CN101774760B - Lightweight pharmaceutical glass molded bottle - Google Patents
Lightweight pharmaceutical glass molded bottle Download PDFInfo
- Publication number
- CN101774760B CN101774760B CN200910312905A CN200910312905A CN101774760B CN 101774760 B CN101774760 B CN 101774760B CN 200910312905 A CN200910312905 A CN 200910312905A CN 200910312905 A CN200910312905 A CN 200910312905A CN 101774760 B CN101774760 B CN 101774760B
- Authority
- CN
- China
- Prior art keywords
- percent
- parts
- lightweight
- molded bottle
- bottle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Medical Preparation Storing Or Oral Administration Devices (AREA)
- Glass Compositions (AREA)
Abstract
The invention relates to a lightweight molded bottle, belonging to the technical field of pharmaceutical packaging materials. The invention is characterized in that the lightweight molded bottle contains the following oxides by weight percent: 68-76 percent of SiO2, 1-4 percent of Al2O3, 6-12 percent of CaO, 1-4 percent of MgO, 11-17 percent of K2O+Na2O and 0.05-0.1 percent of Fe2O3; and the lightweight molded bottle is made of the following raw materials in parts by weight: 300-400 parts of quartz sand, 60-70 parts of feldspar, 60-65 parts of calcite, 40-50 parts of dolomite, 90-110 parts of sodium carbonate and 1-5 parts of clarifying agent. Through optimizing glass formula, the invention has the advantages that the strength is improved, the weight of the molded bottle is reduced, the demand of pharmaceutical packaging materials is satisfied and the consumption per unit product of the raw materials is greatly reduced.
Description
Technical field
The invention belongs to pharmaceutical pack material technology field, be specifically related to a kind of lightweight pharmaceutical glass molded bottle and method for making thereof.
Background technology
Because pharmaceutical glass container production cost is higher, add shortcomings such as matter is heavy, frangible, at some packaging field by replacements such as metal vessel, plastic containers, matrix material soft packagings; The medical packaging field is except that high-grade feeding solution, infusion bottle, cillin bottle, and conventional packing has been that Plastic Bottle, flexible pipe and Blister Package replace, for improving homemade pharmaceutical glass Bottle & Can quality scale; Realize saving energy and reduce the cost, the lightweight of glass packaging is exactly under the proof strength certain condition, reduces the weight capacity ratio of vial; Purpose is to improve its economy, and the pharmaceutical glass packing must be accelerated to implement lightweight, reduces cost; Improve performance, could adapt to following industry development trend.
Summary of the invention
The present invention provides a kind of lightweight pharmaceutical glass molded bottle and method for making thereof; Purpose is to realize the pharmaceutical glass molded bottle lightweight; And the requirement of adaptation glass packaging market and greenization; Rely on a series of physicochemical property such as glass material excellent chemical stability, resistance to air loss, clear transparent, high temperature resistant, easy sterilization simultaneously, promote pharmaceutical glass packing development form.It is about 1/4 that the more common mold-formed bottle bottle of this product heavily reduces, effectively save energy and raw materials consumption, thus reducing product cost, its performance index are superior to common mold-formed bottle, and the market price is not higher than common mold-formed bottle.
A kind of lightweight mold-formed bottle is characterized in that, its material is counted with oxide compound according to weight percentage:
SiO
2?68-76％，Al
2O
3?1-4％，CaO?6-12％，MgO?1-4％，K
2O+Na
2O?11-17％，Fe
2O
3?0.05-0.1％；
Said lightweight mold-formed bottle is processed by the raw material of following weight part:
Silica sand 300-400 part, feldspar 60-70 part, calcite 60-65 part, rhombspar 40-50 part, soda ash 90-110 part, finings 1-5 part.
Said lightweight mold-formed bottle weight capacity ratio is 0.15～0.6, and wall thickness is 2-2.5mm.Weight capacity ratio is preferably 0.2～0.3.
The intrinsic strength of glass depends on the staple (prescription) of glass to a certain extent, and the packaging container glass mainly is NaO
2-CaO-SiO
2Be glass, the composition that the consideration of lightweight Glass Containers emphasis is gained in strength improves network former content in the composition, and it is close that glass structure more is becoming tight.It is high that the electric charge of the oxide ion of introducing in the composition is wanted, and ionic radius is little.
Described lightweight mold-formed bottle, its method for making comprises the steps:
1) batching
2) found: temperature of fusion is 1380 ℃-1560 ℃
3) feed
4) moulding
5) move back temperature
6) check and accept.
Compared with prior art; It is light that the common mold-formed bottle of lightweight mold-formed bottle weight ratio of the present invention is wanted; With 20mlA type mold-formed bottle is example; Lightweight mold-formed bottle of the present invention (26.4 gram/only) alleviates 11 grams/only than conventional bottle (37.6 grams/only), thereby reduces starting material unit consumption level greatly, to strengthen the pharmaceutical glass product in pharmaceutical wrapping material competitive power.
Embodiment
Embodiment 1-3: prescription
Table 1: embodiment 1-3 formula table
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Silica sand | 300 | 350 | 400 |
| Feldspar | 60 | 65 | 70 |
| Calcite | 65 | 60 | 60 |
| Rhombspar | 40 | 45 | 50 |
| Soda ash | 100 | 90 | 110 |
| Finings | 1 | 3 | 5 |
All raw materials that adopt among the present invention are the commercial goods, and for example wherein finings is that the commercially available oxide compound that appraises at the current rate is (like AS
2O
3, Sb
2O
3And CeO
2Deng), Sulfates (mainly is Na
2SO
4, also have CaSO
4And BaSO
4Deng), halogenide (like fluorochemical, muriate etc.) and compound clarifier etc.
Embodiment 4: method for making specifically comprises the steps:
1) batching: select among the embodiment 1-3 each prescription, with various raw material pulverizing, mix;
2) found: its process of founding is broadly divided into silicate formation, glass formation, clarification, homogenizing, 5 stages of cooling.This 5 stages are that the different sites at smelting furnace carries out, so that the glass melting temperature of segmentation precise control.Kiln operation process index stable most important; The fluctuation of general requirement temperature of fusion is no more than 10 ℃, and liquid fluctuating is no more than 0.5mm, and klin pressure fluctuation is no more than 2Pa; Prevent that the kiln space from burning with anger, thereby prevent quality problems such as calculus, color, outward appearance, intensity difference.Very high during high-grade Light weight Container is produced to the fluctuation accuracy requirement of minute batching channel temp and metal level, have be controlled at respectively ± 2 ℃ with in interior reaching ± 0.2mm.For guaranteeing high-precision production technique index, use high temperature, wide cross section, large-scale roller bed type horse shoe flame smelting furnace.Kiln is carried out measures such as all risk insurance temperature, furnace bottom bubbling, electricity fusing-aid, weir, thermal parameter use microcomputer control, made melting rate reach 1.5～2.0 (tm-1), refining quality obviously improves.
3) feed
4) moulding: the production process of glasswork can be divided into moulding and two stages of typing.Moulding is carried out with typing continuously, in the moulding process, needs the viscosity, temperature of feed glass and through mould medium heat passage towards periphery.Usually control forming operation from 3 characteristic temperature values: softening temperature, annealing temperature and strain point.Variant prodn is crucial through testing definite reasonable parameter, and advanced system bottle, feed and heating system and the advanced moulding process of employing are the acquisition uniform wall thickness, realize light-weighted basic assurance.
5) move back temperature: annealing is the heat treatment process of eliminating or reduce residual stress to the permissible value in the glass.Any glasswork all exists residual heat stress or permanent stress in the course of processing.In order to eliminate these thermal stresses, need with glass heats to annealing point be incubated, soaking, make the inner structure of glass be able to adjust stress relief.
The annealing process of this product comprises heating, insulation, slowly cooling and 4 stages of fast cooling, and accurately controls soaking time according to wall thickness, and slowly temperature-fall period is wanted strict control cooling rate, in order to avoid produce new stress.In the fast cold stage, adopt different cooling rates according to wall thickness, the temporary stress that produces when preventing to lower the temperature surpasses the glass intensity limit and causes and break.
6) check and accept.
The step that can also comprise in the prior art other among the present invention, for example: coating.
Claims (2)
1. a lightweight mold-formed bottle is characterized in that, its material is counted with oxide compound according to weight percentage: SiO
268-76%, Al
2O
31-4%, CaO 6-12%, MgO 1-4%, K
2O+Na
2O 11-17%, Fe
2O
30.05-0.1%;
Said lightweight mold-formed bottle is processed by the raw material of following weight part:
Silica sand 300-400 part, feldspar 60-70 part, calcite 60-65 part, rhombspar 40-50 part, soda ash 90-110 part,
Finings 1-5 part;
Said lightweight mold-formed bottle weight capacity ratio is 0.15～0.6, and wall thickness is 2-2.5mm;
Its method for making comprises the steps:
1) batching
2) found: temperature of fusion is 1380 ℃-1560 ℃;
3) feed
4) moulding
5) move back temperature
6) check and accept.
2. lightweight mold-formed bottle according to claim 1 is characterized in that, said lightweight mold-formed bottle weight capacity ratio is 0.2～0.3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910312905A CN101774760B (en) | 2009-12-31 | 2009-12-31 | Lightweight pharmaceutical glass molded bottle |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910312905A CN101774760B (en) | 2009-12-31 | 2009-12-31 | Lightweight pharmaceutical glass molded bottle |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101774760A CN101774760A (en) | 2010-07-14 |
| CN101774760B true CN101774760B (en) | 2012-09-05 |
Family
ID=42511381
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910312905A Active CN101774760B (en) | 2009-12-31 | 2009-12-31 | Lightweight pharmaceutical glass molded bottle |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101774760B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103896490A (en) * | 2014-03-13 | 2014-07-02 | 凤阳金星实业有限公司 | High strength glass for vacuum bottle liner and preparation method of high strength glass |
| CN105330127B (en) * | 2015-11-13 | 2017-12-19 | 双峰格雷斯海姆医药玻璃（丹阳）有限公司 | A kind of flat process for upsetting of pipe-produced glass bottle |
| CN107572780A (en) * | 2017-09-29 | 2018-01-12 | 浙江才府玻璃股份有限公司 | A kind of production technology of the presetting bottle of high internal pressure resistance |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101456671A (en) * | 2007-12-14 | 2009-06-17 | 山东省药用玻璃股份有限公司 | Method for preparing medicinal brown bottle by using cullet |
-
2009
- 2009-12-31 CN CN200910312905A patent/CN101774760B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101456671A (en) * | 2007-12-14 | 2009-06-17 | 山东省药用玻璃股份有限公司 | Method for preparing medicinal brown bottle by using cullet |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101774760A (en) | 2010-07-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101717276B (en) | Transparent lead-free fritted glaze with low expansion coefficient and preparation method thereof | |
| CN101186437A (en) | Neutral boron silicate glass used for medicinal mold-formed bottle and manufacturing method thereof | |
| CN112811813B (en) | Borosilicate glass composition, borosilicate glass, and preparation method and application of borosilicate glass | |
| CN102531397B (en) | Milky white glass ceramic suitable for all electric melting and preparation process for milky white glass ceramic | |
| CN101948243B (en) | Compound fluxing agent for float glass | |
| TW201524919A (en) | Soda-lime glass from 100% recycled glass-forming materials | |
| CN101835718A (en) | Glass composition for substrate and method for producing the same | |
| CN104496152B (en) | It is a kind of to control the method that boron volatilizees in neutral boron silica glass melting process | |
| CN101443284A (en) | Float glass for display substrate and method for producing it | |
| CN104926127A (en) | First grade water-fast pharmaceutical glass tube and preparation method | |
| CN101439932A (en) | Low-expansion glass-ceramics with lithia ore tailings as principal raw material and manufacturing method thereof | |
| CN101759364A (en) | Manufacturing method of medical high white material molded glass bottle | |
| CN104261676A (en) | Neutral borosilicate glass and application thereof | |
| CN101774760B (en) | Lightweight pharmaceutical glass molded bottle | |
| CN113105120A (en) | Production and processing technology of special-shaped glass bottle | |
| CN101565274B (en) | Glass ceramic and preparation method thereof | |
| CN102491644A (en) | High magnesium content boron-free glass fiber | |
| CN114195382B (en) | Borosilicate glass composition, borosilicate glass preparation method and medicinal glass | |
| JP7477293B2 (en) | Manufacturing method of colored glass for pharmaceutical containers and colored glass for pharmaceutical containers | |
| CN101456670B (en) | Floating preparation process of Na2O-CaO-SiO2 system flat-plate opacified glass | |
| CN101205115B (en) | Yellow transparent glass | |
| CN110117156B (en) | Preparation method of high borosilicate explosion-proof glass cover | |
| CN102718403A (en) | Energy-saving and environmentally friendly glass and preparation method thereof | |
| CN105271743A (en) | Formula and production method of pharmaceutical neutral borosilicate glass tube | |
| CN211946777U (en) | All-electric melting platinum-free gold crucible optical glass kiln |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |