CN101870518B - Anaerobe reactor for treating sewage - Google Patents

Anaerobe reactor for treating sewage Download PDF

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CN101870518B
CN101870518B CN2010102301467A CN201010230146A CN101870518B CN 101870518 B CN101870518 B CN 101870518B CN 2010102301467 A CN2010102301467 A CN 2010102301467A CN 201010230146 A CN201010230146 A CN 201010230146A CN 101870518 B CN101870518 B CN 101870518B
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reactor
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sewage
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CN101870518A (en
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刘灿明
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JIANGSU ZEYU ENVIRONMENTAL ENGINEERING Co Ltd
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JIANGSU ZEYU ENVIRONMENTAL ENGINEERING Co Ltd
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Abstract

The invention discloses a CAFT efficient anaerobe reactor for treating sewage, which relates to sewage treating equipment. The CAFT efficient anaerobe reactor comprises a convection area, a suction area and a buffering area. The CAFT efficient anaerobe reactor is characterized in that: anaerobic microorganisms are placed in the convection area; a water distributor for inletting the sewage is arranged at the bottom of the convection area; a plurality of inclined tube settlers are slantways arranged on an upper part of the convection area; the suction area is in communicated connection with the upper part of the convection area; and fillers are placed in the suction area; the buffering area is arranged above the suction area; and a three-phase separator is arranged in the buffering area. The CAFT efficient anaerobe reactor for treating the sewage solves the problems of complicated structure of an anaerobe reactor, instability of a system, substandard water purification effect and high maintaining cost in the prior art, and the provided CAFT efficient anaerobe reactor has the characteristics of simple structure, low manufacturing and maintaining cost, and high removal rate of organic contaminants and the like. The CAFT efficient anaerobe reactor is mainly applied to treatment of wastewater with medium and high-concentration organic matters in brewage, starch processing, biological pharmacy, organic chemical industry, poultry farming, papermaking and the like.

Description

A kind of anaerobic biological reactor that is used for sewage disposal
Technical field
The present invention relates to a kind of sewage disposal device, particularly relate to a kind of utilize anaerobion dispose of sewage in the anaerobic biological reactor equipment of organic pollutant, anaerobic biological treatment is as the metabolic characteristic that utilizes anerobe, need not to provide under the condition of external source energy, to be reduced organism, produce the methane gas that has the energy to be worth simultaneously as hydrogen acceptor.
Background technology
At present using maximum anaerobic biological reactors in the world is the UASB anaerobic biological reactor.This reactor is called as s-generation anaerobic biological reactor.Be characterized in technology maturation, make easy.Along with the utilization of fluidized reaction theory, the UASB reactor that is characteristics with metastable anaerobe bed demonstrates the low inferior position of reaction efficiency.And with anaerobic expanded granular sludge bed (Expanded Granular Sludge Bed, EGSB), internal-circulation type anaerobic reactor (Interna.1Cycle, IC), composite anaerobic sludge bed reactor (Hybrid Anaerobic Reactor, HAR), anaerobic fluidized bed reactor (Anaerobic Fluidized bed rea.ctors, FB) and the baffling type anaerobic reactor (Anaerobic Baffled Reactor ABR) is the new and effective anaerobic reactor of the third generation of representative.The new and effective anaerobic reactor of the third generation has some common characteristics: 1) microorganism all is present in the reactor in the immobilized mode of granule sludge, and it is higher that unit volume reaches the microorganism volume of holding; 2) can bear higher hydraulic load, have higher organic pollutant purification efficiency; 3) have bigger aspect ratio, floor space is little, and power consumption is little; 4) have better mass transfer between granule sludge and the organism, the processing power of reactor is improved greatly.But in secular practical application, above-mentioned reactor has also shown the some shortcomings parts: as EGSB owing in whole reactor, kept very high current upflow velocity, and because the cohesive action of the methane bubble that produces, make in the flow velocity at triphase separator place quite high, when working conditions change is big, make a large amount of organisms run off, cause system's water outlet effect not up to standard, cause system crash when serious.Some have been built in the project in American-European countries, because the instability of system has to keep upflow velocity in lower scope during operation, have reduced this processing power that has; And the structure of IC reactor actual be the stack of two UASB reactors, the bubbles entrain granule sludge that utilize to produce circulates at reaction zone, because reactor has two triphase separators, makes the complex structure of reactor, makes and the maintenance cost height; Start time while is long, the technical requirements height, and China has only less large-scale company to afford its construction and maintenance cost as developing country.
Summary of the invention
In order to solve anaerobic biological reactor complex structure in the prior art, system's instability, purifying water effect is not up to standard, the maintenance cost problem of higher, the invention provides a kind of CAFT efficient anaerobe reactor, have simple in structure, make and maintenance cost low, characteristics such as organic pollutant removal rate height.
In order to achieve the above object, the technical solution used in the present invention is:
A kind of anaerobic biological reactor that is used for sewage disposal, comprise convective region, adsorption zone and buffer zone, it is characterized in that: be placed with the anaerobion bacterium in the described convective region, be provided with the water distributor that feeds sewage in the bottom of convective region, the upper angled in the convective region is provided with some tube settlers; Above the convective region, connect and be connected with adsorption zone, be placed with filler in adsorption zone inside; Above adsorption zone, be provided with buffer zone, in buffer zone, be provided with triphase separator, described triphase separator comprises liquid displacement zone, solids constituent abscission zone and gas disengaging zone, described gas delivery district is connected with the biogas vent pipe, described liquid displacement zone with go out water discharge pipe and be connected, in the solids constituent abscission zone, be provided with the settler that is used to collect the bigger anaerobion bacterium of proportion, described settler is connected with an end of external circulating system, and the other end of described external circulating system is connected with the convective region.
Aforesaid a kind of anaerobic biological reactor that is used for sewage disposal is characterized in that: described filler is a high-density packing.
Aforesaid a kind of anaerobic biological reactor that is used for sewage disposal is characterized in that: described biogas vent pipe is connected with sludge gas collecting device.
Aforesaid a kind of anaerobic biological reactor that is used for sewage disposal is characterized in that: described reactor is the stdn casing, highly is 10m, volumetric loading 8~40kgCOD/m 3.d.
The invention has the beneficial effects as follows: the CAFT efficient anaerobe reactor is a kind of new and effective anaerobic biological reactor that grows up on the UASB basis, and also is simultaneously the improvement to third generation anaerobic biological reactor.The CAFT advantage has adopted special internal structure, makes it not need huge separation bin, does not also need " stature " that additionally exceed, obtains better fluid effect by external circulating system, has higher organic pollutant removal rate.Because it is simple relatively that CAFT constructs ingenious structure, effluent quality is high and stable, do not need multistage setting can once reach design anaerobism water outlet requirement, therefore processing efficiency can be higher than existing anaerobic biological reactor more than one times, investment can reduce more than 50%, manufacturing and maintenance cost are low etc., at sewage treatment area wide application prospect are arranged.The mechanical power streaming system is adopted in outer circulation of the present invention in addition, has overcome traditional internal reflux system backflow poor effect and shortcoming not obvious, that reflux and can't regulate.
Description of drawings
Fig. 1 is a CAFT efficient anaerobe reactor structural representation of the present invention.
Embodiment
The present invention is described further below in conjunction with accompanying drawing.
As shown in Figure 1, a kind of CAFT efficient anaerobe reactor that is used for sewage disposal, comprise convective region 1, adsorption zone 2 and buffer zone 3, in convective region 1, be placed with the anaerobion bacterium, be provided with the water distributor 4 that feeds sewage in the bottom of convective region, 1 upper angled is provided with some tube settlers 5 in the convective region.Above convective region 1, connect and be connected with adsorption zone 2, be placed with high-density packing in adsorption zone 2 inside.Above adsorption zone 2, be provided with buffer zone 3, be provided with triphase separator 7 in buffer zone 3, triphase separator 7 comprises liquid displacement zone, solids constituent abscission zone and gas disengaging zone, the gas delivery district is connected with biogas vent pipe 8, and biogas vent pipe 8 feeds in the sludge gas collecting device again and stores.Liquid displacement zone with go out water discharge pipe and be connected and carry out draining, in the solids constituent abscission zone, be provided with the settler that is used to collect the bigger anaerobion bacterium of proportion, described settler is connected with an end of external circulating system 9, and the other end of external circulating system 9 is connected with convective region 1, forms return-flow system like this.
CAFT efficient anaerobe reactor reactor is the stdn casing, main technologic parameters: volumetric loading 8~40kgCOD/m 3.d, water inlet COD concentration 2000~30000mg/L, COD clearance 60~70%, height for reactor 10m.
Introduce the working process of CAFT efficient anaerobe reactor down below.
In the CAFT anaerobic biological reactor, anaerobion bacterium in water inlet and the reactor in the convective region 1 is in this district's thorough mixing and reaction, in the convective region 1, the anaerobion bacterium fully contacts with former water mixing, not only can allow the anaerobion bacterium be fit to such waste water, can obviously reduce the toxicity of former water simultaneously.Anaerobion bacterium and water inlet mixture move up with biogas simultaneously, arrive tube settler 5, oarse-grained mud 6 is separated from water, glides along the inclined tube wall, can fully contact mixing again with the current that rise, guarantee that water inlet can continue fully to contact mixing with anaerobion.
Through convective region 1, water quality is cleaned gradually, because fine active mud granule proportion is lighter in tube settler 5 water outlets, can't separate, therefore enter adsorption zone 2 with water, because the fine active mud granule in the water has stickiness and absorption property preferably, can be adsorbed in fully on the filler, this reactor adopts high-density packing, the active sludge that is adsorbed on the filler fully contacts with sewage, owing to intake after convective region 1 is handled, raw water quality is well improved, the growth and the propagation that help adsorption zone 2 active sludge guarantee that the water inlet pollutent obtains enough degradeds at adsorption zone 2.
After adsorption zone 2 is handled; entering organic matter of water is farthest degraded; adsorption zone 2 tops are provided with buffer zone 3; at buffer zone 3; the biogas that convective region 1 and adsorption zone 2 produce aggregates into big bubble, and the trickle active sludge generation throwing out that adsorption zone 2 comes off aggregates into the macrobead active sludge.Biogas, activated sludge particles and water enter triphase separator, and triphase separator adopts special construction, effectively solid-liquid gas are separated again, and biogas is by the sludge gas collecting device collection and treatment; The anaerobion bacterium that proportion is bigger is collected by settler and is back to convective region 1 by external circulating system 9, and the less anaerobion bacterium of proportion is then discharged reactor with water outlet.
This equipment external circulating system 9 mechanical powers adopt the anticorrosion pipeline impeller pump.External circulating system 9 has increased the upflow velocity of convective region 1, and the organism of convective region 1 and anaerobion bacterium contact area are increased, and has accelerated purification of water quality speed; Influent concentration has also been diluted in the water inlet that described external circulating system 9 provides, and has reduced organic acid concentration gradient in the reactor, has improved the living environment of anaerobion bacterium, has improved the degradation rate of anaerobion bacterium.
Introduce the concrete application example of CAFT anaerobic biological reactor down below:
The raw material and the intermediate of following product of production and selling and following product: 1. 2. cyanoimino dibenzyl 3. p-chloromethyl styrenes 4.2 of isocyanuric acid three-glycidyl ester (electronic-grade), 6-dibromo pimelic acid diethyl ester 5. pimelonitriles 6. pimelic acid 7. suberonitrile 8.N, two (three silyls) trifluoroacetamide 9. trimethylsilyl cyanides 10. trimethyl silicanes of O-are for morpholine.The waste water of discharging mainly comprises polymer organism such as arene compound, epoxy compounds, waste water COD concentration height, and composition is quite complicated, and microorganism is had stronger inhibition.
The water quality characteristic of comprehensive wastewater, the CAFT efficient anaerobe reactor that adopts my company to produce begins the water inlet debugging, carries out the culturing sludge and the domestication of anaerobic system earlier.CAFT efficient anaerobic device is carried out sludge seeding, and mud adopts the digested sludge of sewage work.Open external circulating system simultaneously, control water inlet COD (cr) is about 1000mg/L, originally two weeks is in the time, initial stage anaerobic device COD is non-to fall anti-liter, reason is because the mud incompatibility raw water quality of inoculation causes the part active sludge to disintegrate, and COD of sewage concentration rises, so this section period, purpose allowed seed sludge adapt to waste water quality mainly based on the anaerobic device external reflux.Through the two weeks sludge acclimatization, slowly adapted to waste water, therefore progressively increase load, and water temperature is slowly risen, after 12 weeks, temperature reaches 35 ℃.Because this waste water lacks trace elements such as the necessary cobalt of anaerobic system, molybdenum, nickel, so in debug process, suitable additional this part trace element.The pH value of strict simultaneously control waste water is about 7.5, and basicity slowly improves influent concentration more than 1000mg/L.Through 4 months commissioning test, the volumetric loading of anaerobic system COD (cr) was by initial 2.0kg/ (m 3D) high to 15.0kg/ (m 3D), COD (cr) clearance reaches more than 65%, and water outlet volatile acid (VFA) is controlled at about 500mg/L, produces a desired effect.
It below is the parameter of each stage water-quality guideline.
Figure BSA00000195613300061
Figure BSA00000195613300071
Show and described ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; that describes in the foregoing description and the specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.

Claims (4)

1. anaerobic biological reactor that is used for sewage disposal, comprise convective region, adsorption zone and buffer zone, it is characterized in that: be placed with the anaerobion bacterium in the described convective region, be provided with the water distributor that feeds sewage in the bottom of convective region, the upper angled in the convective region is provided with some tube settlers; Above the convective region, connect and be connected with adsorption zone, be placed with filler in adsorption zone inside; Above adsorption zone, be provided with buffer zone, in buffer zone, be provided with triphase separator, described triphase separator comprises liquid displacement zone, solids constituent abscission zone and gas disengaging zone, described gas delivery district is connected with the biogas vent pipe, described liquid displacement zone with go out water discharge pipe and be connected, in the solids constituent abscission zone, be provided with the settler that is used to collect the bigger anaerobion bacterium of proportion, described settler is connected with an end of external circulating system, and the other end of described external circulating system is connected with the convective region.
2. a kind of anaerobic biological reactor that is used for sewage disposal according to claim 1 is characterized in that: described filler is a high-density packing.
3. a kind of anaerobic biological reactor that is used for sewage disposal according to claim 2 is characterized in that: described biogas vent pipe is connected with sludge gas collecting device.
4. a kind of anaerobic biological reactor that is used for sewage disposal according to claim 3 is characterized in that: described reactor is the stdn casing, highly is 10m, volumetric loading 8~40kgCOD/m 3.d.
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US4613434A (en) * 1983-01-18 1986-09-23 Oy Tampella Ab Device for treatment of wastewater by means of anaerobic fermentation
EP0213012B1 (en) * 1985-08-09 1989-08-16 "DEGREMONT" Société dite: Fluidized-bed reactor for the biological treatment of water
CN2389888Y (en) * 1999-07-04 2000-08-02 河南省科学院河南省计划委员会地理研究所 Anaerobic reactor with compound structure
CN2647845Y (en) * 2003-10-20 2004-10-13 四川大学 Coking waste water disposal device
MX2007007253A (en) * 2004-12-15 2007-10-18 Ecovation Inc Method and apparatus for the anaerobic treatment of waste.
CN100551845C (en) * 2007-04-03 2009-10-21 山东美泉环保科技有限公司 Circular granular sludge reactor
CN101514066B (en) * 2009-03-27 2011-06-08 哈尔滨工业大学 New technology for IEC anaerobic reaction and device thereof
CN201433134Y (en) * 2009-04-09 2010-03-31 宇星科技发展(深圳)有限公司 Improved UASB reactor

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