Summary of the invention
Deficiency for hair caring approved product before overcoming the purpose of this invention is to provide a kind of hair dressing composition that contains cationic polymer, and it not only has styling but also the effect that makes hair submissive and bright is arranged.
The object of the present invention is achieved like this: a kind of hair dressing composition that contains cationic polymer, and count by weight percentage prescription and comprise:
(1) 0.05% to 20% water solublity setting agent; (2) 0.1% to 20% cationic polymer; (3) 1% to 20% interior phase viscosity is that 5CST~10000CST siloxanes, interior phase viscosity are the organic conditioning oil of 5CST~200CST or its compositions; (4) 0.2%~9% higher alcohol; (5) water surplus.
Described water solublity setting agent is selected from one or both of PVP, polyvinyl pyrrolidone or polyvinyl pyrrolidone/dimethylamino-propyl methacrylamide copolymer.
Described cationic polymer is selected from one or both of polyacrylate-1 cross linked polymer or alkylamide propyl trimethyl ammonium chloride/acrylamide copolymer.
Phase viscosity was the mineral oil of 5CST~200CST, one or more mixing in the saturated or unsaturated alkane in described organic conditioning grease separation was done for oneself.
Described higher alcohol is selected from that to have carbon number be 14~24 saturated, the undersaturated side chain or the alcohol of straight chain.
The present invention not only styling is superior, and uses hair conditioning submissive effect in back obvious, and glossiness significantly improves.
The specific embodiment
The present invention is a kind of hair dressing composition that contains cationic polymer, counts by weight percentage prescription and comprises: (1) 0.05% to 20% water solublity setting agent; (2) 0.1% to 20% cationic polymer; (3) 1% to 20% interior phase viscosity is that 5CST~10000CST siloxanes, interior phase viscosity are the organic conditioning oil of 5CST~200CST or its compositions; (4) 0.2%~9% higher alcohol (5) water surplus.
Below component of the present invention and effect are described.
The content of water solublity setting agent in compositions about 0.05% described in the present invention is to about 20%, and its preferred content about 0.05% is to about 10%, and it is content about 0.05% to about 5% more preferably.Be fit to water solublity setting agent of the present invention and be selected from PVP or polyvinyl pyrrolidone, it is a kind of water miscible polyamide, for example the LUVISKOL K-30 of the PVP K-15 of ISP company, PVP K-30, PVP K-60, PVP K-90, PVP K-120, BASF AG, LUVISKOL K-80, LUVISKOL K-90), PVP/VA is PVP/VA S-635, the W-735 of ISP company for example, the LUVISKOL VA-64 of BASF AG, LUVISKOL VA-73W).Polyvinyl pyrrolidone/dimethylamino-propyl methacrylamide copolymer is the STYLEZE CC-10 of ISP company for example, preferred water dissolubility setting agent PVP or polyvinyl pyrrolidone.
The content of cationic polymer described in the present invention in compositions about 0.1% is to about 20%, and its preferred content about 0.1% is to about 10%, and it is content about 0.1% to about 5% more preferably.Be fit to cationic polymer of the present invention and be selected from polyacrylate-1 cross linked polymer Polyquaternium-37 (the Salcare SC96 of Ciba company, Salcare SC95, the Synthalen CR of 3V SIGMA company), Polyquaternium-6 (the Salcare SC30 of Ciba company), Carbopol Aqua CC (Noveon company), alkylamide propyl trimethyl ammonium chloride/acrylamide copolymer Polyquaternium-7 (the Salcare SC10 of Ciba company, Salcare SC11, Salcare Super 7), Polyquaternium-10 (the UCARE series of polymers of Amerchol company: JR-125, JR-400, LR-400, LR-30M), Polyquaternium-32 (the Salcare SC92 of Ciba company), Salcare SC60 (Ciba company), the preferred cation polymer is: polyacrylate-1 cross linked polymer Polyquaternium-37, alkylamide propyl trimethyl ammonium chloride/acrylamide copolymer Polyquaternium-10.
It is the polydimethylsiloxane of 5CS~500000CS that siloxanes described in the present invention is selected to interior phase viscosity, phase viscosity was the polydimethylsiloxane of 5CS~50000 CS in it was preferred, more preferably interior phase viscosity is the polydimethylsiloxane of 10CS~10000 CS, it is liquid and is hydrophobic, when being coated on the hair both nonirritants, avirulence, for example non-volatile poly-alkylsiloxane liquid (Dow Corning 200 series of Dow Corning Corporation and Viscasil R and the SF96 series of General ElectricCompany), PSI (SF1075 of the Dow Corning 556 of Dow Corning Corporation and General Electric Company), amino-terminated polydimethylsiloxane, hexadecyltrimethylammonium chloride and tridecyl polyoxyethylene ether-12 (the Dow Corning 949 of Dow Corning Corporation).
Phase viscosity was 5CS~200CS in organic conditioning grease separation described in the present invention was done for oneself, phase viscosity was organic conditioning oil of 5CS~100CS in it was preferred, more preferably interior phase viscosity is organic conditioning oil of 5CS~50CS, the organic conditioning oil that is suitable as conditioner of the present invention is hydrocarbon ils preferably, hydrocarbon ils concrete non-limiting is selected from a kind of in paraffin oil, mineral oil, the saturated/undersaturated alkane or their mixture, preferred mineral oil, saturated/undersaturated alkane, for example white mineral oil on the market and isomery dodecane, the isomery tetradecane, isomery hexadecane.
For the submissive effect of the conditioning that improves product, add higher alcohol in the present invention with opsonic action, higher alcohol described in the present invention is selected from that to have carbon number be 14~24 saturated, undersaturated side chain or the alcohol of straight chain, for example one or more in hexadecanol, octadecanol, stearyl alcohol, EICOSANOL, tadenan, tetracosanol, isooctadecanol, 2-octyldodecanol, the 2-hexyldecanol.Preferably from the mixture of hexadecanol and octadecanol, wherein the ratio of hexadecanol and octadecanol is 20: 80~80: 20, preferably from 30: 70~70: 30.Higher alcohol is about 0.2%~9%wt in compositions, preferably from the 0.5%~3%wt that accounts for composition total weight, for example mixture of the hexadecanol of Kening Co.,Ltd and octadecanol.
Also have an appointment in the hair dressing composition that contains cationic polymer of the present invention 50% to about 80% deionized water and an amount of antiseptic, toner, chela mediating recipe, essence etc.
Embodiment
Be the limiting examples that contains the hair dressing composition of cationic polymer of the present invention below, without prejudice to category of the present invention, can change the present invention, in following example, not have all concentration of specified otherwise all to count by weight percentage each preparation of compositions such as table 1.
Table 1
|
Comparison example 1 |
Embodiment 2 |
Embodiment 3 |
Embodiment 4 |
Embodiment 5 |
Embodiment 6 |
Embodiment 7 |
Deionized water |
To 100 |
To 100 |
To 100 |
To 100 |
To 100 |
To 100 |
To 100 |
Polyacrylate-1 cross linked polymer (1) |
|
??0.5 |
??1 |
??1.5 |
??1.5 |
??2 |
??2 |
Polyquaternary ammonium salt-10 |
?0.4 |
??0.3 |
??0.3 |
??0.3 |
??0.2 |
??0.2 |
??0.2 |
Polydimethylsiloxane (2) |
|
??4 |
??3 |
??5 |
??4 |
??3 |
??2 |
??SF1075 |
|
??6 |
??6 |
??7 |
??7 |
??7 |
??7 |
Polyquaternary ammonium salt-7 |
|
|
|
|
|
|
|
The isomery dodecane |
?3 |
??3 |
??4 |
??4 |
??2 |
??2 |
??2 |
??DC?949 |
|
??2 |
??2 |
??2 |
??2 |
??2 |
??1 |
??PVPK-90 |
?5 |
??5 |
??4 |
??4 |
??4 |
??3 |
??3 |
16/octadecanol |
|
??0.2 |
??0.5 |
??0.8 |
??0.8 |
??1.0 |
??1.0 |
Antiseptic, chela mediating recipe, essence |
In right amount |
In right amount |
In right amount |
In right amount |
In right amount |
In right amount |
In right amount |
(continuous table 1)
|
Embodiment 8 |
Embodiment 9 |
Embodiment 10 |
Embodiment 11 |
Embodiment 12 |
Embodiment 13 |
Embodiment 14 |
Deionized water |
To 100 |
To 100 |
To 100 |
To 100 |
To 100 |
To 100 |
To 100 |
Polyacrylate-1 cross linked polymer (1) |
??2.5 |
??3.5 |
??3 |
??3.5 |
??4 |
??4.5 |
|
Polyquaternary ammonium salt-10 |
|
??0.1 |
??0.1 |
|
|
|
|
Polydimethylsiloxane (2) |
??3 |
??4 |
??3 |
??5 |
??4 |
??3 |
??2 |
??SF1075 |
??5 |
??6 |
??6 |
??7 |
??7 |
??7 |
??7 |
Polyquaternary ammonium salt-7 (3) |
??0.3 |
??0.5 |
??0.4 |
??0.1 |
??0.2 |
??0.3 |
??0.1 |
The isomery dodecane |
??3 |
??3 |
??4 |
??4 |
??2 |
??2 |
??2 |
??DC?949 |
??2 |
??2 |
??2 |
??2 |
??2 |
??2 |
??1 |
??PVP?K-90 |
??2 |
??3 |
??3 |
??2 |
??1.5 |
??0.05 |
??0.1 |
16/octadecanol |
??1.2 |
??1.2 |
??1.8 |
??2.0 |
??3.0 |
??6.0 |
??9.0 |
|
Embodiment 8 |
Embodiment 9 |
Embodiment 10 |
Embodiment 11 |
Embodiment 12 |
Embodiment 13 |
Embodiment 14 |
Antiseptic, chela mediating recipe, essence |
In right amount |
In right amount |
In right amount |
In right amount |
In right amount |
In right amount |
In right amount |
(1) is selected from the Salcare SC96 of Ciba company
(2) be selected from the Dow Corning200 of Dow Corning Corporation
(3) be selected from the JR-400 of Amerchol company
Preparation method: an amount of water is joined in the emulsifying pot, add polyacrylate-1 cross linked polymer, polyquaternary ammonium salt aqueous solution, the abundant mix homogeneously of PVP K-90 aqueous solution successively, and then add after polydimethylsiloxane, SF1075, isomery dodecane, DC 949 make its mix homogeneously, add antiseptic, chela mediating recipe, essence and remaining deionized water at last, stir and get final product.
Above 14 examples of test and appraisal are assessed by the assessment panel that 30 people form, evaluation grade 1~3 for poor, 3~5 be generally, 5~7 for well, 7~9 be fine.The results are shown in Table 2.
Table 2
|
Comparison example 1 |
Embodiment 2 |
Embodiment 3 |
Embodiment 4 |
Embodiment 5 |
Embodiment 6 |
Embodiment 7 |
Compliance |
?5.5 |
??7.7 |
??7.8 |
??7.7 |
??7.9 |
??7.8 |
??8.2 |
Curling persistency |
?8.7 |
??8.5 |
??8.3 |
??8.2 |
??8.4 |
??8.5 |
??8.3 |
Glossiness |
?4.9 |
??7.2 |
??7.5 |
??7.7 |
??7.9 |
??7.5 |
??8.2 |
The white scales degree of control |
?5.7 |
??7.1 |
??6.8 |
??7.2 |
??6.9 |
??6.7 |
??7.3 |
Repeat typing power |
?8.5 |
??8.2 |
??8.2 |
??8.7 |
??8.5 |
??8.6 |
??8.4 |
Be difficult for being stained with ash |
?8.3 |
??8.1 |
??7.9 |
??8.0 |
??8.2 |
??8.4 |
??8.7 |
The protectiveness of hair |
?8.9 |
??8.6 |
??8.1 |
??8.6 |
??8.7 |
??8.3 |
??8.8 |
(continuous table 2)
|
Embodiment 8 |
Embodiment 9 |
Embodiment 10 |
Embodiment 11 |
Embodiment 12 |
Embodiment 13 |
Embodiment 14 |
Compliance |
??8.5 |
??8.1 |
??8.5 |
??8.7 |
??8.9 |
??8.8 |
??8.2 |
Curling persistency |
??7.7 |
??7.5 |
??7.8 |
??7.2 |
??6.4 |
??4.5 |
??4.3 |
Glossiness |
??7.9 |
??8.2 |
??8.5 |
??8.7 |
??8.9 |
??8.5 |
??8.7 |
The white scales degree of control |
??7.7 |
??7.6 |
??7.8 |
??8.2 |
??8.5 |
??8.7 |
??8.8 |
Repeat typing power |
??8.5 |
??8.2 |
??7.6 |
??5.7 |
??5.5 |
??4.6 |
??4.4 |
Be difficult for being stained with ash |
??8.5 |
??8.7 |
??8.9 |
??8.5 |
??8.6 |
??8.4 |
??8.5 |
The protectiveness of hair |
??8.5 |
??8.6 |
??8.4 |
??8.7 |
??8.7 |
??8.6 |
??8.4 |
Embodiment of the present invention and embodiment only are illustrative, and in the case without departing from the scope of the present invention, one of skill in the art can carry out various changes and variation to it.