CN101838493A - Heat-insulating coating for inner wall - Google Patents

Heat-insulating coating for inner wall Download PDF

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CN101838493A
CN101838493A CN 201010186715 CN201010186715A CN101838493A CN 101838493 A CN101838493 A CN 101838493A CN 201010186715 CN201010186715 CN 201010186715 CN 201010186715 A CN201010186715 A CN 201010186715A CN 101838493 A CN101838493 A CN 101838493A
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陈孟
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China Paint Manufacturing (shenzhen) Ltd
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China Paint Manufacturing (shenzhen) Ltd
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Abstract

The invention discloses a heat-insulating coating for an inner wall. The heat-insulating coating comprises the following components in percentage by weight: 20 to 40 percent of acrylic acid latex, 0.1 to 5 percent of moistening agent, 0.1 to 5 percent of dispersing agent, 5 to 20 percent of diatomite, 5 to 10 percent of hollow glass microsphere, 5 to 25 percent of titanium white powder, 0.1 to 5 percent of thickening agent, 1 to 10 percent of swelling microsphere, 3 to 10 percent of opaque polymer and 20 to 40 percent of water. The novel heat-insulating coating for the inner wall has the characteristics of slow temperature rise during heating and slow temperature drop during heat emission, and can properly adjust the indoor temperature and make the housing environment more comfortable; and, the aqueous latex is used, so that the heat-insulating coating is safe to the human body and the environment, and belongs to green environmentally-friendly product.

Description

A kind of heat-insulating coating for inner wall
Technical field
The present invention relates to a kind of heat-insulating coating for inner wall.
Background technology
Saving energy and reduce the cost, increasing economic efficiency is one of elementary object of scientific research and technological development, and coating technology is no exception.After the seventies in 20th century, world climate warms, and earth energy is exhausted day by day.In AND ENERGY RESOURCES CONSUMPTION IN CHINA, building energy consumption accounts for 1/4 of national energy consumption greatly, and lagging material for building only accounts for about 11% of total amount, and visible building energy conservation potentiality are very big.Popularize energetically abroad under the background of heat-insulation and heat-preservation material, can predict, China will progressively put into effect the rules that need take the heat-insulation and heat-preservation measure to new dwelling house.Insulating mold coating for construction more and more is subjected to people's favor, development prospect light because of advantages such as economic, easy to use and good heat-insulation effect in the heat-insulating material.Therefore, the exploitation heat insulating coatings especially has bigger realistic meaning with the closely-related insulating mold coating for construction of human lives.
Different according to heat insulation mechanism of insulating mold coating for construction and heat insulation mode can be divided three classes present thermal insulating coating: barrier thermal insulating coating, reflective heat-insulation paint and radiation heat insulation coating.No matter according to the thermal insulation coatings of which kind of principle design, the thermal conductivity that reduces coating itself is a very important proposition.Be to add ceramic microspheres or glass microsphere etc. to the method that reduces the employing of coating thermal conductivity at present, can under the situation that does not change other performances of coating, reduce the coating thermal conductivity to a certain extent, but effect be still not ideal enough.
Therefore, prior art awaits improving and development.
Summary of the invention
The heat-insulating coating for inner wall that provides a kind of thermal conductivity low is provided problem to be solved by this invention, to reach better heat insulation effect.
In order to solve the problems of the technologies described above, technical scheme of the present invention is as follows:
A kind of heat-insulating coating for inner wall, wherein, comprise following components in weight percentage: ACRYLIC EMULSION 20~40%, wetting agent 0.1~5%, dispersion agent 0.1~5%, diatomite 5~20%, hollow glass micro-ball 5~10%, titanium dioxide 5~25%, thickening material 0.1~5%, expandable microspheres 1~10%, Opacifying polymers 3~10%, water 20%~40%.
Described heat-insulating coating for inner wall, wherein, described expandable microspheres is a microspheric form thermoplasticity particulate, mean diameter is 6~45 microns.
Described heat-insulating coating for inner wall, wherein, described Opacifying polymers is the hollow polymer spheroid, its shell is the polymkeric substance of forming with acrylate, vinylbenzene.
Described heat-insulating coating for inner wall, wherein, described wetting agent is the polyethenoxy ether class wetting agent.
Described heat-insulating coating for inner wall, wherein, described dispersion agent is the ammonium polyacrylate dipersant.
Described heat-insulating coating for inner wall, wherein, described thickening material is one or both in alkali swelling class thickening material and the polyurethanes thickening material.
Described heat-insulating coating for inner wall, wherein, described titanium dioxide is a Rutile type Titanium Dioxide.
Described heat-insulating coating for inner wall wherein, further comprises: other auxiliary agents 1~5%.
Described heat-insulating coating for inner wall, wherein, described other auxiliary agents are one or more in mould inhibitor, sanitas, antiseptic-germicide, the frostproofer.
The manufacture method of described heat-insulating coating for inner wall, wherein, comprise: mixed dispersant, wetting agent, titanium dioxide, diatomite, portion water under stirring at low speed, after middling speed stirs, add the part thickening material, and carry out high speed dispersion, continue afterwards under middling speed stirs, to add ACRYLIC EMULSION, hollow glass micro-ball, Opacifying polymers, residue thickening material, add thermoplasticity expandable microspheres, surplus water, middling speed stirs again.
The employing such scheme the invention provides a kind of novel heat-insulating coating for inner wall, and this product thermal conductivity is low, and slow, the also slow characteristics of lowering the temperature when dispelling the heat that heat up when having heating can moderately be regulated room temp, make living environment more comfortable; Density is low, uses less amount can reach heat-insulation and heat-preservation and covering effect; Adopt water-based emulsion, human body and environment are safe from harm, belong to Green Product.
Description of drawings
Fig. 1 is the heat preservation and insulation test curve figure of heat-insulating coating for inner wall of the present invention.
Embodiment
The invention discloses a kind of heat-insulating coating for inner wall, it is a water-borne coatings, comprise acrylic emulsion, wetting agent, dispersion agent, hollow glass micro-ball, diatomite, titanium dioxide, thickening material and other auxiliary agents, and add the expandable microspheres that can effectively reduce coating density and thermal conductivity.Because the thermal conductivity of expandable microspheres own is low, and has microvoid structure, density is little, good mechanical property, hydrophobicity are strong, can reduce the volume density of coating effectively, can pin more still air in coating inside during film forming, thereby reduce the thermal convection of coating thermal conductivity and obstruct air effectively.This has just greatly strengthened the heat insulation effect of coating.
The present invention adopts following technical scheme: a kind of heat-insulating coating for inner wall, and this coating comprises following component by weight percentage: water: 20%~40%; Wetting agent 0.1~5%; Dispersion agent: 0.1~5%; Thickening material 0.1~5%; Rutile type Titanium Dioxide: 5~25%; Diatomite 5~20%; Hollow glass micro-ball 5~10%; Expandable microspheres: 1~10%; ACRYLIC EMULSION: 20~40%; Opacifying polymers: 3~10%; Other coatings additive(s)s (as mould inhibitor, sanitas, antiseptic-germicide, frostproofer etc.) 1~5%.
That glass microsphere has is in light weight, volume is big, thermal conductivity is low, the advantage of dispersed, mobile, good stability, and have excellent mechanical intensity and an erosion resistance, density, the flowability of coating be can reduce as stopping composition, the shock strength and the hardness of filming improved.The present invention adopts glass microsphere to substitute the higher filler (titanium white, diatomite and lime carbonate etc.) of portion of hot conductance, reduces coating thermal conductivity and maintenance even strengthens the physical strength of filming.
In order to improve heat insulation and preservation effect, the present invention designs on the basis of glass microsphere thermal insulating coating, adds expandable microspheres simultaneously, significantly reduces coating density, further reduces the coating thermal conductivity simultaneously.Therefore coating of the present invention promptly possesses good heat insulation and preservation effect under the less situation of consumption.
The expandable microspheres that the present invention uses is for adopting the microspheric form thermoplasticity particulate of special process preparation, form by enclosing gas and hydrophobic acrylic acid's polymer shell, the mean diameter of these tiny balloons is 6~45 microns, and microballoon expands behind the contact water, and the volume increase can be above 40 times.Just because of the foaming character of expandable microspheres, make its density that can reduce coating significantly, pin more still air in the inside of filming during film forming, thereby reduce the thermal convection of coating thermal conductivity and obstruct air effectively.Adopt the expandable microspheres of import in an embodiment, as the Expencal microballoon series of Akzo Nobel N.V..When the heating microballoon, the gaseous tension in the shell increases and the thermoplasticity shell softens, and causes microsphere volume significantly to increase, and the cooling microballoon causes shell hardening once more, and slight expansible microballoon can use at any time.This composition has advantages such as excellent elasticity, light weight, chemicals-resistant, low gas permeability, excellent mechanical intensity, can obviously reduce coating density and improve the coating heat insulation and preservation effect.
The ACRYLIC EMULSION that the present invention uses is esters of acrylic acid polymerization emulsion, has excellent elasticity and the good anti-performance that stains, and formed filming is highly resistant to crackle, and weathering resistance is good.
The Opacifying polymers that the present invention uses is the hollow polymer spheroid, and its shell is the very high polymkeric substance of forming with acrylate/vinylbenzene of second-order transition temperature.Opacifying power can be provided, can replace the part titanium dioxide, not participate in film forming simultaneously.Have fabulous covering performance, can improve water-fast, the weather resistance of filming.
The titanium dioxide that the present invention uses has the covering and the dispersing property of high gloss, excellence, preferably uses Rutile type Titanium Dioxide.
The diatomite that the present invention uses, it has good thermal insulation, filling and dispersing property.
The wetting agent that the present invention uses is preferably the polyethenoxy ether class wetting agent.
The dispersion agent that the present invention is to use is preferably high-molecular weight ammonium polyacrylate dipersant.
The thickening material that the present invention uses is mainly alkali swelling property class and polyurethanes thickening material.
Production technique of the present invention is: the manufacture method of novel heat insulation coating, earlier take by weighing raw material according to formula rate, low-speed stage adds 20~30 parts of deionized waters successively, 0.1~5 part of dispersion agent, 0.1~5 part of wetting agent, 5~25 parts of Rutile type Titanium Dioxides, 5~20 parts in diatomite, middling speed stirs 3~5min, adds 0.1~2 part of thickening material, treat that above raw material adding finishes, middling speed stirs after carrying out high speed dispersion 15min, adds 20~35 parts of emulsions, 5~10 parts of hollow glass micro-balls, 3~10 parts of Opacifying polymers, middling speed stirs down and adds 0.1~3 part of thickening material, adds the thermoplasticity expandable microspheres, 10~20 parts in water and other compositions, middling speed stirs 15min again, again after filtration, the packing of weighing.
Wherein, described stirring at low speed is meant that the rotating speed of agitating vane is between 500 rev/mins-800 rev/mins, high-speed stirring is meant the rotating speed of agitating vane between 1000 rev/mins-1500 rev/mins, and middling speed stirs and is meant that the rotating speed of agitating vane is between 800 rev/mins-1000 rev/mins.
Make thermal insulation coatings according to the present invention and adopt water-based emulsion, human body and environment are safe from harm, belong to Green Product.Slow, the also slow characteristics of lowering the temperature when dispelling the heat heat up when product has heating.In hot summer, this coating can intercept heat energy effectively and transmit in the inlet chamber from wall, makes the indoor relatively low temperature that remains in south; At northern cold winter, when making room temp, heating installation raises, and effectively trap heat is distributed to outdoor, reduces the loss of heat, and when room temp reduces, can slowly discharge heat energy, the loss of reinforcement heat.Can moderately regulate room temp, make living environment more comfortable.This product construction is very convenient, by adding different other mill bases, can provide multiple color to select, and has good decoration and defencive function.
Below, preferred embodiment of the present invention is described in further detail.
Embodiment one:
Embodiment: novel heat insulation coating, its formulation ratio are (weight percent):
The manufacture method of novel heat insulation coating, earlier take by weighing raw material according to formula rate, low-speed stage adds 15 parts of deionized waters successively, 0.5 part of wetting agent, 0.5 part of dispersion agent, 10 parts of Rutile type Titanium Dioxides, 5 parts in diatomite, 0.5 part of polyurethane thickener treats that above raw material adding finishes, and carries out high speed dispersion middling speed stirring after 15 minutes, add 29.5 parts of emulsions, 10 parts of hollow glass micro-balls, 5 parts of Opacifying polymers add 0.5 part of 0.2 part of alkali swelling class thickening material and polyurethane thickener under the stirring at low speed, add the thermoplasticity expandable microspheres, surplus water and other compositions, restir 15min, more after filtration, the packing of weighing.
Embodiment two:
Novel heat insulation coating, its formulation ratio are (weight percent):
Figure GSA00000139721600061
The manufacture method of novel heat insulation coating: take by weighing raw material according to formula rate earlier, low-speed stage adds 15 parts of deionized waters successively, 0.5 part of wetting agent, 0.5 part of dispersion agent, 10 parts of Rutile type Titanium Dioxides, 10 parts in diatomite, 0.5 part of polyurethane thickener, treat that above raw material adding finishes, carry out high speed dispersion middling speed stirring after 15 minutes, add 31.5 parts of emulsions, 8 parts of hollow glass micro-balls, 3 parts of Opacifying polymers, add 0.5 part of 0.2 part of alkali swelling class thickening material and polyurethane thickener under the stirring at low speed, add the thermoplasticity expandable microspheres, surplus water and other compositions, restir 15min, again after filtration, the packing of weighing.
Embodiment three:
Novel heat insulation coating, its formulation ratio are (weight percent):
Figure GSA00000139721600062
Figure GSA00000139721600071
The manufacture method of novel heat insulation coating: take by weighing raw material according to formula rate earlier, low-speed stage adds 15 parts of deionized waters successively, 0.5 part of wetting agent, 0.5 part of dispersion agent, 12 parts of Rutile type Titanium Dioxides, 8 parts in diatomite, 0.5 part of polyurethane thickener, treat that above raw material adding finishes, carry out high speed dispersion middling speed stirring after 15 minutes, add 33.5 parts of emulsions, 5 parts of hollow glass micro-balls, 10 parts of Opacifying polymers, add 0.5 part of 0.2 part of alkali swelling class thickening material and polyurethane thickener under the stirring at low speed, add the thermoplasticity expandable microspheres, surplus water and other compositions, restir 15min, again after filtration, the packing of weighing.
Embodiment four:
Novel heat insulation coating, its formulation ratio are (weight percent):
Figure GSA00000139721600072
The manufacture method of novel heat insulation coating: take by weighing raw material according to formula rate earlier, low-speed stage adds 15 parts of deionized waters successively, 0.5 part of wetting agent, 0.5 part of dispersion agent, 5 parts of Rutile type Titanium Dioxides, 20 parts in diatomite, 0.5 part of polyurethane thickener, treat that above raw material adding finishes, carry out high speed dispersion middling speed stirring after 15 minutes, add 40 parts of emulsions, 5 parts of hollow glass micro-balls, 5 parts of Opacifying polymers, add 0.2 part of alkali swelling class thickening material under the stirring at low speed, add the thermoplasticity expandable microspheres, surplus water and other compositions, restir 15min, again after filtration, the packing of weighing.
Embodiment five:
Novel heat insulation coating, its formulation ratio are (weight percent):
Figure GSA00000139721600081
The manufacture method of novel heat insulation coating: take by weighing raw material according to formula rate earlier, low-speed stage adds 15 parts of deionized waters successively, 0.5 part of wetting agent, 0.5 part of dispersion agent, 5 parts of Rutile type Titanium Dioxides, 12 parts in diatomite, 0.5 part of polyurethane thickener, treat that above raw material adding finishes, carry out high speed dispersion middling speed stirring after 15 minutes, add 20 parts of emulsions, 5 parts of hollow glass micro-balls, 5 parts of Opacifying polymers, add 0.2 part of alkali swelling class thickening material under the stirring at low speed, add the thermoplasticity expandable microspheres, surplus water and other compositions, restir 15min, again after filtration, the packing of weighing.
Embodiment six:
Novel heat insulation coating, its formulation ratio are (weight percent):
Figure GSA00000139721600082
Figure GSA00000139721600091
The manufacture method of novel heat insulation coating: take by weighing raw material according to formula rate earlier, low-speed stage adds 15 parts of deionized waters successively, 2 parts of wetting agents, 5 parts of dispersion agents, 25 parts of Rutile type Titanium Dioxides, 5 parts in diatomite, 0.1 part of polyurethane thickener, treat that above raw material adding finishes, carry out high speed dispersion middling speed stirring after 15 minutes, add 20 parts of emulsions, 5 parts of hollow glass micro-balls, 5 parts of Opacifying polymers, add 0.1 part of alkali swelling class thickening material under the stirring at low speed, add thermoplasticity expandable microspheres, surplus water and other compositions, restir 15min, again after filtration, the packing of weighing.
Embodiment seven:
Novel heat insulation coating, its formulation ratio are (weight percent):
Figure GSA00000139721600092
The manufacture method of novel heat insulation coating: take by weighing raw material according to formula rate earlier, low-speed stage adds 15 parts of deionized waters successively, 2 parts of wetting agents, 0.1 part of dispersion agent, 25 parts of Rutile type Titanium Dioxides, 5 parts in diatomite, 0.1 part of polyurethane thickener, treat that above raw material adding finishes, carry out high speed dispersion middling speed stirring after 15 minutes, add 20 parts of emulsions, 5 parts of hollow glass micro-balls, 5 parts of Opacifying polymers, add 4.9 parts of alkali swelling class thickening materials under the stirring at low speed, add thermoplasticity expandable microspheres, surplus water and other compositions, restir 15min, again after filtration, the packing of weighing.
The heat preservation and insulation testing method:
1) paint brush to be tested is applied on the iron plate, fixed temperature and humidity maintains after film is done and brushes again.To dried film thickness 5mm, place thermostatic constant wet chamber's (25 ± 1 ℃, relative humidity 55 ± 3%) maintenance to test after one week iron plate.(coating consumption: common coating 600g, heat insulating coatings 400g of the present invention.)
2) the heat insulation thermostat container that an inwall has thermal insulation layer and top layer openings is set.During measurement iron plate is covered the hot box top layer, make coating face in, thermal source (for example, fluorescent lamp) dorsad, and with space around the transparent adhesive tape sealing.Thermal source is placed 30cm place directly over the iron plate, and in hot box below the iron plate use temperature tester measure the coating surface temperature.
3) behind the use thermal source heat temperature raising 30min, close thermal source cooling 30min, the use temperature tester is measured the coating surface temperature during this time, and every the 5min record data, obtain time-temperature variation curve (wherein, prescription 1,2,3 is respectively the coating of making among embodiment 1, embodiment 2 and the embodiment 3) as shown in Figure 1.
The heat preservation and insulation test result:
Because coating density of the present invention is low, therefore the more common coating of coating consumption of identical thickness few 1/3.As shown in Figure 1, in preceding 30 minutes heat-processed, the blank iron plate temperature of uncoated coating rises to nearly 65 degree always, then drops near room temperature fast at back 30 minutes.And be coated with the iron plate of coating of the present invention, and although consumption is few, compare with the iron plate that is coated with common coating, temperature rises slowly during intensification, temperature descends slowly when lowering the temperature, and shows good heat insulation and preservation effect.
Should be understood that, for those of ordinary skills, can be improved according to the above description or conversion, and all these improvement and conversion all should belong to the protection domain of claims of the present invention.

Claims (10)

1. heat-insulating coating for inner wall, it is characterized in that, comprise following components in weight percentage: ACRYLIC EMULSION 20~40%, wetting agent 0.1~5%, dispersion agent 0.1~5%, diatomite 5~20%, hollow glass micro-ball 5~10%, titanium dioxide 5~25%, thickening material 0.1~5%, expandable microspheres 1~10%, Opacifying polymers 3~10%, water 20%~40%.
2. heat-insulating coating for inner wall according to claim 1 is characterized in that, described expandable microspheres is a microspheric form thermoplasticity particulate, and mean diameter is 6~45 microns.
3. heat-insulating coating for inner wall according to claim 1 is characterized in that, described Opacifying polymers is the hollow polymer spheroid, and its shell is the polymkeric substance of forming with acrylate, vinylbenzene.
4. heat-insulating coating for inner wall according to claim 1 is characterized in that, described wetting agent is the polyethenoxy ether class wetting agent.
5. heat-insulating coating for inner wall according to claim 1 is characterized in that, described dispersion agent is the ammonium polyacrylate dipersant.
6. heat-insulating coating for inner wall according to claim 1 is characterized in that, described thickening material is one or both in alkali swelling class thickening material and the polyurethanes thickening material.
7. heat-insulating coating for inner wall according to claim 1 is characterized in that, described titanium dioxide is a Rutile type Titanium Dioxide.
8. heat-insulating coating for inner wall according to claim 1 is characterized in that, further comprises: other auxiliary agents 1~5%.
9. heat-insulating coating for inner wall according to claim 8 is characterized in that, described other auxiliary agents are one or more in mould inhibitor, sanitas, antiseptic-germicide, the frostproofer.
10. the manufacture method of the described heat-insulating coating for inner wall of claim 1, it is characterized in that, comprise: mixed dispersant, wetting agent, titanium dioxide, diatomite, portion water under stirring at low speed, after middling speed stirs, add the part thickening material, and carry out high speed dispersion, continue afterwards under middling speed stirs, to add ACRYLIC EMULSION, hollow glass micro-ball, Opacifying polymers, residue thickening material, add thermoplasticity expandable microspheres, surplus water, middling speed stirs again.
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Application publication date: 20100922