CN101880766A - Compound type binder used for pellet - Google Patents
Compound type binder used for pellet Download PDFInfo
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- CN101880766A CN101880766A CN2010102224780A CN201010222478A CN101880766A CN 101880766 A CN101880766 A CN 101880766A CN 2010102224780 A CN2010102224780 A CN 2010102224780A CN 201010222478 A CN201010222478 A CN 201010222478A CN 101880766 A CN101880766 A CN 101880766A
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- pellet
- complex adhesive
- clay powder
- sodium humate
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Abstract
The invention discloses a compound type binder used for pellet, which comprises the following raw materials in percentage by weight: 70-80% of clay powder, 10-20% of sodium humate, 3-6% of sodium carboxymethyl cellulose and 2-4% of sodium carbonate. The compound type binder used for the pellet of the invention is a pellet binder prepared by combining inorganic substance and organic substance, has good hydrophily and high viscosity, can be dissolved into water, replaces bentonite completely, has extremely low carry-in amount of detrimental impurity of the inorganic substance and does not influence the iron grade of the pellet; and when added into iron finemeal pellet for production, the invention does not change the original process and is an ideal and synergistic pellet binder.
Description
One, technical field:
The present invention relates to a kind of used binding agent of oxide pellet of producing, particularly relate to a kind of used complex adhesive of oxide pellet of producing.
Two, background technology:
The iron ore oxide pellet has advantages such as epigranular, cold strength height, iron be of high grade, Well-recovered, is a kind of fine blast furnace burden, in recent years acid pellet in China's development rapidly, annual capacity has reached more than 100,000,000 tons.Iron concentrate pelletization need add binding agent, makes pelletizing have certain intensity, satisfies it and is kept perfectly and unlikely fragmentation in processes such as running, drying, roasting, and meet the requirement of blast-furnace smelting.Binding agent is as the indispensable raw material of preparation iron ore pellets, and the problem that should be noted that when selecting pellet binder is: (1) will have good cohesiveness and balling-up; (2) Zhi Bei green-ball should have good heat resistanceheat resistant explosion performance, has higher compression and dropping strength simultaneously; (3) binding agent does not influence the iron grade of finished ball nodulizing as far as possible.At present, domestic and international most pelletizing plants produce pelletizing and generally adopt wilkinite as binding agent, and its consumption is generally 2.0～3.0, and high person reaches 5%.Wilkinite is the alumino-silicate clays mineral, SiO
2, Al
2O
3Content is up to 70～95%.Knowhow shows that the wilkinite of every adding 1% can be brought 0.6～0.7% SiO into
2, make the iron grade reduce about 0.6%.The reduction of iron grade and the increase of gangue content are disadvantageous to blast-furnace smelting, the every decline 1% of iron grade, and coke ratio rises 2%, and furnace processor descends 3%; SiO
2Every rising 1%, ton scum amount increases 30kg.Therefore, improve pellet iron grade, reduce SiO
2Content realizes that to blast furnace high yield, low consumption are significant.A kind ofly can not bring the binding agent of impurity to substitute wilkinite to prepare pelletizing, will be the method in a kind of good production quality pellets ore deposit if can use to pelletizing.
Then, further work out a kind of organic binder bond, organic binder bond is the high molecular polymer of natural high moleculer eompound or synthetic, has good wetting ability, the water-soluble solution that makes has very high viscosity, is a kind of more satisfactory alternative bentonitic pellet binder.But, prepare in the acid pellet process at using organic binder, also have following problem: (1) is because the high-hydrophilic and the high-adhesion of organic adhesive, when it adds in the moisture iron ore concentrate, binding agent is met water and just is easy to agglomerating, outer suction back forms viscosity, the good mucous membrane of toughness, the binding agent that promptly uses intensive mixer also to be difficult to bond together spreads out, cause it in iron ore concentrate, to be difficult to be uniformly dispersed, make easy Cheng Daqiu in the ball process, and the quality of green-ball is inhomogeneous, makes that the green-ball qualification rate is low, brings great difficulty to pellet forming process; (2) because the organic binder bond consumption is little, the fluctuation in the interpolation process is very big to the production process influence; (3) form little pore because organic binder bond decomposes or burns in the drying and preheating process,, make its finished ball intensity compare and adopt the pelletizing of wilkinite preparation that reduction is largely arranged for the part concentrate.Thereby the existence of the problems referred to above has limited the application of organic binder bond in China's acid pellet is produced.Therefore, develop a kind of can the solution simultaneously and adopt wilkinite and organic binder bond the two is used for the binding agent of the existing problem of pellet formation process, be very important.
Three, summary of the invention:
The technical problem to be solved in the present invention is: in order to solve the existing problem of above-mentioned pellet binding agent, the invention provides a kind of complex adhesive that adopts inorganics and organism to combine, can fully instead of bentonite produce acid pellet.
The technical solution used in the present invention is:
The invention provides a kind of complex adhesive of used for pellet, represent with weight percentage, described complex adhesive raw material contains clay powder 70～80%, sodium humate 10～20%, Xylo-Mucine 3～6% and soda ash 2～4% in forming.
According to the complex adhesive of above-mentioned used for pellet, described complex adhesive raw material also contains polyoxyethylene in forming, and the add-on of described polyoxyethylene accounts for 2～4 ‰ of clay powder, sodium humate, Xylo-Mucine and soda ash gross weight.
According to the complex adhesive of above-mentioned used for pellet, the granularity of described clay powder is less than 0.074mm.
According to the complex adhesive of above-mentioned used for pellet, the granularity of described sodium humate is less than 0.074mm.
The preparation method of the complex adhesive of used for pellet of the present invention: organism macromolecular material (sodium humate, Xylo-Mucine) joined in the inorganics (clay powder, soda ash) stir, mix and get final product.
Positive beneficial effect of the present invention:
1, pellet complex adhesive of the present invention is to adopt inorganics (clay powder, soda ash) and organism (sodium humate, Xylo-Mucine) to combine and the pellet binding agent made, has wetting ability preferably, and is water-soluble, viscosity is high.Complex adhesive of the present invention adds and has preferably divergent function in the fine iron breeze, do not bring into or bring acid gangue less into, and extremely strong cohesiveness is arranged.
2, the add-on of complex adhesive of the present invention in iron ore extract powder compared with bentonitic add-on, and its add-on is lower, only is 0.8～1.0%, can fully instead of bentonite; And the detrimental impurity amount of bringing into of inorganics is extremely low, and organism decomposition combustion in the pelletizing preparation process does not reduce the pelletizing grade.Thereby complex adhesive of the present invention has overcome a large amount of SiO that bring into when wilkinite adds pellet
2, Al
2O
3Shortcoming, improved pellet iron grade simultaneously.
3, complex adhesive of the present invention is compared with organic binder bond, has overcome organic binder bond under the prior art condition reduces finished ball intensity in high-temperature sintering process defective.
4, product application of the present invention is in the smart sphere of powder nodulizing of iron is produced, and the dropping strength of its green-ball is greater than 5 times/0.5m; When temperature was split in the antiknock of green-ball greater than 850 ℃, finished pellet ultimate compression strength was 2200～2800N/, and reduction degree rises 10%, reduction degradation index decreased 15%, and the reduction swellability rate reduces 8%, thereby has effectively improved the metallurgical performance of pelletizing.
5, complex adhesive of the present invention is nonpoisonous and tasteless, joins the smart sphere of powder nodulizing of iron when producing, and does not change original production technique, is a kind of ideal and can synergistic pellet binder.
6, adopt complex adhesive of the present invention, can reduce SiO in the pellet
2Content is more than 1.2%, and coke ratio descends 2.4% in the blast-furnace smelting, and furnace processor rises more than 3.6%, and ton scum amount reduces about 36kg.Thereby, have the remarkable economical meaning.
Four, embodiment:
Following examples only in order to further specify the present invention, do not limit content of the present invention.
Embodiment 1:
The complex adhesive raw material of used for pellet of the present invention consists of: represent clay powder 75%, sodium humate 16%, Xylo-Mucine 6% and soda ash 3% with weight percentage.
The ingredient requirement that is adopted: the granularity of clay powder is less than 0.074mm; The granularity of sodium humate is less than 0.074mm.
The preparation method of complex adhesive: sodium humate and Xylo-Mucine joined in clay powder and the soda ash stir, mix and get final product.
Embodiment 2: substantially the same manner as Example 1, difference is:
The complex adhesive raw material of used for pellet of the present invention consists of: represent clay powder 70%, sodium humate 20%, Xylo-Mucine 6% and soda ash 4% with weight percentage.
Embodiment 3: substantially the same manner as Example 1, difference is:
The complex adhesive raw material of used for pellet of the present invention consists of: represent clay powder 80%, sodium humate 13%, Xylo-Mucine 5% and soda ash 2% with weight percentage.
Embodiment 4: substantially the same manner as Example 1, difference is:
The complex adhesive raw material of used for pellet of the present invention consists of: represent clay powder 72%, sodium humate 18%, Xylo-Mucine 6% and soda ash 4% with weight percentage.
Embodiment 5: substantially the same manner as Example 1, difference is:
The complex adhesive raw material of used for pellet of the present invention consists of: represent clay powder 78%, sodium humate 15%, Xylo-Mucine 3% and soda ash 4% with weight percentage.
Embodiment 6: substantially the same manner as Example 1, difference is:
The complex adhesive raw material of used for pellet of the present invention consists of: represent clay powder 74%, sodium humate 19%, Xylo-Mucine 4% and soda ash 3% with weight percentage.
Embodiment 7: substantially the same manner as Example 1, difference is:
Used for pellet complex adhesive raw material of the present invention adds polyoxyethylene in forming, and its add-on accounts for clay powder, sodium humate, Xylo-Mucine and soda ash gross weight 2 ‰.
Embodiment 8: substantially the same manner as Example 2, difference is:
Used for pellet complex adhesive raw material of the present invention adds polyoxyethylene in forming, and its add-on accounts for clay powder, sodium humate, Xylo-Mucine and soda ash gross weight 3 ‰.
Embodiment 9: substantially the same manner as Example 3, difference is:
Used for pellet complex adhesive raw material of the present invention adds polyoxyethylene in forming, and its add-on accounts for clay powder, sodium humate, Xylo-Mucine and soda ash gross weight 4 ‰.
Embodiment 10: substantially the same manner as Example 1, difference is:
Used for pellet complex adhesive raw material of the present invention adds polyoxyethylene in forming, and its add-on accounts for clay powder, sodium humate, Xylo-Mucine and soda ash gross weight 2.5 ‰.
Embodiment 11: substantially the same manner as Example 1, difference is:
Used for pellet complex adhesive raw material of the present invention adds polyoxyethylene in forming, and its add-on accounts for clay powder, sodium humate, Xylo-Mucine and soda ash gross weight 3.5 ‰.
Embodiment 12: substantially the same manner as Example 1, difference is:
Used for pellet complex adhesive raw material of the present invention adds polyoxyethylene in forming, and its add-on accounts for clay powder, sodium humate, Xylo-Mucine and soda ash gross weight 2.8 ‰.
Claims (4)
1. the complex adhesive of a used for pellet is characterized in that: represent that with weight percentage described complex adhesive raw material contains clay powder 70～80%, sodium humate 10～20%, Xylo-Mucine 3～6% and soda ash 2～4% in forming.
2. the complex adhesive of used for pellet according to claim 1, it is characterized in that: described complex adhesive raw material also contains polyoxyethylene in forming, and the add-on of described polyoxyethylene accounts for 2～4 ‰ of clay powder, sodium humate, Xylo-Mucine and soda ash gross weight.
3. the complex adhesive of used for pellet according to claim 1 and 2 is characterized in that: the granularity of described clay powder is for less than 0.074mm.
4. the complex adhesive of used for pellet according to claim 1 and 2 is characterized in that: the granularity of described sodium humate is for less than 0.074mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010222478 CN101880766B (en) | 2010-07-09 | 2010-07-09 | Compound type binder used for pellet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010222478 CN101880766B (en) | 2010-07-09 | 2010-07-09 | Compound type binder used for pellet |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101880766A true CN101880766A (en) | 2010-11-10 |
| CN101880766B CN101880766B (en) | 2013-05-29 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010222478 Expired - Fee Related CN101880766B (en) | 2010-07-09 | 2010-07-09 | Compound type binder used for pellet |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103820638A (en) * | 2014-02-26 | 2014-05-28 | 廊坊紫光化工建材有限公司 | Pellet binder |
| CN104004906A (en) * | 2014-03-12 | 2014-08-27 | 北京宇航同辉能源科技有限公司 | Pellet additive and preparation method thereof |
| CN104229813A (en) * | 2014-08-28 | 2014-12-24 | 中南大学 | Preparation method and application of modified bentonite |
| CN104805279A (en) * | 2015-05-27 | 2015-07-29 | 李建文 | Magnesium-containing compounded additive and preparation method thereof |
| CN104977252A (en) * | 2015-06-30 | 2015-10-14 | 武汉钢铁(集团)公司 | Method for determining adhesion performance of adhesive particles in iron ore sintered materials |
| CN105505501A (en) * | 2016-01-04 | 2016-04-20 | 孟力 | Production method of refined flammable portable type moulded coal |
| CN105907954A (en) * | 2016-06-06 | 2016-08-31 | 江苏省冶金设计院有限公司 | Composite bonding agent and application of composite bonding agent in mineral powder forming |
| CN105950862A (en) * | 2016-07-21 | 2016-09-21 | 北京神雾环境能源科技集团股份有限公司 | Composite binder for formation of copper slag carbon-containing pellets |
| CN108103309A (en) * | 2017-12-19 | 2018-06-01 | 东北大学 | A kind of converter dust-removing ash coal-pressing ball adhesive special |
| CN112195338A (en) * | 2020-09-23 | 2021-01-08 | 山东金团新材料科技有限公司 | High-efficiency energy-saving composite material additive for metallurgical pellets |
| CN112745133A (en) * | 2020-12-31 | 2021-05-04 | 河南强耐新材股份有限公司 | Fly ash-based high-strength ceramsite and preparation method thereof |
| CN113122710A (en) * | 2021-03-16 | 2021-07-16 | 赵万英 | Composite pellet soil additive and composite pellet soil production method |
Citations (2)
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|---|---|---|---|---|
| CN1229144A (en) * | 1998-03-17 | 1999-09-22 | 李学曾 | Compound binder for pelletizing ore and technology thereof |
| CN101570821A (en) * | 2009-06-15 | 2009-11-04 | 中南大学 | Sintering method of high proportion specularite concentrate |
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2010
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Patent Citations (2)
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|---|---|---|---|---|
| CN1229144A (en) * | 1998-03-17 | 1999-09-22 | 李学曾 | Compound binder for pelletizing ore and technology thereof |
| CN101570821A (en) * | 2009-06-15 | 2009-11-04 | 中南大学 | Sintering method of high proportion specularite concentrate |
Non-Patent Citations (2)
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| 《烧结球团》 19970531 黄天正 球团添加物的研究现状与发展 第6页倒数第2段 1-4 第22卷, 第3期 2 * |
| 周取定 等: "《铁矿石造块理论及工艺》", 31 May 1989 * |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103820638A (en) * | 2014-02-26 | 2014-05-28 | 廊坊紫光化工建材有限公司 | Pellet binder |
| CN104004906A (en) * | 2014-03-12 | 2014-08-27 | 北京宇航同辉能源科技有限公司 | Pellet additive and preparation method thereof |
| CN104229813A (en) * | 2014-08-28 | 2014-12-24 | 中南大学 | Preparation method and application of modified bentonite |
| CN104805279A (en) * | 2015-05-27 | 2015-07-29 | 李建文 | Magnesium-containing compounded additive and preparation method thereof |
| CN104977252A (en) * | 2015-06-30 | 2015-10-14 | 武汉钢铁(集团)公司 | Method for determining adhesion performance of adhesive particles in iron ore sintered materials |
| CN105505501A (en) * | 2016-01-04 | 2016-04-20 | 孟力 | Production method of refined flammable portable type moulded coal |
| CN105907954A (en) * | 2016-06-06 | 2016-08-31 | 江苏省冶金设计院有限公司 | Composite bonding agent and application of composite bonding agent in mineral powder forming |
| CN105950862A (en) * | 2016-07-21 | 2016-09-21 | 北京神雾环境能源科技集团股份有限公司 | Composite binder for formation of copper slag carbon-containing pellets |
| CN108103309A (en) * | 2017-12-19 | 2018-06-01 | 东北大学 | A kind of converter dust-removing ash coal-pressing ball adhesive special |
| CN112195338A (en) * | 2020-09-23 | 2021-01-08 | 山东金团新材料科技有限公司 | High-efficiency energy-saving composite material additive for metallurgical pellets |
| CN112745133A (en) * | 2020-12-31 | 2021-05-04 | 河南强耐新材股份有限公司 | Fly ash-based high-strength ceramsite and preparation method thereof |
| CN112745133B (en) * | 2020-12-31 | 2023-03-24 | 河南强耐新材股份有限公司 | Fly ash-based high-strength ceramsite and preparation method thereof |
| CN113122710A (en) * | 2021-03-16 | 2021-07-16 | 赵万英 | Composite pellet soil additive and composite pellet soil production method |
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| Publication number | Publication date |
|---|---|
| CN101880766B (en) | 2013-05-29 |
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