CN101760291B - Energy-saving agent for spindle of textile machine and preparation method thereof - Google Patents
Energy-saving agent for spindle of textile machine and preparation method thereof Download PDFInfo
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- CN101760291B CN101760291B CN 200910227711 CN200910227711A CN101760291B CN 101760291 B CN101760291 B CN 101760291B CN 200910227711 CN200910227711 CN 200910227711 CN 200910227711 A CN200910227711 A CN 200910227711A CN 101760291 B CN101760291 B CN 101760291B
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Abstract
The invention discloses an energy-saving agent for a spindle of a textile machine and a preparation method thereof. The energy-saving agent is prepared by raw materials of nanometer level diamond micro powder, nanometer level diamond micro powder dispersing agent, royaltac, butyl cellosolve, polyving akohol solution/oil soluble chitosan ramification solution and Mobil Velocite No10 base oil. The preparation method comprises the steps of: firstly, adding the raw materials of the nanometer level diamond micro powder, the nanometer level diamond micro powder dispersing agent and the polyving akohol solution/oil soluble chitosan ramification solution into a stirrer to mix and stir, dispersing into even dispersing agent, and putting for later use; secondly, adding the Mobil Velocite No10 base oil into the butyl cellosolve and stirring to form into base oil combination solution; adding the dispersing agent which is put for later use into the base oil combination solution; and finally, adding the royaltac into a regulating pot, and evenly stirring to obtain the energy-saving agent. The technical scheme combines the nanometer technology with the existing lubricating technology, and the prepared product is used for the spindle of the textile machine with the obvious effects of good wear-resistant effect, stable high/low temperature performance, obvious electricity saving performance, and long adding period, etc.
Description
One, technical field:
Patent of the present invention relates to a kind of spindle oil, particularly relates to energy-saving agent of a kind of spindle of textile machine special use and preparation method thereof.
Two, technical background:
Since nearly half a century, along with the sustainable growth of human being's production and consume activity, earth atmosphere percent of greenhouse gases (CO
2, CH
4, N
2O, O
3Deng, wherein be mainly carbonic acid gas) gather swift and violent increase, reduced the ability of the earth to the space radiation heat, thereby further aggravated the original Greenhouse effect of earth atmosphere, these greenhouse gases have directly caused the rising of earth surface temperature, cause global warming.This not only causes the variation of climatic model to cause the great change of terrestrial ecosystem, also can bring huge economy, society, environmental loss.Therefore, how to promote that reduction of greenhouse gas discharge becomes one of hot issue of international concern.
For adapting to international and domestic development situation, China is tentative carbon intensity check-up system also, explores the system mechanism of control greenhouse gas emission, and exploration is carried out the carbon emission transaction in specific region or industry.Moreover, China also plans to tackle climate change and includes the national economic and social development planning in, and the important evidence of Study on Long-team Strategy and planning is formulated in control greenhouse gas emission and acclimatization variation targets as governments at all levels.
And textile industry is the traditional advantage industry of China, for a long time outstanding contributions has been made in economic construction and the social development of China.Entered since 21st century, textile industry has obtained more rapidly development, but some problems also highlight gradually simultaneously, as the deficiency of natural resources, power supply in short supply, to the pollution of ecotope etc., retrained tempo and the scale of textile industry, and day by day serious.Country's Eleventh Five-Year Development Plan outline and textile industry Eleventh Five-Year Plan outline have all proposed more strict requirement to the textile industry energy-saving and emission-reduction, have formulated concrete index.
At present, in Textile Machinery, there is the major defect that consumes additional energy, reduces mechanical efficiency in the friction of spindle.Thereby the serious problems that the spindle friction exists have caused wasting a large amount of energy consumptions, and the generation of wearing and tearing can make gradually component lose dimensional precision gradually again and lose efficacy, thereby causes scrapping of product.Therefore, in spindle of textile machine, usually take various lubricant methods with the generation of the friction and wear of minimizing spindle.Wherein the most frequently used and simple and effective method is to adopt lubricating oil to be lubricated.But find in research and practical application, adopt merely lubricating oil, its lubricant effect still difficulty satisfies the life cycle of spindle and energy-conservation effect.
At present, many bibliographical informations about spindle oil are arranged, for example: 1, application number is 200410018241.5, denomination of invention is environment protective energy-saving spindle nursing liquid, this spindle nursing liquid mainly is comprised of base oil, oxidation inhibitor and rust-preventive agent, this invention product mainly solves wear problem and the wearing and tearing rear problem that produce a large amount of metal fragments of spindle in the situation of running up, the spindle wearing and tearing reduce more than 80% after using, and metal filings obviously reduces, and can economize on electricity 8～10%.2, application number is 92112408.2, denomination of invention is energy saving composite spindle oil, this special oil comprises antioxidant preservative, wear-resistant rust-preventive agent, viscosity temperature characteristic improving agent, defoamer etc., and this product extreme pressure property is high, anti-oxidant security is good, the drain period is long, with low cost.
In recent years, nano material has been owing to its special physics and chemistry character has been subject to widely paying close attention to, and obtained Preliminary Applications at numerous areas.In tribological field, people conduct a research for the nanoparticle lubricating oil additive.Find that at present multiple nano metal particulate all can improve the antifriction of oil product, wear-resistant and extreme pressure property effectively as additive.Therefore, nanotechnology and existing lubrication technology are organically combined, thus will improve widely frame operational efficiency and energy utilization rate, reduce unnecessary frictional dissipation, raising product row yielding reaches energy-saving effect.
Three, summary of the invention:
The technical problem to be solved in the present invention provides a kind of energy-saving agent for spindle of textile machine and preparation method thereof, technical solution of the present invention is that nanotechnology and existing lubrication technology are combined, and the product energy-saving agent of preparation is used for spindle of textile machine and has the unusual effects such as anti-wear effect is good, high temperature performance stable, economize on electricity is obvious, the interpolation cycle is long.
The technical solution used in the present invention is:
The invention provides a kind of energy-saving agent for spindle of textile machine, represent with weight part, contain 0.5～2.0 part of nano-diamond micro mist in the described energy-saving agent proportioning raw materials, 0.8～3.0 part of nano-diamond powder dispersion agent, 20～80 parts of nonylcarbinols, 5.0～20 parts of butyl glycol ethers, 20～100 parts of polyvinyl alcohol solution or oil soluble chitosan derivative solution, 800～1000 parts of Mobil Velocite No 10 base oils.
According to above-mentioned energy-saving agent for spindle of textile machine, the granularity of described nano-diamond micro mist is 10～80nm; The granularity of described nano-diamond powder dispersion agent is 50～100nm.
According to above-mentioned energy-saving agent for spindle of textile machine, described nano-diamond powder dispersion agent is S-2108 diamond dispersion agent or LH-710 type diamond dispersion agent.
According to above-mentioned energy-saving agent for spindle of textile machine, the density of described nonylcarbinol is 0.8287g/cm
3The relative density of described butyl glycol ether under 20 ℃/4 ℃ conditions is 0.90/0.75.
According to above-mentioned energy-saving agent for spindle of textile machine, the mass percentage concentration of described polyvinyl alcohol solution is 10%, and relative density is 1.02.
According to above-mentioned energy-saving agent for spindle of textile machine, described oil soluble chitosan derivative solution is prepared from by the following method:
Getting chitosan 1.5g, to dissolve in 50～100ml, mass percentage concentration be in 1% the acetum, and add butyl acrylate 0.5g, add again 50～100ml ethanol after, be warming up to 70～90 ℃ and place and namely be prepared into oil soluble chitosan derivative solution in 2～3 hours.
A kind of preparation method of above-mentioned energy-saving agent for spindle of textile machine, described preparation method's detailed step is as follows:
A, take by weighing various raw materials according to the proportioning ratio of above-mentioned energy-saving agent for spindle of textile machine, raw material nano grade diamond micro mist, nano-diamond powder dispersion agent and polyvinyl alcohol solution/oil soluble chitosan derivative solution is added stirrer carry out mix and blend, heating is controlled at 30～50 ℃ with its temperature, with rotating speed dispersed with stirring 2～3h of 4500～6000r/min, it is stand-by to form dispersion agent placement 1～2h after the dispersed with stirring;
B, raw material Mobil Velocite No 10 base oils are put into butyl glycol ether stir 2～3h basis of formation oil combination liquid, the stand-by dispersion agent of the placement of again step a being made adds in the base oil combination liquid, add at last nonylcarbinol and import Mixer pot, start stirring 1～2h and get final product.
Nano-diamond powder dispersion agent: the main chemical compositions of such dispersion agent is the alkyl aryl polyether of silicon, and Main Function is to strengthen dispersive ability, has fabulous pressing down and steeps and their defoaming function.
S-2108 diamond dispersion agent: outward appearance is light yellow transparent liquid, and proportion is 1.042～1.048, active matter content 〉=99%, and pH value (1% aqueous solution) is 5 ± 0.5; This dispersion agent can reduce the viscosity of oleoresin system, thereby can improve to greatest extent loading level, improves flexility and physical and mechanical properties, has the dispersive ability that strengthens resin, and is water-fast, resistant, and the moisture resistance performance has fabulous pressing down and steeps and their defoaming function.The manufacturer of this dispersion agent is that positive Chemical Industry Science Co., Ltd is kept in the Guangzhou.
LH-710 type diamond dispersion agent: outward appearance is weak yellow liquid, and relative density is 1.020～1.035, and viscosity is 210, and pH value is 6～7, and effective content is 100%.The characteristic of this dispersion agent: 1, this product is alkyl aryl polyether, has obvious low surface tension and low bubble property; 2, fabulous wetting emulsifying property, extremely strong dispersiveness and perviousness appear in performance; 3, prevent that loose colour, sagging, sedimentation etc. from producing effect very much; 4, improve storage stability, prevent the thick and flocculation of returning of pigment.Manufacturer is Yangzhou Lida Resin Co., Ltd. and Guangzhou Hope chemistry company limited.
Positive beneficial effect of the present invention:
1, product energy-saving agent for spindle of textile machine anti-wear effect of the present invention is good, and its anti-wear effect is that spindle of textile machine is with 210 times of plain oil; Product use range of the present invention is wide, needs mechanical means and the high and low temperature environment of liquid lubrication applicable to other.
2, the high and low temperature stable performance of product energy-saving agent for spindle of textile machine of the present invention can be fit to the use under the varying environment condition, and also can carry out self-repair function to the spindle of existing wearing and tearing according to the rolling principle.
3, be added with the nano-diamond material in the product energy-saving agent for spindle of textile machine of the present invention, utilize its brilliant metal to become sliding friction and be rolling resistance, thereby the reduction frictional coefficient makes its high loading, the fuel-economizing of low-speed running machinery, economize on electricity obviously, and its reducing power consumption can reach more than 10%.
4, the product energy-saving agent for spindle of textile machine interpolation cycle of the present invention long, more fuel-efficient than lubricating oil of the same race, save time, laborsaving.
5, the friction-wear test of product energy-saving agent for spindle of textile machine of the present invention sees Table one:
The friction-wear test test result of table one product energy-saving agent of the present invention
| Title | Piece weightless (mg) after the test |
| Spindle lightweight oil (10W30CC) | 26 |
| Product energy-saving agent of the present invention | 0.3 |
Indicate: the test conditions of above-mentioned friction-wear test is that 294N, reciprocating speed are 600 times/minutes, and test period is 180 minutes.
The conclusion of friction-wear test: the nano material in the product energy-saving agent for spindle of textile machine of the present invention can be with the form slip Nano diamond of ball, can become " sliding friction " originally take the principle of similar " bearing ball " as " rolling resistance ", frictional coefficient descends greatly.When reducing friction and eliminating wearing and tearing, the frictional property in-fighting that brings thus also obtains effective control.
6, product energy-saving agent for spindle of textile machine of the present invention is applied to the repairing test of spindle:
The present invention carries out preliminary discussion by the research with reference to Nanotribology for the nano level energy-saving agent principle that reaches energy-saving friction-reducing.
Think that in the oil film of sliding surface owing to be the existence of the Nano diamond particle of perfect spheroidal, frictional coefficient descends greatly.When reducing friction and eliminating wearing and tearing, the frictional property in-fighting that brings thus also obtains effective control.And the spindle with wearing and tearing is under the effect of rolling resistance, and the part of wearing and tearing rests on wearing part and nano-beads is rolled not stopping in the moving process of nano-beads, reached the function of selfreparing.
7, the economize on electricity of product spindle of textile machine energy-saving agent special of the present invention test:
Economize on electricity experiment (referring to accompanying drawing 1): the present invention adopts FA506 type 384 spindle spinning frames, adopts energy-saving agent for spindle of textile machine of the present invention.Find that by the economize on electricity experiment energy-saving agent for spindle of textile machine of the present invention can make the friction and wear of spinning frame reduce, this effect reaction occurs descending on load current.By baseline relatively, can find out that electric current descends 10% before and after the test interpolation.According on average energy-conservation 10% calculating, per hour can save 2.2 degree electricity for every, it is electric to save 52.8 degree every day, and such spinning frame just can be saved 19008 degree electricity in 1 year, and 19008 degree electricity are amounted to into 2.33 tons of mark coals or are amounted to into 5.03 tons of CO
2
Four, description of drawings:
Curent change synoptic diagram before and after Fig. 1 energy-saving agent for spindle of textile machine and plain oil use
Five, embodiment:
Following examples only in order to further specify the present invention, do not limit content of the present invention.
Embodiment one: energy-saving agent for spindle of textile machine and preparation method thereof:
The composition of raw materials of energy-saving agent for spindle of textile machine: represent with weight part, nano-diamond micro mist 1.0g, nano-diamond powder dispersion agent (S-2108 diamond dispersion agent) 1.5g, nonylcarbinol 50g, butyl glycol ether 12g, polyvinyl alcohol solution (mass percentage concentration of solution is 10%) 60g, Mobil Velocite No 10 base oil 900g.
The granularity of above-mentioned nano-diamond micro mist is 10～80nm, and the granularity of nano-diamond powder dispersion agent is 50～100nm; The density of described nonylcarbinol is 0.8287g/cm
3The relative density of described butyl glycol ether under 20 ℃/4 ℃ conditions is 0.90/0.75; The mass percentage concentration of described polyvinyl alcohol solution is 10%, and relative density is 1.02.
The preparation method of energy-saving agent for spindle of textile machine, detailed step is as follows:
A, take by weighing various raw materials according to the proportioning ratio of above-mentioned energy-saving agent for spindle of textile machine, raw material nano grade diamond micro mist, nano-diamond powder dispersion agent and polyvinyl alcohol solution are added stirrer carry out mix and blend, heating is controlled at 30～50 ℃ with its temperature, with rotating speed dispersed with stirring 2～3h of 4500～6000r/min, it is stand-by to form dispersion agent placement 1～2h after the dispersed with stirring;
B, raw material Mobil Velocite No 10 base oils are put into butyl glycol ether stir 2～3h basis of formation oil combination liquid, the stand-by dispersion agent of the placement of again step a being made adds in the base oil combination liquid, add at last nonylcarbinol and import Mixer pot, start stirring 1～2h and get final product.
Embodiment two: basic identical with embodiment one, difference is:
The composition of raw materials of energy-saving agent for spindle of textile machine: nano-diamond micro mist 0.5g, nano-diamond powder dispersion agent (S-2108 diamond dispersion agent) 0.8g, nonylcarbinol 20g, butyl glycol ether 5.0g, polyvinyl alcohol solution 20g, Mobil Velocite No 10 base oil 800g.
Embodiment three: basic identical with embodiment one, difference is:
The composition of raw materials of energy-saving agent for spindle of textile machine: nano-diamond micro mist 2.0g, nano-diamond powder dispersion agent (LH-710 type diamond dispersion agent) 3.0g, nonylcarbinol 80g, butyl glycol ether 20g, polyvinyl alcohol solution 100g, Mobil Velocite No 10 base oil 1000g.
Embodiment four: basic identical with embodiment one, difference is:
The composition of raw materials of energy-saving agent for spindle of textile machine: nano-diamond micro mist 1.5g, nano-diamond powder dispersion agent (LH-710 type diamond dispersion agent) 2.5g, nonylcarbinol 70g, butyl glycol ether 16g, polyvinyl alcohol solution 80g, Mobil Velocite No 10 base oil 950g.
Embodiment five: basic identical with embodiment one, difference is:
The composition of raw materials of energy-saving agent for spindle of textile machine: nano-diamond micro mist 0.8g, nano-diamond powder dispersion agent (S-2108 diamond dispersion agent) 1.2g, nonylcarbinol 35g, butyl glycol ether 10g, polyvinyl alcohol solution 40g, Mobil Velocite No 10 base oil 850g.
Embodiment six: basic identical with embodiment one, difference is:
The composition of raw materials of energy-saving agent for spindle of textile machine: nano-diamond micro mist 1.8g, nano-diamond powder dispersion agent (S-2108 diamond dispersion agent) 1.7g, nonylcarbinol 65g, butyl glycol ether 18g, polyvinyl alcohol solution 90g, Mobil Velocite No 10 base oil 980g.
Embodiment seven: basic identical with embodiment one, difference is:
The composition of raw materials of energy-saving agent for spindle of textile machine: nano-diamond micro mist 0.5g, nano-diamond powder dispersion agent (S-2108 diamond dispersion agent) 0.8g, nonylcarbinol 20g, butyl glycol ether 5.0g, oil soluble chitosan derivative solution 20g, Mobil Velocite No 10 base oil 800g.
The preparation method of oil soluble chitosan derivative solution: getting chitosan 1.5g, to dissolve in 50～100ml, mass percentage concentration be in 1% the acetum, and add butyl acrylate 0.5g, after adding again 50～100ml ethanol, be warming up to 70～90 ℃ of placements and namely be prepared into oil soluble chitosan derivative solution in 2～3 hours.
Embodiment eight: basic identical with embodiment seven, difference is:
The composition of raw materials of energy-saving agent for spindle of textile machine: nano-diamond micro mist 2.0g, nano-diamond powder dispersion agent (S-2108 diamond dispersion agent) 3.0g, nonylcarbinol 80g, butyl glycol ether 20g, oil soluble chitosan derivative solution 100g, Mobil Velocite No 10 base oil 1000g.
Embodiment nine: basic identical with embodiment seven, difference is:
The composition of raw materials of energy-saving agent for spindle of textile machine: nano-diamond micro mist 1.2g, nano-diamond powder dispersion agent (LH-710 type diamond dispersion agent) 1.8g, nonylcarbinol 50g, butyl glycol ether 13g, oil soluble chitosan derivative solution 60g, Mobil Velocite No 10 base oil 900g.
Embodiment ten: basic identical with embodiment seven, difference is:
The composition of raw materials of energy-saving agent for spindle of textile machine: nano-diamond micro mist 0.8g, nano-diamond powder dispersion agent (LH-710 type diamond dispersion agent) 1.2g, nonylcarbinol 35g, butyl glycol ether 9g, oil soluble chitosan derivative solution 40g, Mobil Velocite No 10 base oil 850g.
Embodiment 11: basic identical with embodiment seven, difference is:
The composition of raw materials of energy-saving agent for spindle of textile machine: nano-diamond micro mist 1.6g, nano-diamond powder dispersion agent (S-2108 diamond dispersion agent) 2.5g, nonylcarbinol 70g, butyl glycol ether 17g, oil soluble chitosan derivative solution 80g, Mobil Velocite No 10 base oil 950g.
Embodiment 12: basic identical with embodiment seven, difference is:
The composition of raw materials of energy-saving agent for spindle of textile machine: nano-diamond micro mist 1.0g, nano-diamond powder dispersion agent (S-2108 diamond dispersion agent) 2.0g, nonylcarbinol 60g, butyl glycol ether 10g, oil soluble chitosan derivative solution 50g, Mobil Velocite No 10 base oil 920g.
Claims (5)
1. energy-saving agent for spindle of textile machine, it is characterized in that: represent with weight part, contain 0.5～2.0 part of nano-diamond micro mist in the described energy-saving agent proportioning raw materials, 0.8～3.0 part of nano-diamond powder dispersion agent, 20～80 parts of nonylcarbinols, 5.0～20 parts of butyl glycol ethers, 20～100 parts of polyvinyl alcohol solution or oil soluble chitosan derivative solution, 800～1000 parts of Mobil Velocite No 10 base oils;
Described nano-diamond powder dispersion agent is S-2108 diamond dispersion agent or LH-710 type diamond dispersion agent;
Described oil soluble chitosan derivative solution is prepared from by the following method: getting chitosan 1.5g, to dissolve in 50～100ml, mass percentage concentration be in 1% the acetum, and adding butyl acrylate 0.5g, after adding again 50～100ml ethanol, be warming up to 70～90 ℃ of placements and namely be prepared into oil soluble chitosan derivative solution in 2～3 hours.
2. energy-saving agent for spindle of textile machine according to claim 1, it is characterized in that: the granularity of described nano-diamond micro mist is 10～80nm; The granularity of described nano-diamond powder dispersion agent is 50～100nm.
3. energy-saving agent for spindle of textile machine according to claim 1, it is characterized in that: the density of described nonylcarbinol is 0.8287g/cm
3The relative density of described butyl glycol ether under 20 ℃/4 ℃ conditions is 0.90/0.75.
4. energy-saving agent for spindle of textile machine according to claim 1, it is characterized in that: the mass percentage concentration of described polyvinyl alcohol solution is 10%, relative density is 1.02.
5. the preparation method of an energy-saving agent for spindle of textile machine claimed in claim 1 is characterized in that, described preparation method is:
A, take by weighing various raw materials according to proportioning ratio claimed in claim 1, raw material nano grade diamond micro mist, nano-diamond powder dispersion agent and polyvinyl alcohol solution/oil soluble chitosan derivative solution is added stirrer carry out mix and blend, heating is controlled at 30～50 ℃ with its temperature, with rotating speed dispersed with stirring 2～3h of 4500～6000r/min, it is stand-by to form dispersion agent placement 1～2h after the dispersed with stirring;
B, raw material Mobil Velocite No 10 base oils are put into butyl glycol ether stir 2～3h basis of formation oil combination liquid, the stand-by dispersion agent of the placement of again step a being made adds in the base oil combination liquid, add at last nonylcarbinol and import Mixer pot, start stirring 1～2h and get final product.
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| CN 200910227711 CN101760291B (en) | 2009-12-30 | 2009-12-30 | Energy-saving agent for spindle of textile machine and preparation method thereof |
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| CN101760291B true CN101760291B (en) | 2013-01-23 |
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|---|---|---|---|---|
| CN1858168A (en) * | 2005-05-08 | 2006-11-08 | 李远松 | Lipophilic nano copper powder lubricating repairing agent |
| CN101016496A (en) * | 2006-02-10 | 2007-08-15 | 孙文志 | Nano diamond nano copper composite lube additive |
| CN101225122A (en) * | 2007-12-26 | 2008-07-23 | 浣石 | Chitosan-nano diamond microspheres as well as preparation method and uses thereof |
| CN101235337A (en) * | 2007-01-26 | 2008-08-06 | 日产自动车株式会社 | Lubricant composition |
-
2009
- 2009-12-30 CN CN 200910227711 patent/CN101760291B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1858168A (en) * | 2005-05-08 | 2006-11-08 | 李远松 | Lipophilic nano copper powder lubricating repairing agent |
| CN101016496A (en) * | 2006-02-10 | 2007-08-15 | 孙文志 | Nano diamond nano copper composite lube additive |
| CN101235337A (en) * | 2007-01-26 | 2008-08-06 | 日产自动车株式会社 | Lubricant composition |
| CN101225122A (en) * | 2007-12-26 | 2008-07-23 | 浣石 | Chitosan-nano diamond microspheres as well as preparation method and uses thereof |
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