CN101838446A - Flame-retardant enhanced polybutylece terephthalate (PBT) material and preparation method thereof - Google Patents
Flame-retardant enhanced polybutylece terephthalate (PBT) material and preparation method thereof Download PDFInfo
- Publication number
- CN101838446A CN101838446A CN201010179614A CN201010179614A CN101838446A CN 101838446 A CN101838446 A CN 101838446A CN 201010179614 A CN201010179614 A CN 201010179614A CN 201010179614 A CN201010179614 A CN 201010179614A CN 101838446 A CN101838446 A CN 101838446A
- Authority
- CN
- China
- Prior art keywords
- parts
- flame retardant
- polybutylene terephthalate
- retardant resistance
- pbt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000003063 flame retardant Substances 0.000 title claims abstract description 65
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000000463 material Substances 0.000 title abstract description 44
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 title abstract 3
- 239000003112 inhibitor Substances 0.000 claims abstract description 20
- 239000002131 composite material Substances 0.000 claims abstract description 19
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 12
- 239000000314 lubricant Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 9
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 9
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 63
- -1 polybutylene terephthalate Polymers 0.000 claims description 34
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 14
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 10
- 239000004417 polycarbonate Substances 0.000 claims description 10
- 229920000515 polycarbonate Polymers 0.000 claims description 10
- 239000003365 glass fiber Substances 0.000 claims description 9
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 8
- 229920006380 polyphenylene oxide Polymers 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 239000003513 alkali Substances 0.000 claims description 7
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 6
- 239000003822 epoxy resin Substances 0.000 claims description 6
- 229920000647 polyepoxide Polymers 0.000 claims description 6
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
- 235000010290 biphenyl Nutrition 0.000 claims description 5
- 239000004305 biphenyl Substances 0.000 claims description 5
- 239000011258 core-shell material Substances 0.000 claims description 5
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims description 3
- 239000004609 Impact Modifier Substances 0.000 claims description 3
- 239000004734 Polyphenylene sulfide Substances 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 125000006267 biphenyl group Chemical group 0.000 claims description 3
- 238000005893 bromination reaction Methods 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229920000069 polyphenylene sulfide Polymers 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 239000001993 wax Substances 0.000 claims description 3
- DGZQEAKNZXNTNL-UHFFFAOYSA-N 1-bromo-4-butan-2-ylbenzene Chemical class CCC(C)C1=CC=C(Br)C=C1 DGZQEAKNZXNTNL-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 2
- 239000002585 base Substances 0.000 claims description 2
- 229920002379 silicone rubber Polymers 0.000 claims description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 2
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 abstract description 5
- 150000002367 halogens Chemical class 0.000 abstract description 5
- 239000004033 plastic Substances 0.000 abstract description 3
- 229920003023 plastic Polymers 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 abstract description 3
- 239000004677 Nylon Substances 0.000 abstract description 2
- 229920001778 nylon Polymers 0.000 abstract description 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 11
- 238000012360 testing method Methods 0.000 description 9
- 239000000843 powder Substances 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 230000000977 initiatory effect Effects 0.000 description 4
- 230000004048 modification Effects 0.000 description 4
- 238000012986 modification Methods 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- BIEHXHIWQHAVFZ-UHFFFAOYSA-M bromoantimony Chemical compound [Sb]Br BIEHXHIWQHAVFZ-UHFFFAOYSA-M 0.000 description 3
- 239000003610 charcoal Substances 0.000 description 3
- 229920006351 engineering plastic Polymers 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- NSBGJRFJIJFMGW-UHFFFAOYSA-N trisodium;stiborate Chemical compound [Na+].[Na+].[Na+].[O-][Sb]([O-])([O-])=O NSBGJRFJIJFMGW-UHFFFAOYSA-N 0.000 description 3
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 2
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- GRKDVZMVHOLESV-UHFFFAOYSA-N (2,3,4,5,6-pentabromophenyl)methyl prop-2-enoate Chemical compound BrC1=C(Br)C(Br)=C(COC(=O)C=C)C(Br)=C1Br GRKDVZMVHOLESV-UHFFFAOYSA-N 0.000 description 1
- OWICEWMBIBPFAH-UHFFFAOYSA-N (3-diphenoxyphosphoryloxyphenyl) diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=C(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)C=CC=1)(=O)OC1=CC=CC=C1 OWICEWMBIBPFAH-UHFFFAOYSA-N 0.000 description 1
- NDERRIHSWCOMJJ-UHFFFAOYSA-N C(C(=C)C)(=O)OC(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(=O)(O)(O)O Chemical compound C(C(=C)C)(=O)OC(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.P(=O)(O)(O)O NDERRIHSWCOMJJ-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 206010020843 Hyperthermia Diseases 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010504 bond cleavage reaction Methods 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 230000036031 hyperthermia Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920003190 poly( p-benzamide) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920000137 polyphosphoric acid Polymers 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B29C47/92—
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
Description
Component | Comparative Examples 1 | Comparative Examples 2 | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 | Embodiment 9 | Embodiment 10 | Embodiment 11 | Embodiment 12 | Embodiment 13 |
??PBT | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 | ??100 |
??Br-Sb-1 | ??40 | ??70 | ??50 | ??55 | ??58 | ??70 | |||||||||
??Br-Sb-2 | ??80 | ??70 | ??60 | ??65 | ??70 | ||||||||||
??Br-Sb-3 | ??70 | ??55 | ??65 | ??70 | |||||||||||
??C-P-1 | ??5 | ??14 | ??15 | ??20 | ??25 | ??21 | ??23 | ||||||||
??C-P-2 | ??5 | ??5 | ??18 | ??20 | ??15 | ??25 | |||||||||
Toughner | ??5 | ??12 | ??5 | ??5 | ??0 | ??12 | ??10 | ??15 | |||||||
Stablizer | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 |
Lubricant | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 | ??2 |
E type alkali free glass fibre | ??60 | ??80 | ??75 | ??75 | ??80 | ??72 | ??72 | ??84 | ??83 | ??77 | ??85 | ??90 | ??90 | ??85 | ??90 |
Material category | The producer and the trade mark |
??PBT | Engineering plastics factory of Yihua Group Corporation, L2100 |
TDE | Jinan safe star Fine Chemical Co., Ltd |
CR210K (brominated epoxy resin oligopolymer) | Suzhou day novel material company limited, CR-210K |
Antimonous oxide | Yiyang, hunan antimony product factory (0 grade) |
Sodium antimonate | U.S. big lake |
Toughner: MBS EXL-2620 | ROHM AND HAAS |
Polycarbonate | Saudi Arabia's innovation (U.S. GE) |
The polyphenylene oxide powder | Ruicheng branch office of Lanxing Chemical New Material Co., Ltd. |
Phosphoric acid ester Fyrolflex RDP | U.S.'s rising sun is auspicious to be reached |
E type alkali free glass fibre | Zhejiang Jushi Group Co., Ltd. |
Stablizer: antioxidant 1010, oxidation inhibitor 168 (weight ratio 1: 1) | Jin Haiyabao |
Lubricant: silicone powder | Ningbo three benefits |
Index | Comparative Examples 1 | Comparative Examples 2 | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 | Embodiment 9 | Embodiment 10 | Embodiment 11 | Embodiment 12 | Embodiment 13 |
Tensile strength | ??127 | ??120 | ??125 | ??121 | ??118 | ??120 | ??124 | ??110 | ??115 | ??115 | ??108 | ??105 | ??118 | ??112 | ??100 |
Flexural strength | ??185 | ??190 | ??180 | ??185 | ??180 | ??185 | ??178 | ??170 | ??185 | ??180 | ??176 | ??185 | ??186 | ??175 | ??173 |
Modulus in flexure | ??8100 | ??8500 | ??7800 | ??7600 | ??7500 | ??8200 | ??8000 | ??7500 | ??8300 | ??8200 | ??8000 | ??8500 | ??8200 | ??7900 | ??7800 |
Notched Izod impact strength | ??8 | ??6.2 | ??7.2 | ??7 | ??7.5 | ??6.5 | ??6.7 | ??7 | ??6.5 | ??6.2 | ??6.5 | ??6.4 | ??6.5 | ??7.5 | ??7.1 |
Non-notched Izod impact strength | ??42 | ??35.5 | ??38 | ??35 | ??40 | ??32 | ??36 | ??38 | ??35 | ??35 | ??35 | ??33 | ??32 | ??40 | ??39 |
Vertical combustion | ??V-0 | ??V-0 | ??V-0 | ??V-0 | ??V-0 | ??V-0 | ??V-0 | ??V-0 | ??V-0 | ??V-0 | ??V-0 | ??V-0 | ??V-0 | ??V-0 | ??V-0 |
Index | Comparative Examples 1 | Comparative Examples 2 | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 | Embodiment 9 | Embodiment 10 | Embodiment 11 | Embodiment 12 | Embodiment 13 |
Glowing filament ignition temperature GWI T | ??675 | ??700 | ??750 | ??750 | ??725 | ??775 | ??775 | ??800 | ??800 | ??800 | ??775 | ??800 | ??775 | ??800 | ??775 |
Heat-drawn wire HDT | ??205 | ??205 | ??200 | ??200 | ??198 | ??200 | ??198 | ??196 | ??195 | ??195 | ??198 | ??190 | ??194 | ??193 | ??192 |
Relative discharge index CTI | ??275 | ??225 | ??225 | ??225 | ??225 | ??200 | ??200 | ??200 | ??200 | ??200 | ??200 | ??200 | ??200 | ??200 | ??200 |
Sequence number | Inspection item | Unit | Testing standard |
??1 | Tensile strength | ??MPa | ??GB/T?1040.2-2008 |
??2 | Flexural strength | ??MPa | ??GB/T?9341-2008 |
??3 | Modulus in flexure | ??MPa | ??GB/T?9341-2008 |
??4 | Simple beam impact strength | ??Kj/m 2 | ??GB/T?1043.1-2008 |
??5 | Heat-drawn wire (A method) | ??℃ | ??GB/T1634.1-2004 |
??6 | Relative discharge index CTI | ??V | ??GB/T?4207-2003 |
??7 | Glowing filament ignition temperature GWIT | ??℃ | GB/T5169.13-2006 (with IEC 60695-2-13 standard) |
??8 | Vertical combustion | ??- | ??UL?94 |
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN2010101796142A CN101838446B (en) | 2010-05-21 | 2010-05-21 | Flame-retardant enhanced polybutylece terephthalate (PBT) material and preparation method thereof |
Applications Claiming Priority (1)
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CN2010101796142A CN101838446B (en) | 2010-05-21 | 2010-05-21 | Flame-retardant enhanced polybutylece terephthalate (PBT) material and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
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CN101838446A true CN101838446A (en) | 2010-09-22 |
CN101838446B CN101838446B (en) | 2012-08-08 |
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Country Status (1)
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102250450A (en) * | 2011-07-14 | 2011-11-23 | 金发科技股份有限公司 | Flame-retardant polyester material with high glow wire ignition temperature and preparation method thereof |
CN105400158A (en) * | 2015-12-16 | 2016-03-16 | 华南理工大学 | Reinforced flame-retardation PBT/PA6 composite material and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001106881A (en) * | 1999-10-01 | 2001-04-17 | Teijin Ltd | Flame-retardant polyester resin composition and molded item made therefrom |
US20020111409A1 (en) * | 1999-05-28 | 2002-08-15 | Talibuddin Sapna H. | Polyester compositions having improved color stability |
CN101117431A (en) * | 2007-08-29 | 2008-02-06 | 浙江俊尔新材料有限公司 | Fire-retardant super-tough polybutylene terephthalate |
CN101469106A (en) * | 2007-12-25 | 2009-07-01 | 上海普利特复合材料股份有限公司 | Flame-retardant reinforced PBT composition |
CN101565536A (en) * | 2009-05-08 | 2009-10-28 | 南通中蓝工程塑胶有限公司 | Flame-retardant polybutylece terephthalate resin composition with high glow wire ignition temperature |
-
2010
- 2010-05-21 CN CN2010101796142A patent/CN101838446B/en not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20020111409A1 (en) * | 1999-05-28 | 2002-08-15 | Talibuddin Sapna H. | Polyester compositions having improved color stability |
JP2001106881A (en) * | 1999-10-01 | 2001-04-17 | Teijin Ltd | Flame-retardant polyester resin composition and molded item made therefrom |
CN101117431A (en) * | 2007-08-29 | 2008-02-06 | 浙江俊尔新材料有限公司 | Fire-retardant super-tough polybutylene terephthalate |
CN101469106A (en) * | 2007-12-25 | 2009-07-01 | 上海普利特复合材料股份有限公司 | Flame-retardant reinforced PBT composition |
CN101565536A (en) * | 2009-05-08 | 2009-10-28 | 南通中蓝工程塑胶有限公司 | Flame-retardant polybutylece terephthalate resin composition with high glow wire ignition temperature |
Non-Patent Citations (2)
Title |
---|
张保卫,翟燕,孙锡龙: "PBT的低烟阻燃性研究", 《塑料工业》, vol. 31, no. 6, 30 June 2003 (2003-06-30) * |
郭建鹏,项军,范潇潇,等: "高灼热丝环保型阻燃增强PBT的研制", 《塑料工业》, vol. 38, no. 2, 28 February 2010 (2010-02-28) * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102250450A (en) * | 2011-07-14 | 2011-11-23 | 金发科技股份有限公司 | Flame-retardant polyester material with high glow wire ignition temperature and preparation method thereof |
CN102250450B (en) * | 2011-07-14 | 2014-04-16 | 金发科技股份有限公司 | Flame-retardant polyester material with high glow wire ignition temperature and preparation method thereof |
CN105400158A (en) * | 2015-12-16 | 2016-03-16 | 华南理工大学 | Reinforced flame-retardation PBT/PA6 composite material and preparation method thereof |
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