CN101906735A - Aqueous gloss oil for beer cartons and preparation method thereof - Google Patents
Aqueous gloss oil for beer cartons and preparation method thereof Download PDFInfo
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- CN101906735A CN101906735A CN 201010219564 CN201010219564A CN101906735A CN 101906735 A CN101906735 A CN 101906735A CN 201010219564 CN201010219564 CN 201010219564 CN 201010219564 A CN201010219564 A CN 201010219564A CN 101906735 A CN101906735 A CN 101906735A
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- gloss oil
- beer
- aqueous gloss
- beer cartons
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Abstract
The invention discloses aqueous gloss oil for beer cartons, which is prepared from the following raw materials in percentage by mass: 70%-80% of modified styrene-acrylate emulsions, 10%-20% of styrene-acrylate emulsions, 2%-6% of wear-resistant wax slurry, 0.1%-0.3% of defoamers, 0.1%-0.3% of preservatives and 3%-5% of isopropyl alcohol. The preparation method comprises the following steps of: firstly adding the modified styrene-acrylate emulsions at normal temperature, and then slowly and sequentially adding the defoamers, the styrene-acrylate emulsions, the wear-resistant wax slurry, the preservatives and the isopropyl alcohol when stirring; after adding various raw materials, stirring for 10 minutes at the rotary speed of 500-1000 revolutions/minute to uniformly disperse various raw materials in the system for obtaining the aqueous gloss oil for the beer cartons. The aqueous gloss oil has the advantages of high skid resistance, wear resistance, adhesion resistance, wet-adhesion resistance and waterproofing performance, is suitable for the glossing of the beer cartons and has a good protection action on the beer cartons.
Description
Technical field
The invention belongs to a kind of water-based gloss oil, be specifically related to a kind of aqueous gloss oil for beer cartons and preparation method thereof.
Background technology
In recent years, China's beer industry development presents powerful ascendant trend, and the demand of beer cartons also increases.The beer cartons surface often needs to be coated with the last layer water-based gloss oil, and therefore the performance to gloss oil has proposed strict specification requirement.Certain pressure is arranged in the beer bottle, be easy to bottle explosion, so in stock was stacked and transported, must guarantee had enough frictions between the carton, slippage between the beer case that prevents to pile up causes beer case to tilt, fall down, collide, and causes the beer bottle explosion.Water-based gloss oil is coated the beer cartons surface, and this just requires gloss oil to have high non-skid property.Beer cartons is had relatively high expectations to the pattern on carton surface, and the printing ink that crocking resistance is low fades can be very serious, requires gloss oil to have very high abrasion resistance, and the pattern on protection carton surface is not fragile.Beer is in the process of stock or transportation, and the case number of stacking is many, under the situation of high temperature, notice preventing that carton and carton from sticking together, so gloss oil will possess high resistance to blocking.Simultaneously, case dress beer can be formed droplet on the surface of carton from the air that refrigerating chamber comes out to run into heat, and the gloss oil on carton surface is easy to be dissolved in the water, makes easily to be deposited in together that carton bonds, therefore the printing effect on infringement carton surface requires gloss oil to possess high moisture-resistant viscosity energy.The gloss oil performance technologies requirement that beer cartons is used is difficult to reach for its performance of general water-based gloss oil.In view of this, the inventor is on the basis based on a series of research and test, develop a kind of aqueous gloss oil for beer cartons, make its performance satisfy high anti-skidding, wear-resistant, anti-stick company, sticking, the waterproof requirement of moisture-resistant simultaneously, solved the contradictory problems of anti-skidding and wear-resistant, waterproof and anti-stick company, this case is produced thus.
Summary of the invention
The object of the present invention is to provide a kind of aqueous gloss oil for beer cartons and preparation method thereof water; this water-based gloss oil possesses high anti-skidding, wear-resistant, anti-stick company, sticking, the water resistance of moisture-resistant; be applicable to the glazing of beer cartons, beer cartons is played a very good protection.
To achieve these goals, the objective of the invention is to realize by the following technical solutions:
A kind of aqueous gloss oil for beer cartons, make by following raw material raw material by mass percentage:
Modified phenylethylene-acrylic acid ester emulsion 70～80%;
Cinnamic acrylic ester emulsion 10～20%;
Wear-resistant wax slurry 2～6%;
Defoamer 0.1～0.3%;
Preservative agent 0.1～0.3%;
Isopropyl alcohol 3～5%;
The mass percent sum of above raw material equals 100%.
Described modified phenylethylene-acrylic acid ester emulsion be a kind of Tg value (glass transition temperature) for-10 ℃, high heat-resisting be 180 ℃ emulsion, have good filming performance.
Described cinnamic acrylic ester emulsion is that a kind of Tg value is 95 ℃, not the emulsion of film forming.
Described wear-resistant wax slurry is modified polyethylene wax, and its solid content is 50%.
Described defoamer is the silanes defoamer.
Described preservative agent is water-based chloromethyl/methylisothiazolinone (CMI/MI) mixture preservative agent.
The preparation method of this water-based gloss oil: at normal temperatures, add modified phenylethylene-acrylic acid ester emulsion earlier, stirring (rotating speed is 500～1000 rev/mins) limit in limit adds defoamer, cinnamic acrylic ester emulsion, wear-resistant wax slurry, preservative agent, isopropyl alcohol lentamente successively then, after adding various raw materials, be to stir ten minutes under 500～1000 rev/mins the state at rotating speed, the various raw materials of system are uniformly dispersed, promptly obtain a kind of aqueous gloss oil for beer cartons.
After adopting such scheme; the gloss oil of the present invention's preparation has high skid resistance, wear resistence, resistance to blocking, moisture-resistant viscosity and water resistance, reaches the specification requirement of beer cartons with gloss oil; be applicable to the glazing of beer cartons, beer cartons is played a very good protection.
The specific embodiment
Embodiment 1
(1) the water-based gloss oil prescription one
Modified phenylethylene-acrylic acid ester emulsion 80%;
Silanes defoamer 0.1%;
Cinnamic acrylic ester emulsion 10%;
Modified polyethylene wax 4%;
Water-based chloromethyl/methylisothiazolinone (CMI/MI) mixture preservative agent 0.1%;
Isopropyl alcohol 5.8%.
The mass percent sum of above raw material equals 100%.
(2) preparation method
At normal temperatures, add modified phenylethylene-acrylic acid ester emulsion earlier, stirring (rotating speed is 500～1000 rev/mins) limit in limit adds silanes defoamer, cinnamic acrylic ester emulsion, modified polyethylene wax, water-based chloromethyl/methylisothiazolinone (CMI/MI) mixture preservative agent, isopropyl alcohol lentamente successively then.After adding various raw materials, be to stir ten minutes under 500～1000 rev/mins the state at rotating speed, make the various dispersion of materials of system even, promptly obtain the water-based gloss oil that a kind of beer cartons is used.
Embodiment 2
(1), the water-based gloss oil prescription two
Modified phenylethylene-acrylic acid ester emulsion 70%;
Silanes defoamer 0.1%;
Cinnamic acrylic ester emulsion 20%;
Modified polyethylene wax 5%;
Water-based chloromethyl/methylisothiazolinone (CMI/MI) mixture preservative agent 0.1%;
Isopropyl alcohol 4.8%.
The mass percent sum of above raw material equals 100%.
(2) preparation method is identical with embodiment 1, so do not give unnecessary details.
The application implementation explanation
Get the water-based gloss oil that the present invention makes, with 180LPI color spreading instrument very thin one deck gloss oil in exhibition on the beer cartons of oil polish not, after treating gloss oil coating intensive drying, respectively with wear resistant instrument, sticking back of the body analyzer, anti-skidding goniometry instrument, the sticking analyzer of moisture-resistant carry out wear-resistant, anti-stick company, anti-skidding and moisture-resistant viscosity can be tested.
Get the water-based gloss oil that the present invention makes, diluent with 30% (1: 1 mixed getting of alcohol and water) dilutes gloss oil, use 180LPI color spreading instrument very thin one deck gloss oil in exhibition on the beer cartons of oil polish not then, after treating gloss oil coating intensive drying, respectively with wear resistant instrument, sticking back of the body analyzer, anti-skidding goniometry instrument, the sticking analyzer of moisture-resistant carry out wear-resistant, anti-stick company, anti-skidding and moisture-resistant viscosity can be tested.
Test result is as shown in the table:
Test condition:
Wear resistence: SUTHERLAND 2000 friction instrument, 4 pounds of pressure, Speed4,200 back and forth
Resistance to bond: Specac6000 surveys sticking instrument, 2 tons of pressure, 40 ℃, 30min
Moisture-resistant viscosity: after water coated the gloss oil surface,,, test under 2 hours conditions in 80 ℃, 1.8 kilograms pressure with the face-to-face doubling of beer cartons
Skid resistance a: beer cartons that is coated with gloss oil is placed on the anti-skidding goniometry instrument, another is coated with the beer cartons of gloss oil contacts with carton on placing anti-skidding goniometry instrument, the angle of the slow anti-skidding goniometry instrument of lifting, when sliding relatively appearred in two cartons, the angle that this moment, anti-skidding inclinometer showed was the anti-skidding angle of gloss oil.Anti-skidding angle can characterize the skid resistance of gloss oil.
By test result as can be known: increase the consumption of cinnamic acrylic ester emulsion, its moisture-resistant viscosity meeting variation; Increase the consumption of wax slurry, little to the non-skid property influence, the problem that the consumption that having solved increases wax can make the gloss oil non-skid property descend also can improve abrasion resistance simultaneously; After the gloss oil dilution, its non-skid property can descend, and still wear-resistant, anti-stick company, moisture-resistant viscosity can influence not quite, and as seen the gloss oil that is made by the present invention has excellent wear-resistant, anti-stick company, moisture-resistant profit, non-skid property.
Being preferred embodiment of the present invention only below, is not the qualification to protection scope of the present invention, and all equivalent variations of doing according to the mentality of designing of this case all fall into the protection domain of this case.
Claims (7)
1. aqueous gloss oil for beer cartons is characterized in that: made by following raw material raw material by mass percentage:
Modified phenylethylene-acrylic acid ester emulsion 70～80%;
Cinnamic acrylic ester emulsion 10～20%;
Wear-resistant wax slurry 2～6%;
Defoamer 0.1～0.3%;
Preservative agent 0.1～0.3%;
Isopropyl alcohol 3～5%;
The mass percent sum of above raw material equals 100%.
2. a kind of aqueous gloss oil for beer cartons according to claim 1 is characterized in that: described modified phenylethylene-acrylic acid ester emulsion be a kind of Tg value for-10 ℃, high heat-resisting be 180 ℃ emulsion.
3. a kind of aqueous gloss oil for beer cartons according to claim 1 is characterized in that: described cinnamic acrylic ester emulsion is that a kind of Tg value is 95 ℃, not the emulsion of film forming.
4. a kind of aqueous gloss oil for beer cartons according to claim 1 is characterized in that: described wear-resistant wax slurry is modified polyethylene wax, and its solid content is 50%.
5. a kind of aqueous gloss oil for beer cartons according to claim 1 is characterized in that: described defoamer is the silanes defoamer.
6. a kind of aqueous gloss oil for beer cartons according to claim 1 is characterized in that: described preservative agent is water-based chloromethyl/methylisothiazolinone mixture preservative agent.
7. a kind of aqueous gloss oil for beer cartons according to claim 1, it is characterized in that: the preparation method is: at normal temperatures, add modified phenylethylene-acrylic acid ester emulsion earlier, add defoamer, cinnamic acrylic ester emulsion, wear-resistant wax slurry, preservative agent, isopropyl alcohol then while stirring lentamente successively, after adding various raw materials, be to stir ten minutes under 500～1000 rev/mins the state at rotating speed, the various raw materials of system are uniformly dispersed, promptly obtain a kind of aqueous gloss oil for beer cartons.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2010102195646A CN101906735B (en) | 2010-07-07 | 2010-07-07 | Aqueous gloss oil for beer cartons and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2010102195646A CN101906735B (en) | 2010-07-07 | 2010-07-07 | Aqueous gloss oil for beer cartons and preparation method thereof |
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| CN101906735A true CN101906735A (en) | 2010-12-08 |
| CN101906735B CN101906735B (en) | 2011-08-31 |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102517982A (en) * | 2011-12-22 | 2012-06-27 | 东莞市英科水墨有限公司 | Waterproof high-gloss waterborne gloss oil for corrugated case and preparation method thereof |
| CN102943412A (en) * | 2012-11-14 | 2013-02-27 | 海南必凯水性涂料有限公司 | Wear-resistant high-gloss waterborne glazing oil and preparation method thereof |
| CN103031774A (en) * | 2012-12-24 | 2013-04-10 | 东莞市鸿海化工涂料有限公司 | Aqueous universal oil polish and preparation method thereof |
| CN104277716A (en) * | 2013-07-08 | 2015-01-14 | 苏州市相城区印刷材料厂 | Anti-skid gloss oil and its preparation method and examination method |
| CN104817908A (en) * | 2015-04-29 | 2015-08-05 | 惠州市舜丰印材科技有限公司 | Water-based varnish with anti-adhesion performance for beer cartons and preparation method of water-based varnish |
| CN104817864A (en) * | 2015-04-29 | 2015-08-05 | 惠州市舜丰印材科技有限公司 | Water-based gloss oil for gravure printing and method for manufacturing water-based gloss oil |
| CN106592334A (en) * | 2016-12-13 | 2017-04-26 | 佛山市东大包装有限公司 | Waterproof quick drying coating for paper boxes and preparation method of waterproof quick drying coating |
| CN109233517A (en) * | 2018-08-21 | 2019-01-18 | 广东天龙油墨有限公司 | A kind of preparation method of the pre- print-polishing oil of water-based temperature resistant anti-skid wearable |
| CN109504211A (en) * | 2018-10-26 | 2019-03-22 | 广州旭川合成材料有限公司 | A kind of aqueous non-skid coating of plastic packaging film and its preparation method and application |
| CN109747214A (en) * | 2019-03-12 | 2019-05-14 | 威海先优包装设计有限公司 | A kind of production technology of carton |
| CN110607709A (en) * | 2019-09-29 | 2019-12-24 | 武汉迪赛环保新材料股份有限公司 | Water-based gloss oil with beer adhesion prevention performance and preparation method thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102517982A (en) * | 2011-12-22 | 2012-06-27 | 东莞市英科水墨有限公司 | Waterproof high-gloss waterborne gloss oil for corrugated case and preparation method thereof |
| CN102517982B (en) * | 2011-12-22 | 2014-03-26 | 东莞市英科水墨有限公司 | Waterproof high-gloss waterborne gloss oil for corrugated case and preparation method thereof |
| CN102943412A (en) * | 2012-11-14 | 2013-02-27 | 海南必凯水性涂料有限公司 | Wear-resistant high-gloss waterborne glazing oil and preparation method thereof |
| CN103031774A (en) * | 2012-12-24 | 2013-04-10 | 东莞市鸿海化工涂料有限公司 | Aqueous universal oil polish and preparation method thereof |
| CN104277716A (en) * | 2013-07-08 | 2015-01-14 | 苏州市相城区印刷材料厂 | Anti-skid gloss oil and its preparation method and examination method |
| CN104817908A (en) * | 2015-04-29 | 2015-08-05 | 惠州市舜丰印材科技有限公司 | Water-based varnish with anti-adhesion performance for beer cartons and preparation method of water-based varnish |
| CN104817864A (en) * | 2015-04-29 | 2015-08-05 | 惠州市舜丰印材科技有限公司 | Water-based gloss oil for gravure printing and method for manufacturing water-based gloss oil |
| CN106592334A (en) * | 2016-12-13 | 2017-04-26 | 佛山市东大包装有限公司 | Waterproof quick drying coating for paper boxes and preparation method of waterproof quick drying coating |
| CN109233517A (en) * | 2018-08-21 | 2019-01-18 | 广东天龙油墨有限公司 | A kind of preparation method of the pre- print-polishing oil of water-based temperature resistant anti-skid wearable |
| CN109504211A (en) * | 2018-10-26 | 2019-03-22 | 广州旭川合成材料有限公司 | A kind of aqueous non-skid coating of plastic packaging film and its preparation method and application |
| CN109747214A (en) * | 2019-03-12 | 2019-05-14 | 威海先优包装设计有限公司 | A kind of production technology of carton |
| CN110607709A (en) * | 2019-09-29 | 2019-12-24 | 武汉迪赛环保新材料股份有限公司 | Water-based gloss oil with beer adhesion prevention performance and preparation method thereof |
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|---|---|
| CN101906735B (en) | 2011-08-31 |
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Address after: Chashan town Tong Kok village 523393 Guangdong city of Dongguan Province on Tong industrial area Patentee after: GUANGDONG YINGKE GROUP CO., LTD. Address before: Cha Shan Zhen Tang Jiao Cun 523000 Guangdong city in Dongguan province of Dongguan City Tong industrial area INTCO Ink Co Ltd Patentee before: Dongguan Yingke Printing Ink Co., Ltd. |