Summary of the invention
The object of the present invention is to provide a kind of finish coat mortar take desulfurated plaster as base-material of wall insulation system special use, this finish coat mortar is take desulfurated plaster as base-material, be aided with other industrial solid castoff and calcium lime powder and form composite gelled material, with calcium chloride as chemical activator, with quartz sand for gathering materials, take calcium-base bentonite and Mierocrystalline cellulose-acrylate graft copolymers as water-holding agent, the special-purpose finish coat mortar of the heat-insulation system take cellulosic fibre as the stress dispersion anti-fissuring agent.Finish coat mortar of the present invention can use after directly adding at the construction field (site) the water stirring, and ultimate compression strength is moderate after the product sclerosis, and is high with the thermal insulation mortar cohesive strength, good toughness, and water-tolerant, shrinking percentage is little.
The finish coat mortar take desulfurated plaster as base-material of a kind of wall insulation system special use that the present invention proposes, this finish coat mortar is comprised of desulfurated plaster, flyash, metakaolin, calcining coal gangue, calcium lime powder, calcium chloride, 50-80 order quartz sand, 100-120 order quartz sand, calcium-base bentonite, Mierocrystalline cellulose-acrylate graft copolymers and cellulosic fibre.The weight ratio of its component is as follows:
Desulfurated plaster 100
Flyash 20-100
Metakaolin 30-150
Calcining coal gangue 20-120
Calcium lime powder 5-18
Calcium chloride 2-10
50-80 order quartz sand 400-1200
100-120 order quartz sand 200-800
Calcium-base bentonite 2-16
Mierocrystalline cellulose-acrylate graft copolymers 0.3-1.0
Cellulosic fibre 0.4-2.0.
The better weight ratio of each component is:
Desulfurated plaster 100
Flyash 40-95
Metakaolin 45-130
Calcining coal gangue 45-110
Calcium lime powder 5-12
Calcium chloride 4-9
50-80 order quartz sand 550-1100
100-120 order quartz sand 300-700
Calcium-base bentonite 4-13
Mierocrystalline cellulose-acrylate graft copolymers 0.4-0.9
Cellulosic fibre 0.6-1.8.
Among the present invention, its SO of described desulfurated plaster
3Weight content more than or equal to 42% less than 60%.
Among the present invention, described flyash is a kind of in I level F class flyash or the II level F class flyash.
Among the present invention, described metakaolin be natural kaolin 600-1000 ℃ of calcining more than 1.5 hours and levigate to specific surface area greater than 350m
2The powder of/Kg.
Among the present invention, described calcining coal gangue be the raw coal spoil 600-950 ℃ of calcining more than 2.0 hours and levigate to specific surface area greater than 380m
2The powder of/Kg.
Among the present invention, the length of described cellulosic fibre less than 9mm greater than 0mm.
The preparation method of the finish coat mortar that the present invention proposes, its concrete steps are as follows:
(1) take by weighing by weight raw material, and with 50-80 order quartz sand, 100-120 order quartz sand, in advance dry mixing of cellulosic fibre is to uniform state;
(2) desulfurated plaster, flyash, metakaolin, calcining coal gangue, calcium lime powder, calcium chloride, calcium-base bentonite and Mierocrystalline cellulose-acrylate graft copolymers are added in the mixture in the step (1);
(3) be mixed to uniform state;
More than each step all under normal temperature and normal pressure, carry out.
The finish coat mortar using method of gained of the present invention is: adds and can take after the water uniform mixing streak method to carry out the finish coat construction, and can compound alkali resistant glass fibre open weave cloth and Galvanized Steel Wire Netting, form the integral body with certain impact toughness after the dry sclerosis.
Among the present invention, desulfurated plaster, flyash, metakaolin, calcining coal gangue, calcium lime powder form the cementitious material system of polycomponent non-cement grog jointly.Flyash, metakaolin and calcining coal gangue all contain aluminium sesquioxide and the ferric oxide that has in a large number lateral reactivity, under the alkali environment that the calcium hydroxide that they generate at calcium lime powder chance water hydratable provides, be combined with the sulfate ion of desulfurated plaster stripping, form the extremely low ettringite (3CaO.Al of solubleness
2O
3(Fe
2O
3) .3CaSO
4.32H
2O), the active silica in them is then met the calcium hydroxide that water hydratable generates with calcium lime powder, forms the CSH gel, is filled in the ettringite overlap joint, piles up in the formed spatial network, improves intensity.The existence of calcium chloride can be played and excite flyash, the effect of metakaolin and calcining coal gangue activity.50-80 order quartz sand and 100-120 order quartz sand are as gathering materials, and after mutually arranging in pairs or groups by preferred proportion, the accumulation degree is maximum, can play the effect that hardened paste shrinks and reduce paste content that suppresses.Calcium-base bentonite is a kind of water-swelling and water-retentivity material, and with desulfurated plaster in the product of the present invention, flyash, metakaolin, calcining coal gangue, calcium lime powder and calcium chloride have preferably consistency.Mierocrystalline cellulose-acrylate graft copolymers is a kind of novel water-retaining agent, has preferably water retention capacity, and maintenance action in playing preferably to product of the present invention, improves its interface binding intensity.The adding of cellulosic fibre then makes a large amount of staple fibres that distributing in the product of the present invention, helps dispersive stress, resists the cracking in the dry shrinkage, and can improve the toughness of product of the present invention.
A kind of finish coat mortar take desulfurated plaster as base-material of wall insulation system special use of the present invention, utilized in a large number the industrial solid castoff desulfurated plaster, flyash, metakaolin and calcining coal gangue, production technique is simple, the starting material wide material sources, and performance is better than the like product take cement as base-material, the products production cost can reduce 12%-18%, has preferably market outlook.
Embodiment
The following examples are to further specify of the present invention, rather than limit the scope of the invention.
Embodiment 1
A kind of finish coat mortar take desulfurated plaster as base-material of wall insulation system special use is counted desulfurated plaster 100 by weight, I level F class flyash 100, metakaolin 30, calcining coal gangue 20, calcium lime powder 5, calcium chloride 2,50-80 order quartz sand 400,100-120 order quartz sand 200, calcium-base bentonite 2, Mierocrystalline cellulose-acrylate graft copolymers 0.3, the weight ratio of cellulosic fibre 0.4 is formulated.After water that adding accounts for this product weight 20% stirs, its operable time is 4.0 hours, tensile bond strength (normal temperature 28 days) is 1.1MPa, immersion tensile bond strength (normal temperature 28 days, soaked 7 days) be 0.8MPa, ultimate compression strength is 21.2MPa, and the backfin ratio is 2.6, and shrinking percentage is less than 0.2%.
Embodiment 2
A kind of finish coat mortar take desulfurated plaster as base-material of wall insulation system special use is counted desulfurated plaster 100 by weight, II level F class flyash 20, metakaolin 150, calcining coal gangue 120, calcium lime powder 12, calcium chloride 10,50-80 order quartz sand 800,100-120 order quartz sand 650, calcium-base bentonite 10, Mierocrystalline cellulose-acrylate graft copolymers 0.7, the weight ratio of cellulosic fibre 1.4 is formulated.After water that adding accounts for this product weight 33% stirs, its operable time is 4.2 hours, tensile bond strength (normal temperature 28 days) is 1.0MPa, immersion tensile bond strength (normal temperature 28 days, soaked 7 days) be 0.9MPa, ultimate compression strength is 18.0MPa, and the backfin ratio is 2.8, and shrinking percentage is less than 0.2%.
Embodiment 3
A kind of finish coat mortar take desulfurated plaster as base-material of wall insulation system special use is counted desulfurated plaster 100 by weight, II level F class flyash 90, metakaolin 130, calcining coal gangue 100, calcium lime powder 18, calcium chloride 8,50-80 order quartz sand 1200,100-120 order quartz sand 800, calcium-base bentonite 14, Mierocrystalline cellulose-acrylate graft copolymers 0.9, the weight ratio of cellulosic fibre 1.3 is formulated.After water that adding accounts for this product weight 37% stirs, its operable time is 3.2 hours, tensile bond strength (normal temperature 28 days) is 1.2MPa, immersion tensile bond strength (normal temperature 28 days, soaked 7 days) be 0.8MPa, ultimate compression strength is 21.0MPa, and the backfin ratio is 2.9, and shrinking percentage is less than 0.2%.
Embodiment 4
A kind of finish coat mortar take desulfurated plaster as base-material of wall insulation system special use is counted desulfurated plaster 100 by weight, I level F class flyash 100, metakaolin 150, calcining coal gangue 120, calcium lime powder 18, calcium chloride 10,50-80 order quartz sand 1200,100-120 order quartz sand 800, calcium-base bentonite 16, Mierocrystalline cellulose-acrylate graft copolymers 1.0, the weight ratio of cellulosic fibre 2.0 is formulated.After water that adding accounts for this product weight 42% stirs, its operable time is 3.9 hours, tensile bond strength (normal temperature 28 days) is 1.3MPa, immersion tensile bond strength (normal temperature 28 days, soaked 7 days) be 1.0MPa, ultimate compression strength is 17.5MPa, and the backfin ratio is 2.7, and shrinking percentage is less than 0.2%.