CN101760083B - Water and oil applicable iron oxide color paste - Google Patents

Water and oil applicable iron oxide color paste Download PDF

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Publication number
CN101760083B
CN101760083B CN2009100301648A CN200910030164A CN101760083B CN 101760083 B CN101760083 B CN 101760083B CN 2009100301648 A CN2009100301648 A CN 2009100301648A CN 200910030164 A CN200910030164 A CN 200910030164A CN 101760083 B CN101760083 B CN 101760083B
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China
Prior art keywords
iron oxide
water
color paste
oil
pigment
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Expired - Fee Related
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CN2009100301648A
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Chinese (zh)
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CN101760083A (en
Inventor
伍金平
胡艺民
周华
毕其兵
孙贵生
万强
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SUZHOU SHIMING TECHNOLOGY Co Ltd
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SUZHOU SHIMING TECHNOLOGY Co Ltd
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Abstract

The invention discloses a water and oil applicable iron oxide color paste, which is consisting of iron oxide pigment, wet dispersing agent, multiplying agent, foam killer and latent solvent, which are proportioned in gross weight percent as follows: 40.0-70.0 percent of iron oxide pigment, 8.0-15.0 percent of wet dispersing agent, 0.2-0.5 percent of foam killer, 1.0-2.0 percent of multiplying agent, and the rest percent of latent solvent. The ratio of each component in the invention is appropriate, so that the water and oil applicable iron oxide color paste have good compatibility with water or oil paint color; adding a proper amount of the multiplying agent, the iron oxide color paste may have wide universality with good storage stability. In summary, the water and oil applicable iron oxide color paste according to the invention has the advantages of high pigment content, good fluidity, high tinting strength, excellent storage stability, low cost, powerful versatility, simple preparation process, and is suitable for water or oil paint color system mixing; and the color paste has a simple preparation process and is convenient for industrial production, thus overcoming limitation that traditional color paste requires one to one corresponding tinting.

Description

Water and oil applicable iron oxide color paste
Technical field
The present invention relates to a kind of water-based and oil paint toning field, particularly a kind of water and oil applicable iron oxide color paste.
Background technology
System's toning uses mill base, used mill base to comprise iron oxide, phthalocyanine system, organic red and organic yellow mill base in a large number.Wherein, Because the iron oxide mill base has good photostabilization, weathering resistance, chemical property stability, to ultraviolet-shielding type and low price; Be applied in widely and made rust-stabilising pigment and tinting pigment in the coatings industry, in building industry, be used as the tinting material of artificial marble, surface water grinding stone and coating for internal and external wall.
System's toning is meant that using computer control machinery replaces human metering to inject the work of mill base, thereby carries out a kind of mode of standardized production.In recent years; System's toning development at home is rapid, and each coating manufacturer can not be that each client produces single colored paint separately in order to serve client's in all parts of the country remote toning as manufacturer; Open up the commercial market, rational network and supporting product must be arranged so.So arise at the historic moment in retail toning shop, make the service of personalized color be able to leap like this.And two types of mill bases are arranged on the market, a kind of is water-based, is used for the water-borne coatings toning; Another kind is a butyrous, is used for the oil product toning.Two cover toning equipment and mill bases must be arranged so in retail toning shop, will for water-based and oil paint client toning; So just require businessman in each toning shop, to drop into two complete equipments and mill base; And DB also must be two covers, increased the operation cost and the workload of doing DB of retail store so greatly; If a coating manufacturer opens 200 toning shops in the whole nation, need 400 complete equipments and mill base so; Suppose to have now the cover mill base both can the also adjustable oil product of water transfer property product, his each toning shop only needs 1 cover toning equipment and mill base so, has reduced by nearly 2,000,000 current assets, has accelerated economic turnover.For this reason, the water and oil applicable mill base is an effective means of product being pushed to the toning of commercial market as the toning shop.
At present, the iron oxide pigment slurry that report is maximum is to be used for the painted aqueous color paste of rubber-emulsion paint.Application number is that 03102844.6,03132933.0,200510120763.0 and 03106999.1 patent is this type mill base.Its composition mainly is dispersion agent, skimmer, sanitas, ferric oxide yellow pigment and water; Such mill base and rubber-emulsion paint have good consistency; But be not suitable for the oil paint toning.
Summary of the invention
In order to overcome above-mentioned defective, the present invention provides a kind of water and oil applicable iron oxide color paste, and this water and oil applicable iron oxide color paste overcomes the toning limitation of traditional mill base applicable to the toning of water-based and oil paint.
The present invention for the technical scheme that solves its technical problem and adopt is:
A kind of water and oil applicable iron oxide color paste is made up of iron oxide pigment, wetting dispersing agent, multiplying agent, skimmer and solubility promoter, by the raw material total weight percent:
Iron oxide pigment: 40.0~70.0%;
Wetting dispersing agent: 8.0~15.0%;
Skimmer: 0.2~0.5%;
Multiplying agent: 1.0~2.0%;
Surplus is a solubility promoter.
Described iron oxide pigment is at least a kind of pigment in surface treated red iron oxide, yellow oxide of iron, iron oxide black, iron oxide brown and the iron oxide green.
Described wetting dispersing agent is at least a kind of compound in polymeric amide, soybean lecithin and the modified polyether of phenolic aldehyde Soxylat A 25-7, Soxylat A 25-7, derivative of fatty acid, polyacrylic ester, modification acrylate, self-emulsifying type modification acrylate, unsaturated polyester acid amides, carboxylate salt, polymeric carboxylic salt.
Described skimmer is at least a kind of in ZGK 5, polysiloxane-polyether copolymer, silicone MO, organic silicon modified by polyether multipolymer, organic modified polyorganosiloxane, polyether siloxane copolymer and the dimethyl polysiloxane.
Described multiplying agent is at least a kind of in monoalkoxy silane, corrdination type titanic acid ester, four (2,2-two allyl oxygen methyl isophthalic acid-butoxy) titanium two (phosphorous acid 23 esters), two Unimac 5680 hydroxyethanoic acid titaniums and the monoalkoxy pyrophosphate.
Described solubility promoter is at least N-Methyl pyrrolidone, N-octylpyrrolidone, dipropylene glycol methyl ether, T eraethylene gycol dimethyl ether, W 166, polyoxyethylene glycol, butyleneglycol, Virahol, propylene glycol monomethyl ether, pyrrolidone, propylene glycol monomethyl ether, EGME, DMSO 99.8MIN., dimethyl propylene glycol, HCON (CH 3) 2, a kind of in Ucar 35, terepthaloyl moietie, trimethoxy propane and the TriMethylolPropane(TMP).
The invention has the beneficial effects as follows: each proportioning components of the present invention is suitable, makes water and oil applicable iron oxide color paste and the water-borne coatings of gained or oil paint that good intermiscibility arranged; Adopt the traditional colour sizing process to prepare, thereby reduced the production comprehensive cost of water and oil applicable pigment slurry, save energy has improved the commercial value of product; Add an amount of multiplying agent and can make the iron oxide color paste of gained that versatility is widely arranged, have good preservation stability.In sum, the water and oil applicable iron oxide color paste of the present invention's preparation has higher pigment content, good flowability, higher tinctorial strength and excellent stability in storage, and production cost is low, and highly versatile is applicable to the toning of water-based or oiliness system; And the preparation process is simple, is easy to suitability for industrialized production, has overcome the toning limitation one to one of traditional mill base.
Embodiment
The prescription of the embodiment of the invention is referring to table 1:
Table 1: (unit: weight percent)
During the preparation water and oil applicable iron oxide color paste; In solubility promoter, add wetting dispersing agent, skimmer, multiplying agent and mix the iron oxide pigment that respective amount is dropped in the back; After the high speed dispersion 45 minutes, ground again 2 hours, reach satisfied fineness after; Disperse froth breaking at a slow speed, filter and package and promptly get needed mill base.
The production technique of water and oil applicable iron oxide color paste is identical with general mill base production technique, and the cleaning of production process machine both can also can be used organic solvent washing for water, need not increase equipment and operation, was easy to suitability for industrialized production.
In sum, water and oil applicable iron oxide color paste of preparing by above prescription and step and water-borne coatings or oil paint have good intermiscibility; Adopt the traditional colour sizing process to prepare, thereby reduced the production comprehensive cost of water and oil applicable pigment slurry, save energy has improved the commercial value of product; Add an amount of multiplying agent and can make the iron oxide color paste of gained that versatility is widely arranged, have good preservation stability.In sum, the water and oil applicable iron oxide color paste of the present invention's preparation has higher pigment content, good flowability, higher tinctorial strength and excellent stability in storage, and production cost is low, and highly versatile is applicable to the toning of water-based or oiliness system; And the preparation process is simple, is easy to suitability for industrialized production, has overcome the toning limitation one to one of traditional mill base.
The present invention can be used for water-based and the toning of oiliness system.

Claims (3)

1. water and oil applicable iron oxide color paste is characterized in that: forms by iron oxide pigment, wetting dispersing agent, multiplying agent, skimmer and solubility promoter, by the raw material total weight percent:
Iron oxide pigment: 40.0~70.0%;
Wetting dispersing agent: 8.0~15.0%;
Skimmer: 0.2~0.5%;
Multiplying agent: 1.0~2.0%;
Surplus is a solubility promoter;
Said multiplying agent is at least a kind of in monoalkoxy silane, corrdination type titanic acid ester, four (2,2-two allyl oxygen methyl isophthalic acid-butoxy) titanium two (phosphorous acid 23 esters), two Unimac 5680 hydroxyethanoic acid titaniums and the monoalkoxy pyrophosphate.
2. water and oil applicable iron oxide color paste according to claim 1 is characterized in that: described iron oxide pigment is at least a kind of pigment in surface treated red iron oxide, yellow oxide of iron, iron oxide black, iron oxide brown and the iron oxide green.
3. water and oil applicable iron oxide color paste according to claim 1 is characterized in that: described solubility promoter is at least N-Methyl pyrrolidone, N-octylpyrrolidone, dipropylene glycol methyl ether, T eraethylene gycol dimethyl ether, W 166, polyoxyethylene glycol, butyleneglycol, Virahol, propylene glycol monomethyl ether, pyrrolidone, propylene glycol monomethyl ether, EGME, DMSO 99.8MIN., dimethyl propylene glycol, HCON (CH 3) 2, a kind of in Ucar 35, terepthaloyl moietie, trimethoxy propane and the TriMethylolPropane(TMP).
CN2009100301648A 2009-03-20 2009-03-20 Water and oil applicable iron oxide color paste Expired - Fee Related CN101760083B (en)

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Application Number Priority Date Filing Date Title
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CN101760083B true CN101760083B (en) 2012-04-11

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Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103031023B (en) * 2012-12-20 2015-04-29 广州市番禺科迪色彩有限公司 Method for preparing iron oxide black water-based color paste with high performance-price ratio
CN103923531B (en) * 2013-01-15 2016-02-24 佛山市澳莱德化工有限公司 A kind of preparation method of multi-usage iron oxide red aqueous color paste
CN103923530B (en) * 2013-01-15 2016-02-17 佛山市澳莱德化工有限公司 A kind of preparation method of multi-usage iron oxide yellow aqueous color paste
CN103450709B (en) * 2013-08-19 2016-01-13 铜陵瑞莱科技有限公司 The resistant to elevated temperatures iron oxide green of a kind of surface-coating
CN103450710B (en) * 2013-08-19 2016-05-18 铜陵瑞莱科技有限公司 A kind of coated fire-retardant iron oxide blue
CN103665945B (en) * 2013-11-04 2016-06-15 安徽纽亚达科技有限责任公司 A kind of Granular iron oxide green
CN103666020A (en) * 2013-11-04 2014-03-26 铜陵市镜铁粉厂 Nano iron oxide green for printing ink
CN103965698A (en) * 2014-05-06 2014-08-06 江门骅弘颜料有限公司 Water-oil dual-use color paste
CN104212246B (en) * 2014-09-10 2016-06-08 张家港格瑞特化学有限公司 A kind of ferrum oxide oil pastes
IT201600109323A1 (en) * 2016-10-28 2018-04-28 Giovanni Broggi UNIVERSAL PIGMENTARY PREPARATIONS FOR COLORING AND REINFORCING PLASTIC MATERIALS
CN109504153A (en) * 2018-11-19 2019-03-22 岳西县邦玉铁系颜料有限公司 A kind of iron oxide pigment that wearability is good
CN111978790B (en) * 2020-07-31 2022-08-23 广州市科能化妆品科研有限公司 Water-dispersible cosmetic color paste with high inorganic pigment content and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1530412A (en) * 2003-03-17 2004-09-22 深圳市海川实业股份有限公司 Aqueous yelow paste of iron oxide
CN1569982A (en) * 2003-07-21 2005-01-26 深圳市海川实业股份有限公司 Hydrophobic ferric oxide aqueous color paste

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1530412A (en) * 2003-03-17 2004-09-22 深圳市海川实业股份有限公司 Aqueous yelow paste of iron oxide
CN1569982A (en) * 2003-07-21 2005-01-26 深圳市海川实业股份有限公司 Hydrophobic ferric oxide aqueous color paste

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Address after: 215337 No. 219 Huangpu River Road, Zhou Town, Jiangsu, Kunshan

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