CN101863497A - Mixing heating acid dissolving method and device for fly ash slurry - Google Patents
Mixing heating acid dissolving method and device for fly ash slurry Download PDFInfo
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- CN101863497A CN101863497A CN201010161861A CN201010161861A CN101863497A CN 101863497 A CN101863497 A CN 101863497A CN 201010161861 A CN201010161861 A CN 201010161861A CN 201010161861 A CN201010161861 A CN 201010161861A CN 101863497 A CN101863497 A CN 101863497A
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- primary heater
- slurry
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- flasher
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- 238000000034 method Methods 0.000 title claims abstract description 50
- 239000002253 acid Substances 0.000 title claims abstract description 37
- 239000010881 fly ash Substances 0.000 title claims abstract description 37
- 239000002002 slurry Substances 0.000 title claims abstract description 37
- 238000010438 heat treatment Methods 0.000 title claims abstract description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000010790 dilution Methods 0.000 claims abstract description 13
- 239000012895 dilution Substances 0.000 claims abstract description 13
- 239000012066 reaction slurry Substances 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 47
- 238000009833 condensation Methods 0.000 claims description 43
- 230000005494 condensation Effects 0.000 claims description 43
- 239000007788 liquid Substances 0.000 claims description 8
- 239000010802 sludge Substances 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 6
- 239000012141 concentrate Substances 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 4
- 238000001704 evaporation Methods 0.000 claims description 2
- 230000008020 evaporation Effects 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 6
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 abstract description 4
- 239000000243 solution Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000011268 mixed slurry Substances 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 238000004321 preservation Methods 0.000 abstract 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000007701 flash-distillation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
The invention relates to a mixing heating acid dissolving method and a mixing heating acid dissolving device for fly ash slurry, wherein the method comprises the following steps: a preheating step of the slurry, i.e. preheating the mixed slurry of fly ash and hydrochloric acid, which is prepared by mixing the fly ash with the hydrochloric acid, in a preheating device to raise temperature to be 40 to 70 DEG C; a heating step of the slurry, i.e. heating the preheated slurry in a reaction kettle by live steam to be 140 to 160 DEG C and carrying out heat preservation for 0.5 to 2 hours; and a step of carrying out concentration and temperature reduction on reaction slurry dissolved from the reaction kettle in a flash evaporator to be 118 to 125 DEG C and conveying the slurry subjected to temperature reduction to a dilution trap. The method is in the core position in the whole process for preparing alumina from the fly ash by an acid method. By the processes of the invention, the alumina in the fly ash reacts with the hydrochloric acid to be dissolved in a mode of aluminium chloride to enter solution so as to provide a basic raw material for the subsequent step of preparing the alumina.
Description
Technical field
The present invention relates to a kind of flyash acid system and produce the dissolving-out process method and apparatus of aluminum oxide, particularly relate to the hybrid hot acid method's of adding dissolving-out method of a kind of flyash slurry and device.
Background technology
It is the of paramount importance a kind of mode of total utilization of PCA that flyash extracts aluminum oxide, and this not only can administer plant residue, can also bring economic benefit, environmental benefit and social benefit simultaneously, therefore is subjected to paying close attention to widely.
Flyash production method of alumina mainly concentrates on sintering process (lime sinter process, soda-lime sintering process), alkaline leaching (sodium hydroxide solution molten silicon is earlier carried aluminium again) and acid system (salt acid system, sulfuric acid process) at present.Get the dissolving-out process of aluminum oxide at flyash hydrochloric acid legal system, still do not have this kind Technology at present both at home and abroad, the present invention has filled up the blank in this field.
Summary of the invention
The objective of the invention is to, overcome the defective of above-mentioned prior art and the hybrid hot acid method's of the adding dissolving-out method of flyash slurry that a kind of technology is simple, production process is easy to control is provided.
For achieving the above object, the present invention takes following design:
The hybrid hot acid method's dissolving-out method that adds of a kind of flyash slurry said method comprising the steps of:
The pre-heating step of A, slurry: flyash and the mixed in hydrochloric acid slip that comes of will preparing burden carry out pre-heating temperature elevation to 40 in primary heater unit～and 70 ℃;
The heating steps of B, slurry: the slurry after the described preheating is heated to 140～160 ℃ by live steam in reactor, and is incubated 0.5～2 hour;
C, flash concentration cooling step: reaction slurry that will stripping from reactor concentrates in flasher and is cooled to 118～125 ℃, sends into dilution trap through the slip after the cooling.
Preferably, the secondary steam that comes out in the described flasher leads to described primary heater unit, is used for the preheating of slurry.
Preferably, the described water of condensation that secondary steam produced that leads to primary heater unit is sent into cold water tank, is used for the acid sludge washing.Further preferably, in the pre-heating step of described slurry, comprise first step cannula primary heater and second stage cannula primary heater at least.
Preferably, in the heating steps of described slurry, comprise the two-stage reaction still at least, and 140～170 ℃ live steam is passed in the first step reactor.
Preferably, in described flash concentration cooling step, comprise the double flash evaporation device at least, and link to each other with second stage cannula primary heater with described first step cannula primary heater respectively.
Another object of the present invention is to provide a kind of flyash slurry the hybrid hot acid method's of adding dissolving device, comprising: cannula primary heater, described cannula primary heater comprise end to end I level cannula primary heater and II level cannula primary heater; Reactor, described reactor comprise the 1# reactor that links to each other with described II level cannula primary heater, the 2# reactor that links to each other with described 1# reactor, the 3# reactor that links to each other with described 2# reactor; Flasher, described flasher comprise the I level flasher that links to each other with described 3# reactor, and the II level flasher that links to each other with described I level flasher; Dilution trap, described dilution trap is connected with the discharge port of described II level flasher, and also is provided with the discharging pump that liquid is pumped on described dilution trap; The condensation water pot, described condensation water pot comprises I level condensation water pot and II level condensation water pot, the inlet of wherein said I level condensation water pot is connected with described II level cannula primary heater, the air outlet of described I level condensation water pot is returned and is led to II level cannula primary heater, and the liquid outlet of I level condensation water pot leads to described II level condensation water pot; And the inlet of described II level condensation water pot is connected with described I level cannula primary heater, and the air outlet of described II level condensation water pot is returned and led to I level cannula primary heater, and the liquid outlet place of II level condensation water pot is provided with condensate pump.
Preferably, the air outlet of described II level flasher is connected with described I level cannula primary heater.
Preferably, the air outlet of described I level flasher is connected with described II level cannula primary heater.
Preferably, also comprise the live steam pipeline that is connected with the 1# reactor.
Beneficial effect of the present invention is:
The present invention prepares at whole flyash acid system and has core status in the alumina technology: after this operation, aluminum oxide in the flyash and hydrochloric acid reaction are dissolved into solution with the aluminum chloride form, for postorder is produced the aluminum oxide raw material that provides the foundation.
Description of drawings
Fig. 1 is the technical process and the device synoptic diagram of an embodiment of the present invention.
Embodiment
Referring to Fig. 1, the hybrid preferred embodiment that adds hot acid method's dissolving device of a kind of flyash slurry of the present invention shown in it comprises cannula primary heater, and described cannula primary heater comprises end to end I level cannula primary heater 1 and II level cannula primary heater 2; The hybrid hot acid method's of the adding dissolving device of flyash slurry of the present invention also comprises reactor and flasher, wherein, described reactor comprises the 1# reactor 3 that links to each other with described II level cannula primary heater 2, and the 2# reactor 4 that links to each other with described 1# reactor 3, the 3# reactor 5 that links to each other with described 2# reactor 4, and the pipeline that is connected with live steam leads in the described 1# reactor 3; Described flasher comprises interconnective I level flasher 9 and II level flasher 10, wherein, described I level flasher 9 links to each other with described 3# reactor 5, and, the air outlet of this I level flasher 9 also links to each other with described II level cannula primary heater 2, can reclaim the secondary steam that comes out from I level flasher 9 thus, and the secondary steam that reclaims is passed in the described II level cannula primary heater 2 slip is carried out preheating; The air outlet of described II level flasher 10 also links to each other with described I level cannula primary heater 1, can reclaim the secondary steam that comes out from II level flasher 10 thus, and the secondary steam that reclaims is passed in the described I level cannula primary heater 1, and slip is carried out preheating.
Described II level flasher 10 downstreams are provided with dilution trap 11 and the discharging pump 12 that links to each other successively, and described discharging pump 12 leads to the separation tank (not shown), and described dilution trap 11 also links to each other with acid sludge washing plant (not shown).
Preferably, the preferred embodiments of the present invention also are provided with the condensation water pot, and this condensation water pot comprises interconnective I level condensation water pot 6 and II level condensation water pot 7, and the air outlet of wherein said I level condensation water pot 6 is connected with described II level cannula primary heater 2.When the excess steam that II level cannula primary heater 2 is produced is converted into water of condensation, again send consequent secondary steam back to II level cannula primary heater 2 in company with the secondary steam that produces in the I level flasher 9 and be used for preheating procedure, so, can repeatedly recycle heat and steam, heat energy is utilized fully, energy efficient, reduce cost.On the other hand, the air outlet of described II level condensation water pot 7 is connected with described I level cannula primary heater 1, when the excess steam that I level cannula primary heater 1 is produced is converted into water of condensation, can sends consequent secondary steam back to I level cannula primary heater 1 again in company with the secondary steam that produces in the II level flasher 10 and be used for preheating procedure.So, play too repeatedly recycle heat and steam, with heat energy utilize fully, energy efficient, the effect that reduces cost.Further, flow into the II level condensation water pot 7 from the liquid outlet of I level condensation water pot 6, and together deliver to acid sludge hot wash-water groove (not shown), be used for the acid sludge washing by condensate pump 8 with the water of condensation in the II level condensation water pot 7.
Referring to Fig. 1, wherein also show the preferred embodiment of the hybrid hot acid method's of the adding dissolving-out method of a kind of flyash slurry of the present invention equally.
At first, flyash and mixed in hydrochloric acid slip that batching is come are warming up to 40～70 ℃ through I level pipeline preheater 1, II level cannula primary heater 2, are preferably 63 ℃; Then, enter 1# reactor 3,2# reactor 4,3# reactor 5 successively through the slip after 2 intensifications of II level cannula primary heater, and in 1# reactor 3, feed live steam (about 140～170 ℃ of temperature, be preferably 165 ℃) direct heating with slip to about 140～160 ℃, be preferably 150 ℃, insulation stops after 0.5～2 hour and enters I level flasher 9.
Afterwards, the stripping reaction slurry that comes out from 1～3# reactor concentrates and is cooled to 118～125 ℃ through I level flasher 9, II level flasher 10, preferably is cooled to 123 ℃, enters dilution trap 11 then.
On the other hand, the slip after the stripping flash distillation mixes (about 105 ℃ of mixed slurry temperature) with the once washing overflowing liquid that the acid sludge washing is sent here in dilution trap 11, and mixed slurry is delivered to separation tank with pump 12.
In the present embodiment, the secondary steam that I level flasher 9 comes out (about 119 ℃ of temperature) enters in the II level cannula primary heater 2, is used for the preheating slip, and the water of condensation of secondary steam enters I level condensation water pot 6.
Similarly, the secondary steam that II level flasher 10 comes out (about 105 ℃ of temperature) enters in the I level cannula primary heater 1, is used for the preheating slip, and the water of condensation of secondary steam enters II level condensation water pot 7.
The water of condensation of above-mentioned I level condensation water pot 6, II level condensation water pot 7 is delivered to acid sludge hot wash-water groove by pump 8, is used for the acid sludge washing.
The present invention prepares at whole flyash acid system and has core status in the alumina technology: after this operation, aluminum oxide in the flyash and hydrochloric acid reaction are dissolved into solution with the aluminum chloride form, for postorder is produced the aluminum oxide raw material that provides the foundation.
Obviously, those of ordinary skill in the art can constitute dissolving-out process and equipment that various types of flyash acid systems are produced aluminum oxide with hybrid hot acid method's dissolving-out method and the device of adding of a kind of flyash slurry of the present invention.
The foregoing description is only for the usefulness that the present invention is described; and be not to be limitation of the present invention; the those of ordinary skill in relevant technologies field; without departing from the present invention; can also make various variations and modification; therefore all technical schemes that are equal to also should belong to category of the present invention, and scope of patent protection of the present invention should be limited by each claim.
Claims (10)
1. hybrid hot acid method's dissolving-out method that adds of flyash slurry is characterized in that: said method comprising the steps of:
The pre-heating step of A, slurry: flyash and the mixed in hydrochloric acid slip that comes of will preparing burden carry out pre-heating temperature elevation to 40 in primary heater unit～and 70 ℃;
The heating steps of B, slurry: the slurry after the described preheating is heated to 140～160 ℃ by live steam in reactor, and is incubated 0.5～2 hour;
C, flash concentration cooling step: reaction slurry that will stripping from reactor concentrates in flasher and is cooled to 118～125 ℃, sends into dilution trap through the slip after the cooling.
2. the hybrid hot acid method's dissolving-out method that adds of flyash slurry according to claim 1, it is characterized in that: the secondary steam that comes out in the described flasher leads to described primary heater unit, is used for the preheating of slurry.
3. the hybrid hot acid method's dissolving-out method that adds of flyash slurry according to claim 1, it is characterized in that: the described water of condensation that secondary steam produced that leads to primary heater unit is sent into cold water tank, is used for the acid sludge washing.
4. the hybrid hot acid method's dissolving-out method that adds of flyash slurry according to claim 3 is characterized in that: in the pre-heating step of described slurry, comprise first step cannula primary heater and second stage cannula primary heater at least.
5. the hybrid hot acid method's dissolving-out method that adds of flyash slurry according to claim 4 is characterized in that: in the heating steps of described slurry, comprise the two-stage reaction still at least, and 140～170 ℃ live steam is passed in the first step reactor.
6. the hybrid hot acid method's dissolving-out method that adds of flyash slurry according to claim 4, it is characterized in that: in described flash concentration cooling step, at least comprise the double flash evaporation device, and link to each other with second stage cannula primary heater with described first step cannula primary heater respectively.
7. hybrid hot acid method's dissolving device that adds of flyash slurry, it is characterized in that: described dissolving device comprises:
Cannula primary heater, described cannula primary heater comprise end to end I level cannula primary heater (1) and II level cannula primary heater (2);
Reactor, described reactor comprise the 1# reactor (3) that links to each other with described II level cannula primary heater (2), the 2# reactor (4) that links to each other with described 1# reactor (3), the 3# reactor (5) that links to each other with described 2# reactor (4);
Flasher, described flasher comprise the I level flasher (9) that links to each other with described 3# reactor (5), and the II level flasher (10) that links to each other with described I level flasher (9);
Dilution trap (11), described dilution trap (11) is connected with the discharge port of described II level flasher (10), and also is provided with the discharging pump (12) that liquid is pumped on described dilution trap (11);
The condensation water pot, described condensation water pot comprises I level condensation water pot (6) and II level condensation water pot (7), the inlet of wherein said I level condensation water pot (6) is connected with described II level cannula primary heater (2), the air outlet of described I level condensation water pot (6) is returned and is led to II level cannula primary heater (2), and the liquid outlet of I level condensation water pot (6) leads to described II level condensation water pot (7); And, the inlet of described II level condensation water pot (7) is connected with described I level cannula primary heater (1), the air outlet of described II level condensation water pot (7) is returned and is led to I level cannula primary heater (1), and the liquid outlet place of II level condensation water pot (7) is provided with condensate pump (8).
8. the hybrid hot acid method's dissolving device that adds of flyash slurry according to claim 7 is characterized in that: the air outlet of described II level flasher (10) is connected with described I level cannula primary heater (1).
9. the hybrid hot acid method's dissolving device that adds of flyash slurry according to claim 8 is characterized in that: the air outlet of described I level flasher (9) is connected with described II level cannula primary heater (2).
10. the hybrid hot acid method's dissolving device that adds of flyash slurry according to claim 7 is characterized in that: also comprise the live steam pipeline that is connected with 1# reactor (3).
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010161861A CN101863497A (en) | 2010-04-27 | 2010-04-27 | Mixing heating acid dissolving method and device for fly ash slurry |
| CN2011101037917A CN102205983B (en) | 2010-04-27 | 2011-04-25 | Method and device for dissolving fly ash slurry out by hybrid acid heating method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010161861A CN101863497A (en) | 2010-04-27 | 2010-04-27 | Mixing heating acid dissolving method and device for fly ash slurry |
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| CN101863497A true CN101863497A (en) | 2010-10-20 |
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| CN201010161861A Pending CN101863497A (en) | 2010-04-27 | 2010-04-27 | Mixing heating acid dissolving method and device for fly ash slurry |
| CN2011101037917A Active CN102205983B (en) | 2010-04-27 | 2011-04-25 | Method and device for dissolving fly ash slurry out by hybrid acid heating method |
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| CN2011101037917A Active CN102205983B (en) | 2010-04-27 | 2011-04-25 | Method and device for dissolving fly ash slurry out by hybrid acid heating method |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102642858A (en) * | 2012-04-25 | 2012-08-22 | 吉林大学 | Method for leaching aluminum oxide in fly ash by using microwave acid dissolution |
| CN103435078A (en) * | 2012-12-28 | 2013-12-11 | 中国神华能源股份有限公司 | Method for dissolving out aluminum by coal ash acid process and equipment system for method |
| CN110745850A (en) * | 2019-11-29 | 2020-02-04 | 神华准能资源综合开发有限公司 | Ferrous oxidation method and system for extracting aluminum oxide from fly ash by acid process |
| CN111498884A (en) * | 2020-06-01 | 2020-08-07 | 江苏泰特联合环保科技有限公司 | Treatment process and device for fluorine-containing waste hydrochloric acid |
| CN114309006A (en) * | 2021-12-13 | 2022-04-12 | 生态环境部华南环境科学研究所 | Process and treatment equipment for harmless recovery and treatment of barium slag |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102862999B (en) * | 2012-09-14 | 2015-05-20 | 苏州市中衡压力容器制造有限公司 | Crystallization and concentration device used for extracting alumina from coal ash through acid leaching method |
| CN103803617B (en) * | 2013-12-30 | 2016-03-16 | 中国神华能源股份有限公司 | A kind of flyash acid system produces the method for aluminum oxide |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN201678463U (en) * | 2010-04-27 | 2010-12-22 | 中国神华能源股份有限公司 | Fly ash slurry mixed heating acid-method dissolution device |
-
2010
- 2010-04-27 CN CN201010161861A patent/CN101863497A/en active Pending
-
2011
- 2011-04-25 CN CN2011101037917A patent/CN102205983B/en active Active
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102642858A (en) * | 2012-04-25 | 2012-08-22 | 吉林大学 | Method for leaching aluminum oxide in fly ash by using microwave acid dissolution |
| CN103435078A (en) * | 2012-12-28 | 2013-12-11 | 中国神华能源股份有限公司 | Method for dissolving out aluminum by coal ash acid process and equipment system for method |
| CN110745850A (en) * | 2019-11-29 | 2020-02-04 | 神华准能资源综合开发有限公司 | Ferrous oxidation method and system for extracting aluminum oxide from fly ash by acid process |
| CN111498884A (en) * | 2020-06-01 | 2020-08-07 | 江苏泰特联合环保科技有限公司 | Treatment process and device for fluorine-containing waste hydrochloric acid |
| CN114309006A (en) * | 2021-12-13 | 2022-04-12 | 生态环境部华南环境科学研究所 | Process and treatment equipment for harmless recovery and treatment of barium slag |
| CN114309006B (en) * | 2021-12-13 | 2022-11-25 | 生态环境部华南环境科学研究所 | Process and treatment equipment for harmless recycling of barium slag |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102205983B (en) | 2012-09-19 |
| CN102205983A (en) | 2011-10-05 |
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Open date: 20101020 |