CN101851414B - Composition applied to optical diffusion membrane, optical diffusion membrane and liquid crystal display device - Google Patents
Composition applied to optical diffusion membrane, optical diffusion membrane and liquid crystal display device Download PDFInfo
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Abstract
The invention provides a composition applied to an optical diffusion membrane, the optical diffusion membrane prepared from the composition and a liquid crystal display device using the membrane. The composition consists of the following components in part by weight: 15 to 80 parts of main agent, 1.5 to 16 parts of curing agent, 0.05 to 108 parts of particle filler and 20.1 to 500 parts of solvent, wherein the main agent is polyester polyol; and the solvent consists of 5.9 to 147 weight parts of methyl ethyl ketone, 5.9 to 147 weight parts of butyl acetate, and 8.3 to 206 weight parts of ethyl acetate. The solvent in the composition which is applied to the optical diffusion membrane is almost harmless to a human body and the environment, and meanwhile, luminance of the optical diffusion membrane can be increased.
Description
Technical field
The present invention relates to optical thin film, be specifically related to a kind of compsn that is applied to optical diffusion membrane, and by the made optical diffusion membrane of said composition and use the liquid crystal indicator of this film.
Background technology
Optical thin film occupies critical role in liquid-crystal display is formed, wherein each liquid-crystal display is generally used 5 to 7 optical thin films, and optical diffusion membrane is wherein particularly important a kind of optical thin film.Optical diffusion membrane is widely used in liquid crystal indicator, advertising lamp box, lighting, mobile communication equipment button etc. and needs on the device of light source so that even illumination to be provided.Liquid crystal indicator is fast-developing in recent years; And in mobile communication equipment display unit, notebook computer, desk-top computer and large scale liquid crystal TV, be used widely; This makes liquid crystal indicator also improve day by day the performance requriements of optical diffusion membrane, mainly concentrates on and improves on brightness and the illumination uniformity.
The existing compsn that is applied to optical diffusion membrane is mainly by host, solidifying agent, spherical or ellipsoid shape granular filler and solvent composition; Wherein host is mixed back generation acrylic polymers with solidifying agent; Mostly solvent is the mixing solutions of toluene, YLENE, methylethylketone; Though this compsn commonly used can be met the need of market on performance; But the solvent toluene of wherein using, xylene solution all belong to second type of organic solvent in the organic solvent classification commonly used, promptly belong to no genotoxicity but the solvent of animal carinogenicity is arranged, and are prone in process of production researching and developing and producers' health damages.Other has research data to show, toluene, YLENE can produce certain photochemical reaction after getting into atmospheric layer, and ozonosphere is had certain destruction, thus contaminate environment.Along with the propelling day by day of environmental protection society, low toxic and environment-friendly is the target that all products are pursued.
Therefore, the optical diffusion membrane that how to use the low toxic and environment-friendly solvent to prepare low toxic and environment-friendly, high brightness has become the problem that this area needs to be resolved hurrily.
Summary of the invention
In view of this; Main purpose of the present invention is to provide a kind of compsn that is applied to optical diffusion membrane; And by the made optical diffusion membrane of said composition and use the liquid crystal indicator of this film; Solvent is less to the harm that human body and environment cause in the said composition, the brightness that can improve optical diffusion membrane simultaneously.
In order to achieve the above object, the present invention provides a kind of compsn that is applied to optical diffusion membrane, and said composition is by host, solidifying agent, granular filler and solvent composition, in the said compsn:
Host: 15-80 weight part;
Solidifying agent: 1.5-16 weight part;
Granular filler: 0.05-108 weight part;
Solvent: 20.1-500 weight part;
Wherein, host is polyester polyol, and solvent is made up of the methylethylketone of 5.9-147 weight part, the butylacetate of 5.9-147 weight part, the ETHYLE ACETATE of 8.3-206 weight part;
Wherein, said granular filler is a kind of in silicon compound, silicone resin, PS, the polymethylmethacrylate or at least two kinds mixture wherein, and said granular filler is spherical or the ellipsoid shape, and the particle diameter of granular filler is the 1-100 micron.
Further, the present invention also provides a kind of compsn that is applied to optical diffusion membrane, form by host, solidifying agent, granular filler, solvent and static inhibitor, in the said compsn:
Host: 15-80 weight part;
Solidifying agent: 1.5-16 weight part;
Granular filler: 0.05-108 weight part;
Solvent: 20.1-500 weight part;
Static inhibitor: 0.5-33 weight part;
Wherein, said host is polyester polyol, and said solvent is made up of the methylethylketone of 5.9-147 weight part, the butylacetate of 5.9-147 weight part, the ETHYLE ACETATE of 8.3-206 weight part;
Wherein, said granular filler is a kind of in silicon compound, silicone resin, PS, the polymethylmethacrylate or at least two kinds mixture wherein, and said granular filler is spherical or the ellipsoid shape, and the particle diameter of granular filler is the 1-100 micron.
In the above-mentioned compsn; Solidifying agent is 1; A kind of in hexamethylene-diisocyanate (HDI), isophorone diisocyanate (IPDI), xylylene diisocyanate (XDI), Methylcyclohexyl diisocyanate (HTDI), the dicyclohexyl methane diisocyanate (HMDI) or at least two kinds mixture wherein; Host is mixed the back and is generated polyurethane system with solidifying agent, the SP of polyurethane system is about 10, and the SP of solvent is about 9.00-9.15.
In order to achieve the above object, the present invention also provides a kind of optical diffusion membrane, comprises base material, and this base material single or double is coated with aforesaid compsn.
In order to achieve the above object, the present invention further provides a kind of liquid crystal indicator, comprises module backlight and liquid crystal panel, and this module backlight comprises at least one aforesaid optical diffusion membrane.
Compared with prior art; Technical scheme of the present invention mainly contains following advantage: mostly the solvent that, is applied in the prior art use in the compsn of optical diffusion membrane is toluene, YLENE; All belong to second type of organic solvent, promptly do not have genotoxicity but the solvent of animal carinogenicity is arranged, bigger to HUMAN HEALTH and environmental hazard; And the solvent in the present composition is methylethylketone, butylacetate, ETHYLE ACETATE; The 3rd type of organic solvent that all belongs to low toxicity, less to the harm that human body and environment cause, avoid the use of toluene, YLENE pollutes environment; Production, research staff's health is escaped injury, also make user security use related prods relievedly; The SP of the solvent that two, is mixed by methylethylketone, butylacetate, ETHYLE ACETATE is mixed the SP of the polyurethane system that the back generates with solidifying agent near host; It is dispersed preferably that compsn is had; Solvent in the present composition also has suitable volatility simultaneously; Composition viscosity is changed suitably; Thereby the optical diffusion membrane that makes preparation has homogeneity and higher brightness preferably, and the sticking power after solidifying simultaneously reaches the superlative degree of drawing the lattice grade, and hardness reaches more than the 2H.
Description of drawings
Fig. 1 is the diagrammatic cross-section of optical diffusion membrane of the present invention;
Fig. 2 is the diagrammatic cross-section of directly-down liquid crystal display unit of the present invention;
Fig. 3 is the diagrammatic cross-section of the side entering type liquid crystal indicator of one embodiment of the present of invention;
Fig. 4 is the diagrammatic cross-section of the side entering type liquid crystal indicator of an alternative embodiment of the invention.
Description of reference numerals
100 optical diffusion membranes, 110 base materials
130 times composition coatings of composition coating on 120
140,150 granular fillers, 160 incident beaies
170 emergent raies, 210,310,410 fluorescent tubes
220,320,420 reflector plates, 230,330,430 light guiding plates
240,340,440 optical diffusion membranes, 250,350,450 display panels
Embodiment
The compsn that is applied to optical diffusion membrane of the present invention is by host, solidifying agent, granular filler and solvent composition; Concrete said composition is by the host of 15-80 weight part, the solidifying agent of 1.5-16 weight part, the granular filler of 0.05-108 weight part, the solvent composition of 20.1-500 weight part; Wherein, Said host is polyester polyol, and said solvent is made up of the methylethylketone of 5.9-147 weight part, the butylacetate of 5.9-147 weight part, the ETHYLE ACETATE of 8.3-206 weight part.
Further; The compsn of optical diffusion membrane that is applied to of the present invention is by the host of 30-50 weight part, the solidifying agent of 2.5-7 weight part, the granular filler of 16-57 weight part and the solvent composition of 113-260.5 weight part; Wherein, Said host is polyester polyol, and said solvent is made up of the methylethylketone of 33.25-76.5 weight part, the butylacetate of 33.25-76.5 weight part, the ETHYLE ACETATE of 46.5-107.5 weight part.
Further; The compsn of optical diffusion membrane that is applied to of the present invention is by the host of 40 weight parts, the solidifying agent of 4.75 weight parts, the granular filler of 36.5 weight parts, the solvent composition of 186.5 weight parts; Wherein, Said host is polyester polyol, and said solvent is made up of the methylethylketone of 54.85 weight parts, the butylacetate of 54.85 weight parts, the ETHYLE ACETATE of 76.8 weight parts.
The compsn that is applied to optical diffusion membrane of the present invention also can be made up of host, solidifying agent, granular filler, solvent and static inhibitor; Concrete said composition is made up of the host of 15-80 weight part, the solidifying agent of 1.5-16 weight part, the granular filler of 0.05-108 weight part, the solvent of 20.1-500 weight part and the static inhibitor of 0.5-33 weight part; Said host is polyester polyol, and said solvent is made up of the methylethylketone of 5.9-147 weight part, the butylacetate of 5.9-147 weight part, the ETHYLE ACETATE of 8.3-206 weight part.
Further; The compsn that is applied to optical diffusion membrane of the present invention also can be made up of the host of 30-50 weight part, the solidifying agent of 2.5-7 weight part, the granular filler of 16-57 weight part, the solvent of 113-260.5 weight part and the static inhibitor of 1.25-7.5 weight part; Wherein, Said host is polyester polyol, and said solvent is made up of the methylethylketone of 33.25-76.5 weight part, the butylacetate of 33.25-76.5 weight part, the ETHYLE ACETATE of 46.5-107.5 weight part.
Above-mentioned compsn; Wherein, Polyester polyol is polyethylene glycol adipate glycol (PEA), gathers adipate glycol-propylene glycol ester glycol, gathers hexanodioic acid glycol ether esterdiol (PDA), gathers adipate glycol-the glycol ether esterdiol, gathers hexanodioic acid-1; 4-butanediol ester glycol (PBA), gather adipate glycol-1,4-butanediol ester glycol, gather hexanodioic acid NSC 6366-1, a kind of in the 6-pinakon esterdiol or at least two kinds mixture wherein.
Wherein, Said solidifying agent is a kind of in hexamethylene diisocyanate (HDI), isophorone diisocyanate (IPDI), xylylene diisocyanate (XDI), Methylcyclohexyl diisocyanate (HTDI), the dicyclohexyl methane diisocyanate (HMDI) or at least two kinds mixture wherein.
Wherein, said granular filler is a kind of in silicon compound, silicone resin, PS (PS), the polymethylmethacrylate (PMMA) or at least two kinds mixture wherein.Said granular filler is spherical or the ellipsoid shape, and the particle diameter of granular filler is the 1-100 micron.
Wherein, said static inhibitor is mainly the quaternary ammonium salt static inhibitor.
In the above-mentioned compsn, the SP of solvent is about 9.00-9.15, and host is about 10 with the SP of the polyurethane system that obtains after solidifying agent mixes.
The compsn that the invention described above is applied to optical diffusion membrane is coated and is obtained optical diffusion membrane of the present invention on the base material; The base material of optical diffusion membrane of the present invention can be polyethylene terephthalate (PET), glass, polycarbonate (PC), polymethylmethacrylate (PMMA) or PS (PS); Optical diffusion membrane of the present invention can adopt common coating process preparation, and the base material single or double is coated with aforesaid compsn.
The compsn that the present invention is applied to optical diffusion membrane also can be applicable to other optical thin film, like optical reflectance coating, brightness enhancement film, composite package etc.
The present invention further provides the liquid crystal indicator that uses above-mentioned optical diffusion membrane; This liquid crystal indicator comprises module backlight and liquid crystal panel; This module backlight comprises light source, light guiding plate, reflector plate, optical diffusion membrane etc.; Wherein light source can be arranged on the following or side of light guiding plate, and light source can be at least a in cold-cathode fluorescence lamp, external electrode fluorescent lamp, luminous utmost point pipe and the hot-cathode fluorescent lamp.Can in the module backlight of liquid crystal indicator, use 1 or 2-3 optical diffusion membrane, below in conjunction with description of drawings optical diffusion membrane of the present invention according to practical application.
Fig. 1 is the diagrammatic cross-section of optical diffusion membrane of the present invention; As shown in Figure 1, optical diffusion membrane 100 mainly comprises base material 110, last composition coating 120, following composition coating 130, wherein goes up and contains sphere or ellipsoidal particle filler 140 in the composition coating 120; Following composition coating 130 has pattern structure and granular filler 150; Granular filler 140 in this optical diffusion membrane is 20 microns a polydisperse particle for median size, and granular filler 150 is 3 microns a polydisperse particle for median size, and last composition coating 120 is 25 microns with the total thickness of following composition coating 130; 160 is incident beam among the figure, and 170 is emergent ray.
According to the position of light source and light guiding plate in the module backlight, liquid crystal indicator generally is divided into two kinds of straight-down negative and side entering types, below is that example is explained liquid crystal indicator of the present invention with the indicating meter of notebook computer, desk-top computer, LCD TV respectively.
Fig. 2 is the diagrammatic cross-section of directly-down liquid crystal display unit of the present invention; This liquid crystal indicator is specially the indicating meter of notebook computer; This display unit mainly comprises fluorescent tube 210, reflector plate 220, light guiding plate 230, optical diffusion membrane 240 and display panels 250; Wherein contain a plurality of fluorescent tubes 210 and two optical diffusion membranes 240 in this display unit, fluorescent tube 210 is positioned at below the light guiding plate 230.
Fig. 3 is the diagrammatic cross-section of the side entering type liquid crystal indicator of one embodiment of the present of invention; This liquid crystal indicator is specially the indicating meter of desk-top computer; This display unit mainly comprises fluorescent tube 310, reflector plate 320, light guiding plate 330, optical diffusion membrane 340 and display panels 350; Wherein contain a fluorescent tube 310 and two optical diffusion membranes 340 in this display unit, fluorescent tube 310 is positioned at light guiding plate 330 sides.
The do diagrammatic cross-section of side entering type liquid crystal indicator of an alternative embodiment of the invention of Fig. 4; This liquid crystal indicator is specially the indicating meter of LCD TV; This display unit mainly comprises fluorescent tube 410, reflector plate 420, light guiding plate 430, optical diffusion membrane 440 and display panels 450; Wherein contain the both sides that two fluorescent tubes 410 and 440, two fluorescent tubes 410 of two optical diffusion membranes lay respectively at light guiding plate 430 in this display unit.
Below for the specific embodiment of technical scheme of the present invention
One, preparation of compositions
Embodiment 1: the preparation of compsn 1
(1) solvent of preparation 186.50 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 33.05 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 54.85 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 98.60 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 36.50 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 40.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) that progressively adds 4.75 weight parts then is placed on container 002 on the whisking appliance then and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 4.38 weight parts the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 1.
Embodiment 2: the preparation of compsn 2
(1) solvent of preparation 186.50 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 54.85 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 33.05 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 98.60 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 36.50 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 40.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) that progressively adds 4.75 weight parts then is placed on container 002 on the whisking appliance then and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 4.38 weight parts the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 2.
Embodiment 3: the preparation of compsn 3
(1) solvent of preparation 186.50 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 54.85 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 54.85 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 76.80 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 36.50 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 40.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) that progressively adds 4.75 weight parts then is placed on container 002 on the whisking appliance then and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 4.38 weight parts the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 3.
Embodiment 4: the preparation of compsn 4
(1) solvent of preparation 186.50 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 54.85 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 76.80 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 54.85 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 36.50 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 40.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) that progressively adds 4.75 weight parts then is placed on container 002 on the whisking appliance then and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 4.38 weight parts the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 4.
Embodiment 5: the preparation of compsn 5
(1) solvent of preparation 186.50 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 76.80 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 54.85 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 54.85 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 36.50 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 40.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) that progressively adds 4.75 weight parts then is placed on container 002 on the whisking appliance then and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 4.38 weight parts the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 5.
Embodiment 6: the preparation of compsn 6
(1) solvent of preparation 20.10 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 5.90 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 5.90 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 8.30 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 0.05 weight part in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 15.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) that progressively adds 1.50 weight parts then is placed on container 002 on the whisking appliance then and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 0.50 weight part the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 6.
Embodiment 7: the preparation of compsn 7
(1) solvent of preparation 113.00 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 33.25 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 33.25 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 46.50 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 16.00 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 30.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) that progressively adds 2.50 weight parts then is placed on container 002 on the whisking appliance then and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 1.25 weight parts the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 7.
Embodiment 8: the preparation of compsn 8
(1) solvent of preparation 186.50 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 58.85 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 50.85 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 76.80 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 36.50 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 40.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) that progressively adds 4.75 weight parts then is placed on container 002 on the whisking appliance then and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 16.00 weight parts the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 8.
Embodiment 9: the preparation of compsn 9
(1) solvent of preparation 260.50 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 76.50 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 76.50 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 107.50 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 57.00 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 50.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) that progressively adds 7.00 weight parts then is placed on container 002 on the whisking appliance then and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 7.50 weight parts the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 9.
Embodiment 10: the preparation of compsn 10
(1) solvent of preparation 500.00 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 147.00 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 147.00 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 206.00 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 108.00 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 80.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) that progressively adds 16.00 weight parts then is placed on container 002 on the whisking appliance then and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 33.00 weight parts the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 10.
Embodiment 11: the preparation of compsn 11
(1) solvent of preparation 68.30 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 20.50 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 20.50 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 27.30 weight parts, it is subsequent use to cover bung.
(2) the granular filler PS of adding 4.00 weight parts in container 002, particle diameter is the 1-100 micron, again with the solvent in the said vesse 001; Substep adds in the container 002, granular filler is slowly scatter all solvents in adding container 001 with stainless steel bar; Then container 002 is placed on whisking appliance (DJ660; Wuxi De Aosai whipping device ltd) go up stirring, the whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 23.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) that progressively adds 2.00 weight parts then is placed on container 002 on the whisking appliance then and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 0.75 weight part the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 11.
Embodiment 12: the preparation of compsn 12
(1) solvent of preparation 145.20 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 41.00 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 41.00 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 63.20 weight parts, it is subsequent use to cover bung.
(2) the granular filler silicone resin of adding 22.00 weight parts in container 002, particle diameter is the 1-100 micron, again with the solvent in the said vesse 001; Substep adds in the container 002, granular filler is slowly scatter all solvents in adding container 001 with stainless steel bar; Then container 002 is placed on whisking appliance (DJ660; Wuxi De Aosai whipping device ltd) go up stirring, the whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 35.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) that progressively adds 3.25 weight parts then is placed on container 002 on the whisking appliance then and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 2.30 weight parts the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 12.
Embodiment 13: the preparation of compsn 13
(1) solvent of preparation 216.40 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 63.20 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 63.20 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 90.00 weight parts, it is subsequent use to cover bung.
(2) the granular filler silicon-dioxide of adding 45.00 weight parts in container 002, particle diameter is the 1-100 micron, again with the solvent in the said vesse 001; Substep adds in the container 002, granular filler is slowly scatter all solvents in adding container 001 with stainless steel bar; Then container 002 is placed on whisking appliance (DJ660; Wuxi De Aosai whipping device ltd) go up stirring, the whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 45.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) that progressively adds 5.30 weight parts then is placed on container 002 on the whisking appliance then and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 5.60 weight parts the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 13.
Embodiment 14: the preparation of compsn 14
(1) solvent of preparation 341.90 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 100.70 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 100.70 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 140.50 weight parts, it is subsequent use to cover bung.
(2) granular filler of adding 80.50 weight parts in container 002, wherein granular filler is made up of the PMMA of 40.50 weight parts and the PS of 40.00 weight parts, and particle diameter is the 1-100 micron; Again with the solvent in the said vesse 001; Substep adds in the container 002, granular filler is slowly scatter all solvents in adding container 001 with stainless steel bar; Then container 002 is placed on whisking appliance (DJ660; Wuxi De Aosai whipping device ltd) go up stirring, the whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 65.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) that progressively adds 12.50 weight parts then is placed on container 002 on the whisking appliance then and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 20.60 weight parts the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 14.
Embodiment 15: the preparation of compsn 15
(1) solvent of preparation 20.1 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 5.90 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 5.90 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 8.30 weight parts, it is subsequent use to cover bung.
(2) granular filler of adding 0.05 weight part in container 002, wherein granular filler is made up of PMMA, 0.01 weight part PS and the 0.03 weight part silicone resin of 0.01 weight part, and particle diameter is the 1-100 micron; Again with the solvent in the said vesse 001; Substep adds in the container 002, granular filler is slowly scatter all solvents in adding container 001 with stainless steel bar; Then container 002 is placed on whisking appliance (DJ660; Wuxi De Aosai whipping device ltd) go up stirring, the whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 15.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) that progressively adds 2.50 weight parts then is placed on container 002 on the whisking appliance then and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 1.25 weight parts the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 15.
Embodiment 16: the preparation of compsn 16
(1) solvent of preparation 20.70 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 5.90 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 6.50 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 8.30 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 7.00 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 15.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent IPDI that progressively adds 1.50 weight parts then is placed on container 002 on the whisking appliance then and stirs, and the whisking appliance revolution is 2000r/min; Stop behind the 10min stirring, obtain compsn 16.
Embodiment 17: the preparation of compsn 17
(1) solvent of preparation 113.00 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 33.25 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 33.25 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 46.50 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 16.00 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 30.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent XDI that progressively adds 1.50 weight parts then is placed on container 002 on the whisking appliance then and stirs, and the whisking appliance revolution is 2000r/min; Stop behind the 10min stirring, obtain compsn 17.
Embodiment 18: the preparation of compsn 18
(1) solvent of preparation 116.50 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 33.25 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 33.25 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 50.00 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 36.50 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 30.00 weight parts in container 002; Nippon Paint Co., Ltd), progressively adds the solidifying agent HTDI of 2.50 weight parts then, container 002 is placed on the whisking appliance stirs then; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 7.50 weight parts the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 18.
Embodiment 19: the preparation of compsn 19
(1) solvent of preparation 186.50 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 58.85 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 50.85 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 76.80 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 5.00 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol (PC5000 of adding 40.00 weight parts in container 002; Nippon Paint Co., Ltd); The solidifying agent HMDI that progressively adds 4.75 weight parts then is placed on container 002 on the whisking appliance then and stirs, and the whisking appliance revolution is 2000r/min; Stop behind the 10min stirring, obtain compsn 19.
Embodiment 20: the preparation of compsn 20
(1) solvent of preparation 212.2 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 58.85 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 76.55 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 76.80 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 16.00 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) host of adding 40.00 weight parts in container 002; Wherein host is made up of the polyethylene glycol adipate glycol of 10.00 weight parts, the hexanodioic acid glycol ether esterdiol that gathers that gathers adipate glycol-propylene glycol ester two pure and mild 20.00 weight parts of 10.00 weight parts; The solidifying agent that progressively adds 7.00 weight parts then; Wherein solidifying agent is made up of the HDI of 3.50 weight parts and the IPDI of 3.50 weight parts; Then container 002 is placed on the whisking appliance and stirs, the whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 0.50 weight part the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 20.
Embodiment 21: the preparation of compsn 21
(1) solvent of preparation 260.50 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 76.50 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 76.50 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 107.50 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 57.00 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) host of adding 50.00 weight parts in container 002; Wherein host by 20.00 weight parts gather adipate glycol-glycol ether esterdiol and 30.00 weight parts gather hexanodioic acid-1; 4-butanediol ester glycol is formed; The solidifying agent that progressively adds 4.75 weight parts then, wherein solidifying agent is made up of the HDI of 1.00 weight parts, the IPDI of 1.00 weight parts and the XDI of 2.75 weight parts, container 002 is placed on the whisking appliance stirs then; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 4.38 weight parts the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 21.
Embodiment 22: the preparation of compsn 22
(1) solvent of preparation 233.3 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 76.50 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 80.00 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 76.80 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 108.00 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) host of adding 50.00 weight parts in container 002; Wherein host by 5.00 weight parts gather adipate glycol-glycol ether esterdiol, 5.00 weight parts gather hexanodioic acid-1; 4-butanediol ester glycol, 10.00 weight parts gather adipate glycol-1,4-butanediol ester glycol and 30.00 weight parts gather hexanodioic acid NSC 6366-1,6-pinakon esterdiol is formed; The solidifying agent that progressively adds 7.00 weight parts then; Wherein solidifying agent is made up of the XDI of 2.00 weight parts, the HTDI of 2.00 weight parts and the HMDI of 3.00 weight parts, container 002 is placed on the whisking appliance stirs then, and the whisking appliance revolution is 2000r/min; Stop behind the 10min stirring, obtain compsn 22.
Embodiment 23: the preparation of compsn 23
(1) solvent of preparation 314.00 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 130.00 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 76.50 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 107.50 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 97.00 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) the host polyester polyol of adding 80.00 weight parts is polyethylene glycol adipate glycol in container 002; Solidifying agent HDI (the PC2000 that progressively adds 16.00 weight parts then; Nippon Paint Co., Ltd); Then container 002 is placed on the whisking appliance and stirs, the whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 15.00 weight parts the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 23.
Embodiment 24: the preparation of compsn 24
(1) solvent of preparation 500.00 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 147.00 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 147.00 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 206.00 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 108.00 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) host that in container 002, adds 80.00 weight parts is gathered adipate glycol-propylene glycol ester glycol; Solidifying agent HDI (the PC2000 that progressively adds 13.00 weight parts then; Nippon Paint Co., Ltd); Then container 002 is placed on the whisking appliance and stirs, the whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(4) in container 002, add 33.00 weight parts the quaternary ammonium salt static inhibitor (4000, the Shanghai moral give ltd), container 002 is placed on the whisking appliance stirs then, revolution is 1000r/min, stops behind the 5min stirring, and obtains compsn 24.
Embodiment 25: the preparation of compsn 25
(1) solvent of preparation 453.50 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 147.00 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 100.50 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 206.00 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 57.00 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) host that in container 002, adds 65.00 weight parts is gathered hexanodioic acid glycol ether esterdiol; Solidifying agent HDI (the PC2000 that progressively adds 7.00 weight parts then; Nippon Paint Co., Ltd), container 002 is placed on the whisking appliance stirs then, the whisking appliance revolution is 2000r/min; Stop behind the 10min stirring, obtain compsn 25.
Embodiment 26: the preparation of compsn 26
(1) solvent of preparation 20.10 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 5.90 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 5.90 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 8.30 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 0.05 weight part in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) host that in container 002, adds 15.00 weight parts is gathered adipate glycol-glycol ether esterdiol; Solidifying agent HDI (the PC2000 that progressively adds 1.50 weight parts then; Nippon Paint Co., Ltd), container 002 is placed on the whisking appliance stirs then, the whisking appliance revolution is 2000r/min; Stop behind the 10min stirring, obtain compsn 26.
Embodiment 27: the preparation of compsn 27
(1) solvent of preparation 113.00 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 33.25 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 33.25 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 46.50 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 16.00 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) host that in container 002, adds 30.00 weight parts is gathered hexanodioic acid-1; 4-butanediol ester glycol progressively adds the solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) of 2.50 weight parts then; Then container 002 is placed on the whisking appliance and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring, and obtains compsn 27.
Embodiment 28: the preparation of compsn 28
(1) solvent of preparation 186.50 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 58.85 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 50.85 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 76.80 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 36.50 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) host that in container 002, adds 40.00 weight parts is gathered adipate glycol-1; 4-butanediol ester glycol progressively adds the solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) of 4.75 weight parts then; Then container 002 is placed on the whisking appliance and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring, and obtains compsn 28.
Embodiment 29: the preparation of compsn 29
(1) solvent of preparation 260.50 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 76.50 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 76.50 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 107.50 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 57.00 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) host that in container 002, adds 50.00 weight parts is gathered hexanodioic acid NSC 6366-1; 6-pinakon esterdiol progressively adds the solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) of 7.00 weight parts then; Then container 002 is placed on the whisking appliance and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring, and obtains compsn 29.
Embodiment 30: the preparation of compsn 30
(1) solvent of preparation 500.00 weight parts; Be specially the methylethylketone (Ningbo industrial chemicals ltd) that in container 001, adds 147.00 weight parts successively, the butylacetate (Ningbo industrial chemicals ltd) of 147.00 weight parts, the ETHYLE ACETATE (Ningbo industrial chemicals ltd) of 206.00 weight parts, it is subsequent use to cover bung.
(2) the granular filler PMMA (MBX-20, Japanese ponding changes into article ltd) of adding 108.00 weight parts in container 002, particle diameter is the 1-100 micron; With the solvent in the said vesse 001, substep adds in the container 002, with stainless steel bar granular filler is slowly scatter again; All solvents in adding container 001 are placed on whisking appliance (DJ660, Wuxi De Aosai whipping device ltd) with container 002 then and go up stirring; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring.
(3) host of adding 80.00 weight parts in container 002; Wherein host is made up of the adipate glycol-propylene glycol ester glycol that gathers of polyethylene glycol adipate two pure and mild 50.00 weight parts of 30.00 weight parts, progressively adds the solidifying agent HDI (PC2000, Nippon Paint Co., Ltd) of 16.00 weight parts then; Then container 002 is placed on the whisking appliance and stirs; The whisking appliance revolution is 2000r/min, stops behind the 10min stirring, and obtains compsn 30.
Two, optical diffusion membrane preparation
After above-mentioned compsn 1-30 leaves standstill 2 hours, respectively compsn 1-30 to be coated on the base material, the base material coating process is following: PET base material (T60; Toray Co., Ltd.) unreels through unreeling machine (the full-automatic film unreeling machine of GuangDong ShiCheng Plastic Machine Co., Ltd); Automatic charging toasts through three sections drying-plate casees (the coventional type drying-plate case of the emerging printing equipment of Hangzhou great waves ltd) after compsn is coated with on base material then, and oven temperature is made as 120 ℃ respectively; 100 ℃; 90 ℃, drying tunnel length is 10-30m, about 1-10min of film residence time in drying tunnel; After winder (the full-automatic film take-up machine of GuangDong ShiCheng Plastic Machine Co., Ltd) rolling obtains optical diffusion membrane 1-30.
Three, comparative example
Comparative example 1
Adopt 1 optical diffusion membrane 1-30 and 1 commercially available BS912 optical diffusion membrane respectively, be applied to carry out luminance factor in the module backlight of liquid crystal indicator.
Comparative example 2
Adopt 2 optical diffusion membrane 1-30 and 2 commercially available BS912 optical diffusion membranes respectively, be applied to carry out luminance factor in the module backlight of liquid crystal indicator.
Four, optical diffusion membrane test
Test one
Transmittance and mist degree test: in dust-free workshop; 25 ± 5 ℃ of temperature; Humidity 55% ± 5% utilizes transmittance/mist degree tester (the Shanghai rectangular opticinstrument WGT-S of ltd type transmittance/mist degree tester) to test transmittance and the mist degree of above-mentioned optical diffusion membrane 1-30.
Transmittance calculates formula: transmittance (%)=transmitted ray intensity/incident beam intensity * 100%
Test two
The sticking power test: in dust-free workshop, 25 ± 5 ℃ of temperature, humidity 55% ± 5% utilizes paint film to draw the sticking power of lattice appearance (Kunshan three promise instrument QFH paint films are drawn the lattice appearance, and drawing the lattice grade superlative degree is 0 grade) the above-mentioned optical diffusion membrane 1-30 of test.
Test three
Hardness test: in dust-free workshop, 25 ± 5 ℃ of temperature, humidity 55% ± 5% utilizes pencil method sclerometer (the portable pencil method of Suzhou Ke Lerui QHQ-A sclerometer) to test the hardness of above-mentioned optical diffusion membrane 1-30.
Test four
Luminance test: in dustless darkroom, 25 ± 5 ℃ of temperature, humidity 55% ± 5% is utilized the brightness of optical diffusion membrane 1-30 and commercially available BS912 optical diffusion membrane in YC meter (moral instrument BM-7 type YC meter is ground in Shanghai) the test comparative example 1,2.For ease of comparing; The brightness of adopting the brightness comparative figure to come the calculating optical diffusion film; The brightness that is specially with commercially available BS912 optical diffusion membrane is benchmark (the brightness comparative figure of commercially available BS912 optical diffusion membrane is made as 100), and the brightness comparative figure of optical diffusion membrane adopts following formula to calculate in the embodiment of the invention:
The actual measurement brightness value of brightness (comparative figure)=optical diffusion membrane of the present invention/commercially available BS912 optical diffusion membrane
Actual measurement brightness value * 100
Table 1: each component concentration among the compsn 1-30
Table 2: optical diffusion membrane 1-30 optics and physical properties take off data
| Transmittance % | Mist degree % | Sticking power | Hardness | |
| Embodiment 1 (optical diffusion membrane 1) | 86.5 | 88.0 | 0 grade | 2H |
| Embodiment 2 (optical diffusion membrane 2) | 86.0 | 89.0 | 0 grade | 2H |
| Embodiment 3 (optical diffusion membrane 3) | 87.0 | 90.0 | 0 grade | 2H |
| Embodiment 4 (optical diffusion membrane 4) | 87.0 | 89.0 | 0 grade | 2H |
| Embodiment 5 (optical diffusion membrane 5) | 87.5 | 88.0 | 0 grade | 2H |
| Embodiment 6 (optical diffusion membrane 6) | 88.0 | 87.0 | 0 grade | 2H |
| Embodiment 7 (optical diffusion membrane 7) | 87.0 | 88.0 | 0 grade | 2H |
| Embodiment 8 (optical diffusion membrane 8) | 87.0 | 90.0 | 0 grade | 2H |
| Embodiment 9 (optical diffusion membrane 9) | 86.5 | 91.5 | 0 grade | 2H |
| Embodiment 10 (optical diffusion membrane 10) | 86.0 | 93.0 | 0 grade | 2H |
| Embodiment 11 (optical diffusion membrane 11) | 87.5 | 87.5 | 0 grade | 2H |
| Embodiment 12 (optical diffusion membrane 12) | 87.0 | 87.50 | 0 grade | 2H |
| Embodiment 13 (optical diffusion membrane 13) | 87.0 | 89.00 | 0 grade | 2H |
| Embodiment 14 (optical diffusion membrane 14) | 87.5 | 90.00 | 0 grade | 2H |
| Embodiment 15 (optical diffusion membrane 15) | 88.0 | 87.50 | 0 grade | 2H |
| Embodiment 16 (optical diffusion membrane 16) | 86.0 | 93.5 | 0 grade | 2H |
| Embodiment 17 (optical diffusion membrane 17) | 87.1 | 87.5 | 0 grade | 2H |
| Embodiment 18 (optical diffusion membrane 18) | 87.5 | 90.00 | 0 grade | 2H |
| Embodiment 19 (optical diffusion membrane 19) | 88.0 | 70.0 | 0 grade | 2H |
| Embodiment 20 (optical diffusion membrane 20) | 87.5 | 80.0 | 0 grade | 2H |
| Embodiment 21 (optical diffusion membrane 21) | 86.5 | 90.0 | 0 grade | 2H |
| Embodiment 22 (optical diffusion membrane 22) | 87.0 | 88.0 | 0 grade | 2H |
| Embodiment 23 (optical diffusion membrane 23) | 87.0 | 90.0 | 0 grade | 2H |
| Embodiment 24 (optical diffusion membrane 24) | 86.5 | 90.5 | 0 grade | 2H |
| Embodiment 25 (optical diffusion membrane 25) | 86.5 | 89.0 | 0 grade | 2H |
| Embodiment 26 (optical diffusion membrane 26) | 88.0 | 87.0 | 0 grade | 2H |
| Embodiment 27 (optical diffusion membrane 27) | 87.0 | 88.0 | 0 grade | 2H |
| Embodiment 28 (optical diffusion membrane 28) | 87.0 | 89.0 | 0 grade | 2H |
| Embodiment 29 (optical diffusion membrane 29) | 87.0 | 90.5 | 0 grade | 2H |
| Embodiment 30 (optical diffusion membrane 30) | 86.8 | 91.5 | 0 grade | 2H |
Table 3 optical diffusion membrane 1-30 and commercially available BS912 optical diffusion membrane luminance factor are
Can know according to above technical scheme; The present invention selects for use the 3rd kind solvent methylethylketone, butylacetate, the ETHYLE ACETATE of low toxic and environment-friendly to replace toluene, YLENE as the solvent that is applied to the compsn of optical diffusion membrane, not only makes optical diffusion membrane low toxicity, the environmental protection of preparation, reduces the harm to environment and human body; And compare with existing optical diffusion membrane; Have higher brightness, transmittance is 86.0%-88.0% simultaneously, and mist degree is 87.0%-93.0%; Sticking power after the curing reaches the superlative degree of drawing the lattice grade, and hardness reaches more than the 2H.
The above is merely preferred embodiment of the present invention, just is used for explaining and explaining the present invention, and be not to be used to limit protection scope of the present invention.Within spirit of the present invention and claim protection domain, to any modification that the present invention did, be equal to replacement, all be included in protection scope of the present invention.
Claims (9)
1. a compsn that is applied to optical diffusion membrane by host, solidifying agent, granular filler and solvent composition, is characterized in that, in the said compsn:
Host: 15-80 weight part;
Solidifying agent: 1.5-16 weight part;
Granular filler: 0.05-108 weight part;
Solvent: 20.1-500 weight part;
Wherein, said host is polyester polyol, and said solvent is made up of the methylethylketone of 5.9-147 weight part, the butylacetate of 5.9-147 weight part, the ETHYLE ACETATE of 8.3-206 weight part;
Wherein, said granular filler is a kind of in silicon compound, silicone resin, PS, the polymethylmethacrylate or at least two kinds mixture wherein, and said granular filler is spherical or the ellipsoid shape, and the particle diameter of granular filler is the 1-100 micron.
2. the compsn that is applied to optical diffusion membrane as claimed in claim 1 is characterized in that, in the said compsn:
Host: 30-50 weight part;
Solidifying agent: 2.5-7 weight part;
Granular filler: 16-57 weight part;
Solvent: 113-260.5 weight part;
Wherein, solvent is made up of the methylethylketone of 33.25-76.5 weight part, the butylacetate of 33.25-76.5 weight part, the ETHYLE ACETATE of 46.5-107.5 weight part.
3. the compsn that is applied to optical diffusion membrane as claimed in claim 2 is characterized in that, in the said compsn:
Host: 40 weight parts;
Solidifying agent: 4.75 weight parts;
Granular filler: 36.5 weight parts;
Solvent: 186.5 weight parts;
Wherein, solvent is made up of the methylethylketone of 54.85 weight parts, the butylacetate of 54.85 weight parts, the ETHYLE ACETATE of 76.8 weight parts.
4. the compsn that is applied to optical diffusion membrane as claimed in claim 1; It is characterized in that; Said polyester polyol is the polyethylene glycol adipate glycol, gathers adipate glycol-propylene glycol ester glycol, gathers hexanodioic acid glycol ether esterdiol, gathers adipate glycol-the glycol ether esterdiol, gathers hexanodioic acid-1; 4-butanediol ester glycol, gather adipate glycol-1; 4-butanediol ester glycol, gather hexanodioic acid NSC 6366-1, a kind of in the 6-pinakon esterdiol or at least two kinds mixture wherein;
Said solidifying agent is a kind of in hexamethylene diisocyanate, isophorone diisocyanate, xylylene diisocyanate, Methylcyclohexyl diisocyanate, the dicyclohexyl methane diisocyanate or at least two kinds mixture wherein.
5. a compsn that is applied to optical diffusion membrane is made up of host, solidifying agent, granular filler, solvent and static inhibitor, it is characterized in that, in the said compsn:
Host: 15-80 weight part;
Solidifying agent: 1.5-16 weight part;
Granular filler: 0.05-108 weight part;
Solvent: 20.1-500 weight part;
Static inhibitor: 0.5-33 weight part;
Wherein, said host is polyester polyol, and said solvent is made up of the methylethylketone of 5.9-147 weight part, the butylacetate of 5.9-147 weight part, the ETHYLE ACETATE of 8.3-206 weight part;
Wherein, said granular filler is a kind of in silicon compound, silicone resin, PS, the polymethylmethacrylate or at least two kinds mixture wherein, and said granular filler is spherical or the ellipsoid shape, and the particle diameter of granular filler is the 1-100 micron.
6. the compsn that is applied to optical diffusion membrane as claimed in claim 5 is characterized in that, in the said compsn:
Host: 30-50 weight part;
Solidifying agent: 2.5-7 weight part;
Granular filler: 16-57 weight part;
Solvent: 113-260.5 weight part;
Static inhibitor: 1.25-7.5 weight part;
Wherein, said solvent is made up of the methylethylketone of 33.25-76.5 weight part, the butylacetate of 33.25-76.5 weight part, the ETHYLE ACETATE of 46.5-107.5 weight part.
7. the compsn that is applied to optical diffusion membrane as claimed in claim 6 is characterized in that, said static inhibitor is the quaternary ammonium salt static inhibitor.
8. an optical diffusion membrane comprises base material, it is characterized in that, this base material single or double is coated with each described compsn in the claim 1 to 7.
9. a liquid crystal indicator comprises module backlight and liquid crystal panel, it is characterized in that, this module backlight comprises the described optical diffusion membrane of at least one claim 8.
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| CN104364675B (en) * | 2012-04-23 | 2018-06-12 | 科思创德国股份有限公司 | Sunproof polyurethane composition |
| JP6717295B2 (en) * | 2015-03-30 | 2020-07-01 | 凸版印刷株式会社 | Color conversion film |
| CN107033695B (en) * | 2017-05-05 | 2019-07-09 | 宁波长阳科技股份有限公司 | A kind of antistatic coating fluid and a kind of antistatic reflectance coating and preparation method thereof |
| CN110161601B (en) * | 2018-03-26 | 2021-08-24 | 林成辉 | Light diffusion film with high light transmittance and ultraviolet radiation shielding function and preparation method thereof |
| CN108732818A (en) * | 2018-05-29 | 2018-11-02 | 武汉华星光电技术有限公司 | The production method of backlight module, display device and backlight module |
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