CN101823358B - Method for enhancing paperless membrane-coated artificial board by micro/nano fibril - Google Patents

Method for enhancing paperless membrane-coated artificial board by micro/nano fibril Download PDF

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Publication number
CN101823358B
CN101823358B CN2010101343212A CN201010134321A CN101823358B CN 101823358 B CN101823358 B CN 101823358B CN 2010101343212 A CN2010101343212 A CN 2010101343212A CN 201010134321 A CN201010134321 A CN 201010134321A CN 101823358 B CN101823358 B CN 101823358B
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China
Prior art keywords
fibril
little
artificial board
coated
resin
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Expired - Fee Related
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CN2010101343212A
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Chinese (zh)
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CN101823358A (en
Inventor
张洋
周定国
王思群
吴羽飞
刘艳萍
黄润州
吴燕
周兆兵
贾翀
杨蕊
刘聪
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Nanjing Forestry University
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Nanjing Forestry University
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Abstract

The invention relates to a method for enhancing a paperless membrane-coated artificial board by micro/nano fibrils, which mainly comprises the following process steps: using wood pulp as a raw material, and preparing a micro/nano fibril material with an ultrasonic cell disruption apparatus; mixing micro/nano fibril dispersion solution and water-soluble phenolic (or melamine) resin; coating the well mixed solution of the micro/nano fibrils and the resin on the surface of a prepared artificial board (such as a plywood, a fiberboard or a particleboard) substrate; aging the artificial board with the surface coated with the mixed solution of the micro/nano fibrils and the resin, and feeding the artificial board into a hot press for hot pressing; and naturally cooling and stacking the membrane-coated artificial board after being hot-pressed. The invention has the advantages that: the mixed solution of the micro/nano fibrils and the resin is coated on the surface of the artificial board, and the artificial board is directly compounded through hot pressing to manufacture the membrane-coated artificial board, thereby saving the procedures of paper utilization and resin impregnation.

Description

A kind of usefulness is little/no paper membrane-coated artificial board method that the fibril of receiving strengthens
Technical field:
The present invention relates to be a kind of usefulness little/no paper membrane-coated artificial board method that the fibril of receiving strengthens, belong to the technical field that wood-based plate is made.
Background technology:
Membrane-coated artificial board has improved the performance of common wood-based plate, is used widely at aspects such as furniture material, floor, building templates.Along with the demand of market to the environmental type composite constantly increases, natural little/Biodegradable nanometer composite that the fibril of receiving strengthens will occupy an important position, little/humidification of fibril received can improve Compound Material Engineering intensity significantly.In the technical field of wood-based plate, make the method for membrane-coated artificial board and normally use paper at present as carrier, behind the impregnating resin, compound with wood-based plate again.
Summary of the invention:
The present invention proposes a kind of usefulness little/no paper membrane-coated artificial board method that the fibril of receiving strengthens; Its objective is adopt little/receive and be coated in the wood-based plate surface after fibril and the mixed with resin; Again through hot pressing directly with the compound manufacturing membrane-coated artificial board of wood-based plate, thereby the operation of omission paper and impregnating resin
Technical solution of the present invention: a kind of usefulness is little/no paper membrane-coated artificial board method that the fibril of receiving strengthens, it is characterized in that this method comprises following processing step:
One, little/receive the fibril manufacturing, utilize wood pulp to be raw material, through ultrasonic cell disruption instrument; Get power 450~600W; Amplitude 80~100, the broken time is 0.5-1.5 hour, prepare be dispersed in the water little/receive the fibril material; Its concentration percentage by weight is 1.0-1.5%, promptly contain in the water 1.0-1.5% little/receive the fibril material;
Two, little/receive fibril and mixed with resin; Little/fibril the dispersion liquid of receiving is stirred into mixed liquor with water miscible phenolic resins or water miscible melmac, little/weight ratio that the fibril dispersion liquid of receiving mixes with water miscible phenolic resins or water miscible melmac be 1 part of solid little/fibril of receiving adds the phenolic resins or the water miscible melmac of 30~80 parts of solid, water solubles;
Three, base material is prepared, and wood-based plate (like glued board, fiberboard, particieboard) base material moisture content is adjusted to 8~14%, carries out sanding surface again and handles;
Four, surfaces coated resin, with stir little/receive fibril and resin mixture liquor to be coated in ready artificial board substrate surface, consumption be every square metre of wood-based plate surfaces coated 150~220 grams little/receive fibril and resin mixture liquor;
Five, ageing, with surfaces coated little excessively/receive wood-based plate ageing 2-6 hour of fibril and resin mixture liquor, make its surface moisture volatilization part;
Six, hot pressing overlay film, with the surfaces coated after the ageing little excessively/wood-based plate of fibril and resin mixture liquor received sends into hot press hot pressing, 130~180 ℃ of hot pressing temperatures, hot pressing time 1~6 minute;
Seven, post-processed, the membrane-coated artificial board after the hot pressing need nature cooling 1~2 hour, stack then 2~3 days, make its internal stress release, balancing water content.
Advantage of the present invention: adopt little/receive after fibril and mixed with resin be coated in the wood-based plate surface, through hot pressing directly with the compound manufacturing membrane-coated artificial board of wood-based plate, thereby the operation of omission paper and impregnating resin.
The specific embodiment
Embodiment 1,
One, little/receive the fibril manufacturing, utilize wood pulp to be raw material, through ultrasonic cell disruption instrument; Get power 450~600W; Amplitude 80~100, the broken time is 0.5 hour, prepare be dispersed in the water little/receive the fibril material; Its concentration percentage by weight is 1.0%, promptly contain in the water 1.0% little/receive the fibril material;
Two, little/receive fibril and mixed with resin; With little/receive fibril dispersion liquid and water miscible phenolic resins or water miscible melmac stir into little/receive fibril and resin mixture liquor, little/weight ratio that the fibril dispersion liquid of receiving mixes with water miscible phenolic resins or water miscible melmac be 1 part of solid little/fibril of receiving adds the phenolic resins or the water miscible melmac of 30 parts of solid, water solubles;
Three, base material is prepared, and wood-based plate (like glued board, fiberboard, particieboard) base material moisture content is adjusted to 10%, carries out sanding surface again and handles;
Four, surfaces coated resin, with stir little/receive fibril and resin mixture liquor to be coated in ready artificial board substrate surface, consumption be every square metre of wood-based plate surfaces coated 180 grams little/receive fibril and resin mixture liquor;
Five, ageing, with surfaces coated little excessively/receive the wood-based plate ageing 2 hours of fibril and resin mixture liquor, make its surface moisture volatilization part;
Six, hot pressing overlay film, with the surfaces coated after the ageing little excessively/wood-based plate of fibril and resin mixture liquor received sends into hot press hot pressing, 130 ℃ of hot pressing temperatures, hot pressing time 2 minutes;
Seven, post-processed, the membrane-coated artificial board after the hot pressing needed nature cooling 1~2 hour, stack then 2 big, just its internal stress discharge, balancing water content.
Embodiment 2
One, little/receive the fibril manufacturing, utilize wood pulp to be raw material, through ultrasonic cell disruption instrument; Get power 450~600W; Amplitude 80~100, the broken time is 1.5 hours, prepare be dispersed in the water little/receive the fibril material; Its concentration percentage by weight is 1.5%, promptly contain in the water 1.5% little/receive the fibril material;
Two, little/receive fibril and mixed with resin; Little/fibril the dispersion liquid of receiving is stirred into mixed liquor with water miscible phenolic resins or water miscible melmac, little/weight ratio that the fibril dispersion liquid of receiving mixes with water miscible phenolic resins or water miscible melmac be 1 part of solid little/fibril of receiving adds the phenolic resins or the water miscible melmac of 80 parts of solid, water solubles;
Three, base material is prepared, and wood-based plate (like glued board, fiberboard, particieboard) base material moisture content is adjusted to 12%, carries out sanding surface again and handles;
Four, surfaces coated resin, with stir little/receive fibril and resin mixture liquor to be coated in ready artificial board substrate surface, consumption be every square metre of wood-based plate surfaces coated 200 grams little/receive fibril and resin mixture liquor;
Five, ageing, with surfaces coated little excessively/receive wood-based plate ageing 2-6 hour of fibril and resin mixture liquor, make its surface moisture volatilization part;
Six, hot pressing overlay film, with the surfaces coated after the ageing little excessively/wood-based plate of fibril and resin mixture liquor received sends into hot press hot pressing, 180 ℃ of hot pressing temperatures, hot pressing time 1 minute;
Seven, post-processed, the membrane-coated artificial board after the hot pressing need nature cooling 1~2 hour, stack then 3 days, make its internal stress release, balancing water content.

Claims (1)

1. the manufacturing approach of a no paper membrane-coated artificial board that strengthens with the little/fibril of receiving is characterized in that this method comprises following processing step:
One, little/receive the fibril manufacturing, utilize wood pulp to be raw material, through ultrasonic cell disruption instrument; Get power 450~600W, amplitude 80~100, the broken time is 0.5-1.5 hour; Prepare be dispersed in the water little/receive the fibril material, its concentration percentage by weight is 1.0-1.5%;
Two, little/receive fibril and mixed with resin; Little/fibril the dispersion liquid of receiving is stirred into mixed liquor with water miscible phenolic resins or water miscible melmac, little/weight ratio that the fibril dispersion liquid of receiving mixes with water miscible phenolic resins or water miscible melmac be 1 part of solid little/fibril of receiving adds the phenolic resins or the water miscible melmac of 30~80 parts of solid, water solubles;
Three, base material is prepared, and artificial board substrate's moisture content is adjusted to 8~14%, carries out sanding surface again and handles;
Four, surfaces coated resin, with stir little/receive fibril and resin mixture liquor to be coated in ready artificial board substrate surface, consumption be every square metre of wood-based plate surfaces coated 150~220 grams little/receive fibril and resin mixture liquor;
Five, ageing, with surfaces coated little excessively/receive wood-based plate ageing 2-6 hour of fibril and resin mixture liquor, make its surface moisture volatilization part;
Six, hot pressing overlay film, with the surfaces coated after the ageing little excessively/wood-based plate of fibril and resin mixture liquor received sends into hot press hot pressing, 130~180 ℃ of hot pressing temperatures, hot pressing time 1~6 minute;
Seven, post-processed, the membrane-coated artificial board after the hot pressing need nature cooling 1~2 hour, stack then 2~3 days, make its internal stress release, balancing water content.
CN2010101343212A 2010-03-29 2010-03-29 Method for enhancing paperless membrane-coated artificial board by micro/nano fibril Expired - Fee Related CN101823358B (en)

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Families Citing this family (6)

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Publication number Priority date Publication date Assignee Title
CN102248564A (en) * 2011-05-17 2011-11-23 南京林业大学 Method for enhancing surface antibacterial and wear-resisting property of Chinese fir by using wood micron/nano fibril
CN103991265B (en) * 2014-03-27 2016-08-24 惠州市好的板科技有限公司 A kind of dermatoglyph Surface decorated woodbased panels with paper impregnated thermosetting resins and preparation method thereof
CN103909718B (en) * 2014-03-27 2016-08-24 惠州市好的板科技有限公司 A kind of Flos Rosae Rugosae stricture of vagina wood-based plate and preparation method thereof
CN109403136B (en) * 2018-11-01 2021-05-18 浙江科技学院 Composite coating for improving mechanical property of paper and preparation method thereof
CN109895213B (en) * 2019-03-28 2020-12-04 江苏海美新材料有限公司 Anti-mildew density board with decorative film and preparation method thereof
CN114953093A (en) * 2022-04-19 2022-08-30 安徽瑞格森工木业有限公司 Artificial board film covering forming process method

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CN101337375A (en) * 2008-08-06 2009-01-07 南京林业大学 Method for increasing stalk fiberboard surface-density using cotton wood cellulose nano material

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JPH06200226A (en) * 1992-12-29 1994-07-19 Honen Corp Production of plywood and adhesive therefor
JP2005089535A (en) * 2003-09-12 2005-04-07 Agri Future Joetsu Co Ltd Composite resin composition and method for producing the same

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CN101337375A (en) * 2008-08-06 2009-01-07 南京林业大学 Method for increasing stalk fiberboard surface-density using cotton wood cellulose nano material

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程庆正等.天然木质微/纳纤丝增强纳米复合材料的研究现状.《林产工业》.2007,3~7. *

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Application publication date: 20100908

Assignee: Jiangsu Qiqiao Craft Wood Products Co., Ltd.

Assignor: Nanjing Forestry University

Contract record no.: 2019320000098

Denomination of invention: Method for enhancing paperless membrane-coated artificial board by micro/nano fibril

Granted publication date: 20120926

License type: Common License

Record date: 20190409

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Granted publication date: 20120926

Termination date: 20210329