CN101760087A - Water and oil applicable titanium dioxide color paste - Google Patents

Water and oil applicable titanium dioxide color paste Download PDF

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Publication number
CN101760087A
CN101760087A CN200910030481A CN200910030481A CN101760087A CN 101760087 A CN101760087 A CN 101760087A CN 200910030481 A CN200910030481 A CN 200910030481A CN 200910030481 A CN200910030481 A CN 200910030481A CN 101760087 A CN101760087 A CN 101760087A
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China
Prior art keywords
titanium dioxide
water
color paste
oil
pigment
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CN200910030481A
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Chinese (zh)
Inventor
吕仕铭
胡艺民
伍金平
郭小春
孙贵生
万强
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Kunshan Sunmun Technology Development Co Ltd
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Kunshan Sunmun Technology Development Co Ltd
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Priority to CN200910030481A priority Critical patent/CN101760087A/en
Publication of CN101760087A publication Critical patent/CN101760087A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a water and oil applicable titanium dioxide color paste, which is consisting of titanium dioxide pigment, wet dispersing agent, foam killer, multiplying agent and latent solvent, which are proportioned in gross weight percent as follows: 50.0-70.0 percent of titanium dioxide pigment, 8.0-15.0 percent of wet dispersing agent, 0.2-0.5 percent of foam killer, 1.0-2.0 percent of multiplying agent, and the rest percent of latent solvent. All components are mixed to perform quality testing, slow dispersing and killing foam and filtering package after high-speed dispersion and grinding, and finally the required water and oil applicable titanium dioxide color paste is obtained. The water and oil applicable titanium dioxide color paste according to the invention has the advantages of high pigment content, good fluidity, high tinting strength, excellent storage stability, low cost, powerful versatility, simple preparation process, suitability for industrial production, especially suitable for water or oil paint color system mixing.

Description

Water and oil applicable titanium dioxide color paste
Technical field
The present invention relates to paint field, is water-based and oil paint toning water and oil applicable titanium dioxide color paste specifically.
Background technology
System toning uses mill base, used mill base to comprise iron oxide, phthalocyanine system, organic red, organic yellow, white colorant in a large number; Wherein, white colorant is based on titanium dioxide color paste because titanium dioxide color paste has good photostabilization, weathering resistance, chemical property stability, to ultraviolet-shielding type and low price; And be applied in widely in the coatings industry, in building industry, be used as artificial marble, surface water grinding stone, the allotment tinting material of interior exterior wall depth coating.
System's toning is meant that using computer control machinery substitutes a kind of automatization toning mode that human metering injects mill base.In recent years, system's toning development at home is rapid, and each coating manufacturer can not be that each client produces single colored paint separately in order to serve client's in all parts of the country remote toning as manufacturer, open up the commercial market, rational network and supporting product must be arranged.Therefore, arise at the historic moment in retail toning shop; Make that like this service of personalized color is leaped.And two class mill bases are arranged on the market, a kind of is water-based, is used for the water-borne coatings toning; Another kind is a butyrous, is used for the oil product toning.Two cover toning equipment and mill bases must be arranged so in retail toning shop, will for water-based and oil paint client toning, so just require businessman in each toning shop, to drop into two complete equipments and mill base, and database also must be two covers, increased the operation cost of retail store so greatly and done the workload of database; Offer 200 tame toning shops in the whole nation as certain coating manufacturer, then need 400 complete equipments and mill base; Suppose to have the mill base of a cover water transfer simultaneously and oil product, then every family toning shop only needs 1 cover toning equipment and mill base, has reduced by nearly 2,000,000 occupied fund.
At present, the titanium dioxide pigment slurry that report is maximum is to be used for the painted aqueous color paste of emulsion paint.As application number is that 03108738.8 Chinese patent is this class mill base, and its composition is dispersion agent, defoamer, sanitas, titanium white powder pigment, water.Such mill base and emulsion paint have good consistency, but are not suitable for the oil paint toning.
Summary of the invention
In order to overcome above-mentioned defective, the invention discloses a kind of water and oil applicable titanium dioxide color paste, this mill base has added suitable solubility promoter, wetting dispersing agent and multiplying agent, has guaranteed the mill base over-all properties, do not influence the normal use of mill base, be applicable to the toning of water-based and oil paint.The user has reduced fund input for mill base, has improved the commercial value of product, has overcome the toning limitation one to one of traditional mill base.
The present invention for the technical scheme that solves its technical problem and adopt is: a kind of water and oil applicable titanium dioxide color paste, form by TiO 2 pigment, wetting dispersing agent, multiplying agent, defoamer and solubility promoter, by the raw material total weight percent:
TiO 2 pigment: 50.0~70.0%;
Wetting dispersing agent: 8.0~15.0%;
Defoamer: 0.2~0.5%;
Multiplying agent: 1.0~2.0%;
Surplus is a solubility promoter.
Further technical scheme of the present invention is:
Described TiO 2 pigment is the TiO 2 pigment that coats the super-refinement of handling through the surface
Described wetting dispersing agent is at least a kind of in the compounds such as polymeric amide, soybean lecithin and modified polyether of phenolic aldehyde Soxylat A 25-7, Soxylat A 25-7, derivative of fatty acid, polyacrylic ester, modification acrylate, self-emulsifying type modification acrylate, unsaturated polyester acid amides, carboxylate salt, polymeric carboxylic salt.
Described defoamer is at least a kind of in polysiloxane, polysiloxane-polyether copolymer, silicone mineral oil, organic silicon modified by polyether multipolymer, organic modified polyorganosiloxane, polyether siloxane copolymer and the dimethyl polysiloxane.
Described multiplying agent is at least a kind of in monoalkoxy silane, corrdination type titanic acid ester, monoalkoxy pyrophosphate, two Unimac 5680 hydroxyethanoic acid titaniums and four (2, the 2-two allyl oxygen methyl isophthalic acid-butoxy) titanium two (phosphorous acid 23 esters).
Described solubility promoter is at least N-Methyl pyrrolidone, N-octylpyrrolidone, dipropylene glycol methyl ether, tetraethyleneglycol dimethyl ether, polypropylene glycol, polyoxyethylene glycol, butyleneglycol, Virahol, propylene glycol monomethyl ether, pyrrolidone, propylene glycol monomethyl ether, ethylene glycol monomethyl ether, dimethyl sulfoxide (DMSO), dimethyl propylene glycol, HCON (CH 3) 2, a kind of in propylene glycol, ethylene glycol, trimethoxy propane and the TriMethylolPropane(TMP).
The invention has the beneficial effects as follows: each proportioning components of the present invention is suitable, and the preparation method is easy to suitability for industrialized production, makes the water and oil applicable titanium dioxide color paste of gained and water-borne coatings or oil paint that good intermiscibility be arranged; Pigment slurry pigment powder content height, thus the production comprehensive cost of water and oil applicable pigment slurry reduced, and save energy has improved the commercial value of product; Add an amount of multiplying agent and can make the titanium dioxide color paste of gained that versatility is widely arranged, have good preservation stability.In sum, the water and oil applicable mill base of the present invention's preparation has higher pigment content, good flowability, and higher tinctorial strength, excellent stability in storage, production cost is low, and highly versatile is used for the toning of water-based or oiliness system; Preparation process is simple, is easy to suitability for industrialized production.Overcome the toning limitation one to one of traditional mill base.
Embodiment
The prescription of the embodiment of the invention is referring to table 1:
Table 1:(unit: weight percent)
Figure G200910030481XD0000041
According to the titanium dioxide color paste of above formulation, pigment content is higher, viscosity is suitable, every index (tinting strength, fineness, viscosity, compatibility) no change of good fluidity, storage mill base after 3 years, do not have separatory, do not have disadvantages such as precipitation; Has excellent stability in storage.
Preparation process of the present invention is:
In preparation water and oil applicable titanium dioxide when slurry, add wetting dispersing agent, defoamer, multiplying agent and mix the titanium dioxide toner that respective amount is dropped in the back in solubility promoter, high speed dispersion 45 minutes was ground 2 hours again.Reach satisfied fineness, disperse froth breaking at a slow speed, filter and package and promptly get needed mill base.
The living technology of water and oil applicable titanium dioxide color paste is identical with general mill base production technique, and the cleaning of production process machine not only can water but also can have been used organic solvent washing, need not increase equipment and operation, was easy to suitability for industrialized production.
In sum, the water and oil applicable mill base of the present invention's preparation has higher pigment content, good flowability, and higher tinctorial strength, excellent stability in storage, production cost is low, highly versatile, preparation process is simple, is easy to suitability for industrialized production.Be specially adapted to the toning of water-based or oil paint system.

Claims (6)

1. water and oil applicable titanium dioxide color paste is characterized in that: forms by TiO 2 pigment, wetting dispersing agent, multiplying agent, defoamer and solubility promoter, by the raw material total weight percent:
TiO 2 pigment: 50.0~70.0%;
Wetting dispersing agent: 8.0~15.0%;
Defoamer: 0.2~0.5%;
Multiplying agent: 1.0~2.0%;
Surplus is a solubility promoter.
2. water and oil applicable titanium dioxide color paste according to claim 1 is characterized in that: described TiO 2 pigment is for coating the TiO 2 pigment of the super-refinement of handling through the surface
3. water and oil applicable titanium dioxide color paste according to claim 1 is characterized in that: described wetting dispersing agent is at least a kind of in the compounds such as polymeric amide, soybean lecithin and modified polyether of phenolic aldehyde Soxylat A 25-7, Soxylat A 25-7, derivative of fatty acid, polyacrylic ester, modification acrylate, self-emulsifying type modification acrylate, unsaturated polyester acid amides, carboxylate salt, polymeric carboxylic salt.
4. water and oil applicable titanium dioxide color paste according to claim 1 is characterized in that: described defoamer is at least a kind of in polysiloxane, polysiloxane-polyether copolymer, silicone mineral oil, organic silicon modified by polyether multipolymer, organic modified polyorganosiloxane, polyether siloxane copolymer and the dimethyl polysiloxane.
5. water and oil applicable titanium dioxide color paste according to claim 1, it is characterized in that: described multiplying agent is at least a kind of in monoalkoxy silane, corrdination type titanic acid ester, monoalkoxy pyrophosphate, two Unimac 5680 hydroxyethanoic acid titaniums and four (2, the 2-two allyl oxygen methyl isophthalic acid-butoxy) titanium two (phosphorous acid 23 esters).
6. water and oil applicable titanium dioxide color paste according to claim 1 is characterized in that: described solubility promoter is at least N-Methyl pyrrolidone, N-octylpyrrolidone, dipropylene glycol methyl ether, tetraethyleneglycol dimethyl ether, polypropylene glycol, polyoxyethylene glycol, butyleneglycol, Virahol, propylene glycol monomethyl ether, pyrrolidone, propylene glycol monomethyl ether, ethylene glycol monomethyl ether, dimethyl sulfoxide (DMSO), dimethyl propylene glycol, HCON (CH 3) 2, a kind of in propylene glycol, ethylene glycol, trimethoxy propane and the TriMethylolPropane(TMP).
CN200910030481A 2009-04-13 2009-04-13 Water and oil applicable titanium dioxide color paste Pending CN101760087A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012040889A1 (en) * 2010-09-27 2012-04-05 巴斯夫应用化工有限公司 Aqueous white color paste and preparing method thereof
CN103483599A (en) * 2013-09-11 2014-01-01 吴江市冰心文教用品有限公司 Titanium dioxide powder emulsion preparation method
CN103965698A (en) * 2014-05-06 2014-08-06 江门骅弘颜料有限公司 Water-oil dual-use color paste
CN111978790A (en) * 2020-07-31 2020-11-24 广州市科能化妆品科研有限公司 Water-dispersible cosmetic color paste with high inorganic pigment content and preparation method thereof
CN113444404A (en) * 2021-07-16 2021-09-28 明光科迪新材料有限公司 Color paste for environment-friendly latex and preparation method thereof
CN113755093A (en) * 2021-09-14 2021-12-07 扬州工业职业技术学院 Water-based paint for plastic products

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012040889A1 (en) * 2010-09-27 2012-04-05 巴斯夫应用化工有限公司 Aqueous white color paste and preparing method thereof
CN103080248A (en) * 2010-09-27 2013-05-01 巴斯夫应用化工有限公司 Aqueous white color paste and preparing method thereof
CN103483599A (en) * 2013-09-11 2014-01-01 吴江市冰心文教用品有限公司 Titanium dioxide powder emulsion preparation method
CN103483599B (en) * 2013-09-11 2015-05-20 苏州爱立方服饰有限公司 Titanium dioxide powder emulsion preparation method
CN103965698A (en) * 2014-05-06 2014-08-06 江门骅弘颜料有限公司 Water-oil dual-use color paste
CN111978790A (en) * 2020-07-31 2020-11-24 广州市科能化妆品科研有限公司 Water-dispersible cosmetic color paste with high inorganic pigment content and preparation method thereof
CN111978790B (en) * 2020-07-31 2022-08-23 广州市科能化妆品科研有限公司 Water-dispersible cosmetic color paste with high inorganic pigment content and preparation method thereof
CN113444404A (en) * 2021-07-16 2021-09-28 明光科迪新材料有限公司 Color paste for environment-friendly latex and preparation method thereof
CN113755093A (en) * 2021-09-14 2021-12-07 扬州工业职业技术学院 Water-based paint for plastic products
CN113755093B (en) * 2021-09-14 2022-03-04 扬州工业职业技术学院 Water-based paint for plastic products

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Application publication date: 20100630