CN101848697B - Hair cosmetic composition - Google Patents

Hair cosmetic composition Download PDF

Info

Publication number
CN101848697B
CN101848697B CN2007801014315A CN200780101431A CN101848697B CN 101848697 B CN101848697 B CN 101848697B CN 2007801014315 A CN2007801014315 A CN 2007801014315A CN 200780101431 A CN200780101431 A CN 200780101431A CN 101848697 B CN101848697 B CN 101848697B
Authority
CN
China
Prior art keywords
composition
cosmetic hair
silicone
hair composition
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2007801014315A
Other languages
Chinese (zh)
Other versions
CN101848697A (en
Inventor
王璐
水岛广树
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Publication of CN101848697A publication Critical patent/CN101848697A/en
Application granted granted Critical
Publication of CN101848697B publication Critical patent/CN101848697B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/896Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34Alcohols
    • A61K8/342Alcohols having more than seven atoms in an unbroken chain
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00Preparations for care of the hair
    • A61Q5/12Preparations containing hair conditioners

Abstract

A hair cosmetic composition containing, (a) any one or more of the compounds represented by the following formula (I), 0.1-2.0 wt%, (b) ester oil, 0.1-3.0 wt%, (c) cationic surfactant, 1-7 wt%, and (d) fatty alcohol, 4-15 wt%, wherein the ratio (b)/(a) by weight is 0.05-30. (Wherein, R represents any one or more of hydrocarbon groups from C13H27 to C15H31, and 75% of Z represents a group-CH2CH(OH)CH2OH and the remaining portion represents a hydrogen atom, m is 25 to 1000, n is 0.1 to 200).

Description

Cosmetic hair composition
Technical field
The present invention relates to a kind of cosmetic hair composition that contains silicone, particularly contain the cosmetic hair composition of amino functional silicone, this cosmetic hair composition can improve the slickness and the soft feeling of hair.
Background technology
In cosmetic formulations, using silicone is well-known as nursing agent, and a large amount of records are arranged in patent documentation.In some public publications, also put down in writing the cosmetic hair composition that contains the amino functional silicone.For example, in WO2004/014334, disclose a kind of hair composition of detergent, comprised the silicone derivative that hydroxyl and nitrogen-atoms are arranged in anion surfactant, specific glycerin ether and the side chain in this hair composition of detergent.In addition, in WO99/49836, also disclosed a kind of Haircare composition, this Haircare composition comprises one type of specific amino functional silicone.
In existing technology, have following problem: normally used silicone can not show the good compatibility in hair care agent or hair maintenance agent; In the cosmetic composition in above-mentioned patent application, the nursing efficacy of amino functional silicone is not enough.
Summary of the invention
The present invention provides a kind of cosmetic hair composition, and it contains: any one or more chemical compound of (a) representing with formula (1), 0.1~2.0 weight %;
Figure GPA00001132970800011
(wherein, R representes C 13H 27~C 15H 31In any one or more alkyl, 75% expression-CH among the Z 2CH (OH) CH 2The OH base, the Z of remainder representes hydrogen atom, m is in 25~1000 scopes, n is in 0.1~200 scope);
(b) ester oil, 0.1~3.0 weight %; (c) cationic surfactant, 1~7 weight %; And (d) aliphatic alcohol, 4~15 weight %; Wherein, weight ratio (b)/(a) is in 0.05~30 scope.
The present invention also provides a kind of method of making cosmetic hair composition of the present invention, and this method comprises the steps: that by following order (1) mix (b) ester oil, (c) cationic surfactant and (d) aliphatic alcohol; (2) adding (f) silicone in the mixture that after said step (1), obtains, should (f) silicone not be the amino functional silicone; (3) add said composition (a) in the mixture that after said step (2), obtains.
The present invention also provides a kind of method of making cosmetic hair composition of the present invention, and this method comprises the steps: that by following order (1) mix (c) cationic surfactant and (d) aliphatic alcohol; (2) add said composition (a) and (b) ester oil in the mixture that after said step (1), obtains; (3) adding (f) silicone in the mixture that after said step (2), obtains, should (f) silicone not be the amino functional silicone.
The present invention also provides a kind of hair care agent, and this hair care agent contains cosmetic hair composition of the present invention.
The present invention also provides a kind of hair maintenance agent, and this hair maintenance agent contains cosmetic hair composition of the present invention.
The specific embodiment
The present invention relates to a kind of cosmetic hair composition, this cosmetic hair composition can be given hair smoothing property and soft feeling when flushing and after the dry run, and gives hair excellent repairing damage effect.
The inventor finds: through use the amino functional silicone and the ester oil of particular type with specific mass ratio combination, just can be met the cosmetic hair composition of above-mentioned requirements.
Cosmetic hair composition of the present invention comprises composition (a) one or more chemical compounds by formula (1) expression,
Figure GPA00001132970800021
(wherein, R representes C 13H 27~C 15H 31In any one or more alkyl, 75% expression-CH among the Z 2CH (OH) CH 2The OH base, the Z of remainder representes hydrogen atom, and m is in 25~1000 scopes, and n is in 0.1~200 scope.)
The preference of composition (a) is: by general formula (1) expression and m=68 wherein and one or more chemical compounds of n=2; Its commercially available article have; For example; (CAS number: 237753-63-8), its INCI name is called " the amino-terminated dimethyl polysiloxane of two (C13-15 alkoxyl) PG (BIS (C13-15ALKOXY) PG AMODIMETHICONE) " to " 8500 conditioners (the 8500 Conditioning Agent) " of Dow Corning company.
As composition (a), can make up and use two or more above-claimed cpds, its content is 0.1~2.0 weight % in the cosmetic composition of the present invention.From slickness and flexibility and the slickness of dry back hair and the viewpoint of flexibility of the good compatibility, when flushing hair, preferred 0.3~1.0 weight % of its content being arranged with composition (b).
Cosmetic hair composition of the present invention contains composition (b) ester oil.The example of composition (b) comprises isopropyl palmitate, isopropyl myristate, myristic acid octyldodecanol ester, lauric acid hexyl ester, lactic acid cetyl, propylene glycolmonostearate, Cetiol, 2 ethyl hexanoic acid hexadecane alcohol ester, isononyl isononanoate, different n-nonanoic acid tridecane alcohol ester.Wherein, from composition (a) excellent compatibility, the slickness that improves hair and the viewpoint of soft feeling, preferred isopropyl palmitate.
As composition (b), can two or more combinations in the above-claimed cpd be used, its content is 0.1~3.0 weight % in the cosmetic composition of the present invention.From with composition (a) slickness and flexibility and the slickness of dry back hair and the viewpoint of flexibility of the good compatibility, when flushing hair being arranged, the content of composition (b) is preferably 0.5~1.5 weight %.
The slickness of hair and flexibility and the slickness of dry back hair and the viewpoint of flexibility when the good compatibility, flushing are arranged between composition (a) and composition (b), weight ratio (b)/(a) is preferably 0.5~5.0 in 0.05~30 scope.
About explaining, also not too clear and definite at present through using mentioned component (a) and composition (b) to promote the slickness of hair and the mechanism of flexibility than combination with specified weight.Yet infer that this mechanism is following, but this should not be considered to limit the present invention with theory.In cosmetic hair composition, the silicone of non-amino functional silicone is insoluble in the ester oil usually, can not show the good compatibility between the two.But; In cosmetic hair composition; Amino functional silicone as composition of the present invention (a) can be dissolved in the ester oil in specific weight ratio, and they are considered to be present in the layer structure that is formed by cationic surfactant and aliphatic alcohol in the internal structure of conditioner.On the contrary, the silicone of non-amino functional silicone is not present in the layer structure.Thereby the amino functional silicone tends to stay on the hair more in flushing process He after the dry run, thereby improves the slickness and the flexibility of hair.
Cosmetic hair composition of the present invention contains composition (c) cationic surfactant.The example of composition (c) comprises quaternary ammonium salt cationic surfactant.
The example of quaternary ammonium salt cationic surfactant comprises following compounds (i)~(vi).
(i) alkyl trimethyl ammonium salt
For example can use the chemical compound of following general formula:
R 1-N +(CH 3) 3X -
(wherein, R 1Expression C 12-22Alkyl, X -Expression halide ion (chloride ion or bromide ion) or have the alkylsurfuric acid salt ion of 1 or 2 carbon atom).
(ii) alkoxyl leptodactyline
For example can use the chemical compound of following general formula:
R 2-O-R 3-N +(CH 3) 3X -
(wherein, R 2Expression C 12-22Alkyl, R 3Expression ethylidene or propylidene, X -Implication same as described above).
(iii) dialkyl dimethyl ammonium salt
For example can use the chemical compound of following general formula:
(R 4) 2-N +(CH 3) 2X -
(wherein, R 4The alkyl or the benzyl of expression carbon number 12~22, X -Implication same as described above).
(iv) alkyl dimethyl amine (and salt)
For example can use the material and the salt thereof of following general formula:
R 5-N(CH 3) 2
(wherein, R 5Implication same as described above).
(v) alkoxyl dimethyl amine (and salt)
For example can use the material and the salt thereof of following general formula:
R 6-O-R 7-N(CH 3) 2
(wherein, R 6And R 7Implication same as described above).
(vi) alkylamide dimethyl amine (and salt)
For example can use the material and the salt thereof of following general formula:
R 8-C(=O)NH-R 9-N(CH 3) 2
(wherein, R 8The expression carbon number is 11~21 alkyl, R 9Implication same as described above).
Except above-mentioned (i)~(describe vi); The example of other cationic surfactant comprises lanolin fatty acid aminopropyl ethyl Dimethyl Ammonium sulfovinate (sulfovinate of alkanoylamino propyl-dimethyl ethyl ammonium, this alkanoyl comes from lanoline), lanolin fatty acid amino-ethyl triethyl ammonium sulfovinate, lanolin fatty acid aminopropyl triethyl ammonium sulfovinate, lanolin fatty acid amino-ethyl trimethyl ammonium Methylsulfate, lanolin fatty acid aminopropyl ethyl Dimethyl Ammonium Methylsulfate, different alkane carboxylic acid (C 14-C 20) aminopropyl ethyl Dimethyl Ammonium sulfovinate, different alkane carboxylic acid (C 18-C 22) aminopropyl ethyl Dimethyl Ammonium sulfovinate, isostearic acid aminopropyl ethyl Dimethyl Ammonium sulfovinate, different n-nonanoic acid aminopropyl ethyl Dimethyl Ammonium sulfovinate, glucide alkyl trimethyl ammonium.
Can further improve slickness and soft feeling through adding cationic surfactant.From this viewpoint, in the example of the above-mentioned composition of enumerating (c), preferred stearic oxygen propyl-dimethyl amine, stearamide propyl dimethyl amine, cetrimonium chloride and stearyl trimethyl ammonium chloride.
As composition (c), can make up and use two or more above-claimed cpds, its content is 1~7 weight % that accounts for cosmetic composition of the present invention.The slickness of hair and flexibility and the slickness of dry back hair and the viewpoint of flexibility when washing from improving, preferred 2~5 weight % of its content.
Cosmetic hair composition of the present invention comprises composition (d) aliphatic alcohol.Combination uses fatty alcohol material and cationic surfactant to be considered to advantageous particularly in cosmetic hair composition, is dispersed in lamellar phase wherein because can form cationic surfactant like this.
Typical aliphatic alcohol has 14~22 carbon atoms, preferred 16~22 carbon atoms.The example of suitable aliphatic alcohol comprises myristyl alcohol, cetearyl alcohol, spermol, stearyl alcohol, behenyl alcohol etc.Preferred cetearyl alcohol, stearyl alcohol and spermol.
As composition (d), can make up and use above-mentioned two or more chemical compounds, its content accounts for 4~15 weight % of cosmetic composition of the present invention, preferred 5~10 weight %.
Selectively, cosmetic hair composition of the present invention can also contain composition (e) non-ionic polyalcohol.Here, useful non-ionic polyalcohol comprise cellulose derivative, hydrophobically modified cellulose derivative, oxygen ethene polymers, based on the polymer of oxygen ethylene/oxypropylene.Suitable non-ionic polyalcohol has cellulose derivative, comprises methylcellulose, hydroxyethyl-cellulose, hydroxypropyl cellulose, cetyl hydroxyethyl cellulose.Other nonionic fiber that is fit to have guar gum etc.
Selectively, cosmetic hair composition of the present invention can also contain composition (f) silicone, should (f) silicone not be the amino functional silicone.
The example of the silicone of this non-amino functional silicone comprises dimethyl polysiloxane, polyether modified silicone, methyl phenyl silicone, fatty acid modified silicone, pure modified silicone, alkoxy-modified silicone, epoxide modified silicone, fluorine modified silicone, ring-type silicone, alkyl-modified silicone.
Can make up and use two or more above-mentioned silicone.With the slickness of dry back hair and the viewpoint of soft feeling, the content of this silicone preferably accounts for 0.1~10 weight % of cosmetic hair composition of the present invention, more preferably accounts for 0.3~3 weight % when washing from improving.
According to application target, cosmetic hair composition of the present invention can further contain the composition that is generally used in the cosmetic hair composition.For example, comprising: pH regulator agent, for example lactic acid, malic acid; Viscosity modifier; Polyhydric alcohol, for example glycerin, polypropylene glycol; Non-ionic surface active agent, for example polyoxyethylene alkyl ether, polyoxyethylene sorbitan fatty acid ester, fatty acid glyceride, polyglyceryl fatty acid ester, polyoxyethylene hydrogenated Oleum Ricini, sucrose fatty acid ester, polyglycerol alkyl ether, fatty acid alkanol amides, alkyl polyglucoside; Vitamin preparation; Antibacterial; Antiinflammatory; Antiseptic; Chelating agen; Wetting agent, for example pantothenylol; Coloring agent, for example dyestuff and pigment; Extract, for example the eucalyptus extracts in the polar solvent, from Margarita or have the protein that obtains the shell of pears layer or protein hydrolysate, the protein that from silkworm silk, obtains or protein hydrolysate, from seeds of leguminous plant, obtain contain protein extract, Radix Ginseng extract, Testa oryzae extract, Sargassum extract, Camellia extract, Aloe extract, Alpinia japonica (Thunb.) Miq. leaf extract and green algal extract; Margarita powder, for example mica titanium; Essence; Spice; Color is plain; UV absorbent; Antioxidant; Hair care adjuvant, for example aminoacid, ceramide and fatty acid.
Cosmetic hair composition of the present invention can be hair composition of detergent, Haircare composition or hair maintenance compositions; Yet it is Haircare composition or hair maintenance compositions preferably.
Cosmetic hair composition of the present invention can be used for shampoo, hair conditioning liquid (hairrinse), hair care agent, hair maintenance agent etc.; Yet, preferably use it in hair care agent and the hair maintenance agent.
Method for preparing according to cosmetic hair composition of the present invention comprises following four kinds of methods:
First kind of method for preparing has following steps by following order: (c) cationic surfactant and (d) aliphatic alcohol are mixed in (1) in water; (2) add mentioned component (a) in the mixture that after step (1), obtains with the chemical compound of formula (1) expression and (b) ester oil; (3) add the silicone of (f) non-amino functional silicone in the mixture that after step (2), obtains.
Through using the cosmetic hair composition that obtains by first kind of method for preparing, in the time of can improving the hair flushing and dried slickness and soft feeling.In addition, the cosmetic hair composition that is obtained by first kind of method for preparing can be repaired the effect of damage, and soft sense is arranged during touch, is particularly suitable for the slightly damaged hair.
Second kind of method for preparing that is used for making cosmetic hair composition of the present invention has following steps by following order: (c) cationic surfactant, (d) aliphatic alcohol and the chemical compound of (a) representing with formula (1) are mixed at water in (1); (2) add (b) ester oil in the mixture that after step (1), obtains; (3) add the silicone of (f) non-amino functional silicone in the mixture that after step (2), obtains.
The third method for preparing that is used for making cosmetic hair composition of the present invention has following steps by following order: (a) mixed with any compound of formula (1) expression, (b) ester oil, (c) cationic surfactant and (d) aliphatic alcohol at water in (1); (2) add the silicone of (f) non-amino functional silicone in the mixture that after step (1), obtains.
The 4th kind of method for preparing that is used for making cosmetic hair composition of the present invention has following steps by following order: (b) ester oil, (c) cationic surfactant and (d) aliphatic alcohol are mixed at water in (1); (2) silicone that adds (f) non-amino functional silicone in the mixture that after step (1), obtains; (3) add (a) any compound in the mixture that after step (2), obtains with formula (1) expression.
Through using, in the time of can improving the hair flushing and dried slickness and soft feeling by the 4th kind of cosmetic hair composition that method for preparing obtains.In addition, can repair the effect of damage, more thick and heavy sense is arranged during touch, be particularly suitable for the hair that is badly damaged by the 4th kind of cosmetic hair composition that method for preparing obtains.
In above-mentioned four kinds of method for preparinies, it is effective especially that first kind and the 4th kind of method for preparing make damaged hair have a hair cosmetic composition of better soft/smooth feeling and thick and heavy/apply sense for preparation, and preferred.
Utilize cosmetic hair composition provided by the present invention, its preparation method, hair care agent and hair maintenance agent, can improve when washing and the slickness and the soft feeling of dry back hair, and give the effect of the good injury repairing of hair.
Following example further specifies and explains the present invention.These embodiment are just to example, rather than are used for limiting the present invention.
Embodiment
Preparation has shown in table 1~9 the hair care agent of forming, and with following method and standard evaluation its " slickness ", " flexibility " and " reparation damage effect ".Evaluation result is represented with table 10.
The preparation example
Follow these steps to (corresponding above-mentioned the 4th kind of method for preparing) preparation embodiment 1~4 and comparative example 1~3.
At first, under 55~60 ℃, in water, add isopropyl palmitate (as (b) ester oil), stearic oxygen propyl group DMA (as (c) cationic surfactant), stearyl alcohol (as (d) aliphatic alcohol) by table 1~4, amount shown in 6~8 respectively.Then, in the mixture that obtains like this, pressing respectively, the amount in table 1~4, shown in 6~8 adds dimethicone (as the silicone of (f) non-amino functional silicone).Afterwards, in mixture, pressing respectively, the amount in table 1~4, shown in 6~8 adds two amino-terminated dimethyl polysiloxanes of (C13-15 alkoxyl) PG (as (a)).At last, pressing respectively, the amount in table 1~4, shown in 6~8 adds other compositions.Thereby obtain the hair care agent of embodiment 1~4 and comparative example 1~3.
Follow these steps to (corresponding above-mentioned first kind of method for preparing) preparation embodiment 5 and comparative example 4.
At first, by respectively in table 5, the amount shown in 9, under 55~60 ℃, in water, add stearic oxygen propyl group DMA (as (c) cationic surfactant), stearyl alcohol (as (d) aliphatic alcohol).Then, in the mixture that obtains like this, by adding two amino-terminated dimethyl polysiloxanes of (C13-15 alkoxyl) PG (as (a)) and isopropyl palmitate (as (b) ester oil) respectively in table 5, the amount shown in 9 respectively.Afterwards, in the mixture that obtains, by adding dimethicone (as the silicone of (f) non-amino functional silicone) in table 5, the amount shown in 9 respectively.At last, press other compositions of the adding of the amount shown in the difference in the table 5,9.Thereby obtain the hair care agent of embodiment 5 and comparative example 4.
Evaluation methodology
Estimate the hair care agent for preparing in embodiment 1~5, the comparative example 1~4 with following method.
(about 15~20cm) the Asia women's hairs through cosmetics processing (for example, cold wave or decolouring are handled), shampoo is clean with a branch of 20g.On the topknot of gained, evenly use the agent of 2g hair care, then with flowing water flushing 30 seconds.Afterwards, this topknot being toweled off dry doubling dries up.When flushing and after the drying, " slickness ", " flexibility " and " injury repairing effect " of this topknot are carried out sensory evaluation by 5 members of panel of expert.Its total points is represented in table 10.
Evaluation criterion:
" slickness "
4: very smooth
3: smooth
2: not too smooth
1: rough
" flexibility "
4: very soft
3: softness
2: not too soft
1: not soft
" injury repairing effect "
4: very good
3: good
2: not so good
1: bad
Table 1 (embodiment 1)
Figure GPA00001132970800101
Table 2 (embodiment 2)
Figure GPA00001132970800102
Table 3 (embodiment 3)
Figure GPA00001132970800111
Table 4 (embodiment 4)
Figure GPA00001132970800112
Table 5 (embodiment 5)
Table 6 (comparative example 1)
Figure GPA00001132970800122
Table 7 (comparative example 2)
Figure GPA00001132970800131
Table 8 (comparative example 3)
Figure GPA00001132970800132
Table 9 (comparative example 4)
Figure GPA00001132970800141
Table 10 (evaluation result)
Figure GPA00001132970800142
As shown in table 10, compare the hair care agent that obtains in the comparative example, the hair care agent that obtains among the embodiment 1~5 (weight ratio (b)/(a)=0.05~30) shows better slickness and soft feeling when flushing and after the dry run.
As shown in table 10, hair care agent (embodiment 5) that is obtained by first kind of method for preparing and the hair care agent (embodiment 1~4) that is obtained by the 4th kind of method for preparing can give the good slickness of hair, soft feeling and good injury repairing effect.

Claims (14)

1. cosmetic hair composition is characterized in that:
Contain:
(a) any one or more chemical compound of representing with formula (1), 0.1~2.0 weight %;
Figure FSB00000654096300011
Wherein, R representes C 13H 27~C 15H 31In any one or more alkyl, 75% expression-CH among the Z 2CH (OH) CH 2The OH base, the Z of remainder representes hydrogen atom, and m is in 25~1000 scopes, and n is in 0.1~200 scope;
(b) ester oil; Be selected from isopropyl palmitate, isopropyl myristate, myristic acid octyldodecanol ester, lauric acid hexyl ester, lactic acid cetyl, propylene glycolmonostearate, Cetiol, 2 ethyl hexanoic acid hexadecane alcohol ester, isononyl isononanoate and different n-nonanoic acid tridecane alcohol ester, 0.1~3.0 weight %;
(c) quaternary ammonium salt cationic surfactant, 1~7 weight %; And
(d) has the aliphatic alcohol of 14~22 carbon atoms, 4~15 weight %;
Wherein, weight ratio (b)/(a) is in 0.05~30 scope.
2. cosmetic hair composition as claimed in claim 1 is characterized in that:
The content of said composition (a) is in 0.3~1.0 weight % scope.
3. cosmetic hair composition as claimed in claim 1 is characterized in that:
The content of said composition (b) is in 0.5~1.5 weight % scope.
4. cosmetic hair composition as claimed in claim 1 is characterized in that:
Said weight ratio (b)/(a) is in 0.5~5.0 scope.
5. cosmetic hair composition as claimed in claim 1 is characterized in that:
The content of said composition (c) is in 2~5 weight % scopes.
6. cosmetic hair composition as claimed in claim 1 is characterized in that:
The content of said composition (d) is in 5~10 weight % scopes.
7. cosmetic hair composition as claimed in claim 1 is characterized in that:
Also contain (e) non-ionic polyalcohol.
8. cosmetic hair composition as claimed in claim 1 is characterized in that:
Also contain (f) silicone, this silicone is not the amino functional silicone.
9. like any described cosmetic hair composition in the claim 1~8, it is characterized in that:
Said cosmetic hair composition is a Haircare composition.
10. like any described cosmetic hair composition in the claim 1~8, it is characterized in that:
Said cosmetic hair composition is a hair maintenance compositions.
11. the manufacturing approach of a cosmetic hair composition is characterized in that:
Be the method for making cosmetic hair composition as claimed in claim 8, this method comprises the steps: by following order
(1) mixes (b) ester oil, (c) cationic surfactant and (d) aliphatic alcohol;
(2) adding (f) silicone in the mixture that after said step (1), obtains, should (f) silicone not be the amino functional silicone;
(3) add said composition (a) in the mixture that after said step (2), obtains.
12. the manufacturing approach of a cosmetic hair composition is characterized in that:
Be the method for making cosmetic hair composition as claimed in claim 8, this method comprises the steps: by following order
(1) mixing (c) cationic surfactant and (d) aliphatic alcohol;
(2) add said composition (a) and (b) ester oil in the mixture that after said step (1), obtains;
(3) adding (f) silicone in the mixture that after said step (2), obtains, should (f) silicone not be the amino functional silicone.
13. hair care agent is characterized in that,
Comprise like any described cosmetic hair composition in the claim 1~8.
14. a hair maintenance agent is characterized in that,
Comprise like any described cosmetic hair composition in the claim 1~8.
CN2007801014315A 2007-11-06 2007-11-06 Hair cosmetic composition Expired - Fee Related CN101848697B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2007/003144 WO2009059455A1 (en) 2007-11-06 2007-11-06 Hair cosmetic composition

Publications (2)

Publication Number Publication Date
CN101848697A CN101848697A (en) 2010-09-29
CN101848697B true CN101848697B (en) 2012-05-23

Family

ID=40625348

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2007801014315A Expired - Fee Related CN101848697B (en) 2007-11-06 2007-11-06 Hair cosmetic composition

Country Status (2)

Country Link
CN (1) CN101848697B (en)
WO (1) WO2009059455A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2335678A1 (en) * 2009-12-18 2011-06-22 KPSS-Kao Professional Salon Services GmbH Conditioning composition for hair
EP2380555A1 (en) * 2010-04-23 2011-10-26 KPSS-Kao Professional Salon Services GmbH Conditioning composition for keratin fibres and its use
FR2968209B1 (en) * 2010-12-03 2013-07-12 Oreal COSMETIC COMPOSITIONS CONTAINING NON-AMINOUS SILICONE, LIQUID FATTY ESTER AND AMINO SILICONE, METHODS AND USES
JP5698528B2 (en) * 2010-12-28 2015-04-08 花王株式会社 Hair cosmetics
BR112015033043B1 (en) 2013-09-02 2020-03-24 L'oreal COSMETIC COMPOSITION AND COSMETIC TREATMENT PROCESS
WO2022028809A1 (en) * 2020-08-03 2022-02-10 L'oreal Cosmetic composition comprising anionic and amphoteric surfactants, a cationic polymer, at least 2% of solid fatty alcohol and a particular amino silicone; and process
FR3113245B1 (en) * 2020-08-03 2023-03-10 Oreal Cosmetic composition comprising anionic and amphoteric surfactants, a cationic polymer, at least 2% solid fatty alcohol and a particular amino silicone; and process

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1671355A (en) * 2002-08-09 2005-09-21 花王株式会社 Hair detergent compositions
CN1863501A (en) * 2003-09-08 2006-11-15 纳幕尔杜邦公司 Peptide-based conditioners and colorants for hair, skin, and nails

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1671355A (en) * 2002-08-09 2005-09-21 花王株式会社 Hair detergent compositions
CN1863501A (en) * 2003-09-08 2006-11-15 纳幕尔杜邦公司 Peptide-based conditioners and colorants for hair, skin, and nails

Also Published As

Publication number Publication date
WO2009059455A1 (en) 2009-05-14
CN101848697A (en) 2010-09-29

Similar Documents

Publication Publication Date Title
CN101848697B (en) Hair cosmetic composition
CN101155575B (en) Hair cosmetic
CN105793273B (en) Dihydroxyalkyl-substituted polygalactomannans and methods of making and using same
JP4627333B2 (en) Hair cosmetics
US6878368B2 (en) Composition for blending to hair treating agents and a hair treating agent
AU2005201465B2 (en) Hair cosmetic composition
JP5479689B2 (en) Hair cosmetics
EP1676604B1 (en) Method for enhancing chroma of hair
CN101129303B (en) Aqueous hair cosmetic
JP5325494B2 (en) Hair cosmetics
TWI419707B (en) Hair cosmetic composition
JP2010533704A (en) A conditioning composition comprising a dual cationic surfactant system, an aminosilicone, and a silicone resin
US20100015078A1 (en) Conditioning composition comprising dual cationic surfactant system, aminosilicone and silicone resin
WO2014069388A1 (en) Hair conditioner composition
TW200406225A (en) Hair detergent compositions
JP5138478B2 (en) Hair cosmetics
JP4756249B2 (en) Multi-agent hair cosmetic
CN107412007A (en) Dye composite comprising alkoxy fatty alcohols ether and fatty alcohol or fatty acid ester
JP2006315986A (en) Hair cosmetic
EP0729742A2 (en) Hair cosmetic composition containing an amino-modified silicon polymer
WO2020146931A1 (en) Hair care system, hair care method and use of a hair care system
CN110114049A (en) For handling the oxidising composition comprising scleroglucan glue and the chelating agent based on phosphorus of keratin fiber
CN110114055A (en) Comprising hydrogen peroxide, peroxide salt, carbonate and at least one more phosphorus derivants hair brightening composition
WO1999013840A1 (en) Hair dye composition
JP2020121937A (en) Hair dying composition

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120523

Termination date: 20131106