CN101891993B - Fluoropolymer organic lining anticorrosive material for chimney, flue and other pipelines and containers and construction method thereof - Google Patents
Fluoropolymer organic lining anticorrosive material for chimney, flue and other pipelines and containers and construction method thereof Download PDFInfo
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Abstract
The invention provides an anticorrosive material for a chimney, a flue and other containers and pipelines and an anticorrosive construction process. The construction method of the anticorrosive material comprises the following steps: using crude rubber with higher fluorine content as a raw material, then adding curing agent, stabilizer, special stuffing and other components, and mixing to form precuring gross rubber; dissolving the rubber by using low-molecular weight esters and ketones as the solvent to form a putty type rubber paste; and finally, adding special additives, uniformly mixing, coating to the inner walls of a chimney, a flue and a chemical container, and curing into the polymerized fluororubber organic lining under the room-temperature condition. The material can be independently used as the anticorrosive material, and can also be used for protecting common foam glass bricks (ceramic bricks) and adhesive for anticorrosive purpose in the domestic chimney (flue) at present. The invention well solves the technical problems of fluororubber room-temperature curing and difficult anticorrosive construction, can be used in a high-temperature environment of more than 230 DEG C, and can endure high-concentration sulfuric acid, nitric acid, hydrochloric acid, phosphoric acid, hydrofluoric acid, corresponding salts and a mixture thereof. The anticorrosive lining material is economically affordable, has extremely high comprehensive anticorrosive properties such as temperature resistance, acid resistance and the like, and is applicable to the anticorrosive treatment of a cured chimney.
Description
Technical field
The present invention relates to high temperature resistant, as to be able to bear strong corrosion environment corrosion-resistant lining material and application art; Be mainly used in later chimney of fuel-burning power plant desulfurization and flue anticorrosion on; It is anticorrosion also to can be used for simultaneously oil, chemical industry and metallurgical related container and inner-walls of duct, belongs to the organic polymer material field.
Background technology
At present to the anticorrosive measure of desulfurization after-funnel, no matter aspect standard specificationss such as chimney design, construction, still be on the engineering practical application; All exist blank or do not have enough experiences, because investment and technical problem, headed by China's five big Power Group; Each tame genco is since the second half year in 2006, and 80% startup project has all taked to remove smoke heat replacing device (GGH), so; The minimum exhaust temperature of flue gas is between 40～50 ℃; And flue gas system (FGD) when stopping transport in line temperature reach more than 130 ℃, so chimney must carry out rotproofing.
At present, the chimney anticorrosion technology mainly contains foam glass brick technology, VP technology, glass flake and improved technique, acid resistant adhesive mortar, alloy lining technology etc.That is that all right is ripe and Chinese quality product is with technology, comparatively ripe and good market prospect all be foreign technology, but this series products price is higher, exceeds user's ability to bear.
Viton is a kind of synthetic elastomer that is connected with the extremely strong fluorine atom of electronegativity on the carbon atom on the main chain.Because C-F bond energy big (485kg/mol); And the fluorine atom covalent radius only has C-C bond distance half; 0.064nm; Therefore fluorine atom can well shield the C-C key get up, and has guaranteed the stability of main chain C-C key, makes it have the incomparable oil resistant of other rubber, chemically-resistant, physical and mechanical properties and weathering resistance, electrical insulating property and radiation resistance.
Viton is a kind of multiduty specialty elastomer; It is widely used in fields such as space flight, aviation, automobile, oil, chemical industry, machinery, traffic and household electrical appliances; Obtain the approval of many industries, only had few countries such as the U.S., Japan, Italy, Germany, Belgium, China and Russia to produce in the world.
Viton specific molecule structures shape its have outstanding heatproof and chemical mediator-resitant property, be a kind of good impregnating material.But the viton product that uses now all needs baking, need use the sticker paving when doing impregnating material usually.And the performance of present sticker heatproof and resistant to chemical media is more very different than the performance of viton itself, will hand over seam crossing to stay weak link at offset plate and offset plate like this.Also have some sticker to contain solvent, behind the paving viton plate, solvent can't normally be discharged, and the big area paving is very easily bubbled adhering to of influence and substrate.These factors have all restricted viton as the application of impregnating material at some special dimensions, in the chimney anticorrosion like the fuel-burning power plant mentioned in front, in oil, chemical industry and metallurgical related container and inner-walls of duct are anticorrosion.
In addition; The fluorine carbon coating of use on the steelwork surface is arranged at present, and it does not need caking agent, but this coating solid content is little; Low and the interval recoat poor performance of one-pass film-forming thickness; And heat resistance is poor, can not satisfy the chimney anticorrosion in fuel-burning power plant, or in oil, chemical industry and metallurgical related container and the requirement of inner-walls of duct rot-resistant.
Summary of the invention
The objective of the invention is to be applied in as impregnating material the problems referred to above of technical existence to existing viton; What propose a kind of chimney, flue and other pipeline and container gathers fluoropolymer organic lining anticorrosive material and constructional method; Solve viton well as the big problem of impregnating material difficulty of construction; Realize said material ambient cure and recoat repeatedly, satisfy special dimensions such as chimney and flue the rotproofing needs.
The technical scheme that the present invention adopts is following:
The chimney that the present invention proposes and the inside lining anti-corrosive material of flue are A, B two-component materials.
Wherein the A component is that the high fluorine-containing rubber of employing is a raw material, adds components such as vulcanizing agent, stablizer and reinforcing filler and carries out mixing back with solvent formation putty type rubber cement, and adding special type filler and special addition agent are processed in putty type rubber cement again.
The B component is additive and organic solvent.
After A, B component mix, be coated with and be contained in chimney, flue and pressure vessels for the chemical industry inwall, solidify at ambient temperature and can form polyfluorine rubber organic lining.
This material can independently use as impregnating material, also can protect anticorrosion conventional foam plate glass of present chimney (flue) (ceramic tile) and sticker.Because traditional sticker is a silastic material; Acid resistance is relatively poor; The fragment of brick heat-shock resistance is poor; The harsh corrosion working condition that all can not adapt to Chinese desulfurization after-funnel, necessary consideration is more outstanding in external coating one deck comprehensive anticorrosive performance, and the material of actual working conditions is protected after the desulfurization of adaptation China.
Below the composition of above-mentioned inside lining anti-corrosive material is elaborated:
1, the rubber unvulcanizate of A component:
The A component prepares used crude fluororubber raw material for fluorine content is 55-71%, is preferably binary or the ternary fluororubber of 65-70%.Binary fluorine rubber such as glue vinylidene/R 1216, vinylidene/trifluorochloroethylene, vinylidene/five fluorine propylene, tetrafluoroethylene/propylene; The ternary fluororubber of ternary fluororubber such as vinylidene/tetrafluoroethylene/hexafluoropropylene, vinylidene/tetrafluoroethylene/five fluorine propylene can be selected in them one or more for use.
It is one or more mixture such as MOXs such as quicklime, Natural manganese dioxide, plumbous oxide, zinc oxide and its esters that the A component prepares used stablizer.
It is one or more of carbon black, Calcium Fluoride (Fluorspan), zeyssatite, potter's clay, graphite, talcum powder, mica powder or fiber-like material (like thomel, spun glass, wood fibre, magnesiumcarbonate fiber) that the A component prepares used reinforcing filler.
A component preparation also can further add vulcanizing agent, and vulcanizing agent is one or more a mixture of organo-peroxide, diamines and verivate, dihydric phenol etc.Wherein organo-peroxide is selected from one or more in methylethyl ketone peroxide, Lucidol, the Di Cumyl Peroxide 99.Diamines and verivate thereof can be selected from hexa-methylene diamino formate, hexanediamine base formate, quadrol base formate, N; The two Chinese cassia tree forks-1 of N-; 6-hexanediamine, two-(4-ammonia hexyl cyclohexyl) methane carbaminate, 2, one or more of two (4-phenylor) propane of 2-.Dihydric phenol is selected from 4,4 ,-(hexafluoroisopropyli,ene) bis-phenol.
The prescription of rubber unvulcanizate is as shown in table 1.
Table 1: the rubber unvulcanizate formula table of preparation A component
| Title material | Rubber | Stablizer | Reinforcing filler | Vulcanizing agent | Remarks |
| Parts by weight | 100 | 5-40 | 3-50 | 1-15 |
Because the viton mooney viscosity is high, the molecular chain rigidity is big, and plastication is not obvious, so rubber unvulcanizate selects mill directly to carry out mixing when producing.The viton poor thermal conductivity, mixing living heat is big, and particularly when reinforced additive was selected carbon black for use, when the carbon black add-on was big, living heat was bigger.Along with the rising of melting temperature, cause sizing material roll banding and incipient scorch easily, for this reason, must strengthen the cooling of mixing process, guarantee that preferably glue furnacing temperature remains on below 60 ℃.Refining glue amount is controlled as follows:
150mm (6in) rubber mixing machine per car dress glue amount is no more than 1kg, and 230mm (9in) rubber mixing machine should be controlled at 3kg, and 360mm (14in) rubber mixing machine is 5～9kg.
When mixing, order of addition(of ingredients) is followed successively by rubber, machining of special auxiliary agent, stablizer (acid-acceptor), reinforcing filler, vulcanizing agent (promotor).The roller speed ratio is selected to be controlled within the 1-1.5, is preferably 1: 1.25.
The sizing material that mixes leaves cryodrying place in, avoids contacting with water, prevents that glue from burning, and with carrying out back mixing before the dissolution with solvents, back mixing adopts pony roll apart from thin logical 3 times (controlling within 3-5 time), helps homodisperse.
2, the used putty type of A component rubber cement preparation
The solvent of dissolving rubber unvulcanizate is ketone, ester class or alcoholic solvent in the preparation of A component.A kind of or combination like acetone, methylethylketone, MIBK, pimelinketone, methyl-formiate, ethyl formate, ETHYLE ACETATE, butylacetate, methyl alcohol, ethanol, butanols.
In reaction kettle by weight being rubber unvulcanizate: solvent=100 part: after (150-400 part) adds solvent; The mixing blob of viscose that slow again adding has cut; The rotating speed of phonomoter is controlled at 5-800 rev/min; 10-100 rev/min of rotating speed the best wherein, the final putty type rubber cement concentration that forms is 20～60%.Too high rotating speed can cause the insufficient temperature with rubber cement with contacting of solvent of mixing blob of viscose to raise, and causes that rubber cement is rotten; Cross low rotating speed and can reduce dissolved efficient.
3, the final preparation of A component
After the putty type rubber cement preparation completion, need special special type filler and the special addition agent of adding, finally the A component of meeting.The adding of special type filler and special addition agent is most important to originally gathering fluoropolymer organic lining anticorrosive material.Because coating globality and interval recoat performance are significantly improved,, then do not possess the recoat performance if do not add special type filler in the rubber cement.The adding of special addition agent can improve the surface effect of coating, reduces pin hole and improves globality and closure.
The filler that the present invention adopts is one or more of fiber-like, scale or MOX of different size.Specifically can select the 1mm-3mm spun glass; The 3mm-5mm spun glass; The 5mm-8mm spun glass; The 8mm-10mm spun glass; The 10mm-20mm spun glass; The 1mm-3mm wood fibre; The 3mm-5mm wood fibre; The 5mm-8mm wood fibre; 8mm-10mm wood fibre 10mm-20mm wood fibre; The 1mm-3mm trevira; The 3mm-5mm trevira; The 5mm-8mm trevira; The 8mm-10mm trevira; The 10mm-20mm trevira; 20 order glass flakes; 40 order glass flakes; 60 order glass flakes; 80 order glass flakes; 100 order glass flakes; 140 order glass flakes; 160 order glass flakes; 200 order glass flakes; 250 order glass flakes; 325 order glass flakes; 600 order glass flakes; 800 order glass flakes; 1000 order glass flakes; 200 order MgO powder; 325 order MgO powder; 600 order MgO powder; 800 order MgO powder; 1000 order MgO powder; 1200 order MgO powder; 200 order CaO powder; 325 order CaO powder; 600 order CaO powder; 800 order CaO powder; 1000 order CaO powder; 1200 order CaO powder; 200 order ZnO powders; 325 order ZnO powders; 600 order ZnO powders; 800 order ZnO powders; 1000 order ZnO powders; 1200 order ZnO powders; 200 order PbO powder; 325 order PbO powder; 600 order PbO powder; 800 order PbO powder; 1000 order PbO powder; 1200 order PbO powder; 200 order TiO2 powder; 325 order TiO2 powder; 600 order TiO2 powder; 800 order TiO2 powder; 1000 order TiO2 powder; In the 1200 order TiO2 powder one or more.
Special addition agent adopt the conventional trade mark skimmer, dispersion agent, flow agent or inhibitor one or more.Be specially one or more materials of skimmer DP-2800, skimmer DP-6800, skimmer DF-103, skimmer DF-104, skimmer DF-105, dispersion agent DP-100, dispersion agent DP-270, dispersion agent SM-108 dispersion agent, dispersion agent XD-140, dispersant B YT-164, flow agent RM-2020, flow agent EDL-3855, flow agent SH360, flow agent UH-420, inhibitor VK-B03, inhibitor VK-B04.
Table 2: gather the organic A component of fluorine formula table
| Title material | Putty type rubber cement | Special type filler | Special addition agent | Remarks |
| Weight/part | 100 | 1-60 is preferably 5-50 | 0.1-10 be preferably 0.5-5 |
Addition sequence is followed successively by putty type rubber cement, special addition agent, special type filler.
Mixing equipment can adopt in the high speed agitator and carry out, and rotating speed can be selected 200～1000 rev/mins, and how many mixing times is confirmed according to material, obtained gathering the organic A component of fluorine after mixing.
4, the preparation that gathers fluoropolymer organic lining anticorrosive material B component
The additive that the B component adopts be organic amine, silane coupling agent one or more.Also need add organic solvent, comprise a kind of or combination of acetone, methylethylketone, MIBK, pimelinketone, methyl-formiate, ethyl formate, ETHYLE ACETATE, butylacetate, methyl alcohol, ethanol, butanols, toluene, YLENE.
The ratio of weight and number of organic solvent and additive is 60-250 in the B component: 100.
Further, the additive of B component also can comprise organo-peroxide (like methylethyl ketone peroxide, Lucidol), and in 100 parts of other weight of additive umbers, the add-on of organo-peroxide is 100-300 part.
Organic amine, silane coupling agent and solvent types selection and add-on are extremely important to gathering fluoropolymer organic lining anticorrosive material in the B component, are the keys that realizes the material ambient cure.Organic amine and silane coupling agent select improper this material that possibly cause can not solidify at normal temperatures at all; What of add-on then can directly have influence on the over-all properties after the material cured; Add-on meeting bigger than normal makes that heat resistance and elasticity obviously descend after the material cured, and material is hard and crisp.The speed and the surface drying time of the evaporation rate of choice of Solvent decision coating internal solvent, the then short meeting formation of the surface drying time coatingsurface defective of volatilizing too soon like pin hole, also can increase difficulty of construction simultaneously; Volatilization has then prolonged the set time of material too slowly, is prone to form sagging.According to material environment for use (mainly being the temperature and humidity environment), the selectivity of superoxide adds can improve the adaptive faculty of this material to temperature.
Compared with prior art, technological core of the present invention prepares selection, special type filler and special addition agent selection and add-on and the selection of B component effective constituent kind and the add-on of viton kind in the process for the A component.The selection of viton kind is improper, and the heatproof of final material, acidproof, heat shock resistance and adhesion property do not reach desulfurization after-funnel or flue requirement of actual working condition.The adding of special type filler and special addition agent is that material interval recoat performance generation qualitative leap is crucial, and add-on meeting bigger than normal causes material hardens, and elasticity reduces, and add-on is on the low side then not to reach raising recoat performance at interval at all.
The construction technology of 5, gathering fluoropolymer organic lining anticorrosive material
The construction technology of gathering on the chimney anticorrosion after the fluorine organic materials is applied in desulfurization is following:
(1) after accomplishing the installation of preparation of construction and operation platform; At first inner wall of stack is carried out base treatment; Be high pressure water washing or mechanical ashing, to sanding inject process or wet method sanding inject process surface that steel base then adopts metal, metal finishing reaches the Sa2.5-3 level.
(2) levelling is handled, and carries out levelling more than the concavo-convex 6-8mm of reaching and handles, and material therefor is potassium silicate acid resistant adhesive mortar, water glass acid resistant adhesive mortar, resin-bonded mastic, Zylox or fluororubber material, and opposite joint is repaired simultaneously, sees just to stitch and mends.
(4) will gather fluorine organic materials A, B component and mix after, blade coating or spray to inner wall of stack, wet-film thickness is controlled at 0.3-3mm, the surface is smooth basically, temperature is more than 10 ℃, humidity is below 85%;
(5) maintenance: room temperature: 1-3 days, or heat: after 50-80 ℃ of maintenance 3-8 hour, again at 100-150 ℃ of maintenance 12-48 hour.
The special stable structure of viton decision said material has good heatproof, antiseptic property such as acidproof.But traditional mode is earlier with its high temperature vulcanized rubber plate that is prepared into; Paste then; Common heatproof of sticker and acid resistance can not satisfy domestic desulfurization after-funnel or there is high temperature simultaneously in flue; Acidic medium, the fluctuation of cigarette temperature causes actual working conditions such as thermal stresses and acidic medium concentration change greatly.Simultaneously, existing other purposes fluorine coating are except heat resistance has much room for improvement, because the viton structure is too stable; In a single day coating solidifies, and common solvent all can not be dissolved it, and same material is recoat at interval; Can only an application; It is low to add solid content, and one-pass film-forming thickness is minimum, can not satisfy the uneven requirement to application thickness of chimney or flue block substrate at all.The present invention passes through to adopt A, the two components of B, and in the A component, adds special type filler and special addition agent, and the solidifying agent kind of selecting the B component cleverly, solves self-vulcanizing and the world of interval recoat, domestic technical barrier well.
Embodiment
Be appreciated that the scope that the present invention protects is not limited to following embodiment, also comprises the arbitrary combination of each embodiment.
Embodiment 1
Gather the organic (VP3-2 of fluorine in the present embodiment; This gives the code name of this material for the applicant) the organic lining impregnating material is made up of A component and B component, and the rubber unvulcanizate that wherein prepares the A component is by ternary fluororubber, 5 parts of Ca (OH) of the vinylidene/tetrafluoroethylene/hexafluoropropylene of 100 parts of fluorine content 55% by ratio of weight and the number of copies
2, 10 parts of MgO, 15 parts of carbon blacks, 8 parts of two-(4-ammonia hexyl cyclohexyl) mixing processing of methane carbaminate vulcanizing agent.
The putty type rubber cement of preparation A component is by 100 parts of rubber unvulcanizates of ratio of weight and number, 400 parts of acetone mixing blob of viscose dissolvings that slow adding has cut in reaction kettle; The rotating speed of phonomoter is controlled at 100 rev/mins, finally obtains preparing the putty type rubber cement that gathers the organic A component of fluorine.
The A component by 100 parts, 10 parts 1mm-3mm spun glass of ratio of weight and number putty type rubber cement, 10 parts of 3mm-5mm spun glass, 1 part of skimmer DP-6800,1 part of inhibitor VK-B03 in high speed agitator; Rotating speed is selected 400～600 rev/mins, obtains gathering the organic A component of fluorine after mixing.
The B component is by 50 parts of Lucidols of ratio of weight and number, 50 parts of γ-aminoethyl-β-aminopropyl trimethoxysilane, and 200 parts of acetone mix and process.
Gathering fluorine preceding A component of organic organic lining impregnating material construction and B component blended ratio of weight and number is the corresponding 5 parts of B components of 100 parts of A components.
The construction process of above-mentioned impregnating material:
At first after preparation of construction and operation platform installation, at first the brick chimney inwall is carried out high pressure water (pressure 5Mpa) flushing, remove dust stratification and unconsolidated formation; To sanding inject process or wet method sanding inject process surface that steel base then adopts metal, metal finishing reaches the Sa2.5-3 level; Brush the brickwork joint and the rough zone of repairing with de-mineralized water again, use the acid resistant adhesive mortar material to repair immediately and handle with levelling at needs; Wait to solidify back (about 48h), more than 10 ℃, under the environment of humidity below 85%, blade coating gathers the organic VP3-2 of fluorine in temperature, blade coating repeatedly, and wet-film thickness is controlled at 0.3-3mm, requires surfacing.Maintenance: room temperature: 1-3 days, or heat: after 50-80 ℃ of maintenance 3-8 hour, again at 100-150 ℃ of maintenance 12-48 hour.
Embodiment 2
Gather fluorine organic (VP3-2) organic lining impregnating material in the present embodiment and be made up of A component and B component, the rubber unvulcanizate that wherein prepares the A component is by ternary fluororubber, 5 parts of Ca (OH) of the vinylidene/tetrafluoroethylene of 100 parts of fluorine content 60%/five fluorine propylene by ratio of weight and the number of copies
2, 10 parts of MgO, 15 parts of Calcium Fluoride (Fluorspan), 8 parts of two-(4-ammonia hexyl cyclohexyl) mixing processing of methane carbaminate vulcanizing agent.
The rest part content is identical with embodiment 1.
Embodiment 3
Gather fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment and be made up of A component and B component, the rubber unvulcanizate that wherein prepares the A component is by binary viton, 5 parts of Ca (OH) of the vinylidene/R 1216 of 100 parts of fluorine content 65% by ratio of weight and the number of copies
2, 15 parts of MgO, 20 parts of mixing processing of zeyssatite.
The rest part content is identical with embodiment 1.
Embodiment 4
Gather fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment and be made up of A component and B component, the rubber unvulcanizate that wherein prepares the A component is by binary viton, 5 parts of Ca (OH) of the vinylidene/trifluorochloroethylene of 100 parts of fluorine content 66% by ratio of weight and the number of copies
2, 10 parts of MgO, 15 parts of potter's clay, 10 parts of two-(4-ammonia hexyl cyclohexyl) mixing processing of methane carbaminate vulcanizing agent.
The rest part content is identical with embodiment 1.
Embodiment 5
Gather fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment and be made up of A component and B component, the rubber unvulcanizate that wherein prepares the A component is by binary viton, 5 parts of Ca (OH) of the vinylidene of 100 parts of fluorine content 68%/five fluorine propylene by ratio of weight and the number of copies
2, 10 parts of MgO, 15 parts of graphite, 8 parts of two-(4-ammonia hexyl cyclohexyl) mixing processing of methane carbaminate vulcanizing agent.
The rest part content is identical with embodiment 1.
Embodiment 6
Gather fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment and be made up of A component and B component, the rubber unvulcanizate that wherein prepares the A component is by binary viton, 5 parts of Ca (OH) of the tetrafluoroethylene/propylene of 100 parts of fluorine content 70% by ratio of weight and the number of copies
2, 10 parts of MgO, 15 parts of talcum powder, 8 parts of two-(4-ammonia hexyl cyclohexyl) mixing processing of methane carbaminate vulcanizing agent.
The rest part content is identical with embodiment 1.
Embodiment 7
Gather fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment and be made up of A component and B component, the rubber unvulcanizate that wherein prepares the A component is by ternary fluororubber, 10 parts of Ca (OH) of the vinylidene/tetrafluoroethylene/hexafluoropropylene of 100 parts of fluorine content 55% by ratio of weight and the number of copies
2, 10 parts of PbO, 20 parts of mica powders, 5 parts of mixing processing of hexa-methylene diamino formate vulcanizing agent.
The rest part content is identical with embodiment 1.
Embodiment 8
Gather fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment and be made up of A component and B component, the rubber unvulcanizate that wherein prepares the A component is by ternary fluororubber, 10 parts of Ca (OH) of the vinylidene/tetrafluoroethylene/hexafluoropropylene of 100 parts of fluorine content 55% by ratio of weight and the number of copies
2, 10 parts of PbO, 20 parts of thomels, 5 parts of mixing processing of hexanediamine base formate vulcanizing agent.
The rest part content is identical with embodiment 1.
Embodiment 9
Gather fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment and be made up of A component and B component, the rubber unvulcanizate that wherein prepares the A component is by ternary fluororubber, 10 parts of Ca (OH) of the vinylidene/tetrafluoroethylene/hexafluoropropylene of 100 parts of fluorine content 55% by ratio of weight and the number of copies
2, 10 parts of PbO, 20 parts of wood fibres, 5 parts of mixing processing of quadrol base formate vulcanizing agent.
The rest part content is identical with embodiment 1.
Embodiment 10
Gather fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment and be made up of A component and B component, the rubber unvulcanizate that wherein prepares the A component is by ternary fluororubber, 10 parts of Ca (OH) of the vinylidene/tetrafluoroethylene/hexafluoropropylene of 100 parts of fluorine content 55% by ratio of weight and the number of copies
2, 10 parts of ZnO, 20 parts of magnesiumcarbonate fibers, 5 parts of N, the two Chinese cassia trees forks-1 of N-, mixing the processing of 6-hexanediamine vulcanizing agent.
The rest part content is identical with embodiment 1.
Embodiment 11
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; The putty type rubber cement that wherein prepares the A component is by 100 parts of rubber unvulcanizates of ratio of weight and number, 150 parts of acetone mixing blob of viscose dissolvings that slow adding has cut in reaction kettle; The rotating speed of phonomoter is controlled at 80 rev/mins, finally obtains preparing the putty type rubber cement that gathers the organic A component of fluorine.
Wherein rubber unvulcanizate selects for use among the embodiment 1-10 any one all can.The rest part content is identical with embodiment 1.
Embodiment 12
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; The putty type rubber cement that wherein prepares the A component is by 100 parts of rubber unvulcanizates of ratio of weight and number, 150 parts of methylethylketone mixing blob of viscose dissolvings that slow adding has cut in reaction kettle; The rotating speed of phonomoter is controlled at 10 rev/mins, finally obtains preparing the putty type rubber cement that gathers the organic A component of fluorine.
Wherein rubber unvulcanizate selects for use among the embodiment 1-10 any one all can.The rest part content is identical with embodiment 1.
Embodiment 13
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; The putty type rubber cement that wherein prepares the A component is by 100 parts of rubber unvulcanizates of ratio of weight and number, 150 parts of hexone mixing blob of viscose dissolvings that slow adding has cut in reaction kettle; The rotating speed of phonomoter is controlled at 5 rev/mins, finally obtains preparing the putty type rubber cement that gathers the organic A component of fluorine.
Wherein rubber unvulcanizate selects for use among the embodiment 1-10 any one all can.The rest part content is identical with embodiment 1.
Embodiment 14
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; The putty type rubber cement that wherein prepares the A component is by 100 parts of rubber unvulcanizates of ratio of weight and number, 200 parts of pimelinketone mixing blob of viscose dissolvings that slow adding has cut in reaction kettle; The rotating speed of phonomoter is controlled at 50 rev/mins, finally obtains preparing the putty type rubber cement that gathers the organic A component of fluorine.
Wherein rubber unvulcanizate selects for use among the embodiment 1-10 any one all can.The rest part content is identical with embodiment 1.
Embodiment 15
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; The putty type rubber cement that wherein prepares the A component is by 100 parts of rubber unvulcanizates of ratio of weight and number, 150 parts of hexone mixing blob of viscose dissolvings that slow adding has cut in reaction kettle; The rotating speed of phonomoter is controlled at 150 rev/mins, finally obtains preparing the putty type rubber cement that gathers the organic A component of fluorine.
Wherein rubber unvulcanizate selects for use among the embodiment 1-10 any one all can.The rest part content is identical with embodiment 1.
Embodiment 16
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; The putty type rubber cement that wherein prepares the A component is by 100 parts of rubber unvulcanizates of ratio of weight and number, 250 parts of methyl-formiate mixing blob of viscose dissolvings that slow adding has cut in reaction kettle; The rotating speed of phonomoter is controlled at 10-100 rev/min, finally obtains preparing the putty type rubber cement that gathers the organic A component of fluorine.
Wherein rubber unvulcanizate selects for use among the embodiment 1-10 any one all can.The rest part content is identical with embodiment 1.
Embodiment 17
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; The putty type rubber cement that wherein prepares the A component is by 100 parts of rubber unvulcanizates of ratio of weight and number, 150 parts of methyl-formiate mixing blob of viscose dissolvings that slow adding has cut in reaction kettle; The rotating speed of phonomoter is controlled at 300 rev/mins, finally obtains preparing the putty type rubber cement that gathers the organic A component of fluorine.
Wherein rubber unvulcanizate selects for use among the embodiment 1-10 any one all can.The rest part content is identical with embodiment 1.
Embodiment 18
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; The putty type rubber cement that wherein prepares the A component is by 100 parts of rubber unvulcanizates of ratio of weight and number, 300 parts of ethyl formate mixing blob of viscose dissolvings that slow adding has cut in reaction kettle; The rotating speed of phonomoter is controlled at 500 rev/mins, finally obtains preparing the putty type rubber cement that gathers the organic A component of fluorine.
Wherein rubber unvulcanizate selects for use among the embodiment 1-10 any one all can.The rest part content is identical with embodiment 1.
Embodiment 19
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; The putty type rubber cement that wherein prepares the A component is by 100 parts of rubber unvulcanizates of ratio of weight and number, 150 parts of ETHYLE ACETATE mixing blob of viscose dissolvings that slow adding has cut in reaction kettle; The rotating speed of phonomoter is controlled at 90 rev/mins, finally obtains preparing the putty type rubber cement that gathers the organic A component of fluorine.
Wherein rubber unvulcanizate selects for use among the embodiment 1-10 any one all can.The rest part content is identical with embodiment 1.
Embodiment 20
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; The putty type rubber cement that wherein prepares the A component is by 100 parts of rubber unvulcanizates of ratio of weight and number, 150 parts of butylacetate mixing blob of viscose dissolvings that slow adding has cut in reaction kettle; The rotating speed of phonomoter is controlled at 100 rev/mins, finally obtains preparing the putty type rubber cement that gathers the organic A component of fluorine.
Wherein rubber unvulcanizate selects for use among the embodiment 1-10 any one all can.The rest part content is identical with embodiment 1.
Embodiment 21
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; The putty type rubber cement that wherein prepares the A component is by 100 parts of rubber unvulcanizates of ratio of weight and number, 400 parts of ethanol mixing blob of viscose dissolvings that slow adding has cut in reaction kettle; The rotating speed of phonomoter is controlled at 600 rev/mins, finally obtains preparing the putty type rubber cement that gathers the organic A component of fluorine.
Wherein rubber unvulcanizate selects for use among the embodiment 1-10 any one all can.The rest part content is identical with embodiment 1.
Embodiment 22
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; The putty type rubber cement that wherein prepares the A component is by 100 parts of rubber unvulcanizates of ratio of weight and number, 200 parts of butanols mixing blob of viscose dissolvings that slow adding has cut in reaction kettle; The rotating speed of phonomoter is controlled at 800 rev/mins, finally obtains preparing the putty type rubber cement that gathers the organic A component of fluorine.
Wherein rubber unvulcanizate selects for use among the embodiment 1-10 any one all can.The rest part content is identical with embodiment 1.
Embodiment 23
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Wherein the A component by 100 parts, 10 parts 5mm-8mm spun glass of ratio of weight and number putty type rubber cement, 10 parts of 8mm-10mm spun glass, 1 part of skimmer DP-6800,1 part of inhibitor VK-B04 in high speed agitator; Rotating speed is selected 400～600 rev/mins, obtains gathering the organic A component of fluorine after mixing.
Wherein putty type rubber cement can be selected any one putty type rubber cement among the embodiment 11-22, and the rest part content is identical with embodiment 1.
Embodiment 24
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Wherein the A component by 100 parts, 10 parts 1mm-3mm trevira of ratio of weight and number putty type rubber cement, 10 parts of 3mm-5mm polyester glass fibers, 1 part of skimmer DP-6800,1 part of inhibitor VK-B04 in high speed agitator; Rotating speed is selected 400～600 rev/mins, obtains gathering the organic A component of fluorine after mixing.
Wherein putty type rubber cement can be selected any one putty type rubber cement among the embodiment 11-22, and the rest part content is identical with embodiment 1.
Embodiment 25
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Wherein the A component by 100 parts, 10 parts 5mm-8mm trevira of ratio of weight and number putty type rubber cement, 10 parts of 8mm-10mm polyester glass fibers, 2 parts of skimmer DP-6800,2 parts of inhibitor VK-B04 in high speed agitator; Rotating speed is selected 400～600 rev/mins, obtains gathering the organic A component of fluorine after mixing.
Wherein putty type rubber cement can be selected any one putty type rubber cement among the embodiment 11-22, and the rest part content is identical with embodiment 1.
Embodiment 26
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Wherein the A component by 100 parts, 10 part 325 order glass flake of ratio of weight and number putty type rubber cement, 10 part of 600 order glass flake, 1 part of skimmer DP-6800,1 part of dispersion agent DP-100 in high speed agitator; Rotating speed is selected 400～600 rev/mins, obtains gathering the organic A component of fluorine after mixing.
Wherein putty type rubber cement can be selected any one putty type rubber cement among the embodiment 11-22, and the rest part content is identical with embodiment 1.
Embodiment 27
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Wherein the A component by 100 parts, 10 part 600 order glass flake of ratio of weight and number putty type rubber cement, 10 part of 1000 order glass flake, 1 part of skimmer DP-6800,1 part of dispersion agent DP-280 in high speed agitator; Rotating speed is selected 400～600 rev/mins, obtains gathering the organic A component of fluorine after mixing.
Wherein putty type rubber cement can be selected any one putty type rubber cement among the embodiment 11-22, and the rest part content is identical with embodiment 1.
Embodiment 28
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Wherein the A component by 100 parts, 10 part 1000 order glass flake of ratio of weight and number putty type rubber cement, 10 part of 1200 order glass flake, 1 part of skimmer DP-6800,1 part of dispersion agent DP-280 in high speed agitator; Rotating speed is selected 400～600 rev/mins, obtains gathering the organic A component of fluorine after mixing.
Wherein putty type rubber cement can be selected any one putty type rubber cement among the embodiment 11-22, and the rest part content is identical with embodiment 1.
Embodiment 29
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Wherein the A component by 100 parts, 20 part 325 order ZnO of ratio of weight and number putty type rubber cement, 10 part of 600 order ZnO, 1 part of skimmer DP-6800,1 part of dispersion agent DP-100 in high speed agitator; Rotating speed is selected 400～600 rev/mins, obtains gathering the organic A component of fluorine after mixing.
Wherein putty type rubber cement can be selected any one putty type rubber cement among the embodiment 11-22, and the rest part content is identical with embodiment 1.
Embodiment 30
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Wherein the A component by 100 parts, 10 part 600 order ZnO of ratio of weight and number putty type rubber cement, 10 part of 1000 order ZnO, 0.1 part of skimmer DP-6800,3 parts of dispersion agent DP-280 in high speed agitator; Rotating speed is selected 400～600 rev/mins, obtains gathering the organic A component of fluorine after mixing.
Wherein putty type rubber cement can be selected any one putty type rubber cement among the embodiment 11-22, and the rest part content is identical with embodiment 1.
Embodiment 31
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Wherein the A component by 100 parts, 10 part 1000 order ZnO of ratio of weight and number putty type rubber cement, 30 part of 1200 order ZnO, 3 parts of skimmer DP-6800,5 parts of dispersion agent DP-280 in high speed agitator; Rotating speed is selected 400～600 rev/mins, obtains gathering the organic A component of fluorine after mixing.
Wherein putty type rubber cement can be selected any one putty type rubber cement among the embodiment 11-22, and the rest part content is identical with embodiment 1.
Embodiment 32
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Wherein the A component by 100 parts, 0.5 part 600 order TiO2 of ratio of weight and number putty type rubber cement, 0.5 part of 800 order TiO2,0.1 part of skimmer DP-6800 in high speed agitator; Rotating speed is selected 400～600 rev/mins, obtains gathering the organic A component of fluorine after mixing.
Wherein putty type rubber cement can be selected any one putty type rubber cement among the embodiment 11-22, and the rest part content is identical with embodiment 1.
Embodiment 33
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Wherein the A component by 100 parts, 20 part 1000 order TiO2 of ratio of weight and number putty type rubber cement, 40 part of 1200 order TiO2,6 parts of skimmer DP-6800,4 parts of flow agent UH-420 in high speed agitator; Rotating speed is selected 400～600 rev/mins, obtains gathering the organic A component of fluorine after mixing.
Wherein putty type rubber cement can be selected any one putty type rubber cement among the embodiment 11-22, and the rest part content is identical with embodiment 1.
Embodiment 34
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Its A component can be selected among the embodiment 1-33 any one for use; Said B component is by 50 parts of methylethyl ketone peroxides of ratio of weight and number, 50 parts of γ-aminoethyl-β-aminopropyl trimethoxysilane, and 200 parts of methylethylketones mix and process.The ratio of weight and number of A component and B component is: 100: 1.
The rest part content is identical with embodiment 1.
Embodiment 35
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Its A component can be selected among the embodiment 1-33 any one for use; Said B component is by 50 parts of ratio of weight and number hexa-methylene diamino formate, 50 parts of anilinomethyl triethoxysilanes, and 250 parts of MIBKs mix and process.The ratio of weight and number of A component and B component is: 100: 2.
The rest part content is identical with embodiment 1.
Embodiment 36
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Its A component can be selected among the embodiment 1-33 any one for use; Said B component is by 50 parts of ratio of weight and number mphenylenediamines, 50 parts of γ-vinyltriethoxysilanes, and 150 parts of pimelinketone mix and process.The ratio of weight and number of A component and B component is: 100 parts: 3.
The rest part content is identical with embodiment 1.
Embodiment 37
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Its A component can be selected among the embodiment 1-33 any one for use; Said B component is by ratio of weight and number N; The two Chinese cassia tree forks-1 of N-, 50 parts, 50 parts vinyl silane tri-butyl peroxides of 6-hexanediamine, 200 parts of methyl-formiates mix and process.The ratio of weight and number of A component and B component is: 100: 4.
The rest part content is identical with embodiment 1.
Embodiment 38
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Its A component can be selected among the embodiment 1-33 any one for use; Said B component is by N; The two Chinese cassia tree forks-1 of N-, 50 parts, 50 parts gamma-mercaptopropyltriethoxysilanes of 6-hexanediamine, 200 parts of ethyl formates mix and process.The ratio of weight and number of A component and B component is: 100: 5.
The rest part content is identical with embodiment 1.
Embodiment 39
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Its A component can be selected among the embodiment 1-33 any one for use; Said B component is by 4; 4,50 parts, 30 parts γ of-(hexafluoroisopropyli,ene) bis-phenol-(methacrylate based) propyl trimethoxy silicane, 100 parts of butylacetates mix and process.The ratio of weight and number of A component and B component is: 100: 6.
The rest part content is identical with embodiment 1.
Embodiment 40
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Its A component can be selected among the embodiment 1-33 any one for use; Said B component is by 50 parts of Dyhard RU 100s, 50 parts of γ-glycidyl ethers propyl-triethoxysilicanes, and 250 parts of methanol mixed are evenly processed.The ratio of weight and number of A component and B component is: 100: 7.
The rest part content is identical with embodiment 1.
Embodiment 41
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Its A component can be selected among the embodiment 1-33 any one for use; Said B component is by 50 parts of polymeric amide, 50 parts of γ-glycidyl ethers propyl-triethoxysilicanes, and 100 parts of ethanol mix and process.The ratio of weight and number of A component and B component is: 100: 8.
The rest part content is identical with embodiment 1.
Embodiment 42
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Its A component can be selected among the embodiment 1-33 any one for use; Said B component is by 50 parts of NSC 446,50 parts of γ-glycidyl ethers propyl-triethoxysilicanes, and 60 parts of butanols mix and process.The ratio of weight and number of A component and B component is: 100: 9.
The rest part content is identical with embodiment 1.
Embodiment 43
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Its A component can be selected among the embodiment 1-33 any one for use; Said B component is by 50 parts of diethylene tetramines, 10 parts of γ-An Bingjisanyiyangjiguiwans, and 200 parts of toluene mix and process.The ratio of weight and number of A component and B component is: 100: 10.
The rest part content is identical with embodiment 1.
Embodiment 44
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Its A component can be selected among the embodiment 1-33 any one for use; Said B component is by 20 parts of quadrols, 50 parts of γ-An Bingjisanyiyangjiguiwans, and 200 parts of toluene mix and process.The ratio of weight and number of A component and B component is: 100: 1.
The rest part content is identical with embodiment 1.
Embodiment 45
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Its A component can be selected among the embodiment 1-33 any one for use; Said B component is by 50 parts of hexanediamines, 50 parts of γ-An Bingjisanyiyangjiguiwans, and 200 parts of YLENE mix and process.The ratio of weight and number of A component and B component is: 100: 2.
The rest part content is identical with embodiment 1.
Embodiment 46
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Its A component can be selected among the embodiment 1-33 any one for use; Said B component is by 50 parts of m-xylene diamines, 50 parts of γ-glycidyl ethers propyl-triethoxysilicanes, and 200 parts of YLENE mix and process.The ratio of weight and number of A component and B component is: 100: 3.
The rest part content is identical with embodiment 1.
Embodiment 47
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Its A component can be selected among the embodiment 1-33 any one for use; Said B component is by 50 parts of boron trifluoride ethylamines, 50 parts of γ-(methacrylate based) propyl trimethoxy silicanes, and 200 parts of YLENE mix and process.The ratio of weight and number of A component and B component is: 100: 4.
The rest part content is identical with embodiment 1.
Embodiment 48
Gathering fluorine organic (VP3-2) inside lining anti-corrosive material in the present embodiment is made up of A component and B component; Its A component can be selected among the embodiment 1-33 any one for use; Said B component is by 50 parts in diamino-dipropyl methane, 50 parts of vinyl silane tri-butyl peroxides, and 200 parts of YLENE mix and process.The ratio of weight and number of A component and B component is: 100: 5.
The rest part content is identical with embodiment 1.
Embodiment 49:
Be below to the chimney after the desulfurization and flue when foam glass brick (ceramic tile) and sticker thereof are protected, keep in repair antiseptic constructional method, step is following:
(1) chimney and flue inwall are carried out base treatment, adopt high pressure water washing or mechanical ashing;
(2) foamed brick (vitreous ceramic brick or foam glass brick) body is repaiied seam and handle, patching material is a Zylox, sees just benefit of seam, changes damaged brick body;
(3) to gather fluorine organic for any one of blade coating embodiment 1-48, and wet-film thickness is controlled at 0.3-3mm, surfacing, and temperature is more than 10 ℃, and humidity is below 85%;
(4) maintenance: room temperature: 1-3 days, or heat: after 50-80 ℃ of maintenance 3-8 hour, again at 100-150 ℃ of maintenance 12-48 hour.
Desulfurization after-funnel inside lining anti-corrosive material requires high especially to the material acid resistance; Not only to consider the simultaneous situation of multiple acidic medium; Also under the considered certain temperature, and when having temperature fluctuation simultaneously, the corrosion situation when material exists multiple acidic medium simultaneously.So just can be consistent with the corrosion working condition of desulfurization after-funnel (flue).It is following with silicone rubber kinds chimney anticorrosion material (brick plate matrix material) the acid resistance contrast situation of widespread use in the market to gather fluorine organic (VP3-2) inside lining anti-corrosive material:
Table 3: gather fluorine organic (VP3-2) and the contrast of traditional silicon rubber-like chimney lining impregnating material acid resistance
| Sequence number | Project | Zylox | Gather fluorine organic (VP3-2) |
| 1 | USS: 177 ℃ of 20%H 2SO 4U.S. mark loop test 30 times 1., sample flawless, foaming, peeling phenomenon, breaking tenacity conservation rate >=0.9 ASTM D 6137-97 (Reapproved 2004) | Circulate 1 preservative coat promptly by completely destroy | Through test |
| 2 | The test of heating: 80 ℃, 40% H 2SO 4Soak 15 days sample flawlesses, foaming, peeling phenomenon, breaking tenacity conservation rate >=0.9DL/T 693-1999 | Soak and begin after 1 day to bubble complete failure after 3 days | Through test |
Claims (17)
1. a chimney, flue and other pipeline and container gathers fluoropolymer organic lining anticorrosive material; It is characterized in that: said material is made up of A and two kinds of components of B, and the A component is to be raw material by fluorine-containing rubber earlier, adds stablizer and reinforcing filler again and carries out mixing; Form rubber unvulcanizate; Make solvent with ketone, ester class or alcohols then, putty type rubber cement is processed in dissolving, adds filler therein again and auxiliary agent is processed; The B component is additive and organic solvent; After A, B component mix, be coated with and be contained in by preserver surface, sulfuration at room temperature forms preservative coat, reaches anticorrosion purpose;
The used rubber raw material of said A component is one or more of ternary fluororubber of binary or vinylidene/tetrafluoroethylene/hexafluoropropylene, the vinylidene/tetrafluoroethylene/five fluorine propylene of vinylidene/R 1216, vinylidene/trifluorochloroethylene, vinylidene/five fluorine propylene, the tetrafluoroethylene/propylene of 55%-71% for fluorine content;
The stablizer of said A component is selected from one or more of quicklime, Natural manganese dioxide, plumbous oxide, zinc oxide and its esters; In the rubber raw materials in part by weight is 100 parts, and it is 5-40 part that stablizer adds weight;
The reinforcing filler of said A component is selected from one or more of carbon black, Calcium Fluoride (Fluorspan), zeyssatite, potter's clay, graphite, talcum powder, mica powder or fiber-like material, is 100 parts in the rubber raw materials in part by weight, and it is 3～50 parts that reinforcing filler adds weight;
The filler that adds in the putty type rubber cement of said A component is: the 1mm-3mm spun glass; The 3mm-5mm spun glass; The 5mm-8mm spun glass; The 8mm-10mm spun glass; The 10mm-20mm spun glass; The 1mm-3mm wood fibre; The 3mm-5mm wood fibre; The 5mm-8mm wood fibre; The 8mm-10mm wood fibre; The 10mm-20mm wood fibre; The 1mm-3mm trevira; The 3mm-5mm trevira; The 5mm-8mm trevira; The 8mm-10mm trevira; The 10mm-20mm trevira; 20 order glass flakes; 40 order glass flakes; 60 order glass flakes; 80 order glass flakes; 100 order glass flakes; 140 order glass flakes; 160 order glass flakes; 200 order glass flakes; 250 order glass flakes; 325 order glass flakes; 600 order glass flakes; 800 order glass flakes; 1000 order glass flakes; 200 order MgO powder; 325 order MgO powder; 600 order MgO powder; 800 order MgO powder; 1000 order MgO powder; 1200 order MgO powder; 200 order CaO powder; 325 order CaO powder; 600 order CaO powder; 800 order CaO powder; 1000 order CaO powder; 1200 order CaO powder; 200 order ZnO powders; 325 order ZnO powders; 600 order ZnO powders; 800 order ZnO powders; 1000 order ZnO powders; 1200 order ZnO powders; 200 order PbO powder; 325 order PbO powder; 600 order PbO powder; 800 order PbO powder; 1000 order PbO powder; 1200 order PbO powder; 200 order TiO
2Powder, 325 order TiO
2Powder, 600 order TiO
2Powder, 800 order TiO
2Powder, 1000 order TiO
2Powder, 1200 order TiO
2In the powder one or more are 100 parts in the parts by weight of putty type rubber cement, and the add-on of filler is 1-60 part;
The auxiliary agent that adds in the putty type rubber cement of said A component is one or more materials of skimmer DP-2800, skimmer DP-6800, skimmer DF-103, skimmer DF-104, skimmer DF-105, dispersion agent DP-100, dispersion agent DP-270, dispersion agent SM-108, flow agent RM-2020, flow agent EDL-3855, flow agent UH-420, inhibitor VK-B03, inhibitor VK-B04; Parts by weight in putty type rubber cement are 100 parts, and the add-on of auxiliary agent is 0.1-10 part;
The additive of said B component is a kind of of organic amine, silane coupling agent or combination, and the ratio of weight and number of organic solvent and additive is 60-250:100;
Said A component and B component blended ratio of weight and number are 100:1-10;
The organic amine additive of said B component is selected from hexa-methylene diamino formate, mphenylenediamine, diamino-dipropyl methane, N; The two Chinese cassia trees forks-1 of N-, one or more of 6-hexanediamine, Dyhard RU 100, polymeric amide, NSC 446, diethylene tetramine, quadrol, hexanediamine, m-xylene diamine, boron trifluoride ethylamine, boron trifluoride aniline;
Said B component silane coupling agent be selected from γ-An Bingjisanyiyangjiguiwan; γ-glycidyl ethers propyl-triethoxysilicane; γ-(methacrylate based) propyl trimethoxy silicane, one or more in gamma-mercaptopropyltriethoxysilane, vinyl silane tri-butyl peroxide, γ-vinyltriethoxysilane, anilinomethyl triethoxysilane, the γ-aminoethyl-β-aminopropyl trimethoxysilane;
The organic solvent of said B component is the one or more combination of acetone, methylethylketone, MIBK, pimelinketone, methyl-formiate, ethyl formate, ETHYLE ACETATE, butylacetate, methyl alcohol, ethanol, butanols, toluene, YLENE.
2. chimney according to claim 1, flue and other pipeline and container gather fluoropolymer organic lining anticorrosive material; It is characterized in that: the material that forms rubber unvulcanizate in the said A component also has vulcanizing agent; Said vulcanizing agent is selected from one or more of organo-peroxide, diamines and verivate thereof, dihydric phenol; In the rubber raw materials in part by weight is 100 parts, and it is 1-15 part that vulcanizing agent adds weight.
3. chimney according to claim 1, flue and other pipeline and container gather fluoropolymer organic lining anticorrosive material, it is characterized in that: the fluorine content of the used rubber raw material of said A component is 65%-70%.
4. chimney according to claim 1, flue and other pipeline and container gather fluoropolymer organic lining anticorrosive material, it is characterized in that: the fiber-like material that the reinforcing filler of said A component is selected for use comprises thomel, spun glass, wood fibre, magnesiumcarbonate fiber.
5. chimney according to claim 2, flue and other pipeline and container gather fluoropolymer organic lining anticorrosive material, it is characterized in that: the organo-peroxide that said A component is selected for use is selected from one or more in methylethyl ketone peroxide, Lucidol, the Di Cumyl Peroxide 99.
6. chimney according to claim 2, flue and other pipeline and container gather fluoropolymer organic lining anticorrosive material; It is characterized in that: diamines that said A component is selected for use and verivate thereof are selected from hexa-methylene diamino formate, hexanediamine base formate, quadrol base formate, N; The two Chinese cassia tree forks-1 of N-; 6-hexanediamine, two-(4-ammonia hexyl cyclohexyl) methane carbaminate, 2, one or more of two (4-phenylor) propane of 2-.
7. chimney according to claim 2, flue and other pipeline and container gather fluoropolymer organic lining anticorrosive material, it is characterized in that: the dihydric phenol that said A component is selected for use is selected from 4,4'-(hexafluoroisopropyli,ene) bis-phenol.
8. chimney according to claim 1, flue and other pipeline and container gather fluoropolymer organic lining anticorrosive material, it is characterized in that: the parts by weight in putty type rubber cement are 100 parts, and the add-on of filler is 5-50 part.
9. chimney according to claim 1, flue and other pipeline and container gather fluoropolymer organic lining anticorrosive material, it is characterized in that: the parts by weight in putty type rubber cement are 100 parts, and the add-on of auxiliary agent is 0.5-5 part.
10. a chimney, flue and other pipeline and container gathers fluoropolymer organic lining anticorrosive material; It is characterized in that: said material is made up of A and two kinds of components of B, and the A component is to be raw material by fluorine-containing rubber earlier, adds stablizer and reinforcing filler again and carries out mixing; Form rubber unvulcanizate; Make solvent with ketone, ester class or alcohols then, putty type rubber cement is processed in dissolving, adds filler therein again and auxiliary agent is processed; The B component is additive and organic solvent; After A, B component mix, be coated with and be contained in by preserver surface, sulfuration at room temperature forms preservative coat, reaches anticorrosion purpose;
The used rubber raw material of said A component is one or more of ternary fluororubber of binary or vinylidene/tetrafluoroethylene/hexafluoropropylene, the vinylidene/tetrafluoroethylene/five fluorine propylene of vinylidene/R 1216, vinylidene/trifluorochloroethylene, vinylidene/five fluorine propylene, the tetrafluoroethylene/propylene of 55%-71% for fluorine content;
The stablizer of said A component is selected from one or more of quicklime, Natural manganese dioxide, plumbous oxide, zinc oxide and its esters; In the rubber raw materials in part by weight is 100 parts, and it is 5-40 part that stablizer adds weight;
The reinforcing filler of said A component is selected from one or more of carbon black, Calcium Fluoride (Fluorspan), zeyssatite, potter's clay, graphite, talcum powder, mica powder or fiber-like material, is 100 parts in the rubber raw materials in part by weight, and it is 3～50 parts that reinforcing filler adds weight;
The filler that adds in the putty type rubber cement of said A component is: the 1mm-3mm spun glass; The 3mm-5mm spun glass; The 5mm-8mm spun glass; The 8mm-10mm spun glass; The 10mm-20mm spun glass; The 1mm-3mm wood fibre; The 3mm-5mm wood fibre; The 5mm-8mm wood fibre; The 8mm-10mm wood fibre; The 10mm-20mm wood fibre; The 1mm-3mm trevira; The 3mm-5mm trevira; The 5mm-8mm trevira; The 8mm-10mm trevira; The 10mm-20mm trevira; 20 order glass flakes; 40 order glass flakes; 60 order glass flakes; 80 order glass flakes; 100 order glass flakes; 140 order glass flakes; 160 order glass flakes; 200 order glass flakes; 250 order glass flakes; 325 order glass flakes; 600 order glass flakes; 800 order glass flakes; 1000 order glass flakes; 200 order MgO powder; 325 order MgO powder; 600 order MgO powder; 800 order MgO powder; 1000 order MgO powder; 1200 order MgO powder; 200 order CaO powder; 325 order CaO powder; 600 order CaO powder; 800 order CaO powder; 1000 order CaO powder; 1200 order CaO powder; 200 order ZnO powders; 325 order ZnO powders; 600 order ZnO powders; 800 order ZnO powders; 1000 order ZnO powders; 1200 order ZnO powders; 200 order PbO powder; 325 order PbO powder; 600 order PbO powder; 800 order PbO powder; 1000 order PbO powder; 1200 order PbO powder; 200 order TiO
2Powder, 325 order TiO
2Powder, 600 order TiO
2Powder, 800 order TiO
2Powder, 1000 order TiO
2Powder, 1200 order TiO
2In the powder one or more are 100 parts in the parts by weight of putty type rubber cement, and the add-on of filler is 1-60 part;
The auxiliary agent that adds in the putty type rubber cement of said A component is one or more materials of skimmer DP-2800, skimmer DP-6800, skimmer DF-103, skimmer DF-104, skimmer DF-105, dispersion agent DP-100, dispersion agent DP-270, dispersion agent SM-108, flow agent RM-2020, flow agent EDL-3855, flow agent UH-420, inhibitor VK-B03, inhibitor VK-B04; Parts by weight in putty type rubber cement are 100 parts, and the add-on of auxiliary agent is 0.1-10 part;
The additive of said B component comprises a kind of of organic amine, silane coupling agent or combination, and the ratio of weight and number of organic solvent and additive is 60-250:100; Also comprise organo-peroxide, in 100 parts of other weight of additive umbers, the add-on of organo-peroxide is 100-300 part;
Said A component and B component blended ratio of weight and number are 100:1-10;
The organic amine additive of said B component is selected from hexa-methylene diamino formate, mphenylenediamine, diamino-dipropyl methane, N; The two Chinese cassia trees forks-1 of N-, one or more of 6-hexanediamine, Dyhard RU 100, polymeric amide, NSC 446, diethylene tetramine, quadrol, hexanediamine, m-xylene diamine, boron trifluoride ethylamine, boron trifluoride aniline;
Said B component silane coupling agent be selected from γ-An Bingjisanyiyangjiguiwan; γ-glycidyl ethers propyl-triethoxysilicane; γ-(methacrylate based) propyl trimethoxy silicane, one or more in gamma-mercaptopropyltriethoxysilane, vinyl silane tri-butyl peroxide, γ-vinyltriethoxysilane, anilinomethyl triethoxysilane, the γ-aminoethyl-β-aminopropyl trimethoxysilane;
The organic solvent of said B component is the one or more combination of acetone, methylethylketone, MIBK, pimelinketone, methyl-formiate, ethyl formate, ETHYLE ACETATE, butylacetate, methyl alcohol, ethanol, butanols, toluene, YLENE.
11. chimney according to claim 10, flue and other pipeline and container gather fluoropolymer organic lining anticorrosive material, it is characterized in that: the organo-peroxide of said B component is selected from methylethyl ketone peroxide, Lucidol.
12. chimney according to claim 1, flue and other pipeline and container gather fluoropolymer organic lining anticorrosive material, it is characterized in that: said rubber is when mixing, and glue furnacing temperature remains on below 60 ℃, the control of refining glue amount as follows:
150mm rubber mixing machine per car dress glue amount is no more than 1kg, and the 230mm rubber mixing machine should be controlled at 3kg, and the 360mm rubber mixing machine is 5～9kg;
When mixing, order of addition(of ingredients) is followed successively by rubber, stablizer, reinforcing filler, and the roller speed ratio selects 1: (1-1.5).
13. chimney according to claim 12, flue and other pipeline and container gather fluoropolymer organic lining anticorrosive material, it is characterized in that: the said sizing material that mixes carries out back mixing before with dissolution with solvents, back mixing adopts pony roll apart from thin logical 3-5 time.
14. chimney according to claim 1, flue and other pipeline and container gather fluoropolymer organic lining anticorrosive material, it is characterized in that: be used for preparing the ketones solvent that dissolves rubber unvulcanizate in the said A component and select one or more of acetone, methylethylketone, MIBK, pimelinketone for use; Said esters solvent is selected one or more in methyl-formiate, ethyl formate, ETHYLE ACETATE, the butylacetate for use; Said alcoholic solvent is selected from one or more in methyl alcohol, ethanol, the butanols; Be dissolved in the reaction kettle and carry out, than being rubber unvulcanizate: solvent=100:150-400, behind the adding solvent, slowly add mixing blob of viscose more by weight, the rotating speed of phonomoter is controlled at 5-800 rev/min; The concentration that forms putty type rubber cement in the said A component is 20～60%.
15. chimney according to claim 14, flue and other pipeline and container gather fluoropolymer organic lining anticorrosive material, it is characterized in that: the rotating speed of said phonomoter is controlled at 10-100 rev/min rotating speed.
16. utilize chimney and the flue of fluoropolymer organic lining anticorrosive material after for desulfurization that gather of each described chimney, flue and other pipeline and the container of claim 1-14 to carry out antiseptic constructional method, step is following:
(1) chimney and flue inwall are carried out base treatment;
(2) seam is repaiied in substrate and handled, patching material is potassium silicate inorganic clay, water glass acid resistant adhesive mortar, resin-bonded mastic, Zylox or fluororubber material;
(3) the described inside lining anti-corrosive material of one of blade coating claim 1-14, wet-film thickness is controlled at 0.3-3mm, surfacing, temperature is more than 10 ℃, and humidity is below 85%;
(4) maintenance: room temperature: 1-3 days, or heat: after 50-80 ℃ of maintenance 3-8 hour, again at 100-150 ℃ of maintenance 12-48 hour.
17. utilize claim 1-14 each described chimney, flue and other container and pipeline gather the maintenance rotproofing constructional method that chimney and foam glass brick in flue or ceramic tile and the sticker thereof of fluoropolymer organic lining anticorrosive material after for desulfurization protected, step is following:
(1) chimney and flue inwall are carried out base treatment;
(2) foam glass brick or ceramic tile are repaiied the seam processing, patching material is a Zylox, sees just benefit of seam, changes damaged brick body;
(3) the described inside lining anti-corrosive material of one of blade coating claim 1-14, wet-film thickness is controlled at 0.3-3mm, surfacing, temperature is more than 10 ℃, and humidity is below 85%;
(4) maintenance: room temperature: 1-3 days, or heat: after 50-80 ℃ of maintenance 3-8 hour, again at 100-150 ℃ of maintenance 12-48 hour.
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