CN101775351A - Novel vertical flexible covering film anaerobic fermentation device - Google Patents

Novel vertical flexible covering film anaerobic fermentation device Download PDF

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CN101775351A
CN101775351A CN201010107565A CN201010107565A CN101775351A CN 101775351 A CN101775351 A CN 101775351A CN 201010107565 A CN201010107565 A CN 201010107565A CN 201010107565 A CN201010107565 A CN 201010107565A CN 101775351 A CN101775351 A CN 101775351A
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water
anaerobic fermentation
tubing string
pipe
covering film
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张华�
张冲
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    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/04Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
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    • C12M23/00Constructional details, e.g. recesses, hinges
    • C12M23/26Constructional details, e.g. recesses, hinges flexible
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    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M23/00Constructional details, e.g. recesses, hinges
    • C12M23/34Internal compartments or partitions
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    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M27/00Means for mixing, agitating or circulating fluids in the vessel
    • C12M27/02Stirrer or mobile mixing elements
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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Abstract

The invention provides a novel vertical flexible covering film anaerobic fermentation device, comprising an anaerobic fermentation reactor and a flexible covering film fixed to the anaerobic fermentation reactor, wherein the anaerobic fermentation reactor is provided with, from bottom to top, a methane stirring device, a multipoint self-rotating water distributing device and a four-phase separator. The device is a novel vertical flexible covering film anaerobic fermentation device having the characteristics of: being low constant pressure and anaerobic, high-efficiency production of methane, long sludge age, low energy consumption and convenient operation and maintenance.

Description

Novel vertical flexible covering film anaerobic fermentation device
[technical field]
The present invention relates to a kind of anaerobic ferment devices, particularly a kind of novel vertical flexible covering film anaerobic fermentation device.
[background technology]
Continuous-stirring reactor (continuous stirred tank reactor) is called for short CSTR, is a kind of airtight groove type reactor that has whipping appts, is to use at most a kind of anaerobic ferment devices that the scope of application is the widest in the past.It is by the successive stirring action, make substrate and microorganism in the reactor be in complete admixture all the time, and newly advance raw material can be rapidly with reactor in whole fermented liquids mix, concentration of substrate keeps relatively low state, is specially adapted to the anaerobically fermenting of the stock liquid of higher suspension solids content.Material is evenly distributed in the CSTR anaerobic ferment devices, it is balanced to conduct heat, substrate contacts with microorganism well, and reaction is quick, efficient, and capacity of resisting impact load is strong, and there are not phenomenons such as the smooth and channel of scum silica frost crust, obstruction, gas evolution, but because HRT, SRT are equal fully with MRT, the feed liquid of discharge equates that with the concentration of substrate of fermented liquid microorganism also is discharged from the lump during discharging, cause discharging concentration higher, microorganism is run off serious; And for the propagation that makes poky methanogen and the speed of going out keep balance, HRT requires longer, generally want 10~15d or longer time, device volume is big, capital construction cost height, also need enough stirrings, power consumption is big, failure frequency height, operation, maintenance cost height, and be difficult to accomplish to mix fully in large-scale industrial scale, treatment effect is not good; This fermentation unit still is an airtight integral body, dismounting inconvenience, and the input and output material difficulty, and high to device stopping property and ultimate compression strength requirement, manufacture difficulty is big, and work-ing life is short; No slag discharging device in the device, scum silica frost flows out in the lump with water outlet or assembles crust, influences effluent quality, and is unfavorable for that biogas generates.
[summary of the invention]
The technical problem to be solved in the present invention is to provide a kind of low constant voltage anaerobism, efficient aerogenesis, long mud age, less energy-consumption, operation, novel vertical flexible covering film anaerobic fermentation device easy to maintenance.
The technical problem to be solved in the present invention is achieved in that a kind of novel vertical flexible covering film anaerobic fermentation device, comprise that anaerobic fermentation reactor and the flexibility that is fixed on this anaerobic fermentation reactor cover skin, it is characterized in that: be provided with a biogas whipping appts, a multi-point self-rotating water-distributing device in the described anaerobic fermentation reactor from bottom to top, and one or four separators.
Described four separators comprise that one can support the center tubing string of these four separators and a reaction zone, a gas collection district, a negative area, an exhalant region and a dreg discharging area of arranging around this center tubing string; Described reaction zone, negative area, exhalant region and dreg discharging area all are positioned at the below of liquid level, described reaction zone is positioned at the bottommost of four separators, and dreg discharging area and exhalant region arrange from outside to inside that above described negative area described gas collection is distinguished the top that is distributed in liquid level.
The upper end of described center tubing string has the getter hole, and described getter hole is that microscler aperture is surrounded on tubing string upper end, center, and shape is identical, equal and opposite in direction, and be symmetrically distributed; The below that described center tubing string is positioned at this getter hole is respectively equipped with the skirt of giving vent to anger, water outlet skirt and the deslagging skirt that extends outside the described anaerobic fermentation reactor; Described center tubing string is upper to be connected with an anti-aeration plate in the reaction zone epimere,, this anti-aeration plate is fixed by a slotted-angle shelving, and this anti-aeration plate is open chamfered edge platform structure; Place, the top of described anti-aeration plate is provided with flow deflector around described center tubing string, and the space of the cube structure that this flow deflector surrounds is described negative area, and separated by a distancely between this flow deflector and the described anti-aeration plate goes into head piece as the negative area; Also connect a reflection vertebra that is used for returned sluge on the tubing string of described center, this reflection vertebra below the described anti-aeration plate and and anti-aeration plate between leaving the gap, this reflection vertebra is a pyramidal structure; The top of described flow deflector is provided with an ash pit and an effluent trough from outside to inside, also be provided with one between this ash pit and the effluent trough and cross aquaporin, zone in this ash pit is described dreg discharging area, zone in this effluent trough is described exhalant region, and the bottom of described effluent trough connects described center tubing string by a rising pipe; The bottom of described ash pit connects described center tubing string by two scum pipes.
Described center tubing string is connected to form by flange by the upper and lower pipeline section of two sealings, this upper and lower pipeline section is independent pipeline section, last pipeline section is divided into the section of giving vent to anger and water exit end from top to bottom, and the bottom of the section of giving vent to anger draws a described skirt of giving vent to anger, and a described water outlet skirt is drawn in the bottom of water exit end; Lower tube section is the deslagging section, and the bottom of lower tube section is established a spoil disposal section in addition, and the bottom of spoil disposal section also is provided with a mud-removing bucket, and a described deslagging skirt is drawn in the bottom of deslagging section, and the bottom of mud-removing bucket is drawn a spoil disposal skirt again; Described exhalant region is provided with the triangle overflow weir, and this triangle overflow weir is positioned at the top of effluent trough outer wall, and the inwall of ash pit is higher than the water outlet water level.
Described multi-point self-rotating water-distributing device comprises a water inlet pipe, two water distributors and a water-dispensing cover; Water distributor is provided with spray orifice, and described water inlet pipe fixedly installs, and connects and run through described center tubing string; Described water-dispensing cover is placed in the outside of described center tubing string rotationally, forms the concentric annular water distributing area between this water-dispensing cover and the described center tubing string; Be distributed in to described two water distributor lateral symmetry the both sides of described water-dispensing cover, fixedly connected with described water-dispensing cover and connect, and these two water distributors and described water-dispensing cover form a rotatable integral body; Described two water distributors are separately along offering spray orifice on the side of water distributor longitudinal axis face, and about the spray orifice of two water distributors towards on the contrary, and the spray orifice on described arbitrary water distributor is along rotation center outward direction aperture and increases progressively trend, the trend and the spacing in adjacent two holes tapers off; The terminal oblique bending down of described water distributor is hook-shaped, and does not do shutoff.。
Described biogas whipping appts comprises that the biogas that is distributed in the described anaerobic fermentation reactor stirs pipeline, and be located at described anaerobic fermentation reactor outer a purge unit, an air storage equipment, a supercharging device and a robot control system(RCS), the input terminus of described purge unit is connected in the gas collection district of anaerobic fermentation tank, output terminal stirs pipeline by described air storage equipment with described supercharging device, biogas and is connected successively, and described robot control system(RCS) stirs pipe connection with described supercharging device and biogas respectively again.
Described biogas stirs the bottom that pipeline is fixed in the center tubing string, comprise the gas distribution pipe that complex root is connected with described center tubing string, this gas distribution pipe serves as axially outer evenly scatter distributions with the center tubing string, the center tubing string with the gas distribution pipe linkage section by on lower clapboard separate, form cylindric cloth gas area, and be communicated with an external feed stream pipeline; Every gas distribution pipe end is connected to a transverse tube, transverse tube is the center left-right symmetry with the gas distribution pipe, each upwards connects a vertical tube by 90 ° of elbows the two-port of this transverse tube, the end of this vertical tube connects two sections short tubes of giving vent to anger by threeway, this short tube of giving vent to anger is connected with 90 ° of bend pipes of a band single hole plug, described bend pipe is towards unanimity, porous nickel; Described purge unit comprises interconnective air water separator and ferric oxide desulfurizer; Described air water separator comprises an outer tube and is arranged in pipe in one in this outer tube, described in the top of pipe have the inlet mouth that is communicated with the gas collection district of anaerobic fermentation tank, described interior pipe hypomere be provided with the cloth air cavity that can lead to outer tube; Stage casing in the space between outer tube and the interior pipe is provided with a hole pattern baffle plate, the hole pattern baffle plate is divided into one on the other liquefied room and condensing chamber with the space between outer tube and the interior pipe, the bottom of described condensing chamber has a water port, in the described liquefied room granulated glass sphere is housed, and liquefied room top also has an air outlet that is used to connect described ferric oxide desulfurizer; Described desulfurizer is to have the housing structure that mixes two-chamber, the desulfurization layer that fill for ferric oxide at the tower body middle part, the top of desulfurization layer is last hybrid chamber, the below is following hybrid chamber, the top of last hybrid chamber has inlet mouth on, and the bottom of following hybrid chamber has inlet mouth, is provided with a middle air outlet in the desulfurization layer, the described inlet mouth of going up is connected described air water separator with following inlet mouth, and described middle air outlet connects described supercharging device; Described supercharging device comprises interconnective supercharger and pressure reserveir; Described pressure reserveir is the vertical tank body structure, with the supporting use of supercharger, tank interior is the air storage cavity, the sidewall of air storage cavity is offered an inlet mouth and is connected described supercharger, the top of air storage cavity is provided with an air outlet and connects described biogas stirring pipeline, and place, contiguous described air outlet also is provided with a safety valve; Described robot control system(RCS) comprises that one can manual and automatic double-purpose housing and at least one magnetic valve, and described each magnetic valve is connected described supercharger and biogas and stirs between the gas distribution main of pipeline and by the control of the circulation rly. in the described double-purpose housing and open and close.
It is to be fixed on this anaerobic fermentation reactor by a stationary installation that described flexibility is covered skin, this stationary installation comprises hook, fixedly buckle and subsidiary conduit, described subsidiary conduit and described flexibility are covered skin and are connected and fixed, described fixedly buckle is held subsidiary conduit tightly, and this fixing catch is buckled and also is provided with through hole, and described hook is arranged in this through hole.
Described fixedly buckle is paid by two symmetric band short handle semicircle ring locks and is formed by connecting, two semicircular ring intermediate formation are used to hold the cavity of described subsidiary conduit, the not closed and leaving certain gaps uncovered by the economic plan in the top of this cavity, described short handle bottom has the through hole that just can wear described hook; Described subsidiary conduit intert continuously cover with described flexible anaerobism that the skin periphery is rolled and the pipe box that is welded in, this sleeve pipe is interspersed in the cavity of described fixedly buckle again, and described flexibility is covered skin, and to be connected in the extension of described pipe box overhanging along the breach of cavity; The numeral " 5 " of described hook-shaped as standing upside down, 270 ° of circular arc crotches are with in the upper end, lower end band one horizontal short handle, and toss about with described crotch, and this crotch with laterally be connected by a long handle between the short handle, described horizontal short handle is embedded in described uncovered anaerobic pond periphery in advance, and described crotch is external side towards the pond, and is arranged in the described fixedly buckle through hole.
The invention has the advantages that: complete assembly merges flexibility and covers skin characteristic and CSTR structural advantages in one, adopts low pressure-constant voltage-anaerobic technique to realize efficient aerogenesis and water purification process, adopts unpowered self-rotating water-distributing device, and water distribution is evenly constant, no energy consumption; Realize effective separation of gas, liquid, mud, slag solving the microorganism losing issue by the ingenious design of four separators, prolong SRT, reach the purpose that improves factor of created gase, and shorten HRT to a certain extent, reduce device volume, reduce the capital construction cost; Device also is provided with special scum silica frost collection, the bleed member of getting, and effectively reduces the influence of scum silica frost to effluent quality and gas generation process; Flexible Application biogas stirs realizes the complete mixed state of fermentation system, simple in structure, low cost, automatic control degree height, good mixing effect is in conjunction with intermittent circulation stirring theory, factor of created gase height, energy consumption is low, and can be by adjusting the actual engineering that the tracheae arrangement form adapts to various scales, the biogas of producing with internal system serves as to stir source of the gas, makes full use of the renewable energy resources, and biogas can be recycled again, and economy, environmental benefit develop simultaneously; Portable covers the skin capping, and fixed form is made simply flexibly, and demolition, installation are convenient, but only needs just assurance device stopping property of overflowing liquid setting-out envelope, realization low pressure anaerobically fermenting.
[description of drawings]
The present invention is further illustrated in conjunction with the embodiments with reference to the accompanying drawings.
Fig. 1 is the structural representation of vertical flexible covering film anaerobic fermentation device of the present invention, the main internal structure that shows anaerobic fermentation reactor among the figure.
Fig. 1 a is the enlarged view of the centre portions of Fig. 1.
Fig. 2 is the A-A cross-sectional schematic of Fig. 1.
Fig. 3 is the B-B cross-sectional schematic of Fig. 1.
Fig. 4 a and Fig. 4 b are respectively that the master of multi-point self-rotating water-distributing device of the present invention looks and overlook the status architecture synoptic diagram.
Fig. 5 is the structural representation of biogas whipping appts among the present invention.
Fig. 6 is the structural representation that the biogas of biogas whipping appts among the present invention stirs pipeline.
Fig. 7 and Fig. 8 are respectively the local structure synoptic diagram that the biogas of different visual angles stirs pipeline.
Fig. 9 is the structural representation of the air water separator of biogas whipping appts among the present invention.
Figure 10 is the structural representation of the ferric oxide desulfurizer of biogas whipping appts among the present invention.
Figure 11 a Figure 11 b is respectively that the flexible master of covering the stationary installation of skin looks and side-looking status architecture synoptic diagram among the present invention.
[embodiment]
See also Fig. 1 to shown in Figure 7, novel vertical flexible covering film anaerobic fermentation device of the present invention, comprise that anaerobic fermentation reactor 10 and the flexibility that is fixed on this anaerobic fermentation reactor cover skin 20, be provided with a biogas whipping appts 1, a multi-point self-rotating water-distributing device 2 in the described anaerobic fermentation reactor 10 from bottom to top, and one or four separators 3.
Fig. 1 is to shown in Figure 3 again, described four separators 3 comprise that one can support the center tubing string 31 of these four separators, and the reaction zone 3A, a gas collection district 3B, a negative area 3C, an exhalant region 3D and the dreg discharging area 3E that center on these center tubing string 31 settings, described reaction zone 3A, negative area 3C, exhalant region 3D and dreg discharging area 3E all are positioned at the below of liquid level, described reaction position 3A is in the bottommost of four separators, and dreg discharging area 3E and exhalant region 3D arrange from outside to inside that above described negative area 3C described gas collection district 3B is distributed in the top of liquid level.Four separators of this structure can reach the effect of gas, water, mud, slag separated in synchronization.Described reaction zone 3A has gathered the upstream that ascending current, reaction generate and the different fluid of returned sluge three big proportions of sinking, forms circulating fluidizedly, and gas, water, solid, slag thorough mixing react thorough.
The upper end of described center tubing string 31 has getter hole 310, and described getter hole 310 is surrounded on tubing string upper end, center for microscler aperture, and shape is identical, equal and opposite in direction, and be symmetrically distributed; The below that described center tubing string 31 is positioned at this getter hole 310 is respectively equipped with extends outer give vent to anger skirt 3110, water outlet skirt 3120 and the deslagging skirt 3130 of described anaerobic fermentation reactor 10; Be positioned at reaction zone 3A epimere on the described center tubing string 31 and be connected with an anti-aeration plate 32, this anti-aeration plate 32 is fixing by a slotted-angle shelving 328, and this anti-aeration plate 32 is open chamfered edge platform structure; Place, the top of described anti-aeration plate 32 is described negative area 3C around the space that described center tubing string 31 is provided with the cube structure that flow deflector 33 these flow deflectors 33 surround, and separated by a distancely between this flow deflector 33 and the described anti-aeration plate 32 goes into head piece as the negative area; Also connect a reflection vertebra 34 that is used for returned sluge on the described center tubing string 31, this reflection vertebra 34 below the described anti-aeration plate 32 and and anti-aeration plate 32 between leave the gap as the mud refluxing opening, this reflection vertebra 34 is a pyramidal structure; The top of described flow deflector 33 is provided with an ash pit 35 and an effluent trough 36 from outside to inside, also be provided with one between this ash pit 35 and the effluent trough 36 and cross aquaporin 37, zone in this ash pit 35 is described dreg discharging area 3E, zone in this effluent trough 36 is described exhalant region 3D, and the bottom of described effluent trough 36 connects described center tubing string 31 by a rising pipe 362; The bottom of described ash pit 35 connects described center tubing string 31 by two scum pipes 352.
Described center tubing string 31 is connected to form by flange by the upper and lower pipeline section of two sealings, this upper and lower pipeline section is independent pipeline section, last pipeline section is divided into section of giving vent to anger 311 and water exit end 312 from top to bottom, and a described skirt 3110 of giving vent to anger is drawn in the bottom of the section of giving vent to anger 311, and a described water outlet skirt 3120 is drawn in the bottom of water exit end 312; Lower tube section is a deslagging section 313, and the bottom of lower tube section is established a spoil disposal section 314 in addition, and the bottom of spoil disposal section 314 also is provided with a mud-removing bucket 315, and a described deslagging skirt 3130 is drawn in the bottom of deslagging section 314, and the bottom of mud-removing bucket 315 is drawn a spoil disposal skirt 3140 again; Described exhalant region 3D is provided with triangle overflow weir 38, and this triangle overflow weir 38 is positioned at the top of effluent trough 36 outer walls and towards center tubing string 31, and the inwall of ash pit 35 is higher than the water outlet water level.
Sewage is uniformly distributed in described reaction zone 3A bottom from water-distributing device, the upstream that current that rise and reaction generate drives mud, the water thorough mixing in the reaction zone 3A, quicken anaerobic reaction, gas generates and carries muddy water mixed solution in a large number and rises along the pond body together.Merging density along with bubble in the three-phase mixed solution uphill process reduces gradually, constantly upwards flows, until arriving anti-aeration plate 32, gas is folded to gas collection district 3B, rises to liquid level, is discharged into air chamber, be directed into center tubing string 31 by getter hole 310, discharge, separate with solid, liquid by the section of giving vent to anger 311.Bubble is carried small-particle mud and slag come-up secretly at uphill process and is flowed into gas collection district 3B in the lump, floats on the solution-air surface, is discharged by deslagging skirt 3130 by two scum pipes 35 at last, and the moving peripheral scum silica frost of broken belt flows to ash pit 35.Mud part after separated from the gas falls after rise to reaction zone 3A, and a part is gone into head piece with fluid and entered negative area 3C along the negative area under the guiding of flow deflector 3, do the flow lifting type sedimentation.In the 3C of negative area, mud granule active low, quantity is few, and organic concentration is low, and aerogenesis is very little, and is little to the solid-liquid separation influence.Eliminated the castering action of gas, mixed solution slows down gradually in uphill process speed, realizes mud-water separation by mud, water self difference of specific gravity, and clear liquor passed through the aquaporin overflow to V-notch weir 38, was discharged by rising pipe; Sludge settling is to anti-aeration plate 32 inboards, along the wall landing to the mud refluxing opening and through reflecting vertebra 34 uniformly distributings to reaction zone 3A.Returned sluge does not contain gas, and proportion is big than reaction zone 3A mixed solution, forms circulating fluidizedly with reaction zone 3A ascending current, promotes mud granule fully to contact with organic, and reaction thoroughly.
As shown in Figure 4, described multi-point self-rotating water-distributing device 2 comprises a water inlet pipe 21, two water distributors 22 and water-dispensing covers 23; Water distributor 22 is provided with spray orifice 222, and described water inlet pipe 21 fixedly installs, and connects and run through described center tubing string 31; Described water-dispensing cover 23 is placed in the outside of described center tubing string 31 rotationally, forms concentric annular water distributing area 232 between this water-dispensing cover 23 and the described center tubing string 31; Be distributed in to described two water distributor 22 lateral symmetry the both sides of described water-dispensing cover 23, fixedly connected with described water-dispensing cover 23 and connect, described water-dispensing cover 23 can be realized two water distributor 22 uniform water distributions by this concentric annular water distributing area 232.And these two water distributors 22 form a rotatable integral body with described water-dispensing cover 23; Described each water distributor 22 is separately along offering spray orifice 222 on the side of water distributor 22 longitudinal axis faces, and about the spray orifice 222 of two water distributors towards on the contrary, and the spray orifice 222 on described arbitrary water distributor 22 is along rotation center outward direction aperture and increases progressively trend, the trend and the spacing in adjacent two holes tapers off; The terminal oblique bending down of described water distributor 22 is hook-shaped, and does not do shutoff.
The water of being introduced by water inlet pipe 21 is evenly distributed to the end of the water distributor 22 that is communicated with water-dispensing cover 23, and the flow through spray orifice 222 in different positions on the water distributor 22, different apertures of current sprays with certain speed.Spray orifice 222 pore sizes carry out appropriate design according to the influence of different positions cloth water spot drag losses difference, have guaranteed the homogeneity of each spray orifice 222 flow and flow velocity.Continuous injection along with current, the reverse thrust effect that water distributor 22 is produced by jet moves into the spontaneous rotation of water vertical tube and moves in a circle, so that the heavy mud in bottom is produced centripetence power, driving heavy mud draws close to the central row bucket, be beneficial to spoil disposal, and current are uniformly distributed in the anaerobic fermentation reactor 10 along water distributor 2 rotary motion trace.The water yield begins to go up in the described anaerobic fermentation reactor 10, do not have multi-point self-rotating water-distributing device 2 gradually, water distributor 22 was subjected to calm-water resistance and influenced rotating speed and reduce gradually until reaching a certain equilibrium value this moment, and water distribution system has entered stable state, invariablenes turning speed, water distribution is even.Spray orifice 222 effusive stir and the rotation of water-distributing device 2 drives peripheral muddy water thorough mixing, and spray orifice does not have obstruction, does not have heavy mud at the bottom of the pond, stable, and operation phase spray orifice 222 is in non-static condition all the time, and water distribution is continuous, also efficiently solves the blockage problem that traditional water-distributing device is used to have.Described water distributor 22 continuously and smoothly under self water-jet reactive force promotes rotate, the effect of having served as agitator when realizing continuous water distribution uniformity, and combine mechanical stirring and waterpower whipping characteristic, played good muddy water mixed effect, prevented anaerobic fermentation reactor 10 bottom depositions and local short flow phenomenon, and need not external power-equipment, no energy consumption, and because of no auxiliary facility, simple in structure, system peace, easy to maintenance.
Extremely shown in Figure 10 as Fig. 5, described biogas whipping appts 1 comprises that the biogas that is distributed in described anaerobic fermentation reactor interior 10 stirs pipeline 11, and be located at described anaerobic fermentation reactor 10 outer a purge unit 12, an air storage equipment 13, a supercharging device 14 and a robot control system(RCS) 15, the input terminus of described purge unit 11 is connected in the gas collection district 3B of anaerobic fermentation tank, output terminal stirs pipeline 11 by described air storage equipment 13 with described supercharging device 14, biogas and is connected successively, and described robot control system(RCS) 15 stirs pipeline 11 with described supercharging device 14 and biogas respectively again and is connected.Described purge unit 12 further comprises interconnective air water separator 121 and ferric oxide desulfurizer 122.
Please main reference Fig. 6 to shown in Figure 8, described biogas stirs the bottom that pipeline 11 is fixed in center tubing string 31, comprise the gas distribution pipe 111 that complex root is connected with described center tubing string, this gas distribution pipe 111 serves as axially outer evenly scatter distributions with center tubing string 31, center tubing string 31 with the linkage section of gas distribution pipe 111 by on lower clapboard separate, form cylindric cloth gas area, and be communicated with an external feed stream pipeline 112; Every gas distribution pipe 111 ends are connected to a transverse tube 113, transverse tube 113 is the center left-right symmetry with gas distribution pipe 111, each upwards connects a vertical tube 115 by 90 ° of elbows 114 two-port of this transverse tube 113, the end of this vertical tube 115 connects two sections short tubes 116 of giving vent to anger by threeway, this short tube 116 of giving vent to anger is connected with 90 ° of bend pipes 117 of a band single hole plug, described bend pipe is towards unanimity, porous nickel.
As shown in Figure 9, described air water separator 121 comprises an outer tube 1211 and is arranged in pipe 1212 in one in this outer tube 1211, pipe 1211 top has the inlet mouth Q1 that is communicated with the gas collection district of anaerobic fermentation tank in described, manage in described 1211 hypomere be provided with the cloth air cavity 1213 that can lead to outer tube 1211; Stage casing in the space between outer tube 1211 and the interior pipe 1212 is provided with a hole pattern baffle plate 1214, hole pattern baffle plate 1214 is divided into one on the other liquefied room 1215 and condensing chamber 1216 with the space between outer tube 1211 and the interior pipe 1212, the bottom of described condensing chamber 1216 has a water port Q2, in the described liquefied room 1215 granulated glass sphere 1217 is housed, and liquefied room 1215 tops also has an air outlet Q3 who is used to connect described ferric oxide desulfurizer 122;
As shown in figure 10, described desulfurizer 122 is for having the housing structure that mixes two-chamber, the desulfurization layer 1221 that fill for ferric oxide at the tower body middle part, the top of desulfurization layer 1221 is last hybrid chamber 1222, the below is following hybrid chamber 1223, the top of last hybrid chamber 1222 has inlet mouth Q4 on, the bottom of following hybrid chamber 1222 has inlet mouth Q5, air outlet Q6 in the middle of being provided with one in the desulfurization layer 1221, the described inlet mouth Q4 that goes up is connected described air water separator 121 with following inlet mouth Q5, and described middle air outlet Q6 connects described supercharging device 13;
Described supercharging device 14 comprises interconnective supercharger 141 and pressure reserveir 142; Described pressure reserveir 142 is the vertical tank body structure, with supercharger 141 supporting uses, tank interior is an air storage cavity 1422, the sidewall of air storage cavity 1422 is offered an inlet mouth Q7 and is connected described supercharger 141, the top of air storage cavity 1422 is provided with an air outlet Q8 and connects described biogas stirring pipeline 11, and Q8 place, contiguous described air outlet also is provided with a safety valve 1424;
Described robot control system(RCS) 15 comprises that one can manual and automatic double-purpose housing 151 and at least one magnetic valve 152, and described each magnetic valve 152 is connected described supercharger 141 and biogas and stirs between the gas distribution main 111 of pipeline 11 and by the circulation rly.s control in the described double-purpose housing 151 and open and close.
Please main reference Figure 11 a and Figure 11 b shown in, it is to be fixed on this anaerobic fermentation reactor 10 by a stationary installation 6 that described flexibility is covered skin 20, this stationary installation 6 comprises hook 61, fixedly buckle 62 and subsidiary conduit 63, described subsidiary conduit 63 covers skin 20 with described flexibility and is connected and fixed, described fixedly buckle 62 is held subsidiary conduit 63 tightly, and should fixedly also be provided with through hole 626 on the buckle 62, described hook 61 is arranged in this through hole 626.
Described fixedly buckle 62 is paid by two symmetric semicircular ring 621 butt joints and by hexagon bolt 622 locks and is formed, two semicircular ring, 621 intermediate formation are used to hold the cavity 623 of described subsidiary conduit 63, the not closed and leaving certain gaps uncovered by the economic plan 624 in the top of this cavity 623, the lower end of this two semicircular ring 621 is also subsidiary respectively a short handle 625, and described short handle 625 bottoms have the through hole 626 that just can wear described hook 61.Described subsidiary conduit 63 intert continuously described flexibility cover that skin 20 peripheries are rolled and the pipe box 202 that is welded in, be connected and fixed to cover skin 20 with described flexibility, this sleeve pipe 202 is interspersed in the cavity 623 of described fixedly buckle 62 again, so, described fixedly buckle 62 can be held subsidiary conduit 63 tightly, and described flexibility is covered skin 20, and to be connected in the extension 204 of described pipe box 202 protruding along the breach 624 of cavity 623 again.The numeral " 5 " of described hook 61 shapes as standing upside down, 270 ° of circular arc crotches 611 are with in the upper end, lower end band one horizontal short handle 612, and toss about with described crotch 611, and this crotch 611 with laterally be connected by a long handle 613 between the short handle 612, described horizontal short handle 612 is embedded in described uncovered anaerobic pond periphery (not shown) in advance, and described crotch 611 is external side towards the pond, and is arranged in described fixedly buckle 62 through holes 626.
Described subsidiary conduit 63 is interspersed in described flexibility continuously and covers in the peripheral ready-formed pipe box 202 of skin 20, supporting flexibility covers skin 20 and makes it to be evenly distributed on the fermentation vat of anaerobic fermentation reactor 10, improve the flexible stressing conditions that covers skin 20, this subsidiary conduit 63 can be avoided covering perforate on the skin 20 in flexibility, prevents that flexibility from covering skin 20 cracking phenomenas and taking place.Described fixedly buckle 62 is easy for installation, dismounting flexibly, fixedly the position of buckle 62 can be covered skin 20 inflated configuration with described flexibility and adjusts automatically, makes each link up with 61 and is in best strained condition.Described hook 61 is with horizontal short handle 625, conveniently is bonded to described uncovered anaerobic pond periphery; The crotch of 270 ° of circular arcs, radian is big, and towards to cover the expand pulling force that produces of skin 20 opposite with flexibility, can effectively prevent belled buckle obscission.With the carrying out that anaerobically fermenting reacts, gas constantly generates, the effusion liquid level, and the pond internal gas pressure constantly rises, and flexibility is covered skin 20 and is outwards expanded, expands under gas pressure, is subjected to the stationary installation restriction and is covered in the pond face, is not shifted.During dismounting, fixedly buckle 62 is taken off one by one from linking up with on 61, and flexibility covers skin 20 and subsidiary conduit 63 just can relatedly draw off.
Principle of work of the present invention:
The novel vertical flexible covering film anaerobic fermentation device of this structure, sewage enters concentric annular water distributing area 232 from the water inlet pipe 21 of described multi-point self-rotating water-distributing device 2 by center tubing string 31, two water distributors 22 about being evenly distributed to, spray from each spray orifice 222 with certain flow velocity, spray orifice 222 flow velocitys 3~6m/s, current slowly rise in reaction zone 3A, upflow velocity<1m/h, and HRT is long; Jet produces deboost to water distributor 22 in the course of injection, because two water distributors, 22 perforate directions are tossed about, the moment of generation deviates from the rotation of spray orifice 222 directions thereby drive described multi-point self-rotating water-distributing device 2 moving parts around axis in the same way; Spray orifice 222 even water outlets, water distributor 22 uniform rotation, thus guarantee that water distribution all measures in the equilibrium of whole anaerobic fermentation reactor 10 and even each water distribution spray orifice 222, realize that anaerobic fermentation reactor 10 water distributions are in the space and temporal homogeneity.The rotation of the injection of current and multi-point self-rotating water-distributing device 2 produces waterpower simultaneously to peripheral muddy water and stirs and mechanical agitation, promotes muddy water to mix.Described multi-point self-rotating water-distributing device 2 below biogas whipping apptss then evenly penetrate biogas from pore with higher relatively speed, forming the intensive air-flow stirs, and significantly forming strong convection current up and down under gas, the effect of liquid density difference, force current to form a plurality of little vortexs by each to disturbance, flow at entire reaction district 3A internal recycle, the interior muddy water of reaction zone 3A is mixed fully, microorganism contacts with organism well, degraded, gas production rate improve, and effectively prevent heavy mud at the bottom of the pond.Carrying out along with the anaerobically fermenting reaction, the interior gas of reaction zone 3A generates and carries muddy water mixed solution in a large number and rises along the pond body together, merging density along with bubble in the three-phase mixed solution uphill process reduces gradually, constantly upwards flow, until arriving anti-aeration plate 32, gas is folded to gas collection district 3B, rise to liquid level, be discharged into air chamber, import tracheae by the getter hole and discharge, separate with solid, liquid; Bubble is carried small-particle mud and slag come-up secretly at uphill process and is flowed into gas collection district 3B in the lump, forms scum silica frost and floats on the solution-air surface, is discharged by ash pit 35, and the moving peripheral scum silica frost of broken belt flows to ash pit 35; Mud part after separated from the gas falls after rise to reaction zone 3A, and a part is gone into head piece with fluid along negative area 3C and entered exhalant region 3D under the guiding of flow deflector 33, does the flow lifting type precipitation, sedimentation speed 1~2m/s.In the 3C of negative area, mud granule active low, quantity is few, and organic concentration is low, and aerogenesis is very little, and is little to the solid-liquid separation influence; Owing to eliminated the castering action of gas, mixed solution slows down gradually in uphill process speed, realizes mud-water separation by mud, water self difference of specific gravity, improves SRT greatly, clear liquor is crossed aquaporin 37 overflows to V-notch weir 38 by 36 of ash pit 35 and effluent troughs, is discharged by water outlet skirt 3120; Sludge settling is to anti-aeration plate 32 inboards, along the wall landing to the mud refluxing opening and through reflecting the vertebra uniformly distributing to reaction zone 3A; Returned sluge does not contain gas, proportion is big than reaction zone 3A mixed solution, form circulating fluidized with reaction zone 3A ascending current, promote that mud granule fully contacts with organism, thoroughly reaction, the heavy mud of part is concentrated to tank base central row bucket 315 under waterpower promotes gradually, is discharged by spoil disposal skirt 3140.Increase along with gas among the gas collection district 3B, flexibility is covered skin 20 and is expanded gradually and heave, be hemispherical, firmly be fixed under the effect of stationary installation 6 above the anaerobic fermentation reactor 10, fixed area edge current overflow along seam, form certain water seal liquid level, make whole device be in air-tight state, to keep constant low pressure anaerobically fermenting environment.

Claims (9)

1. novel vertical flexible covering film anaerobic fermentation device, comprise that anaerobic fermentation reactor and the flexibility that is fixed on this anaerobic fermentation reactor cover skin, it is characterized in that: be provided with a biogas whipping appts, a multi-point self-rotating water-distributing device in the described anaerobic fermentation reactor from bottom to top, and one or four separators.
2. novel vertical flexible covering film anaerobic fermentation device according to claim 1, it is characterized in that: described four separators comprise that one can support the center tubing string of these four separators, and center on a reaction zone, a gas collection district, a negative area, an exhalant region and a dreg discharging area that this center tubing string is arranged; Described reaction zone, negative area, exhalant region and dreg discharging area all are positioned at the below of liquid level, described reaction zone is positioned at the bottommost of four separators, and dreg discharging area and exhalant region arrange from outside to inside that above described negative area described gas collection is distinguished the top that is distributed in liquid level.
3. novel vertical flexible covering film anaerobic fermentation device according to claim 2, it is characterized in that: the upper end of described center tubing string has the getter hole, and described getter hole is that microscler aperture is surrounded on tubing string upper end, center, and shape is identical, equal and opposite in direction, and be symmetrically distributed; The below that described center tubing string is positioned at this getter hole is respectively equipped with the skirt of giving vent to anger, water outlet skirt and the deslagging skirt that extends outside the described anaerobic fermentation reactor;
Described center tubing string is upper to be connected with an anti-aeration plate in the reaction zone epimere, and this anti-aeration plate is fixed by a slotted-angle shelving, and this anti-aeration plate is open chamfered edge platform structure;
Place, the top of described anti-aeration plate is provided with flow deflector around described center tubing string, and the space of the cube structure that this flow deflector surrounds is described negative area, and separated by a distancely between this flow deflector and the described anti-aeration plate goes into head piece as the negative area;
Also connect a reflection vertebra that is used for returned sluge on the tubing string of described center, this reflection vertebra below the described anti-aeration plate and and anti-aeration plate between leaving the gap, this reflection vertebra is a pyramidal structure;
The top of described flow deflector is provided with an ash pit and an effluent trough from outside to inside, also be provided with one between this ash pit and the effluent trough and cross aquaporin, zone in this ash pit is described dreg discharging area, zone in this effluent trough is described exhalant region, and the bottom of described effluent trough connects described center tubing string by a rising pipe; The bottom of described ash pit connects described center tubing string by two scum pipes.
4. novel vertical flexible covering film anaerobic fermentation device according to claim 3, it is characterized in that: described center tubing string is connected to form by flange by the upper and lower pipeline section of two sealings, this upper and lower pipeline section is independent pipeline section, last pipeline section is divided into the section of giving vent to anger and water exit end from top to bottom, and a described skirt of giving vent to anger is drawn in the bottom of the section of giving vent to anger, and a described water outlet skirt is drawn in the bottom of water exit end; Lower tube section is the deslagging section, and the bottom of lower tube section is established a spoil disposal section in addition, and the bottom of spoil disposal section also is provided with a mud-removing bucket, and a described deslagging skirt is drawn in the bottom of deslagging section, and the bottom of mud-removing bucket is drawn a spoil disposal skirt again; Described exhalant region is provided with the triangle overflow weir, and this triangle overflow weir is positioned at the top of effluent trough outer wall, and the inwall of ash pit is higher than the water outlet water level.
5. novel vertical flexible covering film anaerobic fermentation device according to claim 2 is characterized in that: described multi-point self-rotating water-distributing device comprises a water inlet pipe, two water distributors and a water-dispensing cover; Water distributor is provided with spray orifice, and described water inlet pipe fixedly installs, and connects and run through described center tubing string; Described water-dispensing cover is placed in the outside of described center tubing string rotationally, forms the concentric annular water distributing area between this water-dispensing cover and the described center tubing string; Be distributed in to described two water distributor lateral symmetry the both sides of described water-dispensing cover, fixedly connected with described water-dispensing cover and connect, and these two water distributors and described water-dispensing cover form a rotatable integral body; Described two water distributors are separately along offering spray orifice on the side of water distributor longitudinal axis face, and about the spray orifice of two water distributors towards on the contrary, and the spray orifice on described arbitrary water distributor is along rotation center outward direction aperture and increases progressively trend, the trend and the spacing in adjacent two holes tapers off; The terminal oblique bending down of described water distributor is hook-shaped, and does not do shutoff.
6. novel vertical flexible covering film anaerobic fermentation device according to claim 2, it is characterized in that: described biogas whipping appts comprises that the biogas that is distributed in the described anaerobic fermentation reactor stirs pipeline, and be located at the outer purge unit of described anaerobic fermentation reactor, one air storage equipment, one supercharging device and a robot control system(RCS), the input terminus of described purge unit is connected in the gas collection district of anaerobic fermentation tank, output terminal is by described air storage equipment and described supercharging device, biogas stirs pipeline and connects successively, and described robot control system(RCS) stirs pipe connection with described supercharging device and biogas respectively again.
7. novel vertical flexible covering film anaerobic fermentation device according to claim 6 is characterized in that:
Described biogas stirs the bottom that pipeline is fixed in the center tubing string, comprise the gas distribution pipe that complex root is connected with described center tubing string, this gas distribution pipe serves as axially outer evenly scatter distributions with the center tubing string, the center tubing string with the gas distribution pipe linkage section by on lower clapboard separate, form cylindric cloth gas area, and be communicated with an external feed stream pipeline; Every gas distribution pipe end is connected to a transverse tube, transverse tube is the center left-right symmetry with the gas distribution pipe, each upwards connects a vertical tube by 90 ° of elbows the two-port of this transverse tube, the end of this vertical tube connects two sections short tubes of giving vent to anger by threeway, this short tube of giving vent to anger is connected with 90 ° of bend pipes of a band single hole plug, described bend pipe is towards unanimity, porous nickel;
Described purge unit comprises interconnective air water separator and ferric oxide desulfurizer; Described air water separator comprises an outer tube and is arranged in pipe in one in this outer tube, described in the top of pipe have the inlet mouth that is communicated with the gas collection district of anaerobic fermentation tank, described interior pipe hypomere be provided with the cloth air cavity that can lead to outer tube; Stage casing in the space between outer tube and the interior pipe is provided with a hole pattern baffle plate, the hole pattern baffle plate is divided into one on the other liquefied room and condensing chamber with the space between outer tube and the interior pipe, the bottom of described condensing chamber has a water port, in the described liquefied room granulated glass sphere is housed, and liquefied room top also has an air outlet that is used to connect described ferric oxide desulfurizer; Described desulfurizer is to have the housing structure that mixes two-chamber, the desulfurization layer that fill for ferric oxide at the tower body middle part, the top of desulfurization layer is last hybrid chamber, the below is following hybrid chamber, the top of last hybrid chamber has inlet mouth on, and the bottom of following hybrid chamber has inlet mouth, is provided with a middle air outlet in the desulfurization layer, the described inlet mouth of going up is connected described air water separator with following inlet mouth, and described middle air outlet connects described supercharging device;
Described supercharging device comprises interconnective supercharger and pressure reserveir; Described pressure reserveir is the vertical tank body structure, with the supporting use of supercharger, tank interior is the air storage cavity, the sidewall of air storage cavity is offered an inlet mouth and is connected described supercharger, the top of air storage cavity is provided with an air outlet and connects described biogas stirring pipeline, and place, contiguous described air outlet also is provided with a safety valve;
Described robot control system(RCS) comprises that one can manual and automatic double-purpose housing and at least one magnetic valve, and described each magnetic valve is connected described supercharger and biogas and stirs between the gas distribution main of pipeline and by the control of the circulation rly. in the described double-purpose housing and open and close.
8. novel vertical flexible covering film anaerobic fermentation device according to claim 2, it is characterized in that: it is to be fixed on this anaerobic fermentation reactor by a stationary installation that described flexibility is covered skin, this stationary installation comprises hook, fixedly buckle and subsidiary conduit, described subsidiary conduit and described flexibility are covered skin and are connected and fixed, described fixedly buckle is held subsidiary conduit tightly, and this fixing catch is buckled and also is provided with through hole, and described hook is arranged in this through hole.
9. novel vertical flexible covering film anaerobic fermentation device according to claim 8 is characterized in that:
Described fixedly buckle is paid by two symmetric band short handle semicircle ring locks and is formed by connecting, two semicircular ring intermediate formation are used to hold the cavity of described subsidiary conduit, the not closed and leaving certain gaps uncovered by the economic plan in the top of this cavity, described short handle bottom has the through hole that just can wear described hook;
Described subsidiary conduit intert continuously cover with described flexible anaerobism that the skin periphery is rolled and the pipe box that is welded in, this sleeve pipe is interspersed in the cavity of described fixedly buckle again, and described flexibility is covered skin, and to be connected in the extension of described pipe box overhanging along the breach of cavity;
The numeral " 5 " of described hook-shaped as standing upside down, 270 ° of circular arc crotches are with in the upper end, lower end band one horizontal short handle, and toss about with described crotch, and this crotch with laterally be connected by a long handle between the short handle, described horizontal short handle is embedded in described uncovered anaerobic pond periphery in advance, and described crotch is external side towards the pond, and is arranged in the described fixedly buckle through hole.
CN201010107565A 2010-02-08 2010-02-08 Novel vertical flexible covering film anaerobic fermentation device Pending CN101775351A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102746985A (en) * 2012-08-01 2012-10-24 刘盛林 Straw methane fermenting pool
CN103204584A (en) * 2012-01-11 2013-07-17 北京格润碧水环境科技有限公司 Application method of novel anaerobic water distributor in sewage processing engineering
CN103589634A (en) * 2013-11-29 2014-02-19 东北大学 Semi-continuous heating-type biogas generation kettle
EP2821476A1 (en) * 2013-07-04 2015-01-07 Valogreen Digester for producing biogas and digestate and method for assembling same
CN104450514A (en) * 2014-11-18 2015-03-25 中国石油大学(北京) Anaerobic vertical plug-flow reactor
CN105567554A (en) * 2016-03-25 2016-05-11 福建省农业科学院农业工程技术研究所 Multifunctional anaerobic biogas fermenting tank structure and application method thereof
CN105950463A (en) * 2016-07-12 2016-09-21 祁彦涛 Service platform for anaerobic fermentation system
CN108636256A (en) * 2018-07-28 2018-10-12 河南东润电子有限公司 A kind of wall plaster coating material agitator
CN111454823A (en) * 2020-04-01 2020-07-28 河北科环环境工程有限公司 Slag discharge system and slag discharge method for methane tank
CN114314803A (en) * 2021-12-28 2022-04-12 南京扬子江生态环境产业研究院有限公司 Quick oxidation device for micro-polluted water

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103204584A (en) * 2012-01-11 2013-07-17 北京格润碧水环境科技有限公司 Application method of novel anaerobic water distributor in sewage processing engineering
CN102746985A (en) * 2012-08-01 2012-10-24 刘盛林 Straw methane fermenting pool
EP2821476A1 (en) * 2013-07-04 2015-01-07 Valogreen Digester for producing biogas and digestate and method for assembling same
FR3008105A1 (en) * 2013-07-04 2015-01-09 Valogreen DIGESTER FOR THE PRODUCTION OF BIOGAS AND DIGESTAT AND METHOD OF MOUNTING
CN103589634A (en) * 2013-11-29 2014-02-19 东北大学 Semi-continuous heating-type biogas generation kettle
CN103589634B (en) * 2013-11-29 2014-12-31 东北大学 Semi-continuous heating-type biogas generation kettle
CN104450514A (en) * 2014-11-18 2015-03-25 中国石油大学(北京) Anaerobic vertical plug-flow reactor
CN104450514B (en) * 2014-11-18 2016-03-16 中国石油大学(北京) The vertical plug-flow reactor of a kind of anaerobism
CN105567554A (en) * 2016-03-25 2016-05-11 福建省农业科学院农业工程技术研究所 Multifunctional anaerobic biogas fermenting tank structure and application method thereof
CN105950463A (en) * 2016-07-12 2016-09-21 祁彦涛 Service platform for anaerobic fermentation system
CN108636256A (en) * 2018-07-28 2018-10-12 河南东润电子有限公司 A kind of wall plaster coating material agitator
CN111454823A (en) * 2020-04-01 2020-07-28 河北科环环境工程有限公司 Slag discharge system and slag discharge method for methane tank
CN111454823B (en) * 2020-04-01 2023-06-23 河北科环环境工程有限公司 Slag discharging system and slag discharging method of biogas tank
CN114314803A (en) * 2021-12-28 2022-04-12 南京扬子江生态环境产业研究院有限公司 Quick oxidation device for micro-polluted water

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Application publication date: 20100714