the washing lotion temperature is about 60 ℃, the substrate that will clean with infrared roasting lamp is dried then, put into evaporation chamber evaporation hole injection layer, hole transmission layer, luminescent layer, electron transfer layer and cathode construction successively, evaporate process middle chamber pressure is lower than 5.0 * 10-3Pa.
In the present embodiment, at first the m-MTDATA of evaporation 100nm is as hole injection layer for organic layer, and the thick NPB of 40nm is as hole transmission layer; ADN that the method evaporation 20nm that steams altogether with double source is thick and TBPe are as luminescent layer, and the ratio of through-rate control TBPe in ADN is 3%; The Alq of evaporation 50nm
3As electron transfer layer; The LiF of evaporation 0.5nm as the Al of electron injecting layer and 150nm as negative electrode.
Second organic electroluminescence device is the ruddiness device, and the organic material of its device architecture and employing is:
ITO/m-MTDATA(100nm)/NPB(20nm)/Alq
3:Ir(piq)
2(acac)(10nm:5%)/Alq
3(50nm)/LiF(0.5nm)/Al(150nm)
The second preparation of devices method is identical with first device.
The Organnic electroluminescent device of the double-sided display that last present embodiment is prepared, one of them light-emitting area is shown as blueness, and another light-emitting area is shown in red.
Embodiment 2:
In conjunction with Fig. 2 is the structural representation of present embodiment 2, and double side display organic electroluminescence light emitting device comprises that first substrate 11, first organic electroluminescence device 12 are arranged on this first substrate; Second substrate 21, second organic electroluminescence device 22 are arranged on this first substrate; The packaging plastic 31 that case chip 30 and being used for bonds case chip respectively with first substrate and second substrate respectively.
The difference of present embodiment and embodiment 1 is, all is provided with two grooves in the case chip face relative with first organic electroluminescence device, places two first drier 13 in groove respectively.Case chip is provided with hole 32, makes the gas that is sealed in second organic electroluminescence device can enter first organic electroluminescence device, even the drier of winning can be shared by two organic electroluminescence devices simultaneously.
The preparation method of double side display organic electroluminescence light emitting device of the present invention as shown in Figure 2 is basic identical with embodiment 1, difference is: when adopting case chip 30 encapsulation first organic electroluminescence device 12, need in two grooves of case chip 30, place two first drier 13, when adopting case chip 30 encapsulation second organic electroluminescence device 22, need not to place drier.
In sum; though the present invention discloses preferred embodiment as above; but can not be in order to as limitation of the invention; those skilled in the art without departing from the spirit and scope of the present invention; any change and the modification made all should be considered as not exceeding the scope that claims of the present invention are protected.
Claims (9)
1. double side display organic electroluminescence light emitting device comprises:
One first substrate, first organic electroluminescence device is arranged on this first substrate;
One second substrate is oppositely arranged with first substrate, and second organic electroluminescence device is arranged on this second substrate;
A case chip, between above-mentioned two organic electroluminescence devices, and bonding respectively by packaging plastic and above-mentioned two substrates.
2. device according to claim 1 is characterized in that, described first organic electroluminescence device and second organic electroluminescence device are respectively by two driving device controls.
3. device according to claim 1 and 2 is characterized in that, described case chip all is provided with groove on relative with two organic electroluminescence devices respectively face, be placed with drier in the groove.
4. device according to claim 1 and 2 is characterized in that, described case chip is provided with at least one groove on the face relative with first organic electroluminescence device, be placed with drier in the groove, and case chip is provided with at least one hole.
5. device according to claim 1 and 2 is characterized in that, described first substrate and second substrate all adopt transparent material, and case chip is transparent or opaque material.
6. device according to claim 1 and 2 is characterized in that, described first organic electroluminescence device is as the light source display device, and second organic electroluminescence device is as matrix display spare.
7. device according to claim 1 and 2 is characterized in that, described two organic electroluminescence devices are all as the light source display device.
8. device according to claim 1 and 2 is characterized in that, described two organic electroluminescence devices are all as matrix display spare.
9. the preparation method of a double side display organic electroluminescence light emitting device comprises that step is as follows:
One first substrate is provided, first organic electroluminescence device is prepared on first substrate;
Case chip is prepared on first substrate to encapsulate first organic electroluminescence device by the packaging plastic bonding;
One second substrate is provided, second organic electroluminescence device is prepared on second substrate;
Assemble this first substrate and second substrate, the another side of case chip is bonding to encapsulate second organic electroluminescence device by the packaging plastic and second substrate.
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CN102185109A (en) * | 2011-04-06 | 2011-09-14 | 中国科学院微电子研究所 | Preparation method of organic multilayer film |
WO2014059603A1 (en) * | 2012-10-16 | 2014-04-24 | 深圳市柔宇科技有限公司 | Double-sided display screen and manufacturing method therefor |
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CN102185109A (en) * | 2011-04-06 | 2011-09-14 | 中国科学院微电子研究所 | Preparation method of organic multilayer film |
WO2014059603A1 (en) * | 2012-10-16 | 2014-04-24 | 深圳市柔宇科技有限公司 | Double-sided display screen and manufacturing method therefor |
CN106206667A (en) * | 2016-08-30 | 2016-12-07 | 武汉华星光电技术有限公司 | Double-sided OLED display and method for packing thereof |
WO2018040235A1 (en) * | 2016-08-30 | 2018-03-08 | 武汉华星光电技术有限公司 | Double-sided oled display and encapsulation method therefor |
US10147781B2 (en) | 2016-08-30 | 2018-12-04 | Wuhan China Star Optoelectronics Technology Co., Ltd. | Dual-sided OLED display and package method thereof |
CN106641897A (en) * | 2017-02-27 | 2017-05-10 | 江苏集萃有机光电技术研究所有限公司 | OLED (Organic Light-Emitting Diode) light source and lamp |
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