CN101781844B - Finishing agent for restoring pH value of fabrics as well as preparation method and application thereof - Google Patents
Finishing agent for restoring pH value of fabrics as well as preparation method and application thereof Download PDFInfo
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- CN101781844B CN101781844B CN2010101179985A CN201010117998A CN101781844B CN 101781844 B CN101781844 B CN 101781844B CN 2010101179985 A CN2010101179985 A CN 2010101179985A CN 201010117998 A CN201010117998 A CN 201010117998A CN 101781844 B CN101781844 B CN 101781844B
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- repair
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- 239000004744 fabric Substances 0.000 title claims abstract description 64
- 238000002360 preparation method Methods 0.000 title claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 67
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims abstract description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000001103 potassium chloride Substances 0.000 claims abstract description 24
- 235000011164 potassium chloride Nutrition 0.000 claims abstract description 24
- IWZKICVEHNUQTL-UHFFFAOYSA-M potassium hydrogen phthalate Chemical compound [K+].OC(=O)C1=CC=CC=C1C([O-])=O IWZKICVEHNUQTL-UHFFFAOYSA-M 0.000 claims abstract description 24
- 239000004094 surface-active agent Substances 0.000 claims abstract description 11
- 238000001035 drying Methods 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000004753 textile Substances 0.000 claims description 40
- 230000008439 repair process Effects 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 12
- ANBZTKMYPDMODS-YPKPFQOOSA-N (z)-n,n-diethyloctadec-9-enamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N(CC)CC ANBZTKMYPDMODS-YPKPFQOOSA-N 0.000 claims description 8
- 239000012224 working solution Substances 0.000 claims description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 239000003085 diluting agent Substances 0.000 claims description 4
- 150000001408 amides Chemical class 0.000 claims description 2
- 238000009776 industrial production Methods 0.000 abstract 1
- 229920000742 Cotton Polymers 0.000 description 27
- 238000004519 manufacturing process Methods 0.000 description 12
- 239000000203 mixture Substances 0.000 description 10
- 230000002950 deficient Effects 0.000 description 6
- 239000003643 water by type Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 4
- 239000000975 dye Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 150000004982 aromatic amines Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 230000037311 normal skin Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 206010063409 Acarodermatitis Diseases 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 206010010219 Compulsions Diseases 0.000 description 1
- 201000004624 Dermatitis Diseases 0.000 description 1
- 241001272567 Hominoidea Species 0.000 description 1
- 241000447727 Scabies Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 208000005687 scabies Diseases 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a finishing agent for restoring the pH value of fabrics, which comprises the following raw materials in percentage by weight: 0.5-12 percent of potassium hydrogen phthalate, 2-30 percent of potassium chloride, 0.5-8 percent of surfactant and the balance of water. By using the finishing agent, the fabrics with the pH value exceeding 7.5 can be restored to have the pH value in range of 4.0-7.5 through simple padding and drying without influencing other qualities of the fabrics, thereby the requirements on the safety technical specification and export can be met. The invention also discloses a preparation method and application of the finishing agent, and has the advantages of simple operation and suitability for industrial production.
Description
Technical field
The present invention relates to the textile finishing technical field, particularly a kind of finishing agent that is used to repair pH value of fabrics.
Background technology
The pH value of human body normal skin is faintly acid between 5.5～7.0, to guarantee the balance of resident bacterium, suppress the intrusion of germ.If the pH value of the pH value of textiles and human body normal skin has big difference, then can produce skin stimulates, and causes diseases such as the skin scabies is overworked, dermatitis, especially serious to infant's influence.For protecting human body skin safety and ensureing health, also for catering to the security requirement of international market, enlarge the outlet of China's textiles simultaneously to textiles, the strict pH value of controlling textiles seems very important.
(A, category-B textiles require pH=4.0～7.5 to the pH value of state compulsion standard GB 18401-2003 " national textile product basic security technical specification " regulation; C class textiles requires pH=4.0～9.0), COLOR FASTNESS, content of formaldehyde, peculiar smell, can decompose in five big types of test items of aromatic amine dyestuff; In the majority because of the underproof textiles of pH value, wherein the pH value surpasses occupying the majority again of 7.5 (to A, category-Bs) or 9.0 (to the C classes).Cause the underproof main cause of pH value of fabrics to be: textiles has used a large amount of dye addictives in production processes such as destarch, kiering, bleaching, dyeing (stamp) and back arrangement after, because of washing insufficient or washing or the pH of industrial water own are not defective causes the textiles pollution.At present, the method for washing is adopted in the processing of the defective textiles of pH value mostly, but the pH value of many textiless after washing once even repeatedly still do not reach qualified requirement, also possibly influence original qualities such as coloured light of textiles.This just need ward off a science and solution route easily in addition.
Summary of the invention
The present invention is directed to the defective that exists in the existing defective method for treating textile of pH value; A kind of finishing agent that is used to repair pH value of fabrics is provided; Answer used additives to put in order and repair the defective textiles of pH value; Under the prerequisite that does not influence other quality of textiles, can make the pH value surpass 7.5 textiles and only need simply pad oven dry and can guarantee that the pH value repairs in 4.0～7.5 scopes, reach the requirement of technical specification of security and outlet.
A kind of finishing agent that is used to repair pH value of fabrics, form by following raw materials by weight percent:
Potassium Hydrogen Phthalate 0.5%～12%;
Potassium chloride 2%～30%;
Surfactant 0.5%～8%;
Water surplus.
Described Potassium Hydrogen Phthalate mainly is to play the pH cushioning effect in finishing agent, and its molecular formula is C
8H
5KO
4, structural formula is following:
Described potassium chloride (KCl) is mainly used in the adjusting ionic strength in finishing agent, can make the pH measured value of textiles water extract more stable.
Described surfactant mainly has been osmosis in finishing agent; Can make auxiliary agent more evenly soak into textiles apace; Can select this area surfactant commonly used for use; In preferred fat alcohol APEO series, the fatty diglycollic amide non-ionic surface active agent one or more, for example paregal O, oleic acid diethyl amide etc. can be selected the commercially available prod for use.
The present invention also provides a kind of preparation method who is used to repair the finishing agent of pH value of fabrics, and it is simple to operate, need not special devices, is suitable for suitability for industrialized production.
A kind of preparation method who is used to repair the finishing agent of pH value of fabrics comprises step:
Potassium Hydrogen Phthalate, potassium chloride, surfactant dissolves in water, are mixed, promptly be mixed with the finishing agent that is used to repair pH value of fabrics.
Described finishing agent can be used for repairing pH value of fabrics, and the application process of using this finishing agent reparation pH value of fabrics may further comprise the steps at least:
(1) with finishing agent or with the solution of finishing agent after with diluent as the finishing agent working solution;
(2) textiles is padded in the finishing agent working solution;
(3) drying textile after will padding has been repaired the textiles of pH value.
Textiles through above-mentioned steps reparation arrangement can make its pH value stabilization be controlled at 4.0～7.5.
Described diluent can be selected from one or more in water, ethanol, isopropyl alcohol, the ethylene glycol, preferred water.
The pick-up rate of the textiles after described the padding is 30%～200%, preferred 50%～120%; Wherein, pick-up rate (also being pick-up or liquid carrying rate) is meant the percentage of the finishing agent working solution that has on the textiles after padding and the ratio of textiles dry weight.
Described baking temperature does not have special qualification, is as the criterion and gets final product textiles is dried and can not damage textiles, is generally 10 ℃～200 ℃; Can adopt air dry; As at room temperature carry out nature and dry, also can carry out drying, when adopting oven drying through baking oven; Temperature is generally 40 ℃～200 ℃, preferred 80～120 ℃.The dry time does not have special restriction yet, and the time dry when general temperature is low is longer, and drier time of temperature is shorter, to guarantee that textiles is not damaged.
Of the present invention pad be this area commonly used pad method; Be generally with textiles in the finishing agent working solution through behind the of short duration dipping; In padding machine, use roll roll compacting immediately; The finishing agent working solution is clamp-oned organizing in the space of textiles, and remove unnecessary finishing agent working solution, finishing agent is evenly distributed on the textiles.
The present invention has following advantage:
The used key component of finishing agent that the present invention is used to repair pH value of fabrics all is the raw material components of using always, and it does not contain formaldehyde, can decompose non-environmental protection compositions such as aromatic amine dyestuff, heavy metal element and APES.Simultaneously; Utilize finishing agent of the present invention only need adopt existing conventional equipment and finishing technique; Carry out simple solution and prepare-pad-dry run, just can reach the reparation of the pH value of defective textiles 4.0～7.5 requirement, and can not influence original quality of textiles.
Finishing agent and application process that the present invention is used to repair pH value of fabrics are applicable to all textiless, and can in time adjust the prescription and the technique for applying of finishing agent as required, make things convenient for suitability for industrialized production.
The pH value repairing effect of finishing agent of the present invention is good, and cost is low, and efficient is high, is a kind of environment-protecting clean after-finishing of textile products agent that is easy to application.
The specific embodiment
Embodiment 1
Table 1 prescription 1
| Component | g |
| Potassium Hydrogen Phthalate | 10 |
| Potassium chloride | 10 |
| Paregal O-15 (production of Hangzhou etherealize worker of a specified duration Co., Ltd) | 2 |
| Water | 78 |
Press the prescription 1 in the table 1, Potassium Hydrogen Phthalate, potassium chloride, paregal O-15 are dissolved in the water, mix, promptly be mixed with the finishing agent that is used to repair pH value of fabrics.
With above-mentioned 4 times of the finishing agent dilute with waters that are used to repair pH value of fabrics that make, direct padding finishing pure cotton fabric at room temperature, and keep pick-up rate 100%, then 105 ℃ dry 3 minutes down.Adopting GB/T 7573-2002 standard to record through the pure cotton fabric pH value of repairing arrangement is 6.57 (the former pH value of pure cotton fabric without finishing agent reparation arrangement is 9.91).
Embodiment 2
Table 2 prescription 2
| Component | g |
| Potassium Hydrogen Phthalate | 7.5 |
| Potassium chloride | 10 |
| Paregal O-15 (production of Hangzhou etherealize worker of a specified duration Co., Ltd) | 2.5 |
| Water | 80 |
Press the prescription 2 in the table 2, Potassium Hydrogen Phthalate, potassium chloride, paregal O-15 are dissolved in the water, mix, promptly be mixed with the finishing agent that is used to repair pH value of fabrics.
The above-mentioned finishing agent that is used to repair pH value of fabrics that makes is not diluted, direct padding finishing pure cotton fabric at room temperature, and keep pick-up rate 80%, then 105 ℃ dry 3 minutes down.Adopting GB/T 7573-2002 standard to record through the pure cotton fabric pH value of repairing arrangement is 4.28 (the former pH value of pure cotton fabric without finishing agent reparation arrangement is 9.70).
Embodiment 3
Table 3 prescription 3
| Component | g |
| Potassium Hydrogen Phthalate | 7 |
| Potassium chloride | 8 |
| Paregal O-20 (production of Hangzhou etherealize worker of a specified duration Co., Ltd) | 2 |
| Water | 83 |
Press the prescription 3 in the table 3, Potassium Hydrogen Phthalate, potassium chloride, paregal O-20 are dissolved in the water, mix, promptly be mixed with the finishing agent that is used to repair pH value of fabrics.
With above-mentioned 3 times of the finishing agent dilute with waters that are used to repair pH value of fabrics that make, direct padding finishing pure cotton fabric at room temperature, and keep pick-up rate 100%, then 105 ℃ dry 4 minutes down.Adopting GB/T 7573-2002 standard to record through the pure cotton fabric pH value of repairing arrangement is 4.96 (the former pH value of pure cotton fabric without finishing agent reparation arrangement is 8.11).
Embodiment 4
Table 4 prescription 4
| Component | g |
| Potassium Hydrogen Phthalate | 4 |
| Potassium chloride | 12 |
| Paregal O-20 (production of Hangzhou etherealize worker of a specified duration Co., Ltd) | 3 |
| Water | 81 |
Press the prescription 4 in the table 4, Potassium Hydrogen Phthalate, potassium chloride, paregal O-20 are dissolved in the water, mix, promptly be mixed with the finishing agent that is used to repair pH value of fabrics.
With above-mentioned 2 times of the finishing agent dilute with waters that are used to repair pH value of fabrics that make, direct padding finishing pure cotton fabric at room temperature, and keep pick-up rate 70%, then 90 ℃ dry 4 minutes down.Adopting GB/T 7573-2002 standard to record through the pure cotton fabric pH value of repairing arrangement is 5.51 (the former pH value of pure cotton fabric without finishing agent reparation arrangement is 7.55).
Embodiment 5
Table 5 prescription 5
| Component | g |
| Potassium Hydrogen Phthalate | 1 |
| Potassium chloride | 15 |
| Paregal O-25 (production of Hangzhou etherealize worker of a specified duration Co., Ltd) | 1 |
| Water | 83 |
Press the prescription 5 in the table 5, Potassium Hydrogen Phthalate, potassium chloride, paregal O-25 are dissolved in the water, mix, promptly be mixed with the finishing agent that is used to repair pH value of fabrics.
The above-mentioned finishing agent that is used to repair pH value of fabrics that makes is not diluted, direct padding finishing pure cotton fabric at room temperature, and keep pick-up rate 110%, then 110 ℃ dry 5 minutes down.Adopting GB/T 7573-2002 standard to record through the pure cotton fabric pH value of repairing arrangement is 7.25 (the former pH value of pure cotton fabric without finishing agent reparation arrangement is 10.69).
Embodiment 6
Table 6 prescription 6
| Component | g |
| Potassium Hydrogen Phthalate | 0.5 |
| Potassium chloride | 30 |
| Oleic acid diethyl amide (production of Hai'an, Jiangsu petrochemical plant) | 1.5 |
| Water | 68 |
Press the prescription 6 in the table 6, Potassium Hydrogen Phthalate, potassium chloride, oleic acid diethyl amide are dissolved in the water, mix, promptly be mixed with the finishing agent that is used to repair pH value of fabrics.
The above-mentioned finishing agent that is used to repair pH value of fabrics that makes is not diluted, direct padding finishing pure cotton fabric at room temperature, and keep pick-up rate 60%, air dry at room temperature then.Adopting GB/T 7573-2002 standard to record through the pure cotton fabric pH value of repairing arrangement is 6.59 (the former pH value of pure cotton fabric without finishing agent reparation arrangement is 7.55).
Embodiment 7
Table 7 prescription 7
| Component | g |
| Potassium Hydrogen Phthalate | 2.5 |
| Potassium chloride | 20 |
| Paregal O-25 (production of Hangzhou etherealize worker of a specified duration Co., Ltd) | 0.5 |
| Water | 77 |
Press the prescription 7 in the table 7, Potassium Hydrogen Phthalate, potassium chloride, paregal O-25 are dissolved in the water, mix, promptly be mixed with the finishing agent that is used to repair pH value of fabrics.
The above-mentioned finishing agent that is used to repair pH value of fabrics that makes is not diluted, direct padding finishing pure cotton fabric at room temperature, and keep pick-up rate 105%, then 120 ℃ dry 4.5 minutes down.Adopting GB/T 7573-2002 standard to record through the pure cotton fabric pH value of repairing arrangement is 6.48 (the former pH value of pure cotton fabric without finishing agent reparation arrangement is 9.91).
Embodiment 8
Table 8 prescription 8
| Component | g |
| Potassium Hydrogen Phthalate | 12 |
| Potassium chloride | 2 |
| Oleic acid diethyl amide (production of Hai'an, Jiangsu petrochemical plant) | 6 |
| Water | 80 |
Press the prescription 8 in the table 8, Potassium Hydrogen Phthalate, potassium chloride, oleic acid diethyl amide are dissolved in the water, mix, promptly be mixed with the finishing agent that is used to repair pH value of fabrics.
With above-mentioned 4 times of the finishing agent dilute with waters that are used to repair pH value of fabrics that make, direct padding finishing pure cotton fabric at room temperature, and keep pick-up rate 50%, air dry at room temperature then.Adopting GB/T 7573-2002 standard to record through the pure cotton fabric pH value of repairing arrangement is 6.76 (the former pH value of pure cotton fabric without finishing agent reparation arrangement is 10.69).
Embodiment 9
Table 9 prescription 9
| Component | g |
| Potassium Hydrogen Phthalate | 7 |
| Potassium chloride | 7 |
| Oleic acid diethyl amide (production of Hai'an, Jiangsu petrochemical plant) | 8 |
| Water | 78 |
Press the prescription 9 in the table 9, Potassium Hydrogen Phthalate, potassium chloride, oleic acid diethyl amide are dissolved in the water, mix, promptly be mixed with the finishing agent that is used to repair pH value of fabrics.
With above-mentioned 3 times of the finishing agent dilute with waters that are used to repair pH value of fabrics that make, direct padding finishing pure cotton fabric at room temperature, and keep pick-up rate 100%, then 105 ℃ dry 4 minutes down.Adopting GB/T 7573-2002 standard to record through the pure cotton fabric pH value of repairing arrangement is 5.08 (the former pH value of pure cotton fabric without finishing agent reparation arrangement is 8.11).
Claims (9)
1. a finishing agent that is used to repair pH value of fabrics is characterized in that, is made up of following raw materials by weight percent:
Potassium Hydrogen Phthalate 0.5%～12%;
Potassium chloride 2%～30%;
Surfactant 0.5%～8%;
Water surplus;
Described surfactant is selected from one or more in AEO, the fatty diglycollic amide non-ionic surface active agent.
2. finishing agent according to claim 1 is characterized in that described surfactant is selected paregal O or oleic acid diethyl amide for use.
3. the preparation method of finishing agent according to claim 1 is characterized in that, comprises step:
Potassium Hydrogen Phthalate, potassium chloride, surfactant dissolves in water, are mixed, promptly be mixed with the finishing agent that is used to repair pH value of fabrics.
4. finishing agent according to claim 1 is in the application of the pH value of repairing textiles.
5. finishing agent according to claim 4 may further comprise the steps at the application process of repairing pH value of fabrics:
(1) with finishing agent or with finishing agent with diluent after as the finishing agent working solution;
(2) textiles is padded in the finishing agent working solution;
The drying textile that (3) will pad has been repaired the textiles of pH value.
6. application process according to claim 5 is characterized in that described diluent is selected from one or more in water, ethanol, isopropyl alcohol, the ethylene glycol.
7. application process according to claim 5 is characterized in that, the pick-up rate of the described textiles that padded is 30%～200%.
8. application process according to claim 5 is characterized in that, the pick-up rate of the described textiles that padded is 50%～120%.
9. application process according to claim 5 is characterized in that, described baking temperature is 10 ℃～200 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101179985A CN101781844B (en) | 2010-03-04 | 2010-03-04 | Finishing agent for restoring pH value of fabrics as well as preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101179985A CN101781844B (en) | 2010-03-04 | 2010-03-04 | Finishing agent for restoring pH value of fabrics as well as preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101781844A CN101781844A (en) | 2010-07-21 |
| CN101781844B true CN101781844B (en) | 2012-01-25 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010101179985A Expired - Fee Related CN101781844B (en) | 2010-03-04 | 2010-03-04 | Finishing agent for restoring pH value of fabrics as well as preparation method and application thereof |
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|---|---|
| CN (1) | CN101781844B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101985807B (en) * | 2010-10-25 | 2012-01-25 | 浙江理工大学 | Finishing agent for regulating pH value of textile product, and preparation method and use thereof |
| CN107611323A (en) * | 2017-08-29 | 2018-01-19 | 苏州市苏真床垫有限公司 | A kind of composite lithium ion cell barrier film of nano-silicon dioxide modified polypropylene non-woven fabric and preparation method thereof |
| CN107574664A (en) * | 2017-08-29 | 2018-01-12 | 苏州市苏真床垫有限公司 | A kind of ventilative fire-retardant heat insulation polypropylene non-woven fabric and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB360402A (en) * | 1929-05-02 | 1931-10-26 | Solomon Farley Acree | Improvements in or relating to hydrogen ion standard buffer solutions |
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2010
- 2010-03-04 CN CN2010101179985A patent/CN101781844B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB360402A (en) * | 1929-05-02 | 1931-10-26 | Solomon Farley Acree | Improvements in or relating to hydrogen ion standard buffer solutions |
Non-Patent Citations (1)
| Title |
|---|
| 束舞云.如何控制纺织品服装的pH值.《中国纤检》.2006,(第9期),第32-33页. * |
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| CN101781844A (en) | 2010-07-21 |
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