CN101768034A - 优化的液相氧化 - Google Patents

优化的液相氧化 Download PDF

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Publication number
CN101768034A
CN101768034A CN201010113905A CN201010113905A CN101768034A CN 101768034 A CN101768034 A CN 101768034A CN 201010113905 A CN201010113905 A CN 201010113905A CN 201010113905 A CN201010113905 A CN 201010113905A CN 101768034 A CN101768034 A CN 101768034A
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CN
China
Prior art keywords
reaction medium
reaction
reaction zone
oxidation
oxidant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201010113905A
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English (en)
Chinese (zh)
Inventor
A·G·万德斯
H·W·小詹金斯
L·R·帕丁
W·S·施特拉泽
M·德弗里德
P·古普塔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Grupo Petrotemex SA de CV
Original Assignee
Eastman Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US11/154,116 external-priority patent/US7507857B2/en
Priority claimed from US11/153,993 external-priority patent/US7589231B2/en
Priority claimed from US11/154,253 external-priority patent/US7692037B2/en
Application filed by Eastman Chemical Co filed Critical Eastman Chemical Co
Publication of CN101768034A publication Critical patent/CN101768034A/zh
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B01J19/1862—Stationary reactors having moving elements inside placed in series
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
    • B01J10/002—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor carried out in foam, aerosol or bubbles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C63/00—Compounds having carboxyl groups bound to a carbon atoms of six-membered aromatic rings
    • C07C63/14—Monocyclic dicarboxylic acids
    • C07C63/15—Monocyclic dicarboxylic acids all carboxyl groups bound to carbon atoms of the six-membered aromatic ring
    • C07C63/26—1,4 - Benzenedicarboxylic acid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00121—Controlling the temperature by direct heating or cooling
    • B01J2219/00123—Controlling the temperature by direct heating or cooling adding a temperature modifying medium to the reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00121—Controlling the temperature by direct heating or cooling
    • B01J2219/00128—Controlling the temperature by direct heating or cooling by evaporation of reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00182—Controlling or regulating processes controlling the level of reactants in the reactor vessel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/0025—Foam formation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00765—Baffles attached to the reactor wall
    • B01J2219/00768—Baffles attached to the reactor wall vertical
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00765—Baffles attached to the reactor wall
    • B01J2219/0077—Baffles attached to the reactor wall inclined
    • B01J2219/00774—Baffles attached to the reactor wall inclined in the form of cones
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00765—Baffles attached to the reactor wall
    • B01J2219/00777—Baffles attached to the reactor wall horizontal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18—Details relating to the spatial orientation of the reactor
    • B01J2219/185—Details relating to the spatial orientation of the reactor vertical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201010113905A 2004-09-02 2005-08-29 优化的液相氧化 Pending CN101768034A (zh)

Applications Claiming Priority (18)

Application Number Priority Date Filing Date Title
US60661804P 2004-09-02 2004-09-02
US60661404P 2004-09-02 2004-09-02
US60680904P 2004-09-02 2004-09-02
US60/606618 2004-09-02
US60/606614 2004-09-02
US60/606809 2004-09-02
US63149004P 2004-11-29 2004-11-29
US63132604P 2004-11-29 2004-11-29
US63138804P 2004-11-29 2004-11-29
US60/631490 2004-11-29
US60/631388 2004-11-29
US60/631326 2004-11-29
US11/154,116 US7507857B2 (en) 2004-09-02 2005-06-16 Optimized liquid-phase oxidation
US11/153993 2005-06-16
US11/153,993 US7589231B2 (en) 2004-09-02 2005-06-16 Optimized liquid-phase oxidation
US11/154253 2005-06-16
US11/154,253 US7692037B2 (en) 2004-09-02 2005-06-16 Optimized liquid-phase oxidation
US11/154116 2005-06-16

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CN2005800295420A Division CN101010267B (zh) 2004-09-02 2005-08-29 优化的液相氧化

Publications (1)

Publication Number Publication Date
CN101768034A true CN101768034A (zh) 2010-07-07

Family

ID=35504394

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201010113905A Pending CN101768034A (zh) 2004-09-02 2005-08-29 优化的液相氧化
CN2005800295420A Expired - Fee Related CN101010267B (zh) 2004-09-02 2005-08-29 优化的液相氧化

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN2005800295420A Expired - Fee Related CN101010267B (zh) 2004-09-02 2005-08-29 优化的液相氧化

Country Status (8)

Country Link
EP (1) EP1786746A2 (OSRAM)
JP (1) JP2008511645A (OSRAM)
KR (1) KR20070048251A (OSRAM)
CN (2) CN101768034A (OSRAM)
BR (1) BRPI0514773A (OSRAM)
CA (1) CA2576246A1 (OSRAM)
MX (1) MX2007002283A (OSRAM)
WO (1) WO2006028766A2 (OSRAM)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7910769B2 (en) * 2004-09-02 2011-03-22 Eastman Chemical Company Optimized liquid-phase oxidation
US8790601B2 (en) * 2010-01-29 2014-07-29 Grupo Petrotemex, S.A. De C.V. Oxidation system with sidedraw secondary reactor
US8936767B2 (en) * 2010-01-29 2015-01-20 Grupo Petrotemex. S.A. de C.V. Oxidation system with sidedraw secondary reactor

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030229247A1 (en) * 2000-01-12 2003-12-11 Housley Samuel Duncan Process for producig carboxylic acids

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE621323A (OSRAM) * 1961-08-14
IT1129759B (it) * 1980-01-23 1986-06-11 Montedison Spa Metodo per ricuperare in forma attiva i componenti del sistema catalitico della sintesi dell'acido tereftalico
JPH07278048A (ja) * 1994-04-01 1995-10-24 Mitsui Petrochem Ind Ltd 芳香族カルボン酸の製造方法および装置
ID19133A (id) * 1996-12-12 1998-06-18 Praxair Technology Inc Pengisian oksigen langsung kedalam reaktor-reaktor ruang gelembung
DE19843573A1 (de) * 1998-09-23 2000-03-30 Degussa Blasensäule und deren Verwendung
MXPA03006122A (es) * 2001-01-10 2004-05-14 Du Pont Proceso mejorado para producir acidos carboxilicos.
US7196215B2 (en) * 2001-06-04 2007-03-27 Eastman Chemical Company Process for the production of purified terephthalic acid
CA2505976A1 (en) * 2002-12-09 2004-06-24 Eastman Chemical Company Process for the purification of a crude carboxylic acid slurry

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030229247A1 (en) * 2000-01-12 2003-12-11 Housley Samuel Duncan Process for producig carboxylic acids

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
R. LEMOINE等: "<hydrodynamic and mass-transfer characteristics in organic liquid mixtures in a large-scale bubble column reactor for the toluene oxidation process>", <IND. ENG. CHEM. RES.> *

Also Published As

Publication number Publication date
WO2006028766A8 (en) 2006-06-08
CN101010267A (zh) 2007-08-01
KR20070048251A (ko) 2007-05-08
EP1786746A2 (en) 2007-05-23
CA2576246A1 (en) 2006-03-16
WO2006028766A3 (en) 2006-07-20
MX2007002283A (es) 2007-04-23
CN101010267B (zh) 2013-05-29
JP2008511645A (ja) 2008-04-17
BRPI0514773A (pt) 2008-06-24
WO2006028766A2 (en) 2006-03-16

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Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
ASS Succession or assignment of patent right

Owner name: PEMEX GROUP LLC

Free format text: FORMER OWNER: EASTMAN CHEM CO.

Effective date: 20110914

C41 Transfer of patent application or patent right or utility model
TA01 Transfer of patent application right

Effective date of registration: 20110914

Address after: Nuevo Leon, Mexico

Applicant after: Grupo Petrotemex Sa De Cv

Address before: Tennessee

Applicant before: Eastman Chem Co.

EE01 Entry into force of recordation of patent licensing contract

Assignee: Jiaxing Petrochemical Co., Ltd.

Assignor: Eastman Chemical Company

Contract record no.: 2012990000015

Denomination of invention: Optimized liquid-phase oxidation

License type: Common License

Open date: 20100707

Record date: 20120113

C05 Deemed withdrawal (patent law before 1993)
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20100707