CN101824746A - Preparation of nano silver spunlace non-woven cloth composite antibacterial material - Google Patents

Preparation of nano silver spunlace non-woven cloth composite antibacterial material Download PDF

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Publication number
CN101824746A
CN101824746A CN200910037682A CN200910037682A CN101824746A CN 101824746 A CN101824746 A CN 101824746A CN 200910037682 A CN200910037682 A CN 200910037682A CN 200910037682 A CN200910037682 A CN 200910037682A CN 101824746 A CN101824746 A CN 101824746A
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China
Prior art keywords
nano silver
nano
spunlace
silver particles
woven cloth
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Pending
Application number
CN200910037682A
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Chinese (zh)
Inventor
尹荔松
胡社军
柳庆新
杨婧
何鑫
范海陆
赵燕
阳素玉
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Wuyi University
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Wuyi University
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Publication date
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Priority to CN200910037682A priority Critical patent/CN101824746A/en
Publication of CN101824746A publication Critical patent/CN101824746A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a preparation process and a method of a nano silver spunlace non-woven cloth composite antibacterial material, which mainly relate to the fields of nano antibacterial materials and spinning. Nano silver with different grain sizes is prepared through a liquid-phase chemical method, to obtain nano silver paste which is dispersed uniformly; the nano silver is uniformly dispersed into aqueous solution, to obtain nano silver dispersion liquid which has high efficiency, quick effect, broad-spectrum antimicrobial activity and different concentration is obtained; the dispersion liquid and PVP, adhesive FWT and the like which are in a certain ratio are compounded into modified nano silver dispersion liquid; and nano silver particles with the grain size of 10 to 30nm are firmly adhered on the surface of a spunlace non-woven cloth fiber, to form the nano silver spunlace non-woven cloth composite antibacterial material. The nano silver spunlace non-woven cloth composite antibacterial material prepared by the invention has quick effect and long effect in antibacterial performance, and spectrum antibacterial properties.

Description

A kind of preparation of nano silver spunlace non-woven cloth composite antibacterial material
One, technical field:
A kind of preparation of nano silver spunlace non-woven cloth composite antibacterial material relates to nano anti-biotic material field and field of textiles.
Two, background technology:
Since the hydro-entangled non-woven fabric appearance of 20th century the mid-1970s by U.S.'s development, develop into nowadays, and the output of China is well below the actual consumption amount with 12% speed increase demand every year of hydro-entangled non-woven fabric on the international market, and the development prospect of visible non-weaving cloth is very considerable.Along with the raising of people's living standard, self-health perception day by day strengthens, and is especially also more and more higher to the antibiotic requirement of hygienic articles.Therefore, be that the serial antimicrobial medical hygienic articles of base cloth arises at the historic moment with the non-weaving cloth.At present, the general technology of preparation antibacterial non-woven that adopts has two kinds: a kind of is to add antiseptic in fibrous raw material, obtains anti-bacterial fibre, utilizes anti-bacterial fibre to be processed into cloth again; Another kind is by the technology of back arrangement, and antiseptic is put in order on the non-weaving cloth, makes it have antibacterial activity.Because a kind of method in back can be controlled the parameters such as kind, particle size, shape of particle and deposition of antiseptic effectively, to satisfy the needs of antibiotic hygienic articles with different antibiotic requirements.Therefore, the research antibacterial finishing agent is more meaningful and be worth to the influence of non-weaving cloth antibacterial effect.
Three, summary of the invention:
The objective of the invention is to produce a kind of production strong disinfecting nano-silver nonwoven cloth composite.The Nano Silver that utilizes the liquid chemical method preparation to have the different-grain diameter size, obtain finely dispersed Nano Silver slurry, and Nano Silver evenly spread in the aqueous solution, obtain having variable concentrations nano silver dispersion efficient, quick-acting, broad spectrum antibiotic activity, utilize postfinishing process, Nano Silver is bonded in cotton non-weaving cloth top layer, forms that distribution of particles is even, coating layer thickness is controlled, satisfy the hygienic articles of different antibiotic requirements.
Production stage of the present invention is as follows:
(1) utilizes liquid chemical method with low cost to prepare Nano Silver, and nano silver particles is dispersed in the stable dispersion of formation in the aqueous solution;
(2) the nano silver dispersion body 1L of 5~400mg/L and PVP, the adhesive FWT of 0.001~0.5g (wherein one or more mix) are compounded to form the nano silver dispersion body of modification;
(3) above-mentioned finely dispersed Nano Silver slurries are cohered in nonwoven surface by rolling process; 120-150 ℃ of roasting 10-15min then, oven dry can obtain the nano-silver nonwoven cloth composite products.
Four, the specific embodiment;
Embodiment one:
With the particle size for preparing is that the nano silver particles of the 0.02g of 10nm evenly spreads in the 1000g water and forms dispersion, successively add PVP0.01g, FWT0.001g then, utilize electric blender to stir 30min, form the Nano Silver compound dispersing agent, by roll-in method silver particles in the above-mentioned Nano Silver slurries is bonded in nonwoven surface then, last 120 ℃ of baking 15min, oven dry can obtain the nano-silver nonwoven cloth composite products.
Embodiment two:
With the particle size for preparing is that the nano silver particles of the 0.2g of 10nm evenly spreads in the 1000g water and forms dispersion, successively add PVP0.1g, FWT0.01g then, utilize electric blender to stir 30min, form the Nano Silver compound dispersing agent, by roll-in method silver particles in the above-mentioned Nano Silver slurries is bonded in nonwoven surface then, last 120 ℃ of baking 15min, oven dry can obtain the nano-silver nonwoven cloth composite products.
Embodiment three:
With the particle size for preparing is that the nano silver particles of the 0.01g of 10nm evenly spreads in the 1000g water and forms dispersion, successively add PVP0.01g, FWT0.001g then, utilize electric blender to stir 30min, form the Nano Silver compound dispersing agent, by roll-in method silver particles in the above-mentioned Nano Silver slurries is bonded in nonwoven surface then, last 120 ℃ of baking 15min, oven dry can obtain the nano-silver nonwoven cloth composite products.
Embodiment four:
With the particle size for preparing is that the nano silver particles of the 0.02g of 100nm evenly spreads in the 1000g water and forms dispersion, successively add PVP0.01g, FWT0.001g then, utilize electric blender to stir 30min, form the Nano Silver compound dispersing agent, by roll-in method silver particles in the above-mentioned Nano Silver slurries is bonded in nonwoven surface then, last 150 ℃ of baking 15min, oven dry can obtain the nano-silver nonwoven cloth composite products.
Embodiment five:
With the particle size for preparing is that the nano silver particles of the 0.02g of 50nm evenly spreads in the 1000g water and forms dispersion, successively add PVP 0.01g, FWT 0.001g then, utilize electric blender to stir 30min, form the Nano Silver compound dispersing agent, by roll-in method silver particles in the above-mentioned Nano Silver slurries is bonded in nonwoven surface then, last 150 ℃ of baking 15min, oven dry can obtain the nano-silver nonwoven cloth composite products.
Embodiment six:
With the particle size for preparing is that the nano silver particles of the 0.02g of 30nm evenly spreads in the 1000g water and forms dispersion, successively add PVP 0.01g then, FWT 0.001g, utilize electric blender to stir 30min, form the Nano Silver compound dispersing agent, by roll-in method silver particles in the above-mentioned Nano Silver slurries is bonded in nonwoven surface then, last 150 ℃ of baking 15min, oven dry can obtain the nano-silver nonwoven cloth composite products.
Embodiment seven:
With the particle size for preparing is that the nano silver particles of the 0.02g of 50nm evenly spreads in the 1000g water and forms dispersion, successively add PVP0.01g, FWT0.001g then, utilize electric blender to stir 30min, form the Nano Silver compound dispersing agent, by roll-in method silver particles in the above-mentioned Nano Silver slurries is bonded in nonwoven surface then, last 150 ℃ of baking 10min, oven dry can obtain the nano-silver nonwoven cloth composite products.
Embodiment eight:
With the particle size for preparing is that the nano silver particles of the 0.8g of 10nm evenly spreads in the 1000g water and forms dispersion, successively add PVP0.1g, FWT0.01g then, utilize electric blender to stir 30min, form the Nano Silver compound dispersing agent, by roll-in method silver particles in the above-mentioned Nano Silver slurries is bonded in nonwoven surface then, last 120 ℃ of baking 15min, oven dry can obtain the nano-silver nonwoven cloth composite products.
Embodiment nine:
With the particle size for preparing is that the nano silver particles of the 0.02g of 10nm evenly spreads in the 1000g water and forms dispersion, successively add PVP0.01g, FWT0.001g then, utilize electric blender to stir 30min, form the Nano Silver compound dispersing agent, by roll-in method silver particles in the above-mentioned Nano Silver slurries is bonded in nonwoven surface then, last 150 ℃ of baking 15min, oven dry can obtain the nano-silver nonwoven cloth composite products.

Claims (5)

1. utilize the liquid chemical method preparation to have the spherical nano silver particles of different-grain diameter size, the nano silver particles size is in 10~100nm adjustable size.
2. obtain the highly concentrated nano silver paste by high speed centrifugation, and nano silver particles is evenly spread in the aqueous solution, obtain the nano silver dispersion of variable concentrations.
3. the nano silver dispersion that prepared nano silver particles and dispersion liquid have efficient, quick-acting broad spectrum antibiotic activities, 200mg/L concentration in 5min to the killing rate of Candida albicans, Escherichia coli, staphylococcus aureus greater than 99.99%.
4. utilize PVP, FWT binder etc. that nano silver particles is carried out surface treatment, nano silver particles is bonded in above the nonwoven fabric cotton fiber by roll-in method.The nanometer silver paste material formula is (mass percent): water (1000g), Nano Silver (0.02~0.8g), PVP (0.01~0.1g), FWT (0.001~0.01g).
5. the non-woven fabrics fiber drying that roll-in is good can obtain the nano-silver nonwoven cloth composite antibacterial material well.
CN200910037682A 2009-03-06 2009-03-06 Preparation of nano silver spunlace non-woven cloth composite antibacterial material Pending CN101824746A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN200910037682A CN101824746A (en) 2009-03-06 2009-03-06 Preparation of nano silver spunlace non-woven cloth composite antibacterial material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN200910037682A CN101824746A (en) 2009-03-06 2009-03-06 Preparation of nano silver spunlace non-woven cloth composite antibacterial material

Publications (1)

Publication Number Publication Date
CN101824746A true CN101824746A (en) 2010-09-08

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104131457A (en) * 2014-07-16 2014-11-05 安徽可丽纳米纺织品有限公司 Preparation method of antibacterial non-woven fabric and dip padding liquid for preparation
CN104589743A (en) * 2014-12-24 2015-05-06 中航复合材料有限责任公司 Conductive designable toughening non-woven fabric and composite material
CN106319938A (en) * 2016-08-25 2017-01-11 厦门博正科技有限公司 Nano silver durable antibacterial cloth permeated by semiconductor and preparing method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104131457A (en) * 2014-07-16 2014-11-05 安徽可丽纳米纺织品有限公司 Preparation method of antibacterial non-woven fabric and dip padding liquid for preparation
CN104589743A (en) * 2014-12-24 2015-05-06 中航复合材料有限责任公司 Conductive designable toughening non-woven fabric and composite material
CN106319938A (en) * 2016-08-25 2017-01-11 厦门博正科技有限公司 Nano silver durable antibacterial cloth permeated by semiconductor and preparing method thereof

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Open date: 20100908

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