CN101748278A - Method for processing scrap dry battery by utilizing rotary hearth furnace process - Google Patents

Method for processing scrap dry battery by utilizing rotary hearth furnace process Download PDF

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CN101748278A
CN101748278A CN201010018247A CN201010018247A CN101748278A CN 101748278 A CN101748278 A CN 101748278A CN 201010018247 A CN201010018247 A CN 201010018247A CN 201010018247 A CN201010018247 A CN 201010018247A CN 101748278 A CN101748278 A CN 101748278A
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dry batteries
hearth furnace
rotary hearth
waste dry
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龙红明
李家新
胡锋锋
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Anhui University of Technology AHUT
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Abstract

本发明公开了一种利用转底炉工艺处理废旧干电池的方法,将废旧干电池破碎、筛分,分选出铁合金皮、电池渣和碳棒渣,电池渣和碳棒渣进行低温焙烧,利用转底炉对钠、钾、锌元素很强的处理能力,将冷却后的焙烧产物与铁矿石、冶金废料混合进入转底炉造金属化球团。本发明利用转底炉工艺处理废旧干电池的方法,能够充分利用现有冶炼工艺,实现大规模有效处理废旧干电池,具有设备投资少,运行费用低的优点;废旧干电池中的铁、镍、锰等金属元素得以回收利用,实现了废旧干电池100%无二次污染处理和资源化利用;具有显著的社会效益和环保效益。

Figure 201010018247

The invention discloses a method for treating waste dry batteries using a rotary hearth furnace process. The waste dry batteries are crushed and sieved to separate ferroalloy skin, battery slag and carbon rod slag, and the battery slag and carbon rod slag are roasted at low temperature. The hearth furnace has a strong ability to process sodium, potassium, and zinc elements. The cooled roasted product is mixed with iron ore and metallurgical waste into the rotary hearth furnace to make metallized pellets. The method for treating waste dry batteries using a rotary hearth furnace process in the present invention can make full use of the existing smelting process to realize large-scale effective treatment of waste dry batteries, and has the advantages of less investment in equipment and low operating costs; iron, nickel, manganese, etc. in waste dry batteries Metal elements can be recycled, realizing 100% non-secondary pollution treatment and resource utilization of waste dry batteries; it has significant social and environmental benefits.

Figure 201010018247

Description

利用转底炉工艺处理废旧干电池的方法 Method for Disposing Waste Dry Batteries Using Rotary Hearth Furnace Technology

技术领域technical field

本发明涉及一种废旧干电池无害化处理技术,更具体的说,它涉及一种利用转底炉工艺处理废旧干电池的方法。The invention relates to a technology for harmless treatment of waste dry batteries, more specifically, it relates to a method for treating waste dry batteries using a rotary hearth furnace process.

背景技术Background technique

大量的废旧干电池不仅对环境造成严重污染,对人体健康造成危害,而且还导致了资源的严重浪费。A large number of waste dry batteries not only cause serious pollution to the environment and harm to human health, but also lead to a serious waste of resources.

目前废旧干电池的回收处理方法主要分为三类,即人工分选法、火法和湿法。人工分选法是将回收的废旧干电池先进行分类,人工分选出碳棒、铜帽、锌皮及各种产品残留物,并分别采用相应的方法予以处理,这种方法简单易行,但使用劳动力多,经济效益差,存在二次污染。火法是在高温下使电池中的金属及其化合物氧化、还原、分解和挥发、冷凝,有效地回收其中的汞、镉等易挥发物,但是技术要求高,空气参与作业造成二次污染,一次性投资大,能耗高,运行成本高。湿法处理技术是基于电池中金属及其化合物溶于酸的原理,将分类、破碎分选后的电池粉末浸泡于酸性溶液中,使目标组分溶于酸液中,然后经过过滤,弃去有机电解质及隔膜杂质,调节所得含目标组分的滤液的pH值,将Al、Fe等微量元素以氢氧化物的形式除去,利用化学沉淀、电化学沉积、离子交换或萃取分离的方法使目标组分以纯金属或金属盐的形式得以回收,此方法工艺流程冗长复杂,回收后电解液含有汞、镉、锌等重金属,污染严重,能耗高。At present, the recycling and processing methods of waste dry batteries are mainly divided into three categories, namely manual sorting method, fire method and wet method. The manual sorting method is to classify the recovered waste dry batteries first, manually sort out carbon rods, copper caps, zinc skins and various product residues, and use corresponding methods to deal with them. This method is simple and easy, but The use of labor is large, the economic benefit is poor, and there is secondary pollution. The fire method is to oxidize, reduce, decompose, volatilize, and condense the metals and their compounds in the battery at high temperature, and effectively recover volatile substances such as mercury and cadmium in them, but the technical requirements are high, and the air involved in the operation causes secondary pollution. The one-time investment is large, the energy consumption is high, and the operating cost is high. Wet treatment technology is based on the principle that metals and their compounds in batteries are soluble in acid. Soak the sorted, crushed and sorted battery powder in acid solution to dissolve the target components in acid solution, then filter and discard Organic electrolyte and diaphragm impurities, adjust the pH value of the obtained filtrate containing the target components, remove Al, Fe and other trace elements in the form of hydroxides, use chemical precipitation, electrochemical deposition, ion exchange or extraction separation methods to make the target The components can be recovered in the form of pure metal or metal salt. The technical process of this method is long and complicated. After recovery, the electrolyte contains heavy metals such as mercury, cadmium, and zinc, which causes serious pollution and high energy consumption.

中国专利公开号CN200410102799.1,公开日2006年7月5日,发明创造的名称为利用烧结工艺处理废旧电池的方法及系统,该申请案公开了一种利用烧结工艺处理废旧电池的方法,其不足之处是利用水洗过滤系统,回收锌、钠、钾金属元素,二次污染严重,工艺流程较为冗长,能耗高,运行成本高。Chinese Patent Publication No. CN200410102799.1, published on July 5, 2006, the name of the invention is a method and system for treating waste batteries by sintering process. The application discloses a method for treating waste batteries by sintering process. The disadvantage is that the water washing and filtering system is used to recover zinc, sodium, and potassium metal elements, resulting in serious secondary pollution, lengthy process flow, high energy consumption, and high operating costs.

到目前为止,尚未出现利用转底炉工艺处理废旧干电池的方法。So far, there is no method for using the rotary hearth furnace process to process waste dry batteries.

发明内容Contents of the invention

本发明的目的是克服现有技术的不足,提供一种利用转底炉工艺处理废旧干电池的方法。The purpose of the present invention is to overcome the deficiencies of the prior art and provide a method for treating waste dry batteries using a rotary hearth furnace process.

本发明通过下述技术方案予以实现。The present invention is achieved through the following technical solutions.

本发明的利用转底炉工艺处理废旧干电池的方法,将废旧干电池破碎、筛分,分选出铁合金皮、电池渣和碳棒渣,电池渣和碳棒渣进行低温焙烧,利用转底炉对钠、钾、锌元素很强的处理能力,将低温焙烧后的冷却产物与铁矿石、冶金废料混合进入转底炉造金属化球团。The method for treating waste dry batteries using a rotary hearth furnace process of the present invention includes crushing and screening the waste dry batteries, sorting out ferroalloy skin, battery slag and carbon rod slag, and performing low-temperature roasting on the battery slag and carbon rod slag, and using a rotary hearth furnace to Sodium, potassium, and zinc elements have strong processing capabilities, and the cooled products after low-temperature roasting are mixed with iron ore and metallurgical waste into the rotary hearth furnace to make metallized pellets.

所述的废旧干电池的焙烧产物按转底炉混合料的1-2%配入。本发明的有益效果是:The roasted product of the waste dry battery is formulated according to 1-2% of the mixed material of the rotary hearth furnace. The beneficial effects of the present invention are:

(1)用转底炉工艺处理废旧干电池的方法,能够充分利用现有冶炼工艺,实现大规模有效处理废旧干电池,具有设备投资少,运行费用低的优点;(1) The method for processing waste dry batteries with a rotary hearth furnace process can make full use of the existing smelting process, realize large-scale effective treatment of waste dry batteries, and has the advantages of less equipment investment and low operating costs;

(2)废旧干电池中的金属元素铁、镍、锰等得以回收利用,实现了废旧干电池100%无二次污染处理和资源化利用;(2) Metal elements such as iron, nickel and manganese in waste dry batteries can be recycled, realizing 100% non-secondary pollution treatment and resource utilization of waste dry batteries;

(3)具有显著的社会效益和环保效益。(3) It has significant social and environmental benefits.

附图说明Description of drawings

附图为本发明的生产工艺流程图。Accompanying drawing is the production process flowchart of the present invention.

具体实施方式Detailed ways

下面结合附图对本发明作进一步的描述。The present invention will be further described below in conjunction with the accompanying drawings.

本发明的工艺流程如附图所示,采用单辊破碎机将废旧干电池破碎,经筛分,分选出铁合金皮、电池渣和碳棒渣,将电池渣和碳棒进行低温焙烧,回收汞等低熔点金属,在焙烧温度为400℃、时间为90min时,汞的回收率可达95%以上,低温焙烧后的产物冷却后,按转底炉混合料的1-2%配入转底炉料仓,与铁矿石、冶金废料混合进入转底炉造金属化球团,充分利用转底炉超强的去除钠、钾、锌元素的能力,成品金属化球团可作为高炉或者电炉的优质原料。The process flow of the present invention is shown in the accompanying drawings. A single-roller crusher is used to crush waste dry batteries, and after screening, iron alloy skin, battery slag and carbon rod slag are sorted out, and the battery slag and carbon rods are roasted at low temperature to recover mercury. For low-melting-point metals, when the roasting temperature is 400°C and the time is 90 minutes, the recovery rate of mercury can reach more than 95%. Furnace feed bin, mixed with iron ore and metallurgical waste into the rotary hearth furnace to make metallized pellets, making full use of the super strong ability of the rotary hearth furnace to remove sodium, potassium, and zinc elements, the finished metallized pellets can be used as blast furnace or electric furnace High quality raw materials.

本发明不仅解决了电池污染的问题,还充分利用了电池的有效资源,并且能够产生巨大的经济效益。The invention not only solves the problem of battery pollution, but also makes full use of the effective resources of the battery and can generate huge economic benefits.

Claims (2)

1.一种利用转底炉工艺处理废旧干电池的方法,其特征是,将废旧干电池破碎、筛分,分选出铁合金皮、电池渣和碳棒渣,电池渣和碳棒渣进行低温焙烧,将冷却后的焙烧产物与铁矿石、冶金废料混合进入转底炉造金属化球团。1. A method utilizing a rotary hearth furnace process to process waste and old dry batteries is characterized in that waste and old dry batteries are crushed and sieved, and ferroalloy skin, battery slag and carbon rod slag are sorted out, and battery slag and carbon rod slag are roasted at low temperature, The cooled roasted product is mixed with iron ore and metallurgical waste into the rotary hearth furnace to make metallized pellets. 2.根据权利要求1所述的利用转底炉工艺处理废旧干电池的方法,其特征是,所述的废旧干电池的焙烧产物按转底炉混合料的1-2%配入。2. The method for treating waste dry batteries using a rotary hearth furnace process according to claim 1, characterized in that the roasted product of said waste dry batteries is mixed in at 1-2% of the mixture in the rotary hearth furnace.
CN201010018247A 2010-01-20 2010-01-20 Method for processing scrap dry battery by utilizing rotary hearth furnace process Pending CN101748278A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103205565A (en) * 2013-04-24 2013-07-17 遵义生之源环保工程有限公司 Catalytic-oxidation high-carbon metal ball produced by waste dry batteries and mobile phone batteries
CN103498170A (en) * 2013-10-30 2014-01-08 沈阳环境科学研究院 Method for recycling mercury from mercurial soot or mercurial salt in environment-friendly mode
CN103540955A (en) * 2013-10-30 2014-01-29 沈阳环境科学研究院 Method for extracting mercury from mercury concentrates through total wet method
CN103545538A (en) * 2013-11-06 2014-01-29 安徽工业大学 A method of using waste zinc-manganese dry batteries to prepare raw materials for manganese-based ferroalloys
CN115354161A (en) * 2022-08-29 2022-11-18 通化建新科技有限公司 Method for recycling lithium from waste power batteries by rotary hearth furnace

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103205565A (en) * 2013-04-24 2013-07-17 遵义生之源环保工程有限公司 Catalytic-oxidation high-carbon metal ball produced by waste dry batteries and mobile phone batteries
CN103498170A (en) * 2013-10-30 2014-01-08 沈阳环境科学研究院 Method for recycling mercury from mercurial soot or mercurial salt in environment-friendly mode
CN103540955A (en) * 2013-10-30 2014-01-29 沈阳环境科学研究院 Method for extracting mercury from mercury concentrates through total wet method
CN103498170B (en) * 2013-10-30 2015-09-23 沈阳环境科学研究院 A kind of method of environmental protection recovery mercury from mercurial soot or mercury salt
CN103540955B (en) * 2013-10-30 2015-09-23 沈阳环境科学研究院 A kind of method of Whote-wet method extraction mercury metal from mercury concentrate
CN103545538A (en) * 2013-11-06 2014-01-29 安徽工业大学 A method of using waste zinc-manganese dry batteries to prepare raw materials for manganese-based ferroalloys
CN115354161A (en) * 2022-08-29 2022-11-18 通化建新科技有限公司 Method for recycling lithium from waste power batteries by rotary hearth furnace
CN115354161B (en) * 2022-08-29 2024-02-02 通化建新科技有限公司 Method for recycling lithium in waste power battery by rotary hearth furnace

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