CN101822258A - Weeding composition - Google Patents
Weeding composition Download PDFInfo
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- CN101822258A CN101822258A CN201010185524A CN201010185524A CN101822258A CN 101822258 A CN101822258 A CN 101822258A CN 201010185524 A CN201010185524 A CN 201010185524A CN 201010185524 A CN201010185524 A CN 201010185524A CN 101822258 A CN101822258 A CN 101822258A
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- composition
- grass amine
- acyl grass
- oxazole acyl
- quinolinic acid
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Abstract
The invention provides a weeding composition, which is characterized by comprising 5 to 30 weight percent of pesticide metamifop and 10 to 60 weight percent of quinclorac. Field tests prove that the weeding effect of the composition comprising the metamifop and quinclorac is superior to that of single metamifop and single quinclorac, so the weeding composition is particularly suitable for weeding in direct-seeded rice fields.
Description
Technical field
The present invention relates to a kind of herbicidal composition.
Background technology
Oxazole acyl grass amine (English name metamifop) belongs to fragrant phenoxy base propionic acid ester weed killer herbicide, can be fabulous prevent and kill off most of annual gramineous weeds, and different with other kind of this type of weed killer herbicide be that oxazole acyl grass amine is safe to paddy rice.
The chemical name of oxazole acyl grass amine is (R)-2-{ (4-chloro-1,3-benzoxazole-2-base oxygen) phenoxy group }-2 '-fluoro-N-methyl-prop anilid, CAS accession number [256412-89-2], its chemical constitution is:
Oxazole acyl grass amine sprays under the situation with the 90-200g/hm2 effective ingredient consumption behind the seedling in transplanting and the direct seading rice field, can effectively prevent and kill off main grassy weed in the rice field, as Echinochloa (Echinochloa spp), moleplant seed (Leptochloa chinensis), knotgrass (Digitaria spp) and eleusine indica (Eleusine indica).Moleplant seed is one of the malignant weed in rice field, have take place wide, the trend that the characteristics that generating capacity is big also have harm to increase the weight of.In recent years along with the use of planting patterns and single variety weed killer herbicide, make moleplant seed rise to the main malignant weed in rice field, endanger more and more serious, the extent of injury in the part rice field surpasses the barnyard grass grass, particularly at direct sowing rice field, can cause the underproduction 30 during serious harm---and 40%, what have reaches more than 70%, even total crop failure, it is vigorous that Chang Yin broadcasts the back moleplant seed, peasant household's replay of turning over of having to.
Oxazole acyl grass amine low toxicity, environmentally friendly, be a rising weed killer herbicide kind.At present the De oxazole acyl of reporting grass amine preparation formulation be 3.3%---10% missible oil, single agent are mainly prevented and kill off and are transplanted and live Tanaka's annual gramineous weed by foliar spray.---1.6% oxazole acyl grass amine and 0.07%---the 0.21% pyrazosulfuron mixing particle agent that also has 0.67% in addition.
Dichloro quinolinic acid belongs to low toxicity hormone-type quinoline carboxylic acid weed killer herbicide.The weeds poisoning symptom is similar to the auxins effect, and it is barnyard grass grass and working life very long to be mainly used in control, and the 1-7 leaf phase is all effective.Dichloro quinolinic acid is good to rice safety.
The pertinent literature report and the patent application of no oxazole acyl grass amine of Shang and dichloro quinolinic acid combination control direct seading rice field weed at present.
Summary of the invention
The object of the present invention is to provide a kind of direct seading rice field weeding composition, to enlarge direct seading rice field weed prevention and treatment range, minimizing when agent for removing grass in paddy field in the conventional weed killer herbicide a large amount of organic solvent to the pollution and the influence of environment, improve produce, the safety in the transporting procedures.
The technical solution adopted in the present invention is: a kind of rice direct-seeding field weeding composition is characterized in that composition contains oxazole acyl grass amine 5% by weight percentage---30%, dichloro quinolinic acid 10%-60%.The present composition preferably is processed into wetting powder and/or oil-suspending agent uses.Composition is by the careless amine of the better proportioning of percentage by weight oxazole acyl grass amine and dichloro quinolinic acid Wei oxazole acyl: dichloro quinolinic acid=1: 3-4.
When Herbicidal combinations of the present invention was processed as wetting powder, its prescription was formed and to be by weight percentage: dichloro quinolinic acid 10%---40%, metamifop 5%---15%, surfactant 1%-10%, carrier 1%-80%; Described surfactant comprises lignosulfonates, lauryl sodium sulfate, fatty acid sulphate, aliphatic alcohol polyethenoxy, nekal, benzylphenol APEO, alkylphenol polyoxyethylene, draw back in the powder one or more, and described carrier comprises a kind of in kaolin, precipitated calcium carbonate, clay, the white carbon.
When Herbicidal combinations of the present invention was processed as oil-suspending agent, its prescription was formed and to be by weight percentage: dichloro quinolinic acid 10%---40%, metamifop 5%---15%, surfactant 5%-10%, carrier 1%-80%; Described surfactant is JFC, 603#, 600#, alkylphenol polyoxyethylene or its phosphate, fatty alcohol-polyoxyethylene ether, one or more in lignosulfonates, the naphthalenesulfonate formaldehyde condensation compound; Described carrier is a kind of in soybean oil, corn oil, cocoa butter, the palm oil.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer, the present invention describes with following specific embodiment, but the present invention is limited to these examples absolutely not.The following stated only is the present invention embodiment preferably, only is used to explain the present invention, can not therefore be interpreted as the restriction to claim of the present invention.Should be pointed out that all any modifications of being made within the spirit and principles in the present invention, be equal to replacement and improvement etc., all should be included within protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with appended claims.
The preparation of embodiment 126% dichloroquinoline Suan oxazole acyl grass amine wetting powder
The former medicine of dichloro quinolinic acid (folding hundred) 20% (weight)
The former medicine of oxazole acyl grass amine (folding hundred) 6% (weight)
Calcium lignosulfonate 13% (weight)
Lauryl sodium sulfate 3% (weight)
Draw back powder 5% (weight)
Kaolin is supplied 100% (weight)
Mentioned component is mixed, behind comminution by gas stream, cross 325 mesh sieves and promptly get product.
Moleplant seed is selected in the laboratory and the barnyard grass grass is more, the paddy rice seedling is grown, and carry out in normal live field, establishes 4 processing during experiment altogether.Handling 1 is 26% dichloroquinoline Suan oxazole acyl grass amine wetting powder, and handling 2 is 10% oxazole acyl grass amine wetting powder, and handling 3 is 10% dichloro quinolinic acid wetting powder, and handling 4 is space management, not dispenser, not weeding.The 15d investigation statistics is respectively handled the quantity of weeds and is calculated preventive effect as follows after the dispenser.
* 100% is counted in strain preventive effect=(check plot weeds strain number-treatment region weeds strain number)/check plot weeds strain
Calculate respectively and respectively handle the herbicidal effect of sub-district.
Handle 126% dichloroquinoline Suan oxazole acyl grass amine wetting powder 180g/ mu
Handle 210% oxazole acyl grass amine wetting powder 108g/ mu
Handle 310% dichloro quinolinic acid wetting powder 360g/ mu
Handle 4 space managements, not dispenser, not weeding
The preparation of embodiment 226% dichloroquinoline Suan oxazole acyl grass amine oil-suspending agent
The former medicine of dichloro quinolinic acid (folding hundred) 20%
The former medicine of oxazole acyl grass amine (folding hundred) 6%
Alkylphenol polyoxyethylene 8%
Sodium lignin sulfonate 7%
The corn oil surplus
Said components added in the grinder grinds 40 jointly---50 minutes, promptly can be made into the oil-suspending agent of milky, good fluidity.
Moleplant seed is selected in the laboratory and the barnyard grass grass is more, the paddy rice seedling is grown, and carry out in normal live field, establishes 4 processing during experiment altogether.Handling 1 is 26% dichloroquinoline Suan oxazole acyl grass amine oil-suspending agent, and handling 2 is 10% oxazole acyl grass amine oil-suspending agent, and handling 3 is 10% dichloro quinolinic acid oil-suspending agent, and handling 4 is space management, not dispenser, not weeding.The 15d statistics is respectively handled the quantity of weeds to compare preventive effect after the dispenser.
* 100% is counted in strain preventive effect=(check plot weeds strain number-treatment region weeds strain number)/check plot weeds strain
Calculate respectively and respectively handle the herbicidal effect of sub-district.
Handle 126% dichloroquinoline Suan oxazole acyl grass amine oil-suspending agent 180g/ mu
Handle 210% oxazole acyl grass amine oil-suspending agent 108g/ mu
Handle 310% dichloro quinolinic acid oil-suspending agent 360g/ mu
Handle 4 space managements, not dispenser, not weeding
Embodiment 340% dichloroquinoline Suan oxazole acyl grass amine wetting powder
The former medicine of dichloro quinolinic acid (folding hundred) 30% (weight)
The former medicine of oxazole acyl grass amine (folding hundred) 10% (weight)
Calcium lignosulfonate 13% (weight)
Lauryl sodium sulfate 3% (weight)
Draw back powder 5% (weight)
Kaolin is supplied 100% (weight)
Mentioned component is mixed, behind comminution by gas stream, cross 325 mesh sieves and promptly get product.
Moleplant seed is selected in the laboratory and the barnyard grass grass is more, the paddy rice seedling is grown, and carry out in normal live field, establishes 4 processing during experiment altogether.Handling 1 is 40% dichloroquinoline Suan oxazole acyl grass amine wetting powder, and handling 2 is 10% oxazole acyl grass amine wetting powder, and handling 3 is 10% dichloro quinolinic acid wetting powder, and handling 4 is space management, not dispenser, not weeding.The 15d statistics is respectively handled the quantity of weeds to compare preventive effect after the dispenser.
* 100% is counted in strain preventive effect=(check plot weeds strain number-treatment region weeds strain number)/check plot weeds strain
Calculate respectively and respectively handle the herbicidal effect of sub-district.
Handle 140% dichloroquinoline Suan oxazole acyl grass amine wetting powder 120g/ mu
Handle 210% oxazole acyl grass amine wetting powder 120g/ mu
Handle 310% dichloro quinolinic acid wetting powder 360g/ mu
Handle 4 space managements, not dispenser, not weeding
The preparation of embodiment 440% dichloroquinoline Suan oxazole acyl grass amine oil-suspending agent
The former medicine of dichloro quinolinic acid (folding hundred) 30%
The former medicine of oxazole acyl grass amine (folding hundred) 10%
Alkylphenol polyoxyethylene 8%
Sodium lignin sulfonate 7%
The soybean oil surplus
Said components is gone in the grinder to grind 40 jointly---50 minutes, promptly can be made into the oil-suspending agent of milky, good fluidity.
Moleplant seed is selected in the laboratory and nutgrass flatsedge is more, the paddy rice seedling is grown that carry out in normal live field, establishes 4 processing during experiment altogether.Handling 1 is 40% dichloroquinoline Suan oxazole acyl grass amine oil-suspending agent, and handling 2 is 10% oxazole acyl grass amine oil-suspending agent, and handling 3 is 10% dichloro quinolinic acid oil-suspending agent, and handling 4 is space management, not dispenser, not weeding.The 15d statistics is respectively handled the quantity of weeds to compare preventive effect after the dispenser.
* 100% is counted in strain preventive effect=(check plot weeds strain number-treatment region weeds strain number)/check plot weeds strain
Calculate respectively and respectively handle the herbicidal effect of sub-district.
Handle 140% dichloroquinoline Suan oxazole acyl grass amine oil-suspending agent 120g/ mu
Handle 210% oxazole acyl grass amine oil-suspending agent 120g/ mu
Handle 310% dichloro quinolinic acid oil-suspending agent 360g/ mu
Handle 4 space managements, not dispenser, not weeding
The preparation of embodiment 560% dichloroquinoline Suan oxazole acyl grass amine oil-suspending agent
The former medicine of dichloro quinolinic acid (folding hundred) 55%
The former medicine of oxazole acyl grass amine (folding hundred) 5%
Alkylphenol polyoxyethylene 10%
Sodium lignin sulfonate 5%
The soybean oil surplus
Said components is gone in the grinder to grind 40 jointly---50 minutes, promptly can be made into the oil-suspending agent of milky, good fluidity.
The preparation of embodiment 615% dichloroquinoline Suan oxazole acyl grass amine wetting powder
The former medicine of dichloro quinolinic acid (folding hundred) 10% (weight)
The former medicine of oxazole acyl grass amine (folding hundred) 5% (weight)
Calcium lignosulfonate 9% (weight)
Lauryl sodium sulfate 3% (weight)
Draw back powder 5% (weight)
Kaolin is supplied 100% (weight)
Mentioned component is mixed, behind comminution by gas stream, cross 325 mesh sieves and promptly get product.
Claims (5)
1. a rice direct-seeding field weeding composition is characterized in that composition contains by weight percentage: oxazole acyl grass amine 5%-30%, dichloro quinolinic acid 10%-60%.
2. according to claim 1, a kind of rice direct-seeding field weeding composition is characterized in that the proportioning by percentage by weight oxazole acyl grass amine and dichloro quinolinic acid is 1 in the composition: 3-4.
3. according to claim 2, a kind of rice direct-seeding field weeding composition that oxazole acyl grass amine and dichloro quinolinic acid are arranged that contains is characterized in that said composition can be processed as wetting powder and oil-suspending agent.
4. according to claim 3, a kind of rice direct-seeding field weeding composition that oxazole acyl grass amine and dichloro quinolinic acid are arranged that contains, when it is characterized in that said composition is processed as wetting powder, its prescription composition is by weight percentage: dichloro quinolinic acid 10%-40%, oxazole acyl grass amine 5%-15%, surfactant 1%-10%, carrier 1%-80%; Described surfactant comprises lignosulfonates, lauryl sodium sulfate, fatty acid sulphate, aliphatic alcohol polyethenoxy, nekal, benzylphenol APEO, alkylphenol polyoxyethylene, draw back in the powder one or more, and described carrier comprises a kind of in kaolin, precipitated calcium carbonate, clay, the white carbon.
5. according to claim 3, a kind of rice direct-seeding field weeding composition that oxazole acyl grass amine and dichloro quinolinic acid are arranged that contains, when it is characterized in that said composition is processed as oil-suspending agent, its prescription composition is by weight percentage: dichloro quinolinic acid 10%-40%, oxazole acyl grass amine 5%-15%, surfactant 5%-10%, carrier 1%-80%; Described surfactant is JFC, 603#, 600#, alkylphenol polyoxyethylene or its phosphate, fatty alcohol-polyoxyethylene ether, one or more in lignosulfonates, the naphthalenesulfonate formaldehyde condensation compound; Described carrier is a kind of in soybean oil, corn oil, cocoa butter, the palm oil.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201010185524A CN101822258A (en) | 2010-05-18 | 2010-05-18 | Weeding composition |
Applications Claiming Priority (1)
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CN201010185524A CN101822258A (en) | 2010-05-18 | 2010-05-18 | Weeding composition |
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CN101822258A true CN101822258A (en) | 2010-09-08 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101965837A (en) * | 2010-09-17 | 2011-02-09 | 北京颖新泰康国际贸易有限公司 | Herbicide composition and application thereof |
CN102792954A (en) * | 2011-05-23 | 2012-11-28 | 山东滨农科技有限公司 | Herbicide composition including metamifop and pyrazosulfuron-ethyl |
CN106465719A (en) * | 2016-08-30 | 2017-03-01 | 佛山市盈辉作物科学有限公司 | Dichloroquinoline oxadiazon and the Herbicidal combinations of azole amide |
CN109287649A (en) * | 2018-11-01 | 2019-02-01 | 安徽远景作物保护有限公司 | A kind of Herbicidal combinations and its application containing dichloro quinolinic acid |
CN109362744A (en) * | 2018-10-15 | 2019-02-22 | 安徽圣丰生化有限公司 | A kind of herbicidal composition containing metamifop and dichloro quinolinic acid |
CN110692642A (en) * | 2019-08-05 | 2020-01-17 | 安徽农业大学 | Dispersible oil suspending agent containing metamifop and quinclorac |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2003024224A2 (en) * | 2001-09-20 | 2003-03-27 | Syngenta Participations Ag | Herbicidal composition |
CN1685824A (en) * | 2005-06-23 | 2005-10-26 | 张志高 | Dichloro quinolinic acid herbicidal composition |
CN1713820A (en) * | 2002-11-21 | 2005-12-28 | 辛根塔参与股份公司 | Herbidical composition |
CN101379998A (en) * | 2008-10-16 | 2009-03-11 | 江苏丘陵地区镇江农业科学研究所 | Compound herbicide for efficiently preventing and curing paddy field weed and use thereof |
CN101410014A (en) * | 2006-01-13 | 2009-04-15 | 拜尔作物科学股份公司 | A herbicide composition for paddy field |
-
2010
- 2010-05-18 CN CN201010185524A patent/CN101822258A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003024224A2 (en) * | 2001-09-20 | 2003-03-27 | Syngenta Participations Ag | Herbicidal composition |
CN1713820A (en) * | 2002-11-21 | 2005-12-28 | 辛根塔参与股份公司 | Herbidical composition |
CN1685824A (en) * | 2005-06-23 | 2005-10-26 | 张志高 | Dichloro quinolinic acid herbicidal composition |
CN101410014A (en) * | 2006-01-13 | 2009-04-15 | 拜尔作物科学股份公司 | A herbicide composition for paddy field |
CN101379998A (en) * | 2008-10-16 | 2009-03-11 | 江苏丘陵地区镇江农业科学研究所 | Compound herbicide for efficiently preventing and curing paddy field weed and use thereof |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101965837A (en) * | 2010-09-17 | 2011-02-09 | 北京颖新泰康国际贸易有限公司 | Herbicide composition and application thereof |
CN101965837B (en) * | 2010-09-17 | 2013-09-11 | 北京颖泰嘉和生物科技有限公司 | Herbicide composition and application thereof |
CN102792954A (en) * | 2011-05-23 | 2012-11-28 | 山东滨农科技有限公司 | Herbicide composition including metamifop and pyrazosulfuron-ethyl |
CN106465719A (en) * | 2016-08-30 | 2017-03-01 | 佛山市盈辉作物科学有限公司 | Dichloroquinoline oxadiazon and the Herbicidal combinations of azole amide |
CN109362744A (en) * | 2018-10-15 | 2019-02-22 | 安徽圣丰生化有限公司 | A kind of herbicidal composition containing metamifop and dichloro quinolinic acid |
CN109287649A (en) * | 2018-11-01 | 2019-02-01 | 安徽远景作物保护有限公司 | A kind of Herbicidal combinations and its application containing dichloro quinolinic acid |
CN110692642A (en) * | 2019-08-05 | 2020-01-17 | 安徽农业大学 | Dispersible oil suspending agent containing metamifop and quinclorac |
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Application publication date: 20100908 |