CN101817948A - Material special for large low-carbon nano plastic alloy hollow containers and preparation method thereof - Google Patents
Material special for large low-carbon nano plastic alloy hollow containers and preparation method thereof Download PDFInfo
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- CN101817948A CN101817948A CN 201010127460 CN201010127460A CN101817948A CN 101817948 A CN101817948 A CN 101817948A CN 201010127460 CN201010127460 CN 201010127460 CN 201010127460 A CN201010127460 A CN 201010127460A CN 101817948 A CN101817948 A CN 101817948A
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Abstract
The invention belongs to the field of plastic processing, in particular to a material special for large low-carbon nano plastic alloy hollow containers and a preparation method thereof. The material special for large low-carbon nano plastic alloy hollow containers comprises 65 to 90 parts of carrier resin, 10 to 25 parts of inorganic filler, 1 to 5 parts of compatilizer, 0.5 to 3 parts of dispersant, 0.1 to 2 parts of surface active agent and 0.2 to 1 part of antioxidizer. The preparation method of the material special for large low-carbon nano plastic alloy hollow containers comprises the steps of: 1) putting the carrier resin, the inorganic filler, the compatilizer, the dispersant, the surface active agent and the antioxidizer into a high speed agitator, agitating the materials, and raising the temperature to 9 DEG C to 110 DEG C; and 2) adding a mixture to a twin-screw extrusion pelletizer for extrusion, water-cooling for bracing and dicing particles. The invention has the advantages of obvious shock resistance, obvious weather resistance, long service life, low cost, and the like.
Description
Technical field
The present invention relates to field of plastics processing, be specifically related to a kind of large-scale hollow container low-carbon (LC) plastic alloy material and preparation method thereof.
Background technology
Along with being showing improvement or progress day by day of plastic processing technology, rotational moulding has also obtained very big progress as a kind of important plastic processing.Rotomoulded articles is single from original kind, the product size specification is less, to the trend development of multiple class, large size even oversize.As rotational moulding yacht, massive rotationally moulded methane-generating pit, rotational moulding inspection shaft or the like.
Though rotomoulded articles has all had new development on goods kind and product size specification, but at present, rotomoulded articles still has two shortcomings: the used raw material ratio of most rotomoulded articles is more single, and performance is relatively poor than alloy material, poor as shock resistance, weathering resistance, work-ing life is short etc.; The small part rotomoulded articles has adopted alloy material, though improved the defective on the single material products performance to a certain extent, can't effectively reduce the goods cost.
Summary of the invention
The objective of the invention is to, a kind of large low-carbon nano plastic alloy hollow container proprietary material is provided, solve the problems of the technologies described above.
The present invention also aims to, a kind of preparation method of large low-carbon nano plastic alloy hollow container proprietary material is provided, solve the problems of the technologies described above.
Technical problem solved by the invention can realize by the following technical solutions:
Large low-carbon nano plastic alloy hollow container proprietary material, it is characterized in that, comprise following phase blended plurality of raw materials, plurality of raw materials title and parts by weight are as follows: 65～90 parts of vector resins, 10～25 parts of inorganic fillers, 1～5 part of compatilizer, 0.5～3 part of dispersion agent, 0.1～2 part in tensio-active agent, 0.2～1 part in oxidation inhibitor.
Described vector resin is one or more in polyethylene, polypropylene, metallocene PE or the ethylene vinyl acetate (EVA).
Described inorganic filler is one or more in nano-calcium carbonate, nano-attapulgite or the talcum powder.Described inorganic filler adopts the nano inorganic powder particle, and more common inorganic powder is trickleer, and the specific surface area of unit mass is bigger, can increase the contact area of inorganic filling material and polymeric matrix, forms better physical entanglement.Use the large low-carbon nano plastic alloy hollow container proprietary material of nano inorganic powder to make rotomoulded articles, can improve the mechanical mechanics property of rotomoulded articles, thermomechanical property and moulding processability as raw material.
Described compatilizer is one or both among PE-g-MAH, the PP-g-MAH.
Described dispersion agent is the compound of erucicamide and stearic amide, and the compound proportion of described erucicamide and stearic amide is 2: 1.
Described tensio-active agent is one or both in aluminate coupling agent, the silane coupling agent.Use composite dispersion agent and tensio-active agent can avoid the reunion of nano inorganic powder to take place, the inorganic powder of different-grain diameter can be dispersed in the vector resin with uniform " sea-island " structure, form filling effect, and then reduce the usage quantity of vector resin, reduce cost.
Described oxidation inhibitor is one or both in antioxidant 1010, the oxidation inhibitor 168.
The preparation method of large low-carbon nano plastic alloy hollow container proprietary material is characterized in that, may further comprise the steps:
1) vector resin, inorganic filler, compatilizer, dispersion agent, tensio-active agent, oxidation inhibitor are put in the homogenizer, stirred material, temperature to 95 ℃～110 ℃ is made compound;
2) described compound is joined in the double-screw extruding pelletizing machine extrude, water-cooled tie rod, pelletizing, promptly get large low-carbon nano plastic alloy hollow container proprietary material.
In the step 1), 65～90 parts of described vector resins, 10～25 parts of inorganic fillers, 1～5 part of compatilizer, 0.5～3 part of dispersion agent, 0.1～2 part in tensio-active agent, 0.2～1 part in oxidation inhibitor.
Described vector resin is one or more in polyethylene, polypropylene, metallocene PE or the ethylene vinyl acetate (EVA).
Described inorganic filler is one or more in nano-calcium carbonate, nano-attapulgite or the talcum powder.
Described compatilizer is one or both among PE-g-MAH, the PP-g-MAH.
Described dispersion agent is the compound of erucicamide and stearic amide, and the compound proportion of described erucicamide and stearic amide is 2: 1.
Described tensio-active agent is one or both in aluminate coupling agent, the silane coupling agent.
Described oxidation inhibitor is one or both in antioxidant 1010, the oxidation inhibitor 168.
Beneficial effect: the present invention passes through nano inorganic powder, vector resin, compatilizer, dispersion agent, tensio-active agent, materials such as oxidation inhibitor organically combine, make large low-carbon nano plastic alloy hollow container proprietary material, this material has significant shock resistance, weathering resistance, long service life, advantage such as with low cost, not only mechanical mechanics property is superior as rotomoulded articles that raw material is made to adopt this material, shock resistance is strong, weathering resistance is strong, the goods long service life, and the resin usage quantity is low, when reducing production costs significantly, can imitate the minimizing emission of carbon-dioxide.
Description of drawings
Fig. 1 is preparation method's of the present invention schematic flow sheet.
Embodiment
For technique means, creation characteristic that the present invention is realized, reach purpose and effect is easy to understand, further set forth the present invention below in conjunction with concrete diagram.
With reference to Fig. 1, large low-carbon nano plastic alloy hollow container proprietary material, comprise following phase blended plurality of raw materials, plurality of raw materials title and parts by weight are as follows: 65～90 parts of vector resins, 10～25 parts of inorganic fillers, 1～5 part of compatilizer, 0.5～3 part of dispersion agent, 0.1～2 part in tensio-active agent, 0.2～1 part in oxidation inhibitor; Vector resin is one or more in polyethylene, polypropylene, metallocene PE or the ethylene vinyl acetate (EVA).Inorganic filler is one or more in nano-calcium carbonate, nano-attapulgite or the talcum powder.Compatilizer is one or both among PE-g-MAH, the PP-g-MAH.Dispersion agent is the compound of erucicamide and stearic amide, and the compound proportion of erucicamide and stearic amide is 2: 1.Tensio-active agent is one or both in aluminate coupling agent, the silane coupling agent.Oxidation inhibitor is one or both in antioxidant 1010, the oxidation inhibitor 168.
The preparation method of large low-carbon nano plastic alloy hollow container proprietary material, may further comprise the steps: the 1st step: vector resin, inorganic filler, compatilizer, dispersion agent, tensio-active agent, oxidation inhibitor are put in the homogenizer 11, stir material 12, temperature to 95 ℃～110 ℃ is made compound; The 2nd step: compound is joined in the double-screw extruding pelletizing machine 21, extrude 22, water-cooled tie rod 23, pelletizing 24, promptly get large low-carbon nano plastic alloy hollow container proprietary material.In the 1st step, 65～90 parts of vector resins, 10～25 parts of inorganic fillers, 1～5 part of compatilizer, 0.5～3 part of dispersion agent, 0.1～2 part in tensio-active agent, 0.2～1 part in oxidation inhibitor.Vector resin is one or more in polyethylene, polypropylene, metallocene PE or the ethylene vinyl acetate (EVA).Inorganic filler is one or more in nano-calcium carbonate, nano-attapulgite or the talcum powder.Compatilizer is one or both among PE-g-MAH, the PP-g-MAH.Dispersion agent is the compound of erucicamide and stearic amide, and the compound proportion of erucicamide and stearic amide is 2: 1.Tensio-active agent is one or both in aluminate coupling agent, the silane coupling agent.Oxidation inhibitor is one or both in antioxidant 1010, the oxidation inhibitor 168.
Embodiment one:
Get 20 kilograms of polyethylene; 40 kilograms of polypropylene; 10 parts of metallocene PEs; 5 kilograms of nano-calcium carbonates; 6 kilograms of talcum powder; 14 kilograms of nano-attapulgites; 3 kilograms of PP-g-MAH; 0.5 kilogram of aluminate coupling agent; 0.6 kilogram of erucicamide-stearic amide compound, 0.2 kilogram of antioxidant 1010 is put into above-mentioned materials and is stirred to 95 ℃ in the homogenizer and emits; put into then in the double-screw extruding pelletizing machine extrude, water-cooled tie rod, pelletizing, promptly get large low-carbon nano plastic alloy hollow container proprietary material.
Embodiment two:
Get 25 kilograms of polyethylene; 60 kilograms of polypropylene; 5 parts of ethylene vinyl acetates (EVA); 3 kilograms of nano-calcium carbonates; 20 kilograms of talcum powder; 5 kilograms of PP-g-MAH; 1 kilogram of silane coupling agent; 1 kilogram of erucicamide-stearic amide compound; 0.2 kilogram of antioxidant 1010,168 0.2 kilograms in oxidation inhibitor is put into above-mentioned materials and is stirred to 100 ℃ in the homogenizer and emits; put into then in the double-screw extruding pelletizing machine extrude, water-cooled tie rod, pelletizing, promptly get large low-carbon nano plastic alloy hollow container proprietary material.
Embodiment three:
Get 60 kilograms of polyethylene; 10 kilograms of ethylene vinyl acetates (EVA); 5 kilograms of nano-calcium carbonates; 10 kilograms of talcum powder; 10 kilograms of nano-attapulgites; 1 kilogram of PE-g-MAH; 0.3 kilogram of aluminate coupling agent; 0.2 kilogram of silane coupling agent; 3 kilograms of erucicamides-stearic amide compound, 168 0.6 kilograms in oxidation inhibitor is put into above-mentioned materials and is stirred to 100 ℃ in the homogenizer and emits; put into then in the double-screw extruding pelletizing machine extrude, water-cooled tie rod, pelletizing, promptly get large low-carbon nano plastic alloy hollow container proprietary material.
More than show and described ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; that describes in the foregoing description and the specification sheets just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.
Claims (10)
1. large low-carbon nano plastic alloy hollow container proprietary material, it is characterized in that, comprise following phase blended plurality of raw materials, plurality of raw materials title and parts by weight are as follows: 65～90 parts of vector resins, 10～25 parts of inorganic fillers, 1～5 part of compatilizer, 0.5～3 part of dispersion agent, 0.1～2 part in tensio-active agent, 0.2～1 part in oxidation inhibitor.
2. large low-carbon nano plastic alloy hollow container proprietary material according to claim 1 is characterized in that: described vector resin is one or more in polyethylene, polypropylene, metallocene PE or the ethylene vinyl acetate.
3. large low-carbon nano plastic alloy hollow container proprietary material according to claim 2 is characterized in that: described inorganic filler is one or more in nano-calcium carbonate, nano-attapulgite or the talcum powder.
4. large low-carbon nano plastic alloy hollow container proprietary material according to claim 3 is characterized in that: described compatilizer is one or both among PE-g-MAH, the PP-g-MAH.
5. large low-carbon nano plastic alloy hollow container proprietary material according to claim 4 is characterized in that: described dispersion agent is the compound of erucicamide and stearic amide, and the compound proportion of described erucicamide and stearic amide is 2: 1.
6. large low-carbon nano plastic alloy hollow container proprietary material according to claim 5 is characterized in that: described tensio-active agent is one or both in aluminate coupling agent, the silane coupling agent.
7. large low-carbon nano plastic alloy hollow container proprietary material according to claim 6 is characterized in that: described oxidation inhibitor is one or both in antioxidant 1010, the oxidation inhibitor 168.
8. the preparation method of large low-carbon nano plastic alloy hollow container proprietary material is characterized in that, may further comprise the steps:
1) vector resin, inorganic filler, compatilizer, dispersion agent, tensio-active agent, oxidation inhibitor are put in the homogenizer, stirred material, temperature to 95 ℃～110 ℃ is made compound;
2) described compound is joined in the double-screw extruding pelletizing machine extrude, water-cooled tie rod, pelletizing, promptly get large low-carbon nano plastic alloy hollow container proprietary material.
9. the preparation method of large low-carbon nano plastic alloy hollow container proprietary material according to claim 8, it is characterized in that: in the step 1), 65～90 parts of described vector resins, 10～25 parts of inorganic fillers, 1～5 part of compatilizer, 0.5～3 part of dispersion agent, 0.1～2 part in tensio-active agent, 0.2～1 part in oxidation inhibitor.
10. the preparation method of large low-carbon nano plastic alloy hollow container proprietary material according to claim 9 is characterized in that: described vector resin is one or more in polyethylene, polypropylene, metallocene PE or the ethylene vinyl acetate;
Described inorganic filler is one or more in nano-calcium carbonate, nano-attapulgite or the talcum powder; Described compatilizer is one or both among PE-g-MAH, the PP-g-MAH;
Described dispersion agent is the compound of erucicamide and stearic amide, and the compound proportion of described erucicamide and stearic amide is 2: 1;
Described tensio-active agent is one or both in aluminate coupling agent, the silane coupling agent;
Described oxidation inhibitor is one or both in antioxidant 1010, the oxidation inhibitor 168.
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102212225A (en) * | 2011-05-10 | 2011-10-12 | 昆明春叶塑料制成品有限公司 | Production method for agricultural greenhouse film master batch reinforced by calcium salt crystal whiskers |
| CN102391572A (en) * | 2011-09-07 | 2012-03-28 | 上海日之升新技术发展有限公司 | High-toughness calcium carbonate-filled polypropylene compound material and preparation method thereof |
| CN102485781A (en) * | 2010-12-06 | 2012-06-06 | 中国石油化工股份有限公司 | Polyethylene composition for large-scale container lining |
| WO2012087092A1 (en) * | 2010-12-21 | 2012-06-28 | Sigma Alimentos, S. A. De C. V. | Polymeric composition incorporating hollow nanoparticles, method for production thereof and a container produced with the composition |
| CN102838792A (en) * | 2012-02-22 | 2012-12-26 | 上海心尔新材料科技股份有限公司 | Modified filling material for laminating film and preparation method thereof |
| CN104086894A (en) * | 2014-06-06 | 2014-10-08 | 浙江俊尔新材料股份有限公司 | A polarity-modified polypropylene composite material and a preparing method thereof |
| CN105694203A (en) * | 2015-09-18 | 2016-06-22 | 怀宁县明发塑业有限责任公司 | Nano modified polypropylene composite plastic for automobile parts |
| CN105694172A (en) * | 2015-09-18 | 2016-06-22 | 怀宁县明发塑业有限责任公司 | Nano modified polyethylene composite damping plastic |
| CN108659352A (en) * | 2017-03-27 | 2018-10-16 | 武汉金发科技有限公司 | A kind of polypropylene-nano-attapulgite composite material and preparation method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1944516A (en) * | 2006-10-31 | 2007-04-11 | 东莞金富亮塑胶颜料有限公司 | High density poly propylene (PP) composite material |
| CN1986627A (en) * | 2005-12-22 | 2007-06-27 | 吴永刚 | Composite polypropylene material and its preparing method |
| CN101659767A (en) * | 2008-08-26 | 2010-03-03 | 金发科技股份有限公司 | Polypropylene composition with scratch resistant performance and use of polypropylene composition as automotive upholstery |
-
2010
- 2010-03-18 CN CN 201010127460 patent/CN101817948A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1986627A (en) * | 2005-12-22 | 2007-06-27 | 吴永刚 | Composite polypropylene material and its preparing method |
| CN1944516A (en) * | 2006-10-31 | 2007-04-11 | 东莞金富亮塑胶颜料有限公司 | High density poly propylene (PP) composite material |
| CN101659767A (en) * | 2008-08-26 | 2010-03-03 | 金发科技股份有限公司 | Polypropylene composition with scratch resistant performance and use of polypropylene composition as automotive upholstery |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102485781A (en) * | 2010-12-06 | 2012-06-06 | 中国石油化工股份有限公司 | Polyethylene composition for large-scale container lining |
| CN102485781B (en) * | 2010-12-06 | 2013-07-17 | 中国石油化工股份有限公司 | Polyethylene composition for large-scale container lining |
| WO2012087092A1 (en) * | 2010-12-21 | 2012-06-28 | Sigma Alimentos, S. A. De C. V. | Polymeric composition incorporating hollow nanoparticles, method for production thereof and a container produced with the composition |
| CN102212225A (en) * | 2011-05-10 | 2011-10-12 | 昆明春叶塑料制成品有限公司 | Production method for agricultural greenhouse film master batch reinforced by calcium salt crystal whiskers |
| CN102391572A (en) * | 2011-09-07 | 2012-03-28 | 上海日之升新技术发展有限公司 | High-toughness calcium carbonate-filled polypropylene compound material and preparation method thereof |
| CN102838792A (en) * | 2012-02-22 | 2012-12-26 | 上海心尔新材料科技股份有限公司 | Modified filling material for laminating film and preparation method thereof |
| CN104086894A (en) * | 2014-06-06 | 2014-10-08 | 浙江俊尔新材料股份有限公司 | A polarity-modified polypropylene composite material and a preparing method thereof |
| CN105694203A (en) * | 2015-09-18 | 2016-06-22 | 怀宁县明发塑业有限责任公司 | Nano modified polypropylene composite plastic for automobile parts |
| CN105694172A (en) * | 2015-09-18 | 2016-06-22 | 怀宁县明发塑业有限责任公司 | Nano modified polyethylene composite damping plastic |
| CN108659352A (en) * | 2017-03-27 | 2018-10-16 | 武汉金发科技有限公司 | A kind of polypropylene-nano-attapulgite composite material and preparation method |
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Application publication date: 20100901 |