CN101822266A - Emulsionofemamectin benzoate and indoxacarb and preparation method thereof - Google Patents
Emulsionofemamectin benzoate and indoxacarb and preparation method thereof Download PDFInfo
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- CN101822266A CN101822266A CN201010109327A CN201010109327A CN101822266A CN 101822266 A CN101822266 A CN 101822266A CN 201010109327 A CN201010109327 A CN 201010109327A CN 201010109327 A CN201010109327 A CN 201010109327A CN 101822266 A CN101822266 A CN 101822266A
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- benzoate
- emamectin
- worm prestige
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Abstract
The invention relates to emulsion of emamectin benzoate and indoxacarb and a preparation method thereof. The emulsion is characterized by comprising the following components in percentage by mass: 0.5 to 5 percent of emamectin benzoate, 5 to 30 percent of indoxacarb, 5 to 25 percent of a solvent, 1 to 5 percent of a cosolvent, 2 to 15 percent of an emulsifier, 1 to 5 percent of an antifreeze, 0.2 to 5 percent of a thickener, 0.1 to 0.3 percent of a defoaming agent and the balance of water. The preparation method adopts ultrasonic emulsification technology to prepare the emulsion of emamectin benzoate and indoxacarb. The ultrasonic emulsification preparation process is simple, low in production cost and easy in scale production; and the prepared products have stable quality.
Description
Technical field
The present invention relates to a kind of pesticidal preparations, relate in particular to a kind of emulsion that contains emamectin-benzoate and indenes worm prestige and preparation method thereof.
Background technology
Indenes worm prestige is the new and effective insecticide of being succeeded in developing by du pont company of oxadiazines class, has and tags and stomach poison function.Indenes worm prestige is to natural enemy insect safety, residual low in crop, there is not cross resistance with other insecticides, can be applicable to integrated pest control (IPM) and resistance management (RPM), be mainly used in and prevent and kill off nearly all lepidoptera pest such as cotton bollworm and various diamond-back moth, beet armyworm, cabbage caterpillar etc.Though indenes worm prestige has preventive effect preferably, its use cost is higher, and insecticidal spectrum is narrower, and to the insect poor effect beyond the Lepidoptera, the lasting period is short partially.In order to overcome and to remedy deficiency on the performance, with indenes worm prestige and other mixed pesticides effectively the expanding prevention spectrum, increase drug effect, prolong the control lasting period, reduce the generation of use cost and pre-pest control the single composition pesticide resistance of long-term use.
Emamectin-benzoate is a kind of new and effective semisynthetic antibiotics insecticide that begins to synthesize from fermented product Avermectin B1, has super-high-efficient, low toxicity (preparation is closely nontoxic), noresidue, the nuisanceless characteristics that wait biopesticide have improved 1-3 the order of magnitude with Avermectin comparison insecticidal activity, active high to the larva of lepidopterous insects and other many insects and mite class, and in the process of pest control, beneficial insect is not injured, help integrated control to insect.
Indenes worm prestige and emamectin-benzoate are composite, both can solve insect to the issuable pesticide resistance of single composition agricultural chemicals, can improve quick-acting again, are beneficial to the resistance management of insect, and can improve control efficiency and reduce the control cost.
Aqueous emulsion is as one of water-based pesticide environmental protection formulation, and development in recent years is rapid.But the condition and the technological requirement of aqueous emulsion production technology are higher at present, need special equipments such as high shear and homogeneous, and large-scale production is subjected to certain limitation.Though make water replace most of aromatic hydrocarbons organic solvent as carrier, but still the aromatic hydrocarbons organic solvent that needs some is as carrier, the safety aspect still can be improved.
Ultrasonic emulsification is continued to use emulsification method with screw, colloid mill and high shear and homogenizer and is compared, have that emulsion quality is good, production efficiency is high, low cost and other advantages, more and more be subjected to the attention and the employing of each industrial trade, and be used widely in industries such as food, papermaking, paint, chemical industry, medicine, oil.
Summary of the invention
The present invention intends providing a kind of new preparation method and does not use the safety and environmental protection performance of aromatic hydrocarbons organic solvent with stability, drug effect and the product of raising aqueous emulsion.
The purpose of this invention is to provide a kind of emulsion that contains emamectin-benzoate and indenes worm prestige and preparation method thereof.The emamectin-benzoate indenes worm prestige emulsion that the present invention relates to does not use any aromatic hydrocarbons organic solvent, environmentally friendly, has improved the safety of production, transportation, storage, use.
The present invention adopts the ultrasonic emulsification technology of preparing, produces simply, and production cost is low, the emulsion of production, good stability.
The emulsion of the emamectin-benzoate indenes worm prestige that the present invention relates to contains emamectin-benzoate 0.5～5%, indenes worm prestige 5～30%, solvent 5～25%, cosolvent 1～5%, emulsifier 2～15%, antifreeze 1～5%, thickener 0.2～5%, defoamer 0.1～0.3% and water surplus in the quality percentage.
Solvent involved in the present invention is chosen one or more in D-citrene, australene, Jatropha curcas oil methyl esters wantonly.The present invention uses not environmentally friendly solvent such as any aromatic hydrocarbons, environmentally friendly, safety.
Cosolvent of the present invention is chosen one or more in N-Methyl pyrrolidone, isooctanol, n-octyl alcohol, n-butanol, isobutanol, isopropyl alcohol wantonly.
The emulsifier that the present invention relates to is a polyoxyethylene polyoxypropylene block copolymer, C12-14 alcohol APEO, sorbitol polyoxyethylene ether, castor oil polyoxyethylene ether, the ethylene glycol APEO, anhydrosorbitol acid anhydride oleate, anhydrous sorbitol acid anhydride trioleate, sorbitan monooleate, polyoxyethylene (20) sorbitan monolaurate, the alkane polyoxyethylene 20 sorbitan monooleate, aliphatic alcohol polyoxyvinethene phosphate, in the C12-14 polyoxyethylene ether phosphate one or more.Above surfactant component all has biodegradability.
Antifreeze of the present invention is chosen one or more in ethylene glycol, propane diols, glycerine, urea wantonly.
Thickener of the present invention is chosen one or more in xanthans, polyvinyl alcohol, aluminium-magnesium silicate, polyvinylpyrrolidone, gum Arabic, acrylate wantonly.
Defoamer of the present invention is chosen one or more in methyl polysiloxane, modified methyl polysiloxanes wantonly.
The preparation method of emamectin-benzoate indenes worm prestige emulsion of the present invention is characterized in that this method comprises following processing step:
1, oil phase is made
Take by weighing in emamectin-benzoate, indenes worm prestige, solvent, cosolvent, the emulsifier adding reactor, mix, form oil phase.
2, water is made
Take by weighing antifreeze, thickener and water and mix, form water.
3, ultrasonic emulsification
Under 1000～8000 rev/mins stirring condition, water is added oil phase, be that 10～50kHz, power are under the condition of 100～1000W in resonant frequency, ultrasonic emulsification 5～15 minutes, the emulsion of formation emamectin-benzoate indenes worm prestige.
The present invention adopts the ultrasonic emulsification technology of preparing, produces simply, and production cost is low, and the emulsion stability of production is good.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer, the present invention describes with following specific embodiment, but the present invention is limited to these examples absolutely not.The following stated only is the present invention embodiment preferably, only is used to explain the present invention, can not therefore be interpreted as the restriction to claim of the present invention.
The former medicine content of used emamectin-benzoate is 90% in the embodiment of the invention, and the former medicine content of indenes worm prestige is 94%, and emamectin-benzoate and indenes worm prestige usage amount are and do not roll over hundred former survival dose in the following specific embodiment.
Embodiment 1,
Take by weighing 5.56 kilograms of emamectin-benzoates, 53.2 kilograms of indenes worm prestige, 50 kilograms of australenes, 25 kilograms of N-octylpyrrolidone, 25 kilograms of polyoxyethylene polyoxypropylene block copolymers, 20 kilograms of aliphatic alcohol polyoxyvinethene phosphates, mix oil phase; Take by weighing 50 kilograms of isooctanol, 20 kilograms of polyvinyl alcohol, 1 kilogram of methyl polysiloxane, 750.24 kilograms in water, mix water; Under 1000 rev/mins stirring condition, water is added oil phase.In resonant frequency is that 20kHz, power are under the condition of 200W, and ultrasonic emulsification 15 minutes forms 1000 kilogram of 5.5% emamectin-benzoate indenes worm prestige emulsion.
Embodiment 2,
Take by weighing 5.56 kilograms of emamectin-benzoates, 319.15 kilograms of indenes worm prestige, 120 kilograms of D-citrenes, 60 kilograms of N-Methyl pyrrolidone, 35 kilograms of C12-14 alcohol APEOs, 20 kilograms of C12-14 polyoxyethylene ether phosphates, mix oil phase; Take by weighing 50 kilograms of n-butanols, 2 kilograms of xanthans, 1 kilogram of modified methyl polysiloxanes, 387.29 kilograms in water, mix water; Under 2000 rev/mins stirring condition, water is added oil phase.In resonant frequency is that 20kHz, power are under the condition of 500W, and ultrasonic emulsification 10 minutes forms 1000 kilogram of 30.5% emamectin-benzoate indenes worm prestige emulsion.
Embodiment 3,
Take by weighing 11.11 kilograms of emamectin-benzoates, 106.38 kilograms of indenes worm prestige, 70 kilograms of D-citrenes, 40 kilograms of N-Methyl pyrrolidone, 25 kilograms of polyoxyethylene polyoxypropylene block copolymers, 20 kilograms of C12-14 polyoxyethylene ether phosphates, mix oil phase; Take by weighing 50 kilograms of isopropyl alcohols, 20 kilograms of aluminium-magnesium silicates, 2 kilograms of modified methyl polysiloxanes, 655.51 kilograms in water, mix water; Under 2000 rev/mins stirring condition, water is added oil phase.In resonant frequency is that 30kHz, power are under the condition of 800W, and ultrasonic emulsification 5 minutes forms 1000 kilogram of 11% emamectin-benzoate indenes worm prestige emulsion.
This example emamectin-benzoate indenes worm prestige emulsion the results are shown in Table 1 carrying out carrying out the low-temperature stability check under heat storage, 0 ± 2 ℃ and-15 ± 2 ℃ of conditions under 54 ± 2 ℃ of conditions.As can be known from Table 1, this example emamectin-benzoate indenes worm prestige emulsion has good cold and hot stable storage performance.
This example of table 1 emamectin-benzoate indenes worm prestige emulsion stability result of the test
| Storage temperature | Stored 14 days | Stored 30 days | Stored 180 days |
| ??54±2℃ | Emamectin-benzoate resolution ratio 0.7% indenes worm prestige resolution ratio 0.5% heat storage stability is qualified | Emamectin-benzoate resolution ratio 1.1% indenes worm prestige resolution ratio 0.9% heat storage stability is qualified | Emamectin-benzoate resolution ratio 2.0% indenes worm prestige resolution ratio 2.1% heat storage stability is qualified |
| 0 ± 2 ℃ (remarks) | It is qualified to return to room temperature | It is qualified to return to room temperature | It is qualified to return to room temperature |
| -15 ± 2 ℃ (remarks) | It is qualified to return to room temperature | It is qualified to return to room temperature | It is qualified to return to room temperature |
Remarks: 0 ± 2 ℃ is after returning to room temperature with sample survey with-15 ± 2 ℃ of low-temperature stabilities checks, the mild agitation test specimen, and no visible particles and grease are as the criterion of acceptability of check.
Embodiment 4,
Take by weighing 11.11 kilograms of emamectin-benzoates, 212.77 kilograms of indenes worm prestige, D-citrene double centner, 50 kilograms of N-Methyl pyrrolidone, 20 kilograms of polyoxyethylene polyoxypropylene block copolymers, 10 kilograms of C12-14 alcohol APEOs, 25 kilograms of C12-14 polyoxyethylene ether phosphates, mix oil phase; Take by weighing 30 kilograms of ethylene glycol, 20 kilograms of polyvinylpyrrolidones, 2 kilograms of methyl polysiloxanes, 519.12 kilograms in water, mix water; Under 2000 rev/mins stirring condition, water is added oil phase.In resonant frequency is that 20kHz, power are under the condition of 800W, and ultrasonic emulsification 10 minutes forms 1000 kilogram of 21% emamectin-benzoate indenes worm prestige emulsion.
This example emamectin-benzoate indenes worm prestige emulsion the results are shown in Table 2 carrying out carrying out the low-temperature stability check under heat storage, 0 ± 2 ℃ and-15 ± 2 ℃ of conditions under 54 ± 2 ℃ of conditions.As can be known from Table 2, this example emamectin-benzoate indenes worm prestige emulsion has the good storing stability energy.
This example of table 2 emamectin-benzoate indenes worm prestige emulsion stability result of the test
| Storage temperature | Stored 14 days | Stored 30 days | Stored 180 days |
| ??54±2℃ | Emamectin-benzoate resolution ratio 0.6% indenes worm prestige resolution ratio 0.4% heat storage stability is qualified | Emamectin-benzoate resolution ratio 1.4% indenes worm prestige resolution ratio 0.8% heat storage stability is qualified | Emamectin-benzoate resolution ratio 2.5% indenes worm prestige resolution ratio 1.7% heat storage stability is qualified |
| 0 ± 2 ℃ (remarks) | It is qualified to return to room temperature | It is qualified to return to room temperature | It is qualified to return to room temperature |
| -15 ± 2 ℃ (remarks) | It is qualified to return to room temperature | It is qualified to return to room temperature | It is qualified to return to room temperature |
Remarks: 0 ± 2 ℃ is after returning to room temperature with sample survey with-15 ± 2 ℃ of low-temperature stabilities checks, the mild agitation test specimen, and no visible particles and grease are as the criterion of acceptability of check.
Embodiment 5,
Take by weighing 22.22 kilograms of emamectin-benzoates, 212.77 kilograms of indenes worm prestige, D-citrene double centner, 50 kilograms of N-Methyl pyrrolidone, 15 kilograms of ethylene glycol APEOs, 15 kilograms of C12-14 alcohol APEOs, 25 kilograms of aliphatic alcohol polyoxyvinethene phosphates, mix oil phase; Take by weighing 40 kilograms of n-octyl alcohols, 2 kilograms of xanthans, 1 kilogram of methyl polysiloxane, 517.01 kilograms in water, mix water; Under 2000 rev/mins stirring condition, water is added oil phase.In resonant frequency is that 30kHz, power are under the condition of 200W, and ultrasonic emulsification 12 minutes forms 1000 kilogram of 22% emamectin-benzoate indenes worm prestige emulsion.
Embodiment 6,
Take by weighing 55.56 kilograms of emamectin-benzoates, 106.38 kilograms of indenes worm prestige, 80 kilograms of Jatropha curcas oil methyl esters, 70 kilograms of N-octylpyrrolidone, 20 kilograms of castor oil polyoxyethylene ethers, 15 kilograms of polyoxyethylene (20) sorbitan monolaurates, 20 kilograms of aliphatic alcohol polyoxyvinethene phosphates, mix oil phase; Take by weighing 40 kilograms of propane diols, 20 kilograms of polyvinyl alcohol, 1 kilogram of modified methyl polysiloxanes, 572.06 kilograms in water, mix water; Under 6000 rev/mins stirring condition, water is added oil phase.In resonant frequency is that 20kHz, power are under the condition of 200W, and ultrasonic emulsification 15 minutes forms 1000 kilogram of 15% emamectin-benzoate indenes worm prestige emulsion.
This example emamectin-benzoate indenes worm prestige emulsion the results are shown in Table 3 carrying out carrying out the low-temperature stability check under heat storage, 0 ± 2 ℃ and-15 ± 2 ℃ of conditions under 54 ± 2 ℃ of conditions.As can be known from Table 3, this example emamectin-benzoate indenes worm prestige emulsion has the good storing stability energy.
This example of table 3 emamectin-benzoate indenes worm prestige emulsion stability result of the test
| Storage temperature | Stored 14 days | Stored 30 days | Stored 180 days |
| ??54±2℃ | Emamectin-benzoate resolution ratio 0.4% indenes worm prestige resolution ratio 0.7% heat storage stability is qualified | Emamectin-benzoate resolution ratio 1.0% indenes worm prestige resolution ratio 1.2% heat storage stability is qualified | Emamectin-benzoate resolution ratio 2.4% indenes worm prestige resolution ratio 2.6% heat storage stability is qualified |
| 0 ± 2 ℃ (remarks) | It is qualified to return to room temperature | It is qualified to return to room temperature | It is qualified to return to room temperature |
| -15 ± 2 ℃ (remarks) | It is qualified to return to room temperature | It is qualified to return to room temperature | It is qualified to return to room temperature |
Remarks: 0 ± 2 ℃ is after returning to room temperature with sample survey with-15 ± 2 ℃ of low-temperature stabilities checks, the mild agitation test specimen, and no visible particles and grease are as the criterion of acceptability of check.
The emamectin-benzoate indenes worm prestige emulsion that the present invention relates to 2.5% commercially available emamectin-benzoate aqueous emulsion, 15% indenes worm prestige missible oil is compared to have that better control efficiency and lasting period are arranged.Below be the field efficacy comparative test result of the emamectin-benzoate indenes worm prestige emulsion that the present invention relates to and 2.5% emamectin-benzoate aqueous emulsion, 15% indenes worm prestige missible oil control brassicaceous vegetable diamond-back moth, cotton cotton bollworm, wild cabbage beet armyworm:
Control brassicaceous vegetable diamond-back moth field trial, the medicament water directly dilutes, field rotating medicine 1 day, 3 days and 7 days " Invest, Then Investigate " control efficiency, result of the test is referring to table 4.
Table 4 control brassicaceous vegetable diamond-back moth field test results
| Medicament | Effective ingredient consumption | 1 day preventive effect % | 3 days preventive effect % | 7 days preventive effect % |
| 15% indenes worm prestige missible oil | 0.5 gram/mu | ??52.1 | ??61.8 | ??60.9 |
| 2.5% emamectin-benzoate aqueous emulsion | 0.5 gram/mu | ??58.9 | ??71.7 | ??62.4 |
| Emamectin-benzoate: indenes worm prestige (1+10) (embodiment of the invention 3) | 0.5 gram/mu | ??89.4 | ??96.1 | ??90.5 |
| Emamectin-benzoate: indenes worm prestige (1+20) (embodiment of the invention 4) | 0.5 gram/mu | ??90.6 | ??94.7 | ??90.1 |
| Emamectin-benzoate: indenes worm prestige (2+20) (embodiment of the invention 5) | 0.5 gram/mu | ??83.1 | ??86.2 | ??80.6 |
| Emamectin-benzoate: indenes worm prestige (5+10) (embodiment of the invention 6) | 0.5 gram/mu | ??84.5 | ??90.1 | ??81.1 |
Control cotton cotton bollworm field trial, the medicament water directly dilutes, field rotating medicine 1 day, 3 days and 15 days " Invest, Then Investigate " control efficiency, result of the test is referring to table 5.
Table 5 cotton cotton bollworm field test results
| Medicament | Effective ingredient consumption | 1 day preventive effect % | 3 days preventive effect % | 15 days preventive effect % |
| 15% indenes worm prestige missible oil | 1 gram/mu | ??41.8 | ??58.6 | ??51.3 |
| 2.5% emamectin-benzoate aqueous emulsion | 1 gram/mu | ??60.4 | ??83.4 | ??71.2 |
| Emamectin-benzoate: indenes worm prestige (1+10) (embodiment of the invention 3) | 1 gram/mu | ??90.6 | ??96.1 | ??90.5 |
| Emamectin-benzoate: indenes worm prestige (1+20) (embodiment of the invention 4) | 1 gram/mu | ??92.7 | ??97.3 | ??93.2 |
| Emamectin-benzoate: indenes worm prestige (2+20) (embodiment of the invention 5) | 1 gram/mu | ??83.1 | ??90.6 | ??82.6 |
| Emamectin-benzoate: indenes worm prestige (5+10) (embodiment of the invention 6) | 1 gram/mu | ??83.3 | ??88.7 | ??81.2 |
Control wild cabbage beet armyworm field trial, the medicament water directly dilutes, and field rotating medicine is difference investigation prevention effect after 1 day, 3 days, and result of the test is referring to table 6.
Table 6 control wild cabbage beet armyworm field test results
| Medicament | Effective ingredient consumption | 1 day preventive effect % | 3 days preventive effect % |
| 15% indenes worm prestige missible oil | 0.5 gram/mu | ??45.8 | ??61.6 |
| 2.5% emamectin-benzoate aqueous emulsion | 0.5 gram/mu | ??61.2 | ??77.5 |
| Emamectin-benzoate: indenes worm prestige (1+10) (embodiment of the invention 3) | 0.5 gram/mu | ??90 | ??94.9 |
| Emamectin-benzoate: indenes worm prestige (1+20) (embodiment of the invention 4) | 0.5 gram/mu | ??92.7 | ??97.3 |
| Emamectin-benzoate: indenes worm prestige (2+20) (embodiment of the invention 5) | 0.5 gram/mu | ??85.7 | ??90.1 |
| Medicament | Effective ingredient consumption | 1 day preventive effect % | 3 days preventive effect % |
| Emamectin-benzoate: indenes worm prestige (5+10) (embodiment of the invention 6) | 0.5 gram/mu | ??83.3 | ??89.7 |
As seen, the emamectin-benzoate indenes worm prestige emulsion that the present invention relates to all is better than the control efficiency of 2.5% emamectin-benzoate aqueous emulsion or 15% indenes worm prestige missible oil to field control effect, quick-acting and the lasting effect of brassicaceous vegetable diamond-back moth, cotton cotton bollworm, wild cabbage beet armyworm.
The emamectin-benzoate indoxacarb emulsion that the present invention relates to has the following advantages: 1) emamectin-benzoate and indoxacarb are composite, have enlarged to prevent and treat spectrum, drug effect raising, long, the use cost reduction of control lasting period. 2) owing to do not contain the emulsifying agent of any aromatic hydrocarbon solvent and use biological degradability, to environment and people's safety, improved the security of product in production, transportation, storage, use procedure. 3) adopt the ultrasonic emulsification technology to prepare emamectin-benzoate indoxacarb emulsion, production technology is simple, and production cost is low, is easy to large-scale production, the production constant product quality.
Claims (8)
1. emulsion that contains emamectin-benzoate and indenes worm prestige and preparation method thereof is characterized by in mass percent and contains emamectin-benzoate 0.5～5%, indenes worm prestige 5～30%, solvent 5～25%, cosolvent 1～5%, emulsifier 2～15%, antifreeze 1～5%, thickener 0.2～5%, defoamer 0.1～0.3% and water surplus.
2. according to claim 1, it is characterized by in the optional D-citrene of described solvent, australene, the Jatropha curcas oil methyl esters one or more.
3. according to claim 1, it is characterized by in the optional N-Methyl pyrrolidone of described cosolvent, isopropyl alcohol, isooctanol, n-octyl alcohol, n-butanol, the isobutanol one or more.
4. according to claim 1, it is characterized by in the optional polyoxyethylene polyoxypropylene block copolymer of described emulsifier, C12-14 alcohol APEO, sorbitol polyoxyethylene ether, castor oil polyoxyethylene ether, ethylene glycol APEO, anhydrosorbitol acid anhydride oleate, anhydrous sorbitol acid anhydride trioleate, sorbitan monooleate, polyoxyethylene (20) sorbitan monolaurate, alkane polyoxyethylene 20 sorbitan monooleate, aliphatic alcohol polyoxyvinethene phosphate, the C12-14 polyoxyethylene ether phosphate one or more.
5. according to claim 1, it is characterized by in the optional ethylene glycol of described antifreeze, propane diols, glycerine, the urea one or more.
6. according to claim 1, it is characterized by in the optional xanthans of described thickener, polyvinyl alcohol, aluminium-magnesium silicate, polyvinylpyrrolidone, gum Arabic, the acrylate one or more.
7. according to claim 1, it is characterized in that described defoamer is one or more in methyl polysiloxane, the modified methyl polysiloxanes.
8. one kind as each described preparation method who contains the emulsion of emamectin-benzoate and indenes worm prestige of claim 1 to 7, it is characterized by and adopt the preparation of ultrasonic emulsification method, specifically being included in resonant frequency is that 10～50kHz, power are under the condition of 100～1000W, ultrasonic emulsification 5～15 minutes.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111836544A (en) * | 2018-03-22 | 2020-10-27 | 江苏龙灯化学有限公司 | Pesticidal compositions with emamectin benzoate and indoxacarb and methods of using such compositions |
| WO2024201452A1 (en) * | 2023-03-24 | 2024-10-03 | Adama Makhteshim Ltd. | Liquid homogeneous agrochemical composition of insecticides |
-
2010
- 2010-01-27 CN CN201010109327A patent/CN101822266A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111836544A (en) * | 2018-03-22 | 2020-10-27 | 江苏龙灯化学有限公司 | Pesticidal compositions with emamectin benzoate and indoxacarb and methods of using such compositions |
| WO2024201452A1 (en) * | 2023-03-24 | 2024-10-03 | Adama Makhteshim Ltd. | Liquid homogeneous agrochemical composition of insecticides |
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Application publication date: 20100908 |