CN101804014A - Stable multifunctional cosmetic composition - Google Patents
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- CN101804014A CN101804014A CN200910046115A CN200910046115A CN101804014A CN 101804014 A CN101804014 A CN 101804014A CN 200910046115 A CN200910046115 A CN 200910046115A CN 200910046115 A CN200910046115 A CN 200910046115A CN 101804014 A CN101804014 A CN 101804014A
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Abstract
The invention relates to a stable multifunctional cosmetic composition, which is a methyl acrylic acid/acrylate crosslinked copolymer with a pro-silicone organic silicon group and pro-oil long-chain alkyl. Based on the total weight of the polymer, the content of the methyl acrylic acid is 25-75 percent in a preferential technical scheme, and is 35-60 percent in a more preferential technical scheme; and the content of the acrylate is 20-80 percent in a preferential technical scheme, and is 35-60 percent in a more preferential technical scheme. The invention has the advantages that: the research shows that the multifunctional cosmetic composition system with the methyl acrylic acid/acrylate crosslinked copolymer suspending agent (i.e. at least one surfactant, at least one ationic conditioning agent, at least one type of silicone oil or fat oil and other functional insolubles (such as a dandruff removing agent, a pearl film and the like)) has good stability.
Description
Technical field
The present invention relates to cosmetic field, relate in particular to a kind of stable multifunctional cosmetic composition.
Background technology
As everyone knows, under the effect of atmospheric factor or machinery and chemical treatment (as dyestuff, bleaching etc.), impaired hair usually is difficult to scatter and finalize the design, and lacks flexibility.Therefore protect in the product washing, usually add cationic polymer or amphiphilic polymers or siloxanes etc. and be used for washing or nursing keratose such as hair, thereby make hair loose and give its flexibility and elasticity with opsonic action.Yet layering etc. takes place in the use of a large amount of silicone oil or fatty oil, cation opsonizing agent, amphoteric conditioning agent easily, tends to cause the instability of composition system.
On the other hand, normal person and dandruff patient's scalp is all being perched pityrosporon ovale dermatophytess such as (Pityrosporum ovale), with people's symbiosis.Seriously dandruff crowd's pityrosporon ovale is movable undesired, and pityrosporon ovale enters in the hair follicle, and its anaerobic metabolism strengthens the epidermis cell resolution ratio, thereby causes abrasion.These dermatophytess enter in the scalp, cause their fertility to strengthen, and its lipase is decomposed into free fatty with triglyceride, and isolated oleic acid will cause class dandruff scale to form.Serious dandruff crowd's this scalp ultrastructure is that their scalp horny layer is responsive more.So in some hair care products, tend to add anti-dandruff dose of 1-oxygen-2-mercaptopyridine salt or selenium sulfide, ketoconazole, climbazole, Octopirox etc.In addition, in order to increase the appearance of product, these washing cleaning products can contain materials such as pearlescent flake, Pearl Concentrate usually.Even also often containing insoluble substances such as Pulvis Talci in some washing products, these insoluble substances precipitate in surfactant system easily.
In sum, make up a stable multifunctional meter surface-active agent system and just seem extremely important.And natural nonionic thickener, since insensitive to pH value, the viscosity of wayward system.Therefore in order to keep the stable of whole system, people have used traditional aggretion type rheology modifier, as carbomers and/or acrylate/acrylic acid C
10-C
30Alkyl ester cross-linked polymer is used to increase viscosity, but and the rheological characteristic of these compositionss still very poor usually, and the salt tolerance of carbomers etc. itself is poor, the difficult dispersion, has limited its application.
It below is the application patent of some similar products like.At present at home, in the rheology modifier starting evening that daily use chemicals are used, develop slower.
For example, US patent 5,656257 relates to a kind of anion shampoo and compositions is used in conditioning, wherein contains oiliness conditioner, shampoo, acrylate copolymer, cation opsonizing agent and water.It also relates to admixture C
8-C
18Fatty acid.This compositions has utilized the combination of oiliness and cation opsonizing agent and anion conditioner acrylate copolymer to keep stability and dispersibility.The used non-crosslinked anionic acrylic ester copolymer of patent is representative with ACULYN22 (ROHM AND HAAS), does not relate to other insoluble functional materials such as ZPT in addition.
WO99/21530 relates to a kind of Haircare composition, contains one or more surfactants that the 1.00wt% to 80.00wt% that has an appointment is selected from anion, nonionic, cation and zwitterionic surfactant and composition thereof; About 0.05wt% is at least a aliphatic alcohol with 10 to 30 carbon atoms of about 15.00wt%; About 0.05wt% is to about 15.00wt% non-volatile siloxane and the extremely noncrosslinking polymer suspension agent of about 2.70wt% of about 1.35wt%.The used anionic polymerisation composition copolymer of patent is ACULYN22, and ACULYN33 (ROHM AND HAAS), this copolymer are the non-crosslinked type, do not relate to other insoluble functional mass such as ZPT in addition.
US patent 4,529,773 relates to the compositions that contains associative thickeners (but alkali-soluble emulsion polymer of hydrophobically modified), and wherein by being neutralized to PH greater than 6.5, then acidify is said thickening agent activation in the presence of surfactant.This patent only relates to the system that contains surfactant, and relates to the stability that it uses in compositions.
WO patent 01/76552 relates to the compositions of a kind of crosslinked basically swellable acrylate copolymer rheology modifier, surfactant, alkaline material, insoluble component (for example siloxanes or lipoid material), and said copolymer has back acid-thickened property.Certainly document has also been mentioned and can be used in the prescription that cation opsonizing agent is formed in addition.This patent relates to a stable aqueous surfactant system and (contains surfactant, insoluble substance silicone oil, anti-dandruff dose, cation opsonizing agent etc.), the face that relates to is wider, with rheology modifier be the crosslinked acrylic copolymer of the activity 30% of BFGOODRICH company, and have back acid-thickened effect.
CN1404816A relates to a kind of methacrylic acid/acrylic acid C that contains
1-C
4The compositions of the cross-linked copolymer of Arrcostab, at least a cation or amphiphilic polymers and at least a functionalized silicone.Patent emphasizes that this compositions compares WO patent 01/76552 and have better foam property and cosmetic character.This patent applies for that main emphasis is different on WO patent 01/76552 patent basis, it emphasizes to also have result of use except stable.The rheology modifier that uses is the CARBOPOL AQUA SF-1 alkali swelling acrylic crosslinking polymer of U.S. NOVEON.The product of polymer of the type and U.S. BFGOODRICH company is similar.
Summary of the invention
The invention provides a kind of stable multifunctional cosmetic composition, with overcome existing wash to protect add cationic polymer with opsonic action or amphiphilic polymers or siloxanes etc. in the product and be used to wash or nurse keratose and cause the unsettled deficiency of composition system.
The technical scheme that realizes the object of the invention is as follows:
A kind of stable multifunctional cosmetic composition contains the methyl-prop diluted acid/acrylate cross linked copolymer (being called DB1900) of close silicone oil organosilicon radical and oleophylic fat chain alkyl;
Wherein the content of methacrylic acid is preferably 25%-75% in this total polymer weight, more preferably 35%-60%;
Wherein the content of acrylic acid ester is preferably 20-80%, and it is one of following that more preferably 35%-60%, described acrylic acid ester are selected from: acrylic acid methyl ester., acrylic acid ethyl ester, butyl acrylate, preferred butyl acrylate;
Wherein contain close silicone oil organosilicon radical for containing the vinyl organosilicon monomer, it can be the organic silicon monomer of following several structures:
Wherein, R
1Can be CH
3Or H, R
2Be C1～C4; Perhaps
——(CH
2CH
2O)
XCH
3
X=1～5; Perhaps
Wherein, R
3Can be CH
3Or H, R
4Be C1～C4; Perhaps
The polysiloxane of other vinyl modification, wherein preferred vinyl triethoxysilane;
Parent's silicone oil organosilicon radical constituent content is preferably 0.01%-2% in this total polymer weight, more preferably 0.05%-0.20%.
Oleophylic fat chain alkyl is long-chain alkyl methacrylates or long-chain aliphatic acrylate, can be the chemicals of following structural:
Wherein, R
5Be CH
3Or H, R
6Be C4～C30;
Wherein, preferable methyl dodecylacrylate, methacrylic acid cetyl ester, methacrylic acid stearyl, more preferably methacrylic acid stearyl;
The content of described oleophylic fat chain alkyl is preferably 0.01%-5% in this total polymer weight, more preferably 0.05%-1%.
A kind of stable multifunctional cosmetic composition of the present invention also comprises surfactant, conditioner, cationic polymer and other insoluble component.
Being suitable for surfactant of the present invention comprises but is not limited to: ammonium lauryl sulfate, cocoyl ammonium sulfate, lauryl potassium sulfate, the cocoyl potassium sulfate, sodium lauryl sulfate, cocoyl sodium sulfate, lauryl sulfate monoethanolamine, cocoyl sulphuric acid monoethanolamine, lauryl sulfate monoethanolamine, cocoyl sulphuric acid monoethanolamine, lauryl polyethenoxy ether sodium sulfate, the laureth potassium sulfate, sodium laureth sulfate, laureth sulphuric acid monoethanolamine, laureth sulphuric acid triethanolamine, the N-disodium octadecyl sulfosuccinate; Lauryl sulphur disodium succinate, lauryl propylhomoserin sodium, cocos nucifera oil acyl aminopropyl betanin, lauryl dimethyl betanin, coco dimethyl third sulfobetaines, cocos nucifera oil both sexes carboxyl Glycine sodium, C14-16 sodium olefin sulfonate, lauryl amine oxide, cocos nucifera oil amidoamines propyl group amine oxide, alkyl-glucoside.The preferred ammonium lauryl sulfate of surfactant, laureth sulphuric acid triethanolamine, lauryl polyethenoxy ether sodium sulfate, lauryl sulfate monoethanolamine, cocos nucifera oil acyl aminopropyl betanin, lauryl amine oxide, lauryl disodium sulfosuccinate, most preferably lauryl polyethenoxy ether sodium sulfate, ammonium lauryl sulfate, cocos nucifera oil acyl aminopropyl betanin; The content of surfactant is at about 5% to 50% (w/w), preferably at about 6% to 40% (w/w), more preferably at about 8% to 35% (w/w), further preferably at about 10% to 30% (w/w), most preferably from about 12% to 25% (w/w) among the present invention.Can determine the optimum quantum of utilization of surfactant according to the composition of employed concrete surfactant and compositions, this is in those skilled in the art's limit of power.
Be applicable to that conditioner of the present invention is to be selected from the following group one or more: polysiloxanes and derivant thereof, organic conditioning oils.Organic conditioning oil can be selected from hydrocarbon ils, polyolefin, fatty ester, as paraffinic oils, mineral oil, isostearic acid isopropyl ester, maleic acid Semen Ricini grease, olive oil, Semen Armeniacae Amarum wet goods.These conditioners can use separately, also can compositely use.Preferably poly-polysiloxanes of conditioner and maleic acid Oleum Ricini.Polysiloxanes is those nonvolatile polysiloxanes conditioners preferably.The viscosity that the polysiloxanes conditioner records under 25 ℃ is 20-5, and 000,000 centistoke is preferably 2,000-4,000,000 centistoke, more preferably 200,000-3,000,000 centistoke, more preferably 5000,000-2,000,000 centistoke most preferably is 100,000-1,500,000 centistokes.The conditioner use amount is at 0.01% to 20.0% (w/w), preferably in the scope of 0.05% to 10.0% (w/w), more preferably in the scope of 0.1% to 5.0% (w/w), most preferably in the scope of 0.2% to 4.0% (w/w).Can determine the optimum quantum of utilization of conditioner according to the composition of employed concrete conditioner and compositions, this is in those skilled in the art's limit of power.
Be applicable to that cationic polymer of the present invention is selected from one or more in the following group: cation guar gum, polyquaternary ammonium salt-2, polyquaternary ammonium salt-4, polyquaternary ammonium salt-7, polyquaternary ammonium salt-10, polyquaternary ammonium salt-11, Salcare SC60 (ciba company), Salcare SC96 (ciba company); Preferred cationic guar gum, polyquaternary ammonium salt-4, polyquaternary ammonium salt-7, polyquaternary ammonium salt-10.Polyquaternary ammonium salt-10 most preferably.The addition of cationic polymer is in the scope of 0.01%-10.0% (w/w), preferably in the scope of 0.02%-4.0% (w/w), more preferably in the scope of 0.05%-3.0% (w/w), most preferably in the scope of 0.1%-1.0% (w/w).
Other insoluble component includes but not limited to following several:
Anti-dandruff dose, include but not limited in the following material one or more: carboxyl pyridine ketone slaine, ketoconazole, miconazole, Octopirox, IPBC, climbazole, selenium sulfide, sulfur coal tar.Preferred anti-dandruff dose is Zinc Pyrithione, ketoconazole, Octopirox, climbazole.Preferred anti-dandruff dose of Zinc Pyrithione, ketoconazole, Octopirox.In compositions of the present invention, gross weight based on compositions, anti-dandruff dose effective dose about 0.01% to about 10.0% (w/w) scope, preferably about 0.02% to about 5.0% (w/w) scope, more preferably about 0.04% to about 4.0% (w/w) scope, more preferably about 0.05% to about 3.0% (w/w) scope, further preferably about 0.1% to about 2.0% (w/w) scope.Can determine anti-dandruff dose optimum quantum of utilization according to the composition of employed concrete anti-dandruff dose and compositions, this is in those skilled in the art's limit of power.
The pearly-lustre material, comprise the Muscovitum that is coated with titanium dioxide, be coated with Muscovitum, ethylene glycol monostearate, glycol distearate, polyglycol distearate, the Muscovitum that is coated with bismuth oxychloride, myristyl myristate, guanine, glitter (glitter) (polyester and metal species) of ferrum oxide and composition thereof, the visible us patent 4 of other pearly-lustre material, 654,207 and us patent 5,019,376, it is incorporated herein by reference; In the gross weight of stable compositions, the use amount of pearly-lustre material can be about 0.05wt% to about 10wt% and preferably about 0.15wt% about 3wt% extremely usually.
Compositions of the present invention is except the above composition and other optional auxiliary element, and water is supplemented to requirement.
Compositions of the present invention can also comprise other optional member, comprising: antistatic additive, antioxidant, foam booster, annual regulator, thickening agent, PH regulator, antiseptic, pigment, organic solvent or diluent, spice, aliphatic alcohol etc. are known or be effective to hair nursing or personal care product's additional optional components.The foam booster that is used for the present composition comprises cocos nucifera oil acyl monoethanolamine, cocos nucifera oil acyl diethanolamine and their mixture.Viscosity modifier of selecting for use and thickening agent are used for compositions of the present invention with effective dose, make overall viscosity be about 4,000mPa.s to 13,000mPa.s.The concrete non-limiting example of this viscosity modifier and thickening agent comprises: sodium chloride, ammonium chloride and their mixture.
A kind of stable multifunctional cosmetic composition of the present invention can be made by many modes, normally other material and surfactant are mixed, then with described methyl-prop diluted acid/acrylate cross linked copolymer with after water mixes, directly add in the surfactant system that mixes, regulate viscosity, obtain final products.
Beneficial effect of the present invention: described methyl-prop diluted acid/acrylate cross linked copolymer obtains by emulsion polymerisation, it is a kind of alkali swellability acrylate polymer emulsion of uniqueness, and the thickening mechanism of general alkali thickening emulsion belongs to " fluid dynamic thickening " (Hydrodynamic) mechanism.Because the polymer molecule great majority exist with the state of carboxylic acid functional, polymer circumnutates in latex particle, therefore viscosity is little, in meeting alkali and after, molecule generation ionizing, produce a large amount of carboxylate anions, because about the mutual repulsion of electric charge, polymer molecule is upheld and is expanded, in its aqueous systems, show the character of thickening and suspension, viscosity and suspending power mainly stem from the physics of polymer molecule and fill (physical packing); But, in order to increase the suspension effect of polymer, polymer has been introduced some functionalization groups especially, increase the affinity of polymer and various ingredients, play synergic effect, wherein, contain the oleophylic organosilicon radical and oleophylic fat chain alkyl functional group is the maximum characteristics of this suspending agent, the thickening of polymer and suspension effect are to be used for realizing by having two kinds of cooperative effect, the expansion of the electrolyte molecule chain by electric charge induction just, and the combination of the lipophilic group that stretches.
The present invention discovers in the multifunctional cosmetic composition system that contains this methyl-prop diluted acid/acrylate cross linked copolymer (DB1900) suspending agent (being at least a surfactant, at least a cation opsonizing agent, at least a silicone oil or fatty oil and other functional insoluble matter (as anti-dandruff dose, pearlescent flake etc.)) to have good stability.
The specific embodiment
Below in conjunction with specific embodiment the present invention is further described.
The making of the described a kind of stable multifunctional cosmetic composition of the embodiment of the invention is that other material and surfactant are mixed, then with described methyl-prop diluted acid/acrylate cross linked copolymer (DB1900) with after water mixes, directly add in the surfactant system that mixes, regulate viscosity, obtain final products.Only providing for illustration purpose of these examples can not be interpreted as limitation of the invention.Because without departing from the spirit and scope of the present invention, can carry out many conversion to the present invention.In these embodiments, unless stated otherwise, used concentration all is percentage by weight.Used term " small amount of matter " refers to those optional materials, as antiseptic, viscosity modifier, PH regulator, essence, pigment etc.
Table one: the composition of various compositionss
Continuous table one: the composition of each example composition
Suspension effect evaluation for embodiment:
Personal care product and home care product stability are to being very important.The shelf-life of general personal care composition is generally 3 years, and the home care product were generally 1 year.The cosmetics series that use contains the methyl-prop diluted acid/acrylate cross linked copolymer of close silicone oil organosilicon radical and oleophylic fat chain alkyl has good stability.
Need to surpass the stability study in 1 year for eliminating, the makers-up investigates the stability of product by changing test condition.In general, under higher static state or lower temperature, carry out accelerated test, usually at 45～50 ℃ or-5～-18 ℃.Usually under 45 ℃ or-18 ℃ of conditions, be stable at least 2 weeks, 1 month is desirable.In addition, often use the freeze-thaw cycling, circulation between 45 ℃ of the temperature that freezes-18 ℃ and thaw points.Compositions should be by minimum 1 freeze-thaw circulation, and preferred 3 times, first-selected 5 circulations.
Test period
| Experimental condition | Test period |
| Heat-resisting 45 ℃ | 4 weeks |
| Cold-resistant-18 ℃ | 4 weeks |
| Circulation (18～45) ℃ | 5 circulations |
Sense cycle and test item
Judgment basis: for heat-resistant stability, heat-resisting 45 ℃ of tests are 4 all heat-resistant stability experimental stage results' qualification determination foundation, but need guarantee that simultaneously heat-resisting 4 weeks of 40 ℃ of tests are qualified.For cold-resistant stability, cold-resistant-18 ℃ of tests are the interim result's of cold-resistant stability test of 4 weeks qualification determination foundation, but 4 weeks of-5 ℃ of tests of need guaranteeing simultaneously to resist cold are qualified.
When all inspection item score 〉=3 timesharing, judge " stability test meets the requirements ".Test item was scored≤2 o'clock as (comprising 1) more than 1, judged " stability test is undesirable ".
Table two, each example composition suspension effect are estimated
Claims (10)
1. a stable multifunctional cosmetic composition is characterized in that: the methyl-prop diluted acid/acrylate cross linked copolymer that contains close silicone oil organosilicon radical and oleophylic fat chain alkyl.
2. a kind of stable multifunctional cosmetic composition according to claim 1, it is characterized in that: the content of described methacrylic acid is counted 25%-75% with this total polymer weight, is preferably 35%-60%; The content of acrylic acid ester is 20-80%, preferred 35%-60%.
3. a kind of stable multifunctional cosmetic composition according to claim 1 and 2, it is one of following to it is characterized in that described acrylic acid ester is selected from: acrylic acid methyl ester., acrylic acid ethyl ester, butyl acrylate, preferred butyl acrylate.
4. a kind of stable multifunctional cosmetic composition according to claim 1 and 2 is characterized in that: describedly contain close silicone oil organosilicon radical for containing the vinyl organosilicon monomer, it can be a structural formula
Organic silicon monomer:
R wherein
1Be CH
3Or H, R
2Be C1～C4; Perhaps
——(CH
2CH
2O)
XCH
3
X=1～5 wherein; Perhaps
Wherein, R
3Be CH
3Or H, R
4Be C1～C4; Perhaps
The polysiloxane of other vinyl modification, wherein preferred vinyl triethoxysilane; Described close silicone oil organosilicon radical constituent content is counted 0.01%-2% with this total polymer weight, is preferably 0.05%-0.20%.
5. a kind of stable multifunctional cosmetic composition according to claim 1 and 2 is characterized in that: described oleophylic fat chain alkyl is long-chain alkyl methacrylates or long-chain aliphatic acrylate, its
Can be the following structural chemicals:
Wherein, R
5Be CH
3Or H, R
6Be C4～C30;
Wherein, preferable methyl dodecylacrylate, methacrylic acid cetyl ester, methacrylic acid stearyl, more preferably methacrylic acid stearyl; The content of described oleophylic fat chain alkyl is counted 0.01%-5% with this total polymer weight, preferred 0.05%-1%.
6. a kind of stable multifunctional cosmetic composition according to claim 1 and 2 is characterized in that: also comprise surfactant, conditioner, cationic polymer, other insoluble component and suitable quantity of water.
7. a kind of stable multifunctional cosmetic composition according to claim 1 and 2, it is characterized in that: described surfactant comprises but is not limited to: ammonium lauryl sulfate, cocoyl ammonium sulfate, lauryl potassium sulfate, the cocoyl potassium sulfate, sodium lauryl sulfate, cocoyl sodium sulfate, lauryl sulfate monoethanolamine, cocoyl sulphuric acid monoethanolamine, lauryl sulfate monoethanolamine, cocoyl sulphuric acid monoethanolamine, lauryl polyethenoxy ether sodium sulfate, the laureth potassium sulfate, sodium laureth sulfate, laureth sulphuric acid monoethanolamine, laureth sulphuric acid triethanolamine, the N-disodium octadecyl sulfosuccinate; Lauryl sulphur disodium succinate, lauryl propylhomoserin sodium, cocos nucifera oil acyl aminopropyl betanin, lauryl dimethyl betanin, coco dimethyl third sulfobetaines, cocos nucifera oil both sexes carboxyl Glycine sodium, C14-16 sodium olefin sulfonate, lauryl amine oxide, cocos nucifera oil amidoamines propyl group amine oxide, alkyl-glucoside; The preferred ammonium lauryl sulfate of wherein said surfactant, laureth sulphuric acid triethanolamine, lauryl polyethenoxy ether sodium sulfate, lauryl sulfate monoethanolamine, cocos nucifera oil acyl aminopropyl betanin, lauryl amine oxide, lauryl disodium sulfosuccinate; Most preferably lauryl polyethenoxy ether sodium sulfate, ammonium lauryl sulfate, cocos nucifera oil acyl aminopropyl betanin; The content of described surfactant is 5% to 50% (w/w), is preferably 6% to 40% (w/w), more preferably 8% to 35% (w/w), more preferably 10% to 30% (w/w), most preferably 12% to 25% (w/w).
8. a kind of stable multifunctional cosmetic composition according to claim 1 and 2, it is characterized in that, described conditioner is to be selected from the following group one or more: polysiloxanes and derivant thereof, such as hydrocarbon ils, polyolefin, fatty ester, as organic conditioning oils of paraffinic oils, mineral oil, isostearic acid isopropyl ester, maleic acid Semen Ricini grease, olive oil, almond oil; The consumption of described conditioner is at 0.01% to 20.0% (w/w), preferably in 0.05% to 10.0% (w/w) scope, more preferably in 0.1% to 5.0% (w/w) scope, most preferably at 0.2% to 4.0% (w/w).
9. a kind of stable multifunctional cosmetic composition according to claim 1 and 2, it is characterized in that described cationic polymer is selected from one or more in the following group: cation guar gum, polyquaternary ammonium salt-2, polyquaternary ammonium salt-4, polyquaternary ammonium salt-7, polyquaternary ammonium salt-10, polyquaternary ammonium salt-11,, SalcareSC60, Salcare SC96; Preferred cationic guar gum, polyquaternary ammonium salt-4, polyquaternary ammonium salt-7, polyquaternary ammonium salt-10; Optimum polyquaternary ammonium salt-10; The addition of described cationic polymer is in the scope of 0.01%-10.0% (w/w), preferably in the scope of 0.02%-4.0% (w/w), more preferably in the scope of 0.05%-3.0% (w/w), most preferably in the scope of 0.1%-1.0% (w/w).
10. a kind of stable multifunctional cosmetic composition according to claim 1 and 2 is characterized in that, described other insoluble component includes but not limited to following several:
Anti-dandruff dose, include but not limited in the following material one or more: carboxyl pyridine ketone slaine, ketoconazole, miconazole, Octopirox, IPBC, climbazole, selenium sulfide, sulfur coal tar; Preferred anti-dandruff dose is Zinc Pyrithione, ketoconazole, Octopirox, climbazole; Preferred anti-dandruff dose of Zinc Pyrithione, ketoconazole, Octopirox; Gross weight based on compositions, anti-dandruff dose effective dose is in 0.01% to 10.0% (w/w) scope, preferably in 0.02% to 5.0% (w/w) scope, more preferably in 0.04% to 4.0% (w/w) scope, more preferably in 0.05% to 3.0% (w/w) scope, further preferably in 0.1% to 2.0% (w/w) scope;
The pearly-lustre material, comprise the Muscovitum that is coated with titanium dioxide, the Muscovitum that is coated with ferrum oxide, ethylene glycol monostearate, glycol distearate, polyglycol distearate, the Muscovitum that is coated with bismuth oxychloride, myristyl myristate, guanine, glitter and composition thereof; In the gross weight of stable compositions, the use amount of pearly-lustre material is 0.05wt% to 10wt%, preferably 0.15wt% to 3wt%.
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|---|---|---|---|
| CN200910046115A CN101804014A (en) | 2009-02-12 | 2009-02-12 | Stable multifunctional cosmetic composition |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103415324A (en) * | 2011-03-10 | 2013-11-27 | 荷兰联合利华有限公司 | Composition |
| CN103547316A (en) * | 2011-01-10 | 2014-01-29 | 道康宁公司 | Personal care and health care compositions |
| US8771377B2 (en) | 2011-03-10 | 2014-07-08 | Conopco, Inc. | Hair care composition comprising pyrithione and a purple, pink or red colouring component |
| US8778318B2 (en) | 2011-03-10 | 2014-07-15 | Conopco, Inc. | Hair care composition comprising pyrithione and a pearliser system based on bismuth oxychloride |
| CN106835714A (en) * | 2017-02-19 | 2017-06-13 | 邵阳阳光发品有限公司 | A kind of human hair fiber process after-treating auxiliary |
| CN113645940A (en) * | 2019-04-04 | 2021-11-12 | 花王株式会社 | Multilayer composition |
| CN115551466A (en) * | 2020-06-25 | 2022-12-30 | 科丝美诗株式会社 | Cationic cosmetic composition for enhancing makeup adhesion and preventing adhesion |
-
2009
- 2009-02-12 CN CN200910046115A patent/CN101804014A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103547316A (en) * | 2011-01-10 | 2014-01-29 | 道康宁公司 | Personal care and health care compositions |
| CN103415324A (en) * | 2011-03-10 | 2013-11-27 | 荷兰联合利华有限公司 | Composition |
| US8771377B2 (en) | 2011-03-10 | 2014-07-08 | Conopco, Inc. | Hair care composition comprising pyrithione and a purple, pink or red colouring component |
| US8778318B2 (en) | 2011-03-10 | 2014-07-15 | Conopco, Inc. | Hair care composition comprising pyrithione and a pearliser system based on bismuth oxychloride |
| CN103415324B (en) * | 2011-03-10 | 2016-04-20 | 荷兰联合利华有限公司 | Comprise the hair care composition of pyrithione and the pearling agent system based on bismuth oxychloride |
| CN106835714A (en) * | 2017-02-19 | 2017-06-13 | 邵阳阳光发品有限公司 | A kind of human hair fiber process after-treating auxiliary |
| CN113645940A (en) * | 2019-04-04 | 2021-11-12 | 花王株式会社 | Multilayer composition |
| CN113645940B (en) * | 2019-04-04 | 2024-02-23 | 花王株式会社 | Multi-layer composition |
| CN115551466A (en) * | 2020-06-25 | 2022-12-30 | 科丝美诗株式会社 | Cationic cosmetic composition for enhancing makeup adhesion and preventing adhesion |
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Application publication date: 20100818 |